The invention relates to a complexing-agent-assisted preparation method of a
cadmium sulfide multi-level-structured nano-grade material. The method is characterized in comprising the steps that: a, a
chemical reaction liquid is prepared, wherein 1 part of
cadmium salt by weight and 0-50 parts of organic small-molecular compound by weight are dissolved in 100 parts of water or water /
ethanol mixture by weight; under a temperature of 30-80 DEG C, stirring is sufficiently carried out, such that a reaction liquid is prepared; b, the
cadmium sulfide multi-level-structured nano-grade material is synthesized, wherein the reaction liquid prepared in the step a is delivered into an
autoclave with a
polytetrafluoroethylene liner; a
sulfur source is added, and a reaction is carried out; after the reaction, the
autoclave is naturally cooled to 60 DEG C;
methanol with a volume of 20-30% of that of the total volume of the reaction liquid is added; a product is filtered, and is washed multiple times by using
anhydrous ethanol; and the product is dried by
vacuum pumping, such that the
cadmium sulfide nano-grade material with different
crystal forms and morphologies is obtained. The method provided by the invention has the advantages of simple process, low cost, and high
operability. With the method, requirements of production and application can be satisfied by one step.