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Continuous aromatization and catalyst regeneration device and method thereof

ActiveCN101244969ANo temperature fluctuationsDoes not affect aromatization reactionMolecular sieve catalystsCatalyst regeneration/reactivationFluidized bedAromatization
The invention discloses and belongs to the chemical equipment field, which more particularly relates to a C1-C2 hydrocarbon or methanol aromatization and catalyst regeneration fluidized bed device (comprising an aromatization fluidized bed, a catalyst continuous regeneration fluidized bed, a pipeline used for catalyst transportation and a solid transportation device which are arranged between the two fluidized beds), and an aromatization catalyst which is suitable for the fluidized bed operations and the operation methods of aromatization reaction, catalyst regeneration and the device. The device, the catalyst and the method are used for regulating the coking status of the catalyst in an aromatization reactor at any time, thus achieving the aim of transforming the C1-C2 hydrocarbon or the methanol continuously and efficiently and generating aromatics with high selectivity. The C1-C2 hydrocarbon or methanol aromatization and catalyst regeneration fluidized bed device of the invention with adjustable catalyst activity and selectivity can improve the purity and yield of the aromatics, can lead the aromatization reactor operates continuously without stopping at the same time, can improve the strength of aromatics production, and lower the operation cost of the catalyst regeneration when stopping and restarting the whole system.
Owner:TSINGHUA UNIV

Co-production of xylose, xylitol and arabinose from agricultural and forestry wastes

The invention relates to a clean technique for co-producing xylose, xylitol and arabinose from agricultural and forestal waste, belonging to the field of utilization of agricultural and forestal waste. The technique comprises the following steps: pretreating and preprocessing the raw material, and hydrolyzing in a thermophilic digestion mode to prepare a hemicellulose hydrolysate; after centrifugalizing to remove solid residues, carrying out TiO2-loaded activated carbon photocatalysis or ion exchange resin decolorization and detoxification treatment on the hydrolysate; carrying out MVR (mechanical vapor recompression) concentration treatment and gradient-cooling crystallization to obtain a xylose product and a xylose mother solution; fermenting L-arabinose unconverted xylitol fermentationhigh-yield strain xylitol by using the xylose mother solution as the medium to produce the xylitol; centrifugalizing to remove thalli, and carrying out decolorization and desalting treatment by membrane-process or resin adsorption; separating by using a simulated moving bed or chromatographic separation technology to obtain a xylitol phase and an L-arabinose phase; and carrying out MVR or vacuum concentration treatment on the two phases, and crystallizing in a gradient programmed cooling mode to respectively obtaining a xylitol product and an L-arabinose product, wherein the two mother solutions can be recycled.
Owner:BEIJING UNIV OF CHEM TECH
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