The present application relates to the technical field of organic
optoelectronic materials and devices, in particular to a preparation method of white organic light-emitting diodes based on a kind of blue, yellow and other color cMa
copper (I) TADF complex with
nitrogen heterocyclic
carbene-
copper-arylamines structure, including three steps: first, synthesis of cMa type
copper (I) TADF complex containing
blue light emitter and yellow
light emitter as representative, obtained by ligand selection, intermediate preparation and purification;Second, construct layered WOLEDs device, from bottom to top in turn for substrate, ITO
anode,
hole injection layer,
hole transport layer, buffer layer, yellow light emitting layer,
blue light emitting layer,
electron transport layer,
electron injection layer and Al
cathode;Third, through substrate pretreatment, mbar high
vacuum evaporation and
nitrogen glove box packaging complete device preparation.The WOLEDs device W1, W2 prepared by the present application has excellent photoelectric performance, the CRI is up to 83, the maximum external
quantum efficiency is greater than or equal to 13.3%, has good stability and low cost, and is suitable for lighting and display fields.