2261 results about "Sodium silicate" patented technology

The invention provides anti-cracking and anti-seepage high-performance concrete, which relates to the technical field of concrete and comprises Portland cement, aggregate, a high-activity mineral admixture, a calcium-magnesium composite expanding agent, nano silicon dioxide particles, a microcapsule-packaged sodium silicate and calcium lactate solution, paraffin / expanded graphite composite phase change microspheres, steel fibers, PVA fibers and nano cellulose. The self-repairing concrete has the characteristics that the anti-cracking performance is comprehensively improved, the anti-seepage grade is broken through, the self-repairing capability is long-acting, the construction adaptability is enhanced, and the like.

The invention discloses a yellow phosphorus tailing-based mine filling material and application thereof. The yellow phosphorus tailing-based mine filling material comprises aggregate and a cementing material, the cementing material comprises the following components in parts by mass: 5-20 parts of red mud, 20-40 parts of yellow phosphorus slag, 10-30 parts of slag, 5-10 parts of fly ash, 5-10 parts of a compound exciting agent, 1-3 parts of an early strength agent and 2-5 parts of a water-retaining agent; wherein the compound exciting agent comprises the following components in parts by mass: 10-20 parts of sodium metasilicate, 30-40 parts of gypsum powder, 20-30 parts of sodium sulfate, 5-10 parts of carbide slag and 5-10 parts of silica fume; according to the invention, the raw materials are compounded and the specific exciting agent is subjected to depolymerization-polycondensation reaction to obtain a cementing material containing Aft (ettringite), C-S-H gel (hydrated calcium silicate gel) and C-A-S-H gel (hydrated calcium aluminosilicate gel), and finally, the mine filling material with high fluidity, low bleeding rate and high strength is obtained while yellow phosphorus tailing solid waste is treated.

The invention relates to a geopolymer-based non-expansive building fireproof coating, and belongs to the field of building materials. A geopolymer prepared from fly ash, granulated blast furnace slag, coal gangue, oil shale waste residues and sodium silicate water glass is used as a binder, and expanded perlite is used as a heat insulation filler to prepare the inorganic building fireproof coating. Meanwhile, tailings and basalt fibers are added, so that the contractibility and integrity of the geopolymer-based fireproof coating are improved. Compared with an organic fireproof coating, the environment-friendly fireproof coating has high environment friendliness in the production and preparation process and the use and action process in the case of a fire disaster. Compared with a traditional Portland cement-based fireproof coating, the fireproof coating has more excellent performance in the aspects of high temperature resistance, corrosion resistance and the like. According to the invention, the way of resource utilization of solid wastes is widened, and the building fireproof coating with excellent performance is provided.

The invention relates to a high-strength stable solid waste-based composite cementing material and a preparation method and application thereof in the field of building materials. The high-strength stable solid waste-based composite cementing material is prepared from the following raw materials in parts by weight: 70-85 parts of composite solid waste micro powder; 10 to 20 parts of Portland cement clinker; 3-8 parts of a composite activator; 0.5 to 2 parts of a nano-scale function regulator; wherein the composite solid waste micro powder is prepared by mixing and grinding the following raw materials in parts by weight: 40-60 parts of blast furnace slag powder; 20 to 30 parts of fly ash; 10-20 parts of chemically modified electrolytic manganese residue powder; and 5-15 parts of steel slag powder. According to the preparation method, sodium metasilicate is adopted to assist medium-temperature calcination to chemically modify the electrolytic manganese residues, so that not only is the gelation activity of the electrolytic manganese residues effectively excited, but also free-state manganese, cadmium and other heavy metal ions in the electrolytic manganese residues are fixed in situ in newly formed zeolite-like silicate mineral lattices through thermochemical reconstruction; and a brand new technical path is opened up for safe and high-value utilization of the typical hazardous waste, namely the electrolytic manganese residues.

The invention discloses a phosphorus removal filler and a preparation method and application thereof, and belongs to the technical field of fillers. Sulphoaluminate cement, chitosan, sodium alginate and calcium peroxide are uniformly mixed in a nitric acid solution in an amino-containing coupling agent, then foaming and pore forming are performed under steam, and the phosphorus removal filler is prepared. And finally, uniformly mixing with titanium dioxide, sodium silicate, a ferrous sulfate solution and sodium borohydride to obtain the phosphorus removal filler with an excellent phosphorus removal effect, and the phosphorus removal filler has a rich pore structure and adsorption activity, can sufficiently perform physical adsorption on phosphorus elements, and has a good phosphorus removal effect. Meanwhile, the phosphorus removal filler further has excellent surface complexing activity and photocatalysis, insoluble salt precipitates can be generated through reaction of iron elements and calcium elements and phosphate in water, so that total phosphorus is removed, the material is ground after adsorption saturation and put into a fish pond to serve as a phosphorus supplementing material, resource recycling can be achieved, and the cost is reduced. Wide application prospects are realized.

The invention provides a mining inorganic environment-friendly reinforcing material and application thereof, and belongs to the technical field of mining reinforcing materials. A component A comprises the following components in parts by mass: 60-80 parts of anhydrite, 5-20 parts of lime, 5-10 parts of silica fume, 2-8 parts of sodium silicate, 1-0.5 part of a naphthalene water reducer, 3-7 parts of an early strength agent and 0.2-0.8 part of lithium salt; the component B comprises the following components in parts by mass: 50-70 parts of cement clinker, 10-30 parts of slag cement, 5-10 parts of iron powder, 1-8 parts of aluminum sulfate, 5-10 parts of calcium carbonate and 0.5-1 part of sodium tripolyphosphate; the component C is prepared from the following components in parts by mass: 10 to 25 parts of water glass, 10 to 20 parts of emulsion, 40 to 60 parts of water, 5 to 10 parts of high-efficiency water reducing agent and 1 to 5 parts of triethanolamine. The mining inorganic environment-friendly reinforcing material provided by the invention is low in reaction heat and is not easy to cause coal combustion.

The invention relates to the technical field of cement-based repair mortar, and particularly discloses a preparation method of an early-strength quick-hardening anti-carbonization cement-based repair mortar material, which comprises the following steps: (1) uniformly mixing calcium silicate or pseudo-wollastonite and saturated lime water, adding basalt fiber, and carrying out heating reaction, and uniformly mixing the fiber with sodium silicate powder, calcining in a protective atmosphere, uniformly mixing the obtained fiber with saturated lime water, and drying to obtain the anti-carbon modified fiber. And (2) uniformly mixing red mud, silica fume, sodium silicate powder and water, curing, grinding, and calcining the powder to obtain the anti-carbonization additive. And (3) mixing sulphoaluminate cement, fine aggregate, solid waste-based filler, the anti-carbon modified fiber, the anti-carbonization additive, a water reducing agent and a defoaming agent, adding mixing water, and uniformly stirring to obtain the cement-based repairing mortar material. According to the invention, the carbonization resistance of the sulphoaluminate cement-based repair mortar is effectively improved, the durability is improved, and the problem of strength shrinkage in the later period is prevented.

The invention relates to a preparation method of a catalyst for synthesizing 2, 6-dimethylphenol, which comprises the following steps: mixing ferric salt, aluminum salt, magnesium salt, an acidic material and water to obtain a solution A; mixing sodium silicate, a template agent and water to obtain a solution B; mixing the solution A and the solution B, aging, crystallizing, filtering, drying and calcining to obtain a catalyst precursor I; mixing with an alkaline solution, and filtering to obtain a catalyst precursor II; then mixing with an acidic solution, filtering to obtain a solid, and then washing and calcining to obtain a catalyst; the preparation method of the 2, 6-dimethylphenol comprises the following step of preparing the 2, 6-dimethylphenol by taking methanol, phenol, water and benzoic acid as raw materials in the presence of the catalyst. The catalyst provided by the invention has good catalytic activity, reduces the problem of carbon deposition, and has good selectivity and high phenol conversion rate when being used for preparing 2, 6-dimethylphenol.

The invention belongs to the field of coal gangue resource utilization, and particularly discloses a method for separating and recovering silicon and aluminum elements from coal gangue. The coal gangue is used as a raw material, and efficient resource utilization of the coal gangue is realized through crushing and ball milling, high-temperature roasting activation and acid-base combined treatment. The coal gangue is subjected to high-temperature fluorination roasting by adopting an activating auxiliary agent fluorinating agent to form soluble fluosilicate (H2SiF6) and a fluorine-aluminum compound (AlF3), so that the subsequent silicon-aluminum separation is obviously promoted. The method comprises the following steps: desiliconizing through alkali treatment, leaching and converting silicon in the coal gangue into sodium silicate, and carrying out solid-liquid separation to obtain sodium silicate filtrate and aluminum-rich leaching residues; and then acid treatment is conducted on the aluminum-rich leaching residues, aluminum salt or aluminum hydroxide is prepared, and finally efficient separation of silicon and aluminum is achieved. According to the method, through high-temperature activation roasting, the normal-pressure alkaline leaching desiliconization effect is improved, the acid extraction aluminum efficiency is remarkably improved, the advantages of an acid method and an alkaline method are effectively combined, and the problems that coal gangue resources are difficult to utilize and the resource recovery rate is low are solved.

The invention relates to a marine machinery technology, and discloses a casting method of a servo valve body, which comprises the following steps: step S100, making casting equipment of a casting process through three-dimensional mapping design, casting simulation, optimization design and simulation verification in sequence, respectively placing patches, risers and chilling blocks on two sides of a valve core of a mold and the upper surface of the mold, and casting the valve body of the servo valve; a temperature gradient is formed through the synergistic effect of the patch, the riser and the chilling block so as to control and optimize the solidification process of the casting; s200, a series core frame used for connecting the resin chromite sand layer and the ester-hardened sodium silicate sand layer in series is placed in the mold, then the working faces of the mold and the core are filled with resin chromite sand, and the non-working faces are filled with ester-hardened sodium silicate sand; and S300, molten steel smelting is carried out, and the molten steel is prepared from, by percentage, 0.34%-0.35% of C, 0.45%-0.46% of Si, 0.70%-0.71% of Mn, 0.93%-0.95% of Cr, 0.20%-0.30% of Mo, smaller than or equal to 0.025% of S and smaller than or equal to 0.025% of P. The technical problems that in the prior art, a valve body is poor in performance and quality can be solved.

The invention relates to the technical field of porcelain, in particular to porous antioxidant composite porcelain and a preparation method thereof, and the preparation method comprises the following steps: weighing the following raw materials in parts by weight: 35-40 parts of clay, 10-15 parts of aluminum oxide, 6-10 parts of an aluminum nitride-doped modified homogenizing agent, 5-9 parts of kaolin and 5-8 parts of a sodium silicate blender. According to the porous anti-oxidation composite porcelain, clay is adopted as a matrix, aluminum oxide and kaolin are added to be matched with an aluminum nitride modified homogenizing agent and a sodium silicate blender, the raw materials are blended and synergized, compression molding is performed, and finally homogenizing sintering is performed, so that the porous anti-oxidation composite porcelain is obtained. The porous performance, the high-temperature oxidation resistance and the mechanical bending strength performance of the obtained composite porcelain are harmoniously improved, and meanwhile, the stability effect of the product is remarkable under different degrees of corrosion conditions.

The invention discloses a rapid concrete repairing material based on microbial mineralization as well as a preparation method and application of the rapid concrete repairing material. According to the method, hydrophobic modified porous particles are used as a carrier, microbial bacteria, nutrient substances and a calcium source with mineralization behaviors are soaked into pores of the porous particles through vacuum impregnation, the pores of the particles are properly sealed by adopting waterborne epoxy, and then the particles are packaged by using metakaolin and sodium silicate, so that the porous particles are obtained. And finally, compounding with fiber composite mortar to prepare the concrete rapid repairing material. The rapid concrete repairing material has the advantages of strong interface adhesion, environment friendliness, light weight, excellent surface compactness improvement effect, crack self-repairing and the like, and can be used for coating and repairing the defect surface of concrete.

The invention belongs to the technical field of water treatment, and particularly relates to a preparation method and application of an organic / inorganic composite flocculant for swimming pool water treatment.The method comprises the steps that magnetic nanoparticles Fe3O4 and sodium silicate powder are mixed to prepare a magnetic polysilicic acid solution, chitosan and acrylamide of a certain mass are dissolved in a glacial acetic acid solution, and the magnetic polysilicic acid solution is prepared; and ammonium ceric nitrate is used as an initiator to prepare the chitosan-polyacrylamide flocculant. The prepared chitosan-polyacrylamide flocculant is stirred in a glacial acetic acid solution for 24 hours for pretreatment. The preparation method comprises the following steps: adding an Al2 (SO4) 3.18 H2O solution, a ZnSO4. 7H2O solution and a pretreated chitosan-polyacrylamide flocculating agent into a magnetic polysilicic acid solution according to a certain proportion, so as to prepare the Fe3O4-PSAZ-CS-AM composite flocculating agent. The method disclosed by the invention is simple in reaction operation, easy in reaction condition control, low in cost and high in turbidity removal and organic matter removal efficiency of the swimming pool water, and has relatively high popularization and application values.

The invention belongs to the technical field of solid waste resource utilization, and discloses an activity-enhanced solid waste-based sludge curing agent as well as a preparation method and application thereof. The sludge curing agent comprises the following raw materials in percentage by mass: 30-40% of cement, 15-25% of S95 mineral powder, 15-23% of steel slag powder, 16-26% of an activity enhancing component and 0.5-3% of a composite exciting agent, wherein the activity enhancing component is prepared from the following raw materials in percentage by mass: 35 to 40 percent of desulfurized gypsum, 35 to 40 percent of carbide slag and 20 to 30 percent of biomass ash; the composite exciting agent comprises the following raw materials in percentage by mass: 30-35% of metakaolin, 30-35% of sodium sulfate, 15-20% of sodium silicate and 15-20% of sulfonated oil. According to the sludge curing agent, the industrial solid waste accounts for 57% or above, the desulfurized gypsum, the carbide slag and the biomass ash form an activity enhancing component, the activity enhancing component is matched with the composite exciting agent to jointly enhance and excite the activity of the metallurgical slag solid waste, and therefore the excellent curing effect is achieved, and when the sludge curing agent is used for sludge curing, the 3d unconfined compressive strength of a sludge curing body is larger than or equal to 0.5 MPa; and the 28d unconfined compressive strength is greater than or equal to 1.4 MPa.

The present invention relates to a sealing method for high-flow water inrush at a side wall of a foundation pit, the method comprising: calculating the minimum radius of a counter-pressure soil berm on the basis of the flow time of a liquid slurry in the counter-pressure soil berm being not less than the chemical setting time of the liquid slurry; piling up filtering sand bags on a foundation pit excavation face at a water inrush point, and constructing the counter-pressure soil berm; constructing annular grouting holes at the foundation pit on the outside of support piles and a cut-off curtain; according to the planar arrangement of the annular grouting holes, successively injecting a double-liquid slurry formed by mixing a cement slurry and sodium silicate into the annular grouting holes; inspecting the water seepage condition on the periphery of the counter-pressure soil berm until no water seepage occurs on the periphery of the counter-pressure soil berm; and excavating the counter-pressure soil berm layer by layer until the excavation reaches the pit bottom without water seepage observed at a side wall of the foundation pit. The present invention has the beneficial effects that: the size of the counter-pressure soil berm is optimally designed on the basis of the condition that the flow time of the double-liquid slurry in the soil berm is longer than the setting time, so as to solve the problems of slurry setting failure and poor grouting and sealing effects, thus saving a large amount of grouting materials, and reducing economic loss caused by secondary sealing.

The invention relates to the technical field of flux-cored wires. The preparation method comprises the following steps: weighing the following raw materials in parts by weight: 4-6 parts of chromium carbide powder, 7-9 parts of molybdenum powder, 6-8 parts of nickel powder, 10-15 parts of niobium powder, 15-18 parts of tungsten carbide powder, 7-11 parts of a modified titanium carbide agent, 5-8 parts of a blending agent added based on boron and 2-4 parts of 30-mesh natural graphite; 1-2 parts of sodium fluosilicate; 1-2 parts of aluminum powder; and 70-75 parts of iron powder. The flux-cored wire can adapt to complex service environments of parts such as rollers and continuous casting crystallizers in the metallurgical industry, the service life of the parts subjected to surfacing repair is prolonged, the production efficiency of the parts subjected to surfacing repair is improved, the obtained flux-cored wire achieves balance of high-temperature performance, mechanical performance and low-temperature stability, and the comprehensive applicability of products is improved.

The invention discloses a grouting reinforcement material and a preparation method and application thereof, and the method comprises the following steps: mixing a sodium silicate aqueous solution, a chain extension cross-linking agent, distilled water and a composite catalyst to obtain a component A; reacting the polymethylene polyphenyl polyisocyanate with polyether polyol to obtain an isocyanate prepolymer, and carrying out self-polymerization on the polymethylene polyphenyl polyisocyanate under the action of a catalyst to obtain an isocyanate polymer; the preparation method comprises the following steps: mixing a component A and a component B according to a mass ratio of (1.2: 1)-(1: 1.2), then stirring an isocyanate prepolymer, an isocyanate polymer, a plasticizer and a diluent at room temperature and constant temperature to obtain the component B, and finally mixing the component A and the component B according to a mass ratio of (1.2: 1)-(1: 1.2) to obtain the target grouting reinforcement material. The invention aims to realize effective compounding of an organic phase and an inorganic phase, and the prepared reinforcing material has early strength and toughening, low heat release, and environment-friendly grouting performance capable of being cured in water.

The invention belongs to the technical field of concrete preparation, and particularly relates to a preparation method of a large-mixing-amount concrete composite admixture with solid waste residues as raw materials. The large-dosage concrete composite admixture provided by the invention comprises the following raw materials: phosphogypsum subjected to activation and modification treatment, lithium slag powder subjected to calcination and fine grinding treatment, silica fume, redispersible latex powder, quartz powder and sodium silicate, and the raw materials are added into concrete to serve as cement replacement components. And the compressive strength, static elastic modulus, impermeability, freezing resistance and other properties of the concrete are not influenced.

The invention discloses a solar photovoltaic cable sheath material and a tear-resistant photovoltaic cable, and belongs to the field of photovoltaic cable manufacturing. The sheath material comprises the following components in parts by weight: 70-120 parts of ethylene propylene rubber, 10-13 parts of crosslinked polyethylene, 3-7 parts of zinc oxide, 1-4 parts of stearic acid, 1-2 parts of paraffin, 2-5 parts of an anti-aging agent RD, 8-12 parts of zinc borate, 150-200 parts of a reinforcing agent, 10-12 parts of high abrasion furnace black, 9-13 parts of tricresyl phosphate, 9-13 parts of red phosphorus, 0.5-1 part of an accelerant TMTD, 3-5 parts of DCP and 1-2 parts of HVA-2. The reinforcing agent composed of sodium silicate, ferric chloride and aluminum hydroxide is added into the sheath material, so that when the sheath material is damaged, sodium silicate and ferric chloride react under the influence of air moisture to generate colloidal silicic acid carrying ferric hydroxide and aluminum hydroxide, and the damaged part is filled with the colloidal silicic acid; and meanwhile, the aluminum hydroxide can promote the colloidal silicic acid to be dried, so that the damaged part is repaired, and the situation that the tear resistance of the cable is remarkably worsened due to damage is avoided.

The invention relates to the technical field of 3D printing building materials, in particular to a 3D printing geopolymer composite material with low drying shrinkage and a preparation method thereof.The 3D printing geopolymer composite material is prepared from, by mass, 400 parts of slag powder, 320 parts of fly ash, 80 parts of steel slag micro powder, 1200 parts of quartz sand, 5.1-25.6 parts of sodium hydroxide, 46.4-66.9 parts of sodium silicate, 8 parts of barium chloride and 296 parts of water. The preparation method comprises the following steps: fully mixing the slag powder, the fly ash, the steel slag micro-powder and the quartz sand according to a preset mass ratio to obtain a uniform basic powder mixture; adding an alkali activator and barium chloride into the basic powder mixture, and continuously mixing until the mixture is uniform to obtain a first mixture; and adding water into the first mixture according to a preset water-binder ratio, and carrying out stirring treatment according to a preset stirring method to obtain the 3D printing geopolymer composite material with low drying shrinkage. According to the invention, the drying shrinkage can be reduced.

The invention relates to the technical field of coating preparation, and discloses a high-adhesion quick-drying inorganic zinc silicate shop primer and a preparation method thereof.The high-adhesion quick-drying inorganic zinc silicate shop primer is prepared from modified zinc powder, modified graphite powder, a sodium silicate solution, alpha-phase nanometer AlO, a quick-drying agent, an adhesion promoter, heat-resistant filler, a dispersing agent, a defoaming agent and a diluting solvent; the quick-drying agent is prepared by compounding zinc naphthenate, EDTA and titanium isopropylate according to the mass ratio of 1: (0.2-0.3): (0.4-0.6), the quick-drying agent accelerates the reaction by catalyzing hydrolysis of silicate through zinc salt, chelating of EDTA and metal ions, titanium isopropylate provides titanium ions to synergistically form a film and improve the quick-drying efficiency, the adhesion promoter is prepared by compounding KH-560 and E-44 epoxy resin according to the mass ratio of 3: 1, and the adhesion promoter is prepared by compounding epoxy resin and epoxy resin. The adhesion promoter enhances interface mechanical occlusion and adhesion through silane bonding base materials and epoxy resin, other raw materials are matched with the adhesion promoter to accelerate the drying speed of the primer, and a coating coated with the primer is not prone to stripping and peeling. The application has the effects of improving the adhesive force and drying speed of the inorganic zinc silicate shop primer.

A “Passive Radiative Coating” (PRC) is designed to dissipate heat generated mainly by solar radiation, intended for use in the manufacture of overhead conductors and cables. Additionally, this coating can dissipate heat produced by the conductors themselves, known as the Joule effect, providing environmental protection and significantly improving heat dissipation capacity. The PRC is composed of at least one filler, at least one binder, and at least one surfactant. In particular, the use of calcium carbonate and / or barium sulfate as fillers, and epoxy resins, alkyd varnishes, polyurethane dispersions, casting resins, silicone-based varnishes, and sodium silicate as binders are highlighted. The surfactant is used to stabilize the mixture and acts as a stabilization additive.

The invention relates to the technical field of heavy metal recovery, in particular to a method for recovering heavy metal from metal waste. Comprising the following steps: preparing silicon-tungsten composite acid salt; preparing heteropolyacid powder; preparing a resin heteropolyacid composite material; heavy metals are recovered from metal wastes by a resin adsorption method. The silicon-tungsten composite acid salt is prepared under mild conditions through reaction of sodium metasilicate, sodium tungstate and potassium chloride, the operation is simple, the conditions are easy to control, the silicon-tungsten composite acid salt has rich active sites and a large specific surface area, the surface of the silicon-tungsten composite acid salt carries negative charges, and the surface of the silicon-tungsten composite acid salt is not prone to damage. Compared with a traditional chemical precipitation method, the method for extracting the heavy metal by using the silicon-tungsten composite acid salt does not need to add a large number of chemical reagents, and secondary pollution is reduced.

The invention belongs to the field of material protection, and particularly relates to a method for improving spraying efficiency and adhesive force by adding a binder in the plasma spraying process. The binder comprises one or more of bentonite, silicon dioxide, borax, sodium silicate and aluminum phosphate. The device has the function of quickly melting spraying particles at high temperature and adhering the spraying particles to a spraying substrate, so that the powder spraying efficiency is improved, and the production efficiency is improved. The method comprises the following steps: firstly, carrying out sand blasting treatment on a spraying base material, removing dust and impurities on the surface to enable the roughness to reach 8-10 microns, weighing, and measuring the surface area to be sprayed; and then weighing the binder and putting the binder into a drying oven to be dried at 120 DEG C; the method comprises the following steps: uniformly mixing a binder and an analytically pure nano spraying material according to a certain proportion, and pouring into a plasma spraying raw material tank; and spraying is carried out at the position with the voltage of 30-50 V, the current of 300-600 A, the air pressure of 8 Mpa and the distance of 80-120 mm. The spraying time is 3-5 min, and after spraying is completed, the powder spraying amount is calculated by weighing the mass difference of the base material before and after the base material is weighed. And by adding the binder, the powdering rate is increased from 30.79% to 51.24%, the consumption of spraying materials is greatly reduced, and the working efficiency is improved.

The invention discloses a composite system geopolymer grouting material and a preparation method thereof. The composite system geopolymer grouting material comprises the following raw materials in percentage by mass: 50-70% of coal gangue, 10-30% of fly ash and 10-30% of cement. Functional additives: 5%-20% of desulfurized gypsum and 5%-15% of bentonite; the composite exciting agent is formed by compounding carbide slag and sodium silicate according to the mass ratio of 1: 1-1: 2. The geopolymer is excellent in mechanical property, meets engineering requirements, is remarkable in environmental protection benefit, conforms to double-carbon target low-carbon process innovation: a calcination-free process: traditional high-temperature calcination is abandoned (the temperature needs to be 550-900 DEG C), carbon emission is reduced by more than 30% (compared with a contrast, the carbon emission of a traditional process is increased by 35%), and the geopolymer conforms to the green positioning of low energy consumption and low three wastes of geopolymers. The cost advantage is prominent, the economic value is remarkable, the raw material cost is reduced, specifically, the coal gangue (low-cost solid waste) is used for replacing 30%-50% of cement, and the comprehensive raw material cost is reduced by 40% (compared with a traditional cement-based grouting material).

The invention discloses stable silicon dioxide microspheres as well as a preparation method and application thereof. Mixing a sodium silicate diluent and an organic acid aqueous solution to form colloidal particles, and carrying out a sol-gel reaction to obtain silica sol; the preparation method comprises the following steps: in an air environment, throwing silica sol into water under stirring to form microspheres, injecting inorganic acid into the water at the same time, then injecting a sodium silicate diluent for reaction, and then adjusting the pH value of the system to 6-7; and aging, washing, drying and roasting to obtain the silicon dioxide microspheres. The preparation method comprises the following steps: mixing a sodium silicate diluent and an organic acid aqueous solution by an acid mixing method, granulating by air to form microspheres, and finally injecting inorganic acid to quickly remove heat, reduce pressure drop and maintain the state of the microspheres, thereby obtaining the stable silicon dioxide microspheres. The porous silicon dioxide microsphere with larger surface area and pore volume is obtained, has better catalytic performance when being used as a catalytic oxidation carrier, and has the advantages of high conversion rate and high stability.

The invention discloses acid-resistant calcium carbonate and a preparation method thereof, and belongs to the technical field of calcium carbonate filler production. According to the invention, industrial waste carbide slag is used as a calcium source, and calcium hydroxide slurry is obtained through impurity removal; then adding sodium polyacrylate and sodium hexametaphosphate, stirring and dispersing, then introducing carbon dioxide for carbonization, adding a surfactant for ultrasonic activation after carbonization, and finally sequentially adding zirconium oxychloride and sodium silicate to prepare the acid-resistant calcium carbonate. The defects of traditional silicon dioxide and titanium dioxide coated calcium carbonate products are overcome, the prepared calcium carbonate product is compact and uniform in coating layer and good in stability, meanwhile, excellent acid resistance and mechanical property are considered, the calcium carbonate can be suitable for more acid environments, and the application range of calcium carbonate is effectively widened.

The invention relates to the technical field of chemical preparations, in particular to a sodium hypochlorite stabilizer, a preparation method and a use method thereof and a stable sodium hypochlorite solution. The sodium hypochlorite stabilizer is prepared from the following components in percentage by mass: 2.5 to 3.5 percent of sodium diethylenetriamine pentaacetate, 2.5 to 3.5 percent of disodium ethylene diamine tetraacetate, 1.0 to 1.25 percent of sodium silicate, 3.5 to 5.0 percent of sodium bicarbonate, 2.5 to 3.0 percent of sodium chloride and the balance of water. The stable sodium hypochlorite solution prepared by adopting the sodium hypochlorite stabilizer disclosed by the invention is higher in stability and longer in validity period.

The invention relates to the technical field of bamboo pulp bleaching, and particularly discloses a method for preparing all-chlorine-free bleached bamboo pulp and application. The method adopts a three-section enhanced bleaching process and comprises the following steps: firstly, decomposing lignin under an alkaline condition of 100-115 DEG C through oxygen delignification (Op section); removing transition metal ions by using sulfuric acid and a metal chelating agent with a specific structure by adopting acid pickling chelation (AQ section); and finally, deeply oxidizing the residual lignin in a high-pressure oxygen environment through oxygen enhanced bleaching (Po section). In each stage, hydrogen peroxide is used as a main bleaching agent, sodium hydroxide, sodium silicate and other assistants are matched, and ineffective decomposition of hydrogen peroxide is effectively inhibited through staged pH regulation and a metal chelation technology. The whiteness of the obtained bamboo pulp is larger than or equal to 83% ISO, the kappa number is smaller than or equal to 3.0, and the requirements of high-grade paper products are completely met.

A method and device for separating and recovering heavy metal ions through membrane-forming mineralization fixation, applicable in the domain of acid wastewater treatment containing heavy metal ions. The process involves mixing composite mineral particles with heavy metal acidic wastewater, then conducting a first hydration reaction under static conditions. This leads to adsorption, precipitation, and crystallization of heavy metal ions in the wastewater via a colloidal liquid membrane, resulting in particles coated with a mineralized membrane. These particles exhibit a gap between the mineralized membrane and their core. The next step is to separate these coated particles and recover them. The preparation of composite mineral particles involves mixing sodium carbonate / sodium silicate, bentonite, carbide slag, and water, followed by a second hydration reaction and subsequent granulation, aging, and dehydration condensation. The particle sizes of both bentonite and carbide slag are maintained at ≤74 m.