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3617 results about "Active group" patented technology

Method for preparing humic acid and salt thereof by oxidation and degradation of brown coal

The invention discloses a method for producing humic acid and salt thereof through the oxidative degradation of young lignite. The method comprises the following steps: carrying out the oxidation reaction of the lignite containing the humic acid and aqueous hydrogen peroxide solution; after the reaction, obtaining water soluble fulvic acid through centrifugal separation, supernatant filtration, concentration and drying; adding alkali into the fulvic acid to prepare a fulvic acid salt product; carrying out the alkaline extraction and centrifugal separation of the residue deposit of the production of the fulvic acid, adding acid into the supernatant till the pH value is 1 to 2, carrying out a reaction at an increased temperature or room temperature, carrying out centrifugal separation after the reaction is finished, and obtaining purified ulmic acid after precipitation and drying; and directly concentrating and drying the supernatant in the previous step to obtain the humate. The method can improve the yield of the fulvic acid and total humic acid in the young lignite, and simultaneously increase the active group in the humic acid. The method can be used for producing fulvic acid, fulvic acid salt, ulmic acid and ulmic acid salt products. In particular, the method puts an end to the environmental pollution caused by the nitric acid which is taken as an oxidation degradation agent. In addition, the method has a short technological line, low cost, simple requirements on equipment, and moderate conditions. The method which can be applied to the industrialized production has good application prospect.
Owner:KUNMING UNIV OF SCI & TECH +4

High-durability super-hydrophobic self-cleaning coating material and preparation method thereof

InactiveCN101962514AHas the following advantages: (1) cleanlinessHas the following advantages: (1) has the functionAntifouling/underwater paintsPaints with biocidesDouble bondDimethyl siloxane
The invention belongs to the technical field of a new chemical material, and in particular relates to a high-durability super-hydrophobic self-cleaning coating material and a preparation method thereof. The coating material of the invention is prepared by curing and drying nanoparticles with photo-catalytic activity, a low-surface-free-energy polymer and a cross-linking agent at the room temperature, wherein the low-surface-free-energy polymer consists of one or more of polysiloxane fluoride, dimethyl silicone polymer and polyphenylene methyl siloxane, which contain active groups, such as hydroxyl alkoxy group, carbon-carbon double bond, silanol group, siloxy group, and the like; the cross-linking agent is hydrogen-containing silicone oil or aminosilane; and the mass content of the photo-catalytic nanoparticles in the coating ranges from 10 to 60 percent. The coating is formed into a micro-nanostructure by nanoparticle self-organization; a super-hydrophobic self-cleaning coating with lotus effect is prepared from the coating and a cross-linked filming matrix with low surface energy; the persistence of a lotus-shaped super-hydrophobic characteristic of the coating is realized by using the photo-catalytic decomposition characteristic of an organic pollutant for the nanoparticles; and thus the material is suitable for large-area construction and has high weathering resistance andprominent self-cleaning characteristic.
Owner:FUDAN UNIV

Graphene/polysiloxane composite coating material and preparation method thereof

The invention provides a graphene / polysiloxane composite coating material and a preparation method thereof. The method comprises the following steps: modifying the graphene surface with active groups by a chemical modification technique to obtain modified graphene, mixing the modified graphene with a silane compound, a dispersion medium, a non-essential comonomer and a non-essential accelerator, and carrying out hydrolytic condensation or hydrolytic condensation-free radical polymerization to generate a graphene / polysiloxane composite resin in situ; and mixing the resin with a non-essential blend resin, a non-essential curing agent, a non-essential solvent, a non-essential pigment and filler and a non-essential aid, and carrying out physical blending, amino epoxy addition reaction, Michael addition reaction and the like to form a film, thereby obtaining the graphene / polysiloxane composite coating material. The uniformly dispersed graphene lamellae and polysiloxane have strong interface effects, also have the gas / liquid barrier and heat shielding effects, and endow the coating with excellent corrosion resistance, flame retardancy and the like, thereby greatly enhancing the mechanical properties, corrosion resistance, scratch resistance, wear resistance and the like of the coating.
Owner:FUDAN UNIV

High-scratch-resistance abrasion-resistant coating material and preparation method thereof

The invention provides a high-scratch-resistance abrasion-resistant coating material and a preparation method thereof. The preparation method comprises the following steps: modifying the graphene surface by using active groups by a chemical modification technique to obtain modified graphene, and blending the modified graphene with polysiloxane to obtain the high-scratch-resistance abrasion-resistant nano composite coating material. The surface modification is carried out to enhance the dispersity of the graphene and the interactions between the graphene and polysiloxane matrix, thereby enhancing the mechanical properties of the coating. No pigment or filler is added. The scratch resistance of the transparent graphene/polysiloxane composite coating is enhanced by 140% or above, and the abrasion loss is reduced by 60% or above. The transparent graphene/polysiloxane composite coating has excellent adhesion, heat resistance, weather resistance, flame retardancy and corrosion resistance. The graphene/polysiloxane composite coating can be used for surface protection and shielding of various metals, plastics, wood, concrete, glass and other substrates, and is applicable to the fields of automobile paints, photoelectric materials, precision instruments, marine heavy-corrosion protection, buildings and the like.
Owner:FUDAN UNIV

Method and system for scaling of resource allocation subject to maximum limits

A software method and computer system using said method are disclosed for efficiently reallocating unused system resources in a system in which unused system resources are initially allocated among groups that may become active or inactive. The method reallocates unused resources among active groups by scaling up these groups' initial entitlement shares, subject to maximum caps that may apply. For each group, the method calculates a scaling ratio equal to the cap divided by the entitlement, and then sorts the groups according their scaling ratios. The method processes each group in increasing order of their scaling ratios and reaches a maximal share of system resources to be allotted to each group, where the maximal share for an active group is between, or equal to, the group's initial entitlement value and its cap. Inactive groups have maximal shares equal to zero, reflecting that they receive no system resources. As the method processes the groups, it attempts to simply scale each active group by its scaling ratio. If scaling all unprocessed groups by the current group's scaling ratio would exceed the unallocated resources, then the remaining groups are scaled by the remaining resources divided by the sum of the entitlements of the remaining groups. Because the groups are sorted in order of increasing scaling ratios, the remaining active groups may be scaled as described without exceeding their caps.
Owner:HEWLETT PACKARD DEV CO LP
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