The invention provides a fume purification
system based on advanced
oxygenation combining wet scrubbing. The
system is a
combustion and exhaust
system formed by a boiler, an
ozone generator, a stirrer, a swirl
nozzle, a reactor, a gas-liquid absorption
tower and a
chimney, wherein fume containing
sulfur oxide,
nitric oxide and mercury generated by
combustion of the boiler and O3 generated by the
ozone generator enter the stirrer together, are mixed, flow through the swirl
nozzle, and are sprayed into the reactor with an
ultraviolet lamp tube; and
hydroxyl radical (.OH) with strong oxidability generated under excitation of
ultraviolet radiation, SO2 in the fume, indissoluble NO and HgO are oxidized into gaseous products with higher dissolubility and enter the gas-liquid absorption
tower to be absorbed and removed by water; Hg<2+> generated in the gas-liquid absorption
tower captures and retrieves mercuric
sulfide by adding sulfidion S<2-> in equal
molar ratio; and the residual
sulfuric acid and
nitric acid mixed solution is used as an industrial
raw material for recycling, and the cleaned fume enters the
chimney so as to be exhausted.