1027 results about "Ortho position" patented technology

Hydrocyanation reactions employing multidentate phosphite ligands and multidentate phosphite ligands are disclosed. The ligands have phenyl containing substituents attached to the ortho position of the terminal phenol group and/or attached to the ortho position of the bridging group. Catalyst compositions havng such ligands achieve 97% or greater distribution in hydrocyanation.

A new light-emitting device utilizing phosphorescence is provided. Further, an electronic device and a lighting device which utilize phosphorescence are provided. One embodiment of the present invention is a light-emitting device including a phosphorescent organometallic iridium complex comprising iridium and either pyrimidine having an aryl group at the 4-position or 1,3,5-triazine having an aryl group at the 2-position. One of nitrogen in the pyrimidine or 1,3,5-triazine is coordinated to the iridium. Also, each of the pyrimidine and 1,3,5-triazine has a substituent such as an alkyl group or an aryl group. Further the ortho position of the aryl group which is bonded to the 4-position of the pyrimidine or the 2-position of the 1,3,5-triazine is bonded to the iridium.

The present invention discloses blend polymer membranes comprising thermally rearranged polymers derived from aromatic polyimides containing ortho-positioned functional groups and methods for making and using these blend polymer membranes. The blend polymer membranes described in the current invention are prepared by heat treatment of blend polymer membranes comprising aromatic polyimides containing ortho-positioned functional groups such as —OH or —SH groups. In some instances, an additional crosslinking step is performed to improve the selectivity of the membrane. These blend polymer membranes have improved flexibility, reduced cost, improved processability, and enhanced selectivity and/or permeability compared to the comparable polymer membranes that comprise a single polymer.

Aromatic silane compounds containing at least an aromatic ring bound directly to the silicon atom, wherein the aromatic ring has at least one substituent located in the ortho position selected from C_1-10 hydrocarbon groups, are useful as electron donors in olefin polymerization catalysts for the production of polyolefins having a stereoblock content of from about 7 to about 25%.

There are provided an organic having both excellent hole transporting property and satisfactory electron transporting and showing excellent durability against electric oxidation/reduction and a high triplet excitation level, and a charge transporting material and an organic electroluminescent device each using the organic compound. The organic compound is represented by following Formula (I):

wherein Cz¹ and Cz² each represent a carbazolyl group; Z represents a direct bond or an arbitrary linkage group enabling the conjugation of nitrogen atoms in the carbazole rings of Cz¹ and Cz² with each other; and Q represents a direct bond connecting to “G” in following Formula (II):

wherein Ring B¹ represents a six-membered aromatic heterocyclic ring having “n” nitrogen atom(s) as hetero atom(s); “n” represents an integer of from 1 to 3; G represents a direct bond or an arbitrary linkage group connecting to Q when G connects to Q; Gs connect to carbon atoms at the ortho-position and the para-position with respect to nitrogen atom(s) in Ring B¹; G represents an aromatic hydrocarbon group when G does not connect to Q; and “m” represents an integer of from 3 to 5.

Multidentate phosphite ligands are disclosed for use in reactions such as hydrocyanation and isomerization. The catalyst compositions made therefrom and the various catalytic processes which employ such multidentate phosphite ligands are also disclosed. In particular, the ligands have heteroatom-containing substituents on the carbon attached to the ortho position of the terminal phenol group.

The invention discloses a dynamic polymer material. The dynamic polymer material comprises a product obtained through reaction of the following components: at least one polyol compound containing two or more 1,2-diol motifs or 1,3-diol motifs as well as at least one phenylboronic acid compound containing two or more phenylboronic acid motifs provided with aminomethyl groups in ortho-positions. Dynamic reversible phenylborate bonds are formed through the reaction of the components and then constitute a dynamic cross-linked polymer. The polymer material has reusability and recoverability because of the dynamic reversibility of the special phenylborate bonds; besides, when the polymer material adopting a specific formula receives external force, dynamic bonds break preferentially to have energy dissipation and stress elimination functions, so that the material has good toughness. The material has broad application prospect in the fields of military space equipment, functional paint and coatings, biomimetic materials, biomedical materials and the like.

An organic compound and a charge-transporting material which are excellent in both a hole-transporting property and an electron-transporting property and have excellent electrical oxidation/reduction durability and a high triplet excitation level are provided, and an organic electroluminescent device which uses this organic compound and has high luminous efficiency and high driving stability and long lifetime is provided. One molecule of the organic compound has two or more partial structures represented by the following Formula (I):

The invention relates to a method for preparing an alkali lignin-phenolic resin composite adhesive for wood adhesive, which comprises the steps that hydroxymethylation alkali lignin is prepared; and the alkali lignin-phenolic resin composite adhesive is prepared. The method adopts hydroxymethyl reaction to improve the activation of alkali lignin; the hydroxymethylation alkali lignin is prepared; lignin is selected and added by three batches; the batch addition of the lignin can achieve the function of adjusting the degree of the hydroxymethyl reaction, contribute to the realization of the hydroxymethyl reaction, reduce the condensation reaction between lignin hydroxymethyls and achieve the aim of the farthest activation of the lignin. In the synthetic process, the PH value and viscosity in the reaction are strictly controlled; and the batch feeding method is used to carry out orderly and rapid hydroxymethyl reaction. As the lignin has huge molecular weight, large space steric hindrance of the active site on aromaticring and low reaction activity, the lignin is needed to be modified so as to improve the reaction activity; as a molecule comprises a phenolic hydroxyl, the ortho-position and the para-position of the molecule have certain activity; and hydrogen in the alpha-carbon atom can be replaced by hydroxymethyl to have the hydroxymethylation reaction, thereby introducing a hydroxymethyl active group in the molecule.

The invention relates to a Schiff base compound and a method for detecting an aniline compound thereof, belonging to the technical field of chemical sensor materials. The Schiff base compound is characterized by being prepared in such a way that an aromatic aldehyde compound with ortho-position hydroxyl reacts with monoamine or polyamine and has the structural formula shown as the figure, wherein n1 is an integer from 1 to 100, and n2 is an integer from 1 to 6; R is an aliphatic hydrocarbon substituted group, an aryl substituted group, heteroatom-substituted aliphatic alkyl or heteroatom-substituted aryl alkyl; and R1 and R2 are electron-withdrawing groups or electron-donating groups. The compound has stable solid fluorescence luminous performance, the fluorescence strength of the compound is changed by the aniline compound, the aniline compound can be detected according to the change of the fluorescence strength of the compound, and the compound is a novel fluorescence sensing material for detecting aniline.

The present invention relates to an arylphenoxy catalyst system producing an ethylene homopolymer or copolymers of ethylene and α-olefins, and a method of producing an ethylene homopolymer or copolymers of ethylene and α-olefins having a high molecular weight under a high temperature solution polymerization condition using the same. The catalyst system includes a group IV arylphenoxy-based transition metal catalyst and an aluminoxane cocatalyst or a boron compound cocatalyst. In the transition metal catalyst, a cyclopentadiene derivative and arylphenoxide as fixed ligands are located around the group IV transition metal, arylphenoxide is substituted with at least one aryl derivative and is located at the ortho position thereof, and the ligands are not crosslinked to each other. The catalyst includes an environmentally-friendly raw material, synthesis of the catalyst is economical, and thermal stability of the catalyst is excellent. It is useful for producing an ethylene homopolymer or copolymers of ethylene and α-olefins having various physical properties in commercial polymerization processes.

The invention relates to ruthenium alkylidene complexes having an N-heterocyclic carbene ligand comprising a 5-membered heterocyclic ring having a carbenic carbon atom and at least one nitrogen atom contained within the 5-membered heterocyclic ring, wherein the nitrogen atom is directly attached to the carbenic carbon atom and is substituted by a phenyl ring, and wherein the phenyl ring has a hydrogen at either or both ortho positions and is substituted at at least one ortho or meta position. The invention also relates to an olefin metathesis reactions and particularly to the preparation of tetra-substituted cyclic olefins via a ring-closing metathesis.

The invention discloses a phenol ortho-methylation catalyst and a preparation method thereof. The catalyst is an alkaline Fe/Mg compound oxide, wherein, the mol ratio of Fe to Mg is 1: (0.1-2). The preparation method comprises the following steps: mixing and dissolving soluble malysite and soluble magnesium salts into alcohols solvent according to a required proportion to prepare a solution A; adding polyethyleneglycol (PEG) into strong aqua ammonia to prepare a solution B; slowly mixing the solution A and the solution B in a cocurrent flow mode under the condition of normal temperature and ultrasound, and then going on with the ultrasound for 30 minutes; filtering, washing, drying and baking the obtained precipitation; porphyrizing the baked solid and repulverizing the solid into 10-20 mesh finely ground particles after tabletting; the finely ground particles are the catalyst. The catalyst has the advantages of high activity at low temperature, simple preparation, innocuity, good stability, high selectivity of ortho position, particularly high selectivity of orthocresol and few by-products.

The provided alpha, omega-end polyaminoether as the new curing agent for epoxy resins belongs to the compound with general formula as (1) (wherein, all m, x and y for integer, 10>=m>=2, 6>=x+y>=1 and n for repetitive unit of polyether chain segment)or the mixture with aromatic polyaminoether, contains substituents on ortho-, meta- or para-position of benzene ring, and has high strength and ductility and filling rate without toxin.

An object of the present invention is to provide a process that enables isocyanates to be stably produced over a long period of time at high yield without encountering various problems as found in the prior art when producing isocyanates without using phosgene. The present invention discloses a process for producing an isocyanate, comprising the steps of: reacting a carbamic acid ester and an aromatic hydroxy compound to obtain an aryl carbamate having a group derived from the aromatic hydroxy compound; and subjecting the aryl carbamate to a decomposition reaction, wherein the aromatic hydroxy compound is an aromatic hydroxy compound which is represented by the following formula (1) and which has a substituent R¹ at least one ortho position of a hydroxyl group:

(wherein ring A represents an aromatic hydrocarbon ring in a form of a single or multiple rings which may have a substitute and which have 6 to 20 carbon atoms;

• • R¹ represents a group other than a hydrogen atom in a form of an aliphatic alkyl group having 1 to 20 carbon atoms, an aliphatic alkoxy group having 1 to 20 carbon atoms, an aryl group having 6 to 20 carbon atoms, an aryloxy group having 6 to 20 carbon atoms, an aralkyl group having 7 to 20 carbon atoms or an aralkyloxy group having 7 to 20 carbon atoms, the group containing an atom selected from a carbon atom, an oxygen atom and a nitrogen atom; and R¹ may bond with A to form a ring structure).

The invention discloses a preparation method of bisphenol F with high ortho-position isomer content. The preparation method comprises the following steps: synthesizing the bisphenol F by adopting a two-step method, separating an organic phase and a phosphoric acid phase, neutralizing the organic phase and removing salt, and recovering phenol under the reduced pressure to obtain the bisphenol F product, wherein in the first step of the two-step synthesis method, the phenol reacts with formaldehyde under the weakly acidic condition; and in the second step, a large amount of catalyst phosphoric acid and formaldehyde are added into the reaction liquid obtained in the first step, and the formaldehyde completely reacts. The invention overcomes the defects that the content of the ortho-position isomer in the bisphenol F prepared by the existing bisphenol F preparation method is low, the curing speed of the synthesized bisphenol F epoxy resin is slow, the resin is easy to crystallize and the like.

The invention provides a method for preparing 2, 2'-biphenyl diphenol derivatives, and the method comprises the step of carrying out oxidation coupling reaction on phenolic compound A with ortho-hydrogen atoms at 0-100DEG C with the help of peroxide, thus preparing 2, 2'-biphenyl diphenol compound B; and the method is simpler and more economical, the post processing is simple and easy to implement and has good universality, and the method can provide a series of 2, 2'-catechol derivatives.

Described herein are compounds and methods of catalyzing ethenolysis reactions, optionally on an industrial scale. In certain embodiments, the catalysts bear cyclic alkyl amino carbene (CAAC) ligands with an ortho substituent, such as a methyl substituent, on an N-aryl ring. When used to catalyze ethenolysis reactions, certain such compounds produce a turnover number greater than 50,000.

A process for the simultaneous trimerization and tetramerization of olefinic monomers, wherein the process comprises contacting at least one olefinic monomer with a catalyst system comprising: a) a source of chromium, molybdenum or tungsten; b) a ligand having the general formula (I);

(R¹)₂P-X-P(R¹)_m(R²)_n  (I)

wherein:

• X is a bridging group of the formula —N(R³)—;
• the R¹ groups are independently selected from an optionally substituted aromatic group bearing a polar substituent on at least one of the ortho-positions; and
• the R² groups are independently selected from hydrocarbyl, substituted hydrocarbyl, heterohydrocarbyl and substituted heterohydrocarbyl groups with the proviso that when the group is aromatic it does not contain a polar substituent at any of the ortho-positions; and c) a cocatalyst.

A polyimide-based polycondensate which may be used as an insulation film by coating a copper foil with the polycondensate and by heating the coated copper foil, which insulation film does not warp the foil, as well as a production process thereof, is disclosed. The polycondensate according to the invention is a solvent-soluble polycondensate containing a benzoxazole component having a carboxylic group and an imide component having a phenolic hydroxyl group, which is obtained by dehydration-condensing one or more tetracarboxylic dianhydrides with one or more aromatic diamines having an amino group and a phenolic hydroxyl group, the amino group and the phenolic hydroxyl group being located at ortho positions with respect to each other, by heating the one or more tetracarboxylic dianhydrides and the one or more aromatic diamines at 150° C. to 220° C. in the presence of an acid catalyst.