Provided is a process for integrating treatment of off gas through
NOx removal, SOx removal and mercury removal, which could avoid
high energy consumption resulting from high temperature required for the reaction, and a corresponding apparatus thereof. The process comprises the splitting of the off gas to a sub-
stream off gas flow line as a carrier for the
oxidizing agent. In the sub-
stream line, a heating chamber is set for the
decomposition of the
oxidizing agent to form free radicals (when
hydrogen peroxide is used, the free radicals formed are hydroxy and peroxy hydroxy free radicals) having stronger oxidative capacity than the original oxidants used, these free radicals carried in the sub-
stream off gas are then combined with the unheated mainstream off gas, and react with the reducible contents such as
NOx, SOx and mercury vapor in the off gas to generate
NOx, SOx and mercury ions with higher
oxidation state, wherein all the acidic products and mercury ions will be removed in the subsequent gas scrubbing device. The process and apparatus enable substantial reduction of energy required for oxidization and effective removal of NO2 and SOx as well as the reducible
heavy metals such as
metallic mercury, owing to only a portion of
flue gas used as the carrier for the oxidizing and ionizing of the oxidative agents.