194 results about "Sodium silicate" patented technology

This invention relates to the field of concrete technology, specifically to a self-healing concrete material, its preparation method, and its application. The self-healing concrete material is a core-shell structured microcapsule, comprising a core material and a wall material. The wall material wraps around the core material. The core material comprises the following raw materials in parts by weight: 4-6 parts β-cyclodextrin, 12-18 parts sepiolite powder, 5-10 parts shellac powder, 25-35 parts sulfoaluminate cement, 10-15 parts magnesium oxide, 12-16 parts sodium silicate aqueous solution, and 14-17 parts calcium carbonate. The wall material comprises the following raw materials in parts by weight: 20-30 parts polyvinyl alcohol, 20-30 parts ethyl cellulose, 15-25 parts bentonite, and 25-35 parts corn starch. The mass ratio of the core material to the wall material is 6-7:3-4. The core material of the self-healing concrete material provided by this invention, comprising β-cyclodextrin, sepiolite powder, and shellac powder, can improve the problems of slow repair speed and poor reinforcement effect of self-healing materials.

This invention discloses a method for preparing a carbon source for microbial culture medium based on enzymatic hydrolysis of bamboo powder and its application, belonging to the field of high-value utilization technology of biomass resources. Using bamboo powder as raw material, the invention involves mild alkali pretreatment to disrupt the dense structure of lignocellulose, followed by enzymatic hydrolysis using a specialized enzyme system of endoglucanase Cel7B and xylanase XynA expressed heterologously by *E. coli* in an optimized ratio. After solid-liquid separation, an enzymatic hydrolysate rich in reducing sugars is obtained. The hydrolysate is then nutritionally fortified with trace elements such as sodium thiosulfate and sodium silicate to produce a low-cost, high-efficiency liquid carbon source. This invention achieves high-value utilization of bamboo waste. The entire process is mild, environmentally friendly, and simple, easily scaled up industrially, and solves the industry bottleneck of high carbon source cost in industrial microbial culture, demonstrating good application prospects and market value.

This invention relates to the field of mineral wool production technology, specifically disclosing a mineral wool material and its preparation method. The mineral wool material comprises the following raw material components in parts by weight: 60-65 parts of blast furnace liquid slag, and 15-25 parts of conditioning material; the conditioning material comprises 42%-48% quartz sand, 22%-28% coal gangue, 11%-18% modified basalt, and 10%-14% modified lithium feldspar powder; wherein the modified basalt is sodium silicate modified basalt; and the modified lithium feldspar powder is citric acid modified calcined lithium feldspar powder. This invention optimizes the composition of the mineral wool material and the combination of the conditioning material components, reduces the generation of loose cotton and cotton balls, and improves the cotton sizing ratio and the overall performance of the finished wool.

The present application belongs to the technical field of cleaning supplies, and particularly relates to a high-efficiency blood-stain removing powder and a preparation method thereof. The high-efficiency blood-stain removing powder provided by the present application comprises the following raw materials and mass fractions: 45.0-65.0 parts of sodium percarbonate, 12.0-18.0 parts of an auxiliary agent, 11.0-18.0 parts of an auxiliary cleaning agent, 4.0-7.0 parts of anhydrous sodium metasilicate, 1.0-3.0 parts of a non-ionic surfactant, 1.5-2.5 parts of an enzyme preparation, 0.2-1.0 parts of an antibacterial agent, 1.0-3.0 parts of a thickening agent, and 0.1-0.5 parts of a fragrance; the auxiliary cleaning agent is composed of sodium carbonate and sodium alpha-alkenyl sulfonate at a mass ratio of 8.0-12.0:3.0-6.0. When the high-efficiency blood-stain removing powder of the present application is used, no complex operation is needed, and blood stains can be easily removed through simple soaking, without laborious scrubbing, so that the effect of 'quick cleaning and complete stain removal' is truly achieved.

This application provides a powdered two-component rapid-setting early-strength grouting material and its preparation method, belonging to the field of grouting materials. The material consists of component A and component B in a volume ratio of (1~3):1. Component A is silicate cement slurry, prepared by mixing ordinary silicate cement and water in a water-cement mass ratio of (0.5~2.0):1. Component B is a fast-dissolving sodium silicate aqueous solution, prepared by mixing fast-dissolving sodium silicate powder and water in a mass ratio of (0.2~0.6):1. The grouting material provided by this application is easy to transport and store. Its core component is solid fast-dissolving sodium silicate, effectively avoiding the corrosiveness and storage and transportation risks of liquid water glass, significantly reducing overall costs. The fast-dissolving sodium silicate reacts rapidly with cement hydration products to form a gel, and the setting time can be flexibly adjusted by concentration and ratio, resulting in rapid and controllable setting. This material is simple to prepare, flexible in construction, requires only two raw materials, and can be prepared and used on-site, making it suitable for various grouting equipment and engineering scenarios.

This application relates to the field of road engineering materials technology, and discloses a method for preparing modified phosphogypsum base material for road engineering, comprising the following steps: mixing aged phosphogypsum with ferrous sulfate heptahydrate, sodium fluorosilicate, and manganese sulfate monohydrate, utilizing the inherent moisture of the phosphogypsum to dissolve the salts and form an acidic slurry; adding heat-curing dry powder and high-speed shearing, utilizing the heat of hydration to raise the temperature to 65℃-85℃ to create a high-temperature strong alkaline environment, initiating manganese catalytic oxidation and slag thermal etching; subsequently, high-pressure injection of a rapid cooling conditioning liquid, utilizing the latent heat of vaporization to rapidly cool to below 45℃ to complete rapid cooling quenching and slow setting locking; unloading and aging to obtain the modified phosphogypsum base material. This invention, through the release of chemical energy by quicklime hydration to construct a high-temperature strong alkaline reaction field, achieves deep mineralization of impurities and reconstruction of the cementitious material network, significantly improving the water stability and mechanical properties of the base material.

The present invention concerns an industrial chemical process (400f) and an apparatus for carrying out that process. The chemical process integrates into a single, combined method: (i) a method (303, 304) of producing iron and / or manganese from their ores, and (ii) a method (205a, 205b, 207, 208, 209) of producing an oxide or hydroxide of at least one of calcium, magnesium and iron from another ore respectively comprising a carbonate mineral of at least one of calcium, magnesium and iron. This combined method has the iron and / or manganese ore and the other ore comprising the carbonate mineral as its only essential ingredients, with common salt and / or water as optional extra ingredients. The combined method produces iron and / or manganese in elemental form, an oxide or hydroxide derived from the carbonate mineral, and oxygen as its corresponding products. If the iron and / or manganese ore also comprises a siliceous mineral, the method may also produce an alkaline mixture comprising sodium silicate as a co-product. Salt and water act as intermediaries to produce these end-products, but are only consumed if supplied in excess. An amount of sodium oxide, hydroxide and / or carbonate determined by the amount of salt consumed may be produced as a co-product, along with a corresponding amount of at least one of chlorine and hydrochloric acid. An amount of hydrogen determined by the amount of water consumed may also be produced as a co-product, along with an increased amount of oxygen. The iron, manganese and oxygen produced may all be used in steelmaking. Any excess oxygen may be safely vented to atmosphere. The oxide or hydroxide derived from the carbonate mineral may be used in cement manufacture, as a flux in steelmaking and / or as an ingredient in the manufacture of soda-lime glass. The alkaline mixture comprising sodium silicate may be used as an alkaline activator for an alkaline activated or geopolymer cement. The sodium carbonate may be used in the manufacture of soda-lime and / or borosilicate glass, for example. The chlorine and / or hydrochloric acid may be used in the manufacture of chlorinated organic compounds, for example. The hydrogen may be used as a fuel in a hydrogen economy. The method of the invention requires no nett input of heat because the chemical reactions it involves are exothermic overall. It also consumes no fossil fuels and has electricity as its only energy requirement. Thus if the electricity is produced from a source of renewable energy, this method produces no greenhouse gas emissions. In some embodiments, the method can even have a negative carbon footprint overall. The invention is intended to replace existing techniques for producing iron and / or manganese from their ores, including hydrogen-DRI, the calcination of limestone and other carbonate minerals, both in cement manufacture and in the production of lime for other purposes, and the ammonia-soda, or Solvay, process for the production of sodium carbonate. The invention therefore has the potential to eliminate up to about 20% of anthropogenic carbon dioxide emissions. [Fig. 9B]

The application discloses a tundish slag line dry material, and relates to the technical field of tundish refractory materials. The mass percentage of each raw material component in the tundish slag line dry material is as follows: 26-30% of 3-1mm fused magnesite, 22-28% of 1-0mm fused magnesite, 20-27% of 200-mesh fused magnesite, 1.5-2% of trisodium phosphate hexahydrate, 2-2.5% of sodium metasilicate nonahydrate, 1-1.5% of adipic acid, 4-5% of calcium carbonate, 0.3-0.5% of vermiculite, and the rest of 5-3mm fused magnesite. The application adopts a new composite binder system, solves the environmental protection problem of a traditional phenolic resin binder, and significantly improves the medium-temperature and high-temperature strength, corrosion resistance, thermal shock resistance and heat insulation performance of the magnesia dry material through the synergistic effect among the components, so that the overall optimization of the material performance is realized.

This invention relates to the field of rubber materials technology, and proposes a wear-resistant and anti-aging rubber granule for sports fields, comprising the following raw materials in parts by weight: 90-110 parts hydrogenated nitrile rubber, 30-40 parts wear-resistant composite filler, 20-30 parts fluororubber, 8-12 parts plasticizer, 1-3 parts antioxidant, 0.5-1 part vulcanizing agent, and 1-2 parts vulcanization accelerator; the wear-resistant composite filler comprises the following raw materials in parts by weight: 100 parts carbon black, 20-30 parts sodium silicate, and 5-15 parts sodium aluminate. This technical solution solves the problem of insufficient aging resistance and wear resistance of rubber granules in related technologies.

This invention proposes an impact-resistant seawall repair adhesive and its preparation method, belonging to the field of adhesive technology. The impact-resistant seawall repair adhesive is prepared from the following raw materials in parts by weight: 70-100 parts water glass, 30-40 parts sodium fluorosilicate, 5-10 parts ammonium chloride, 10-15 parts curing agent, 30-50 parts dimethyl silicone oil, 5-7 parts metal oxide, 2-4 parts emulsifier, and 100-120 parts water. This impact-resistant seawall repair adhesive is a silicate inorganic adhesive that can withstand extremely high temperatures and large tensile and shear forces. It boasts advantages such as high bonding strength with the substrate and abundant raw material sources, good stability, and convenient operation.

This invention relates to the field of inorganic non-metallic adsorbent technology, specifically an oil shale slag nanocomposite adsorbent, its preparation method, and its application. It addresses the problems of low controllability, poor stability, poor adsorption effect, poor repeatability, and short cycle life associated with the application of oil shale slag as an adsorbent. The invention involves dispersing oil shale slag powder in a sodium silicate nonahydrate aqueous solution, stirring, and ultrasonicating to obtain suspension 1. A manganese sulfate aqueous solution is added to suspension 1 to obtain suspension 2. Suspension 2 undergoes a hydrothermal reaction, and the reaction product is centrifuged until the pH is neutral. The product is then dried, ground, and sieved to obtain the oil shale slag nanocomposite adsorbent, which can be applied to the adsorption of organic dyes. This invention significantly improves the reactivity, removal capacity, and adsorption stability of the oil shale slag nanocomposite adsorbent for organic pollutants, exhibiting excellent repeatability and cycle life, providing an economical, environmentally friendly, and sustainable solution for water treatment and solid waste management.

The present invention provides a method (600a) and apparatus for producing an alkaline mixture comprising sodium silicate, which mixture is suitable for use as an alkaline activator for alkaline activated and geopolymer cements, but which may also be used, for example, to mineralize captured carbon dioxide. The method comprises comminuting (301) an ore of a target metal into fines, wherein the ore comprises a siliceous mineral and at least one of iron and manganese as the target metal. The siliceous mineral may comprise the target metal itself and / or it may be silica and / or another silicate mineral present as gangue. The ore is dehydrated and hydroxylated compounds contained therein are dehydroxylated (302). The ore thus treated is then reacted (601) in an inert atmosphere with an amount of liquid sodium in excess of the stoichiometric amount thereof required for a redox reaction between the liquid sodium and an oxide of the target metal from the ore, to precipitate out from the liquid sodium a solid phase comprising both the target metal in elemental form and other insoluble products comprising sodium oxide. The redox reaction is conducted at a temperature of at least 320 °Celsius to induce a reaction between the sodium oxide and silica derived from the siliceous mineral to produce sodium silicate, but also below a temperature at which the liquid sodium can react with the oxide of the target metal to produce a ternary oxide thereof. At least some of the liquid sodium having sodium silicate dissolved therein is then separated (305) from the solid phase and is reacted (602) with at least one of oxygen and water to produce a mixture comprising sodium silicate and at least one of sodium oxide and sodium hydroxide. The corresponding apparatus comprises a comminution device (such as a rock crusher or grinder), means for dehydrating and dehydroxylating the ore (such as a dryer), a gas-tight first reaction vessel for reacting the ore thus treated with the liquid sodium, a solid-liquid sodium phase separator, and a second reaction vessel for reacting the liquid sodium having sodium silicate dissolved therein with at least one of oxygen and water. The resulting alkaline mixture is therefore produced whilst extracting the target metal in elemental form from its ore. Thus the energy consumed is split between the production of these two co-products, making the method of the invention a low-energy method of producing an alkaline activator for alkaline activated and geopolymer cements. Both reactions (601, 602) are also significantly exothermic and at least some of the thermal energy from them may be recycled. The invention does not consume any carbon and is therefore at least carbon-neutral. On the other hand, it consumes the silica content of gangue mineral species and / or of siliceous minerals of the target metal in its ore, which have previously been treated as waste products. The amount of waste material produced when extracting the target metal from its ore is thereby reduced as well.

This invention discloses a method for the resource utilization of phosphate ore sintering flue gas that can efficiently recover fluorine and sulfur resources, reduce treatment costs, and create resource benefits. The method includes the following steps: sequentially subjecting the sintering flue gas to dust removal, denitrification, and heat exchange to obtain a first gas and dust; reacting the first gas with water to generate a first solid-liquid mixture containing fluorosilicic acid and silica gel, and a second gas; performing solid-liquid separation on the first solid-liquid mixture to obtain a first solid phase mainly composed of silica gel and a first liquid phase mainly composed of fluorosilicic acid; reacting the first liquid phase with sodium sulfate to generate a second solid-liquid mixture containing sulfuric acid and sodium fluorosilicate; and performing solid-liquid separation on the second solid-liquid mixture to obtain a second solid phase mainly composed of sodium fluorosilicate and a second liquid phase mainly composed of sulfuric acid.

The application discloses a combined depressor for recovering scheelite from ultra-low-grade tungsten-molybdenum associated ore and a method, the combined depressor comprising sodium humate, sodium mercaptoacetate, ammonium citrate, sodium pyrophosphate, sodium fluosilicate and lead nitrate, and the six kinds of substances are configured into the combined depressor in a proportion of 1:1:(2-5):(1-5):(1-3):(2-5). The application aims at recovering scheelite from low-grade refractory ore, improves the separation effect of scheelite and gangue minerals, improves the scheelite recovery rate and the concentrate grade, and improves the economic benefit.

The application discloses a mine filling and plugging material quick-setting additive and a preparation method thereof. The water-retaining agent in the quick-setting additive is a composite water-retaining system formed by hydroxypropyl methyl cellulose and modified starch. The hydroxypropyl methyl cellulose physically wraps free water in the slurry; the modified starch adsorbs water molecules through hydrogen bonding, and the double mechanism significantly reduces the bleeding rate; the coagulation accelerator adopts a spray drying wrapping technology, and a core-shell structure composite particle is constructed, in which aluminum lithium sulfate is used as a 'quick-release core', and active calcium silicate gel slurry obtained by the reaction of nano calcium silicate and sodium silicate is used as a'slow-release wrapping layer', so that the coagulation accelerator can promote coagulation, prevent sodium silicate from being consumed too early, and realize sustained coagulation. The early strength agent adopts a gel-gelling method, so that the early strength agent can provide persistent early strength excitation and solve the problem of weak late strength growth. The interface reinforcing agent can make the interface transition zone structure more strong and tough, and improve the integrity and damage resistance after the slurry coagulation and hardening.

Abstract A coal-based solid waste eco-restoration material and preparation method are provided. The preparation method includes: mixing and placing calcium oleate, sodium silicate, polyvinylpyrrolidone, oleylamine, anhydrous ethanol, and water in a hydrothermal reactor, heating at a constant temperature, centrifuging, and washing to collect inorganic nano-seed crystal; seeding the inorganic nano-seed crystal to form a cementitious material; mixing coal gangue powder with the cementitious material, mineral activator, and physical pore-forming foam, then curing, crushing, and screening to prepare a porous sandy loam matrix; uniformly mixing the prepared porous sandy loam matrix, coal slime, and composite microbial agent, and then fermenting and maturing to obtain the coal-based solid waste eco-restoration material. Compared with the traditional aluminum powder chemical foaming and strong acid foaming, the physical foaming technology adopted in the present disclosure improves the safety of operation while reducing the cost, and is convenient for standardized production. According to the activation of bacteria-fungi composite microbial agent, the nutrient elements in eco-restoration materials can be fully released. The eco-restoration material can be applied to the fields of mine soil restoration, land reclamation and other environmental restoration. FIG. 1 Abstract A coal-based solid waste eco-restoration material and preparation method are provided. The preparation method includes: mixing and placing calcium oleate, sodium silicate, polyvinylpyrrolidone, oleylamine, anhydrous ethanol, and water in a hydrothermal reactor, heating at a constant temperature, centrifuging, and washing to collect inorganic nano-seed crystal; seeding the inorganic nano-seed crystal to form a cementitious material; mixing coal gangue powder with the cementitious material, mineral activator, and physical pore-forming foam, then curing, crushing, and screening to prepare a porous sandy loam matrix; uniformly mixing the prepared porous sandy loam matrix, coal slime, and composite microbial agent, and then fermenting and maturing to obtain the coal-based solid waste eco-restoration material. Compared with the traditional aluminum powder chemical foaming and strong acid foaming, the physical foaming technology adopted in the present disclosure improves the safety of operation while reducing the cost, and is convenient for standardized production. According to the activation of bacteria-fungi composite microbial agent, the nutrient elements in eco-restoration materials can be fully released. The eco-restoration material can be applied to the fields of mine soil restoration, land reclamation and other environmental restoration. Mixing and placing calcium oleate, sodium silicate, S10 polyvinylpyrrolidone, oleylamine, anhydrous ethanol, and water in a hydrothermal reactor, heating at a constant temperature, centrifuging, and washing to collect inorganic nano-seed crystal; Seeding the inorganic nano-seed crystal to form a cementitious S20 material; mixing coal gangue powder with the cementitious material, mineral activator, and physical pore-forming foam, then curing, crushing, and screening to prepare a porous sandy loam matrix; Uniformly mixing the prepared porous sandy loam matrix, coal S30 slime, and composite microbial agent, and then fermenting and maturing to obtain the coal-based solid waste eco-restoration material. FIG. 1 20 25 20 15 77 04 M ar 2 02 5 2 0 2 5 2 0 1 5 7 7 0 4 M a r 2 0 2 5 a n d o t h e r e n v i r o n m e n t a l r e s t o r a t i o n . S 1 0 S 2 0 S 3 0 F I G . 1 2 0 2 5 2 0 1 5 7 7 0 4 M a r 2 0 2 5 a n d o t h e r e n v i r o n m e n t a l r e s t o r a t i o n . S 1 0 S 2 0 S 3 0 F I G . 1 1 / 2 FIG. 1 FIG. 2 1 / 2 Mixing and placing calcium oleate, sodium silicate, S10polyvinylpyrrolidone, oleylamine, anhydrous ethanol, and water in a hydrothermal reactor, heating at a constant temperature, centrifuging, and washing to collect inorganic nano-seed crystal; Seeding the inorganic nano-seed crystal to form a cementitious S20 material; mixing coal gangue powder with the cementitious material, mineral activator, and physical pore-forming foam, then curing, crushing, and screening to prepare a porous sandy loam matrix; Uniformly mixing the prepared porous sandy loam matrix, coal S30 slime, and composite microbial agent, and then fermenting and maturing to obtain the coal-based solid waste eco-restoration material. FIG. 1 Inorganic nano-seed crystal Hydration products 5 um FIG. 2 20 25 20 15 77 04 M ar 2 02 5 S 1 0 2 0 2 5 2 0 1 5 7 7 0 4 M a r 2 0 2 5 S 2 0 S 3 0 F I G . 2 S 1 0 2 0 2 5 2 0 1 5 7 7 0 4 M a r 2 0 2 5 S 2 0 S 3 0 F I G . 2

This invention discloses a mother liquor circulation device for alumina powder, relating to the field of alumina processing. It includes a pretreatment box and a pretreatment tank located below the pretreatment box. The inner wall of the pretreatment tank is equipped with heating elements. The pretreatment box has a processing chamber inside, with two sets of magnetic separation belts symmetrically installed on both sides of the inner wall of the processing chamber. A feed inlet is installed at the top of the pretreatment box, and a drain box is installed at the bottom of the feed inlet. Drainage channels are symmetrically located on both sides of the drain box. A slow-flow box is installed on the inner wall of the processing chamber below the magnetic separation belts, with the bottom of the magnetic separation belts extending to the bottom of the slow-flow box. This mother liquor circulation device for alumina powder reduces the amount of scale formation in subsequent leaching processes by pre-removing titanium and silicon minerals contained in the circulating mother liquor, thereby avoiding the formation of sodium silicate slag and alkali loss.

The application belongs to the technical field of surface modification, and relates to a preparation method of a flame-retardant ceramic coating based on yttrium oxide concentration regulation, comprising the following steps: dissolving sodium hydroxide and sodium fluoride with a specific mass ratio into a sodium silicate salt electrolyte, and adding a Y2O3 solution with a specific concentration into the electrolyte to obtain a first mixed solution; then placing a magnesium alloy substrate in the first mixed solution, and performing micro-arc oxidation treatment to obtain a magnesium alloy-flame-retardant ceramic composite, and finally obtaining a flame-retardant ceramic coating on the surface of the magnesium alloy substrate through post-processing. The mass ratio of sodium hydroxide and sodium fluoride, the concentration of the sodium silicate salt electrolyte, and the Y2O3 solution with an appropriate concentration are cooperatively regulated to realize accurate regulation of the performance of the flame-retardant coating on the surface of the magnesium alloy, so as to meet the actual application requirements of the flame-retardant performance of the magnesium alloy material for high-temperature key components, and promote the wide application of the magnesium alloy under high-temperature and flammable working conditions.

The present application relates to the field of chemical material environmental protection technology, and particularly to a method for preparing nine-water and five-water sodium metasilicate from by-product lye in the process of producing zirconium oxychloride by alkali fusion method.The method comprises the following steps: removing zirconium from the by-product lye by once concentration and filtration, then adopting stepwise cooling and temperature control crystallization after twice concentration of the filtrate, and finally obtaining nine-water sodium metasilicate by solid-liquid separation through a scraper type centrifuge and obtaining five-water sodium metasilicate by drying through a vibrating fluidized bed.In the preparation process, no reagent for adjusting modulus is needed, and through specific step-by-step concentration and zirconium removal process, full component utilization of waste liquid is realized.The nine-water and five-water sodium metasilicate products prepared by the method have product indexes meeting the requirements of superior products, and have the characteristics of large crystal particles, less mother liquor entrainment, high whiteness, and low water insoluble substance.The process not only significantly reduces the production cost, but also realizes green preparation of non-phosphorus washing aid and closed circuit circulation of zirconium resources, and has significant economic benefits and environmental protection value.

The present application belongs to the field of plant biotechnology, and particularly relates to a Korean pine cell fusion method based on chemical induction combined with a magnetic bead method. The method comprises the following steps: S1, preparing first protoplasts and second protoplasts; S2, preparing passivated first protoplasts and passivated second protoplasts; S3, mixing the passivated first protoplasts with the passivated second protoplasts in equal volumes after the passivated first protoplasts are cultured with a sodium silicate aqueous solution to obtain mixed protoplasts; S4, performing electrofusion on the mixed protoplasts in a cell fusion instrument to obtain fusion products; and S5, screening hybrid cells from the fusion products by using a magnetic bead method. The present application adopts a double screening mechanism of chemical passivation and magnetic bead screening, inactivates parent cells by treating with iodoacetamide and rose Bengal B, and then specifically enriches hybrid cells by using the magnetic bead method, so that the acquisition rate and screening accuracy of hybrid cells are significantly improved.

The present application relates to the technical field of general solid waste harmless treatment, and particularly relates to a method for electrolytic manganese residue harmless treatment. The method for electrolytic manganese residue harmless treatment comprises the following steps: solidifying treatment of electrolytic manganese residue to be treated by using a solidifying agent; the solidifying agent comprises a first solidifying agent and / or a second solidifying agent; the first solidifying agent comprises the following components in parts by weight: 0.5-1.25 parts of sodium phosphate, 4-8 parts of quicklime, 3-12 parts of cement and 2-8 parts of fly ash; the second solidifying agent comprises the following components in parts by weight: 5-7 parts of calcium oxide, 1.5-2.5 parts of sodium hydroxide and 0.8-1.2 parts of sodium silicate. After the electrolytic manganese residue is treated by using the suitable solidifying agent, the electrolytic manganese residue can be harmlessly treated and recycled, and can be used for producing building material raw materials, and the method is simple in operation, high in product added value and low in cost.

The application discloses a kind of sodium fluorosilicate production optimization calculation method, the surface energy of different crystal faces of sodium fluorosilicate is calculated, and the minimum crystal face is selected;For the minimum crystal face of the surface energy, preset the surface of electronic density is used to draw and display surface electrostatic potential and calculate energy;Obtain a preset number of impurity ions, calculate the energy of the preset number of fluorine ions in the minimum crystal face of the surface energy replaced by the impurity ions, and output the energy difference after replacement according to the calculated energy.The application calculates the surface energy of different crystal faces of sodium fluorosilicate, selects the minimum crystal face of the surface energy as the leading crystal face and carries out subsequent calculation.Then, the energy change of the fluorine ion in sodium fluorosilicate replaced by impurity ion is calculated, the binding energy of impurity ion and sodium fluorosilicate leading crystal face is shown by calculation result, the energy change of crystal surface energy and crystal growth caused by impurity ion is given, and the influence of impurity on sodium fluorosilicate production can be accurately judged according to the energy.

This invention relates to a deodorant, its preparation method, and its application, belonging to the field of deodorization technology. The invention provides a deodorant preparation method, specifically involving the following steps: a mineral-based deodorizing carrier, anhydrous calcium chloride, magnesium stearate, calcium peroxide, ferrous sulfate, basic copper carbonate, zinc oxide, and mesoporous silica are orderly mixed to obtain a composite powder. This powder is then mixed with a sodium silicate aqueous solution, kneaded, pressed into shape, and cured to obtain a raw blank. The raw blank is then immersed in a composite treatment solution containing silica sol, a silane coupling agent, and nano-titanium dioxide. After removal, it is dried and heat-treated to obtain the deodorant. The deodorant prepared by this invention can be applied to kitchens, bathrooms, and shoe cabinets, exhibiting excellent deodorizing effects.

This invention belongs to the field of casting binder technology, and particularly relates to an environmentally friendly water glass casting binder with anti-aging function. The raw material composition of this invention includes: sodium water glass, lithium water glass, polymethyl methacrylate, and lithium carbonate, which enables: 1. Polymethyl methacrylate combined with lithium carbonate to provide more hydrogen bonds to the water glass binder system, changing the surface potential energy and solvation ability of the water glass, improving the stability of the water glass, and thus obtaining better "anti-aging" ability; 2. Lithium carbonate itself has the effect of a dispersant, and combined with water glass at a specific modulus, it can further improve the dispersibility of the sand mold; 3. Polymethyl methacrylate itself has basic bonding strength, and by limiting the modulus of the water glass, it can also appropriately improve the bonding strength of the entire binder; 4. The amount of organic polymethyl methacrylate added to this binder is sufficiently small, ensuring that the binder has sufficient safety and environmental protection advantages.

This invention discloses an environmentally friendly coating containing negative oxygen ions and its preparation method, belonging to the technical field of negative oxygen ion coatings. Nano-cerium oxide is obtained by co-precipitating and calcining a ligand and a cerium source; plant straw powder is impregnated with an activator, swollen, dried, and carbonized to obtain an activated carbon carrier; the activated carbon carrier, nano-cerium oxide, nano-tourmaline powder, dispersant, and deionized water are mixed, and a sodium silicate aqueous solution is added, followed by extrusion granulation and heat preservation treatment to obtain a negative oxygen ion agent; the negative oxygen ion agent is grafted with KH570 to obtain a modified negative oxygen ion agent; difunctional polyurethane acrylate, active monomer, active diluent, modified negative oxygen ion agent, wetting and dispersing agent, defoamer, leveling agent, antioxidant, and photoinitiator are mixed and stirred evenly in the dark to obtain an environmentally friendly coating containing negative oxygen ions; this invention improves upon the problems of low release efficiency, poor durability, easy agglomeration and sedimentation of inorganic powders, and poor compatibility with coating resins in existing negative oxygen ion coatings.

The invention belongs to the technical field of domestic ceramics, and discloses an open fire ignition and quenching resistant domestic ceramic and a preparation method thereof. The domestic ceramic resistant to open fire firing and quenching is prepared from kaolin, bentonite, clay, electroquartz, aluminum oxide, nano zirconium silicate, sodium silicate, a sodium hydroxide solution, sodium humate, ammonium chloride, spodumene, lithium carbonate and deionized water, dry powder and slurry are evenly mixed and stirred, then mechanical pressing is conducted, and a complete ceramic body is obtained; according to the preparation method disclosed by the invention, the raw material ratio and the sintering process are optimized, open fire firing resistance and quenching resistance are synergistically improved, thermal shock resistance is enhanced by controlling the crystallinity of the raw materials, and meanwhile, a composite additive is introduced to improve a high-temperature phase change behavior; and the cost is effectively reduced and the process steps are simplified while large-scale production is realized.