The invention relates to a high-voltage static plasma air purifier and a purification method thereof. The high-voltage static plasma air purifier comprises a housing, a high-voltage static electrolysis device, an air filtering device, a fan, an ultraviolet germicidal lamp, a negative electricity metal plate, an ozone processing device and an intelligent control device. Both sides of the housing are provided with air inlets formed above the housing; the right side of the housing is provided with an air quality sensor; the air filtering device comprises a coarse filtering layer, an HEPA (high efficiency particulate air) filtering layer, an activated carbon filtering layer and a photocatalyst filtering layer. The high-voltage static plasma air purifier ionizes air through high-voltage static, and under the action of the HEPA filtering layer, the activated carbon filtering layer, the photocatalyst filtering layer, an ultraviolet filtering layer and the ozone processing device, achieves the aim of purifying the air; under the high-voltage ionization, hazardous substance in the air can be absorbed, so that the absorbing pressure of the next-stage filtering layers can be reduced, the next-stage filtering layers can avoid being blocked by the hazardous substance, and further replacement of consumable materials can be reduced, and the air purification quality can be enhanced.