The invention relates to the technical field of flocculating agents, and discloses a flocculating agent for high-concentration azo printing and
dyeing wastewater, which is prepared from the following components in parts by weight: 4 to 5 parts of
hydroxypropyl chitosan derivative, 2 to 3 parts of
sodium silicate solution, 0.5 to 1 part of
sulfuric acid, 2 to 3 parts of
ferric sulfate solution, 1 to 3 parts of
zinc sulfate solution, and 4 to 5 parts of
polyaluminum chloride solution and composite
antibacterial agent. The preparation method comprises the following steps: preparing a
sodium silicate solution, slowly dropwise adding the
sodium silicate solution into
sulfuric acid, and activating to obtain a polysilicic acid solution; sequentially adding a
ferric sulfate solution, a
zinc sulfate solution and a 50-500mg / L
polyaluminum chloride solution, and standing and curing to obtain the polysilicate
ferric zinc aluminum flocculant. The preparation method comprises the following steps: firstly, preparing a polysilicate ferric zinc aluminum flocculant, then slowly adding a
melamine solution, carrying out ultrasonic action to obtain a carbonitrided polysilicate ferric zinc aluminum flocculant, and carrying out
carbonitriding treatment on the polysilicate ferric zinc aluminum flocculant combined with
metal ions to
delay gelation of the polysilicate flocculant, so that the polysilicate flocculant can be stored for a longer time.