The invention relates to a
corrosion-resistant substitutive PVC (
polyvinyl chloride) film and a production process thereof, and belongs to the technical field of
polymer film materials. The
film material is prepared from the following components in parts by weight: 100 parts of PET resin, 3.2 to 4.5 parts of organic
silicon corrosion-resistant agent, 0.3 to 0.5 part of slipping agent, 0.15 to 0.2 part of nucleating agent and 4 to 6 parts of filler, according to the organic
silicon corrosion-resistant agent, N-methyldiethanolamine and
epoxy-terminated
silicone oil are subjected to ring opening to form an organic
silicon compound with N-methyldiethanolamine as a bridging
chain segment, namely an organic
silicon matrix, then active primary amine of tetramethylpiperidinamine and residual
epoxy groups at the end of the organic
silicon matrix are subjected to ring opening and end capping, an end functional hindered amine structure is introduced, and the organic silicon corrosion-resistant agent is prepared. And finally,
oxalyl chloride monoethyl ester and hydroxyl group obtained after ring opening of the functional intermediate are esterified, diester short chain modification is introduced into a molecular
side chain of the functional intermediate, and the medium corrosion resistance and aging corrosion resistance of the membrane material are improved through introduction of an organic silicon corrosion-resistant agent.