The invention relates to a chiral binuclear Zn (II)-complex constructed on the basis of a chiral Salen-
Schiff base ligand (R, R / S, S-L), a preparation method of the chiral binuclear Zn (II)-complex and application of the chiral binuclear Zn (II)-complex to electro-circularly polarized
luminescence, and along with the change of the configuration of the chiral Salen-
Schiff base ligand, the chiral binuclear Zn (II)-complex shows different light colors in a visible light region. At
room temperature, maximum emission peaks of an
emission spectrum of the chiral binuclear Zn (II)-complex developed by a chiral Salen-
Schiff base ligand introduced based on a methoxy (-OMe) functional group in a CH2Cl2 solution are respectively 467 nm and 462 nm, CIE coordinates are respectively (0.156, 0.192) and (0.158, 0.190), and the chiral binuclear Zn (II)-complex is located in a
blue light emission region, shows a strong
ground state chiral
signal and a Cotton effect, and has an asymmetric factor gPL-10-4. The starting voltages of the electroluminescent devices CP-
OLED-R and R-II and CP-
OLED-S and S-II are both 6V, the maximum emission wavelengths of electro circularly polarized light are respectively 488 nm and 496 nm, and the CIE coordinates are respectively located in
blue light regions (0.288, 0.305) and (0.283, 0.304). The maximum current efficiency of the devices CP-
OLED-R and R-II is 0.90 cd / A, the maximum power efficiency of the devices CP-OLED-R and R-II is 0.47 lm / W, and the maximum external
quantum efficiency of the devices CP-OLED-R and R-II is 0.43%; the maximum current efficiency of the device CP-OLED-S, S-II is 0.83 cd / A, the maximum power efficiency is 0.40 lm / W, the maximum external
quantum efficiency is 0.38%, and the asymmetric factor is gEL-10 <-4 >.