572 results about "Denitrifying bacteria" patented technology

The invention relates to the technical field of water treatment, in particular to a denitrification slow-release composite carbon source as well as a preparation method and application thereof. Comprising the following components in percentage by weight: 2-10% of hydroxy acrylic acid, 2-10% of saccharides, 5-15% of straw waste liquid, 5-15% of kitchen waste liquid, 2-10% of saccharides, 3-15% of porous volcanic ash, 5-15% of polyvinyl alcohol, 0.2-1% of inorganic salt, 1-2% of polypeptide, 0.5-1% of growth factors, 0.2-1.5% of MFC agar, 0.1-0.5% of cellulase, 0.1-0.5% of protease, 0.1-0.5% of denitrifying bacteria and the balance of water. The sum of the percentages of the raw materials is 100%. The invention has the advantages that: each nutrient component is balanced, the nutrition is comprehensive, the activity of denitrifying bacteria is improved, the number of species and community layers of a biological system of a sewage treatment plant are increased, the growth of various microorganisms is facilitated, nutrient substances can be fully utilized, and the denitrification effect is far higher than that of related carbon sources such as single methanol, glucose and the like.

The invention discloses a method for denitrifying wastewater by using a low-temperature-resistant heterotrophic nitrification and aerobic denitrification bacterium, and relates to a method for denitrifying wastewater by using a biological bacterium, the bacterium is Pseudomonas putida, is named as Pseudomonas umsongensis BK17, belongs to Pseudomonas, and is preserved in the China Center for Type Culture Collection (CCTCC), the preservation number is CCTCC M 20242924, and the preservation date is December 27, 2024. The strain is a heterotrophic nitrification-aerobic denitrification bacterium, can efficiently remove inorganic nitrogen pollution in a water body, still has good denitrification performance under low-temperature stress, and is high in low-temperature tolerance. The strain can efficiently treat nitrogen-containing wastewater under the condition of 10 DEG C, and the removal efficiency can reach 99% or above. The method has great potential in the application of inorganic nitrogen pollution treatment of domestic sewage and other water bodies in cold regions in China.

The invention relates to the field of town sewage treatment, in particular to a town sewage carbon-nitrogen-phosphorus synergistic advanced treatment method based on biological manganese oxide. The method comprises the following steps: S1, configuring an upward flow denitrification filter tank; s2, a starting stage: taking a mixed solution of secondary effluent and secondary influent water of an actual town sewage treatment plant and manganese sulfate as influent water of a denitrification filter tank with the manganese concentration of 3.0 mg / L, inoculating hydrolytic acidification bacteria, denitrifying bacteria, anaerobic ammonium oxidation bacteria and manganese oxidation bacteria into the denitrification filter tank, and gradually increasing the ratio of the secondary influent water to the secondary effluent water in the mixed solution to 3%; s3, a stable stage: taking a mixed solution of secondary effluent and secondary inlet water of an actual town sewage treatment plant and manganese sulfate as inlet water of the denitrification filter tank, controlling the manganese concentration to be 3.0 mg / L, controlling the hydraulic retention time to be 3-4 hours, and controlling the backwashing period to be 9-11 days. The method can synchronously and efficiently remove carbon, nitrogen and phosphorus in the secondary effluent of the actual town sewage treatment plant at low cost.

The invention discloses a composite denitrification accelerant and a preparation method thereof, and belongs to the technical field of sewage treatment. The carbon source composite material is prepared from the following raw materials in parts by weight: 30-50% of a carbon source, 2-5% of vitamins, 2-5% of amino acids, 1-3% of a biological stimulant, 1-2% of signal molecules, 1-5% of metal elements, 3-5% of a pH regulator and 25-60% of water. Through metabolites such as vitamins, amino acids and biological stimulants, growth and reproduction of denitrifying bacteria are promoted, and functions of related enzymes in the denitrification process are improved. The signal molecule optimizes the metabolic activity of bacteria by regulating and controlling the expression of genes, related to the denitrification process, of the denitrifying bacteria. The metal ions can enhance the activity of the denitrifying enzyme, so that the efficiency of denitrification treatment is improved. According to the denitrification accelerant, the denitrification process is promoted through the synergistic effect of three aspects of growth and reproduction of denitrifying bacteria, expression of denitrification genes and improvement of activity of denitrification-related enzymes.

The invention provides a mixed nutrition type denitrification nitrogen removal electron donor and a construction method, and relates to the field of biological denitrification, and the construction method comprises the following steps: adopting a simulation reactor to simulate a sewage anoxic tank, taking a liquid sulfur source as an electron donor to culture denitrifying bacteria, and completing domestication of sulfur autotrophic denitrifying bacteria; the method comprises the following steps: taking inflow water of an anoxic tank of a sewage plant as a water source, controlling hydraulic retention time to be consistent with that of the anoxic tank, and adding a carbon source or an alkaline buffering agent to adjust a denitrification nitrogen removal load and a pH value to a preset range; the agent proportion is determined according to the fed liquid sulfur source, the carbon source or the alkaline buffering agent, the proportion is used for preparing a mixed nutritional type denitrification nitrogen removal electron donor, and the mixed nutritional type denitrification nitrogen removal electron donor is used as a nitrogen removal electron donor of a denitrification system of the sewage treatment anoxic tank. The mixed denitrification nitrogen removal electron donor aiming at the sewage quality can be obtained, and the consumption of an organic carbon source is reduced.

The invention discloses a complex microbial inoculant and application thereof, and belongs to the technical field of microorganisms. The composite microbial agent comprises bacillus (bacillus sp.BS-K1) and pseudomonas sp.CN-B1), and the preservation number of the bacillus is CCTCC (China Center for Type Culture Collection) NO: M 20242022, and the preservation number of the pseudomonas is CCTCC NO: M 20242022. The preservation number of the pseudomonas is CCTCC (China Center for Type Culture Collection) NO: M 20242021. According to the complex microbial inoculant provided by the invention, probiotics (Bacillus sp.BS-K1) and denitrifying bacteria (Pseudomonas sp.CN-B1) which have antibacterial effects are compounded to obtain the complex microbial inoculant for aquaculture, and when the complex microbial inoculant is applied to an aquaculture water body, the complex microbial inoculant has excellent denitrification capability and an inhibition effect on related pathogenic bacteria in the water body; the removal efficiency of ammonia nitrogen and nitrite nitrogen in the culture water body can be improved, the number of related pathogenic bacteria is reduced, and the safety of the culture environment is guaranteed.

The present application relates to the field of municipal wastewater treatment, and particularly relates to a highway service area wastewater treatment device and method based on AOOA-MBBR process. The device comprises a first anoxic tank, a first aerobic tank, a second aerobic tank and a second anoxic tank connected in sequence, and is filled with MBBR filler respectively, and the volume of the filled MBBR filler is taken as the effective volume; the first aerobic tank and the second aerobic tank are respectively provided with an aeration device; the first anoxic tank is used for inoculating hydrolytic bacteria and denitrifying bacteria; the first aerobic tank is used for inoculating hydrolytic bacteria, nitrifying bacteria and denitrifying bacteria; the second aerobic tank is used for inoculating nitrifying bacteria, and the second anoxic tank is used for inoculating hydrolytic bacteria and denitrifying bacteria; the second aerobic tank is connected with the first anoxic tank through a reflux pipe, and the reflux pipe is provided with a reflux power assembly. The present application solves the problems of existing highway service wastewater treatment with extremely low carbon-nitrogen ratio, such as the need for additional carbon source / electron donor, high operation cost, poor denitrification effect and high sludge yield.

The invention discloses a biological filler for enhancing denitrification of an aerobic tank as well as preparation and application of the biological filler, the problem of weak activity of denitrifying bacteria is successfully solved by loading three layers of biological fillers, namely an inner layer-denitrifying bacteria, a middle layer-conducting layer and an outer layer-nitrifying bacteria, on the filler, and rapid formation of a biological membrane is realized. In addition, a metal conducting layer is additionally arranged in the middle to participate in electron transfer in the microbial denitrification process, and the biological membrane layers on the two sides achieve rapid formation of biological membranes so as to achieve conversion and removal of nitrogen. According to the method, the biological activity of the thalli can be kept, the rapid formation of a biological membrane is realized, and the separation of the thalli and refractory organic matters can be promoted, so that the toxic action on the thalli is reduced.

The invention provides an environment-friendly microbial strain and a water treatment agent preparation process, and relates to the field of water treatment. The environment-friendly microbial strain is prepared from the following raw materials in parts by weight: 20 parts of nitrifying bacteria, 20 parts of denitrifying bacteria, 35 parts of bacillus and 25 parts of EM bacteria, the nitrifying bacteria comprise nitrosomas and nitrobacteria, and the denitrifying bacteria comprise nitrosomas and nitrobacteria. The denitrifying bacteria comprise denitrifying bacilli and sternobacter, the bacillus comprises bacillus subtilis and bacillus licheniformis, and the EM bacteria comprise rhodopseudomonas, lactococcus lactis and saccharomyces cerevisiae. Through flora screening and culture, the culture efficiency is improved, through a fermentation process, fermentation liquor overflow and insufficient dissolved oxygen caused by excessive foam are effectively prevented, the stability of the fermentation process is ensured, through preparation preparation, a good packaging material and a sealing technology, moisture absorption and pollution of a microbial inoculum are prevented, and the quality and safety of a product are ensured.

This invention discloses a method for remediating groundwater containing organic pollutants, comprising the following steps: 1) Extracting groundwater containing organic pollutants using multiple extraction pumps, adding ferrous salts at a solid-liquid ratio of 1:50-200, mixing thoroughly, and adjusting the pH of the system to 6-8 to obtain intermediate treatment solution one; 2) Adding a remediation agent to the obtained intermediate treatment solution one, mixing and stirring for 3-6 hours to obtain intermediate treatment solution two; 3) Passing the obtained intermediate treatment solution two sequentially into an anaerobic reactor and an aerobic tank for treatment, and discharging after reaching the required standards; the packing material of the anaerobic reactor contains microorganisms, including at least two or more of denitrifying bacteria, Bacillus coagulans, Bacillus subtilis, Bacillus clonorchis, Bacillus indusiata, and Serratia marcescens. The remediation method provided by this invention has high remediation efficiency, thorough removal of organic matter, and is economically feasible, with an organic matter removal rate of over 98%.

The invention belongs to the field of sewage treatment, and discloses a two-phase mud film efficient synchronous nitrogen and phosphorus removal process. By integrating biological denitrification and chemical phosphorus removal technologies and adopting a two-phase treatment unit, efficient and synchronous removal of nitrogen and phosphorus in sewage is realized. According to the process, a biological treatment procedure of denitrifying bacteria and nitrifying bacteria under an anaerobic and aerobic alternating condition is utilized, and ammonia nitrogen and nitrate nitrogen in sewage are effectively removed by controlling reaction conditions and formation of a mud film. Meanwhile, ferric salt and polyaluminum chloride flocculants are used for chemical precipitation, phosphate ions form insoluble precipitates by adjusting the pH value and the adding amount, and activated carbon or a zeolite adsorption material is combined for adsorption, so that phosphorus is further removed. The method has the advantages of high treatment efficiency, low operation cost, simplicity and convenience in operation and wide applicability, and an efficient, economic and environment-friendly solution is provided for sewage treatment.

The invention relates to the technical field of denitrification fillers, in particular to an autotrophic denitrification filler for denitrification and a preparation method thereof. The autotrophic denitrification filler comprises the following raw materials in parts by weight: 80-100 parts of sulfur powder, 8-12 parts of zinc carbonate powder, 8-12 parts of clay, 4-6 parts of ferric oxide, 4-6 parts of polyhydroxyalkanoate, 4-6 parts of sugarcane cellulose, 1-3 parts of cotton, 1-3 parts of a binder and 1-3 parts of a cross-linking agent. According to the method, in the high-frequency ultrasonic treatment, the sulfur powder and sodium sulfide are in non-uniform contact, so that non-uniform sunken dissolving positions can be generated on the surface of the sulfur powder, the specific surface area of the sulfur powder is effectively increased, and after the sulfur powder is used as a main raw material to prepare the filler, the filler has a relatively large contact reaction area with sewage; a good attachment and growth environment is provided for denitrifying bacteria, and the purification effect of the autotrophic denitrification filler for denitrification is improved.

The invention discloses a chemical wastewater biological denitrification device, and relates to the technical field of chemical wastewater. The device comprises a supporting frame, a denitrification barrel is arranged at the center of the top of the supporting frame, an annular limiting groove is formed in the bottom of the inner wall of the denitrification barrel, a drainage pipe is arranged at the bottom of the denitrification barrel, a control assembly is arranged at the top of the denitrification barrel, a water guide pipe is arranged in the control assembly, the bottom of the water guide pipe penetrates through the denitrification barrel, and two liquid injection openings are formed in the top of the denitrification barrel; the two liquid injection ports are symmetrically distributed about the axis of the denitrification barrel, and a cambered surface base is fixedly mounted at the bottom of the inner wall of the denitrification barrel. The separation filter plate is promoted to block and separate large mud blocks or impurities in wastewater, and small mud blocks are promoted to quickly fall down to synchronously perform nitrogen removal treatment with the wastewater in the up-down movement process of the separation filter plate, so that the situation that nitrogen in large mud is difficult to discharge is effectively prevented; therefore, the heterotrophic denitrifying bacteria have poor nitrogen removal effect on the wastewater and are directly discharged to cause environmental pollution.

The invention discloses a five-in-one composite sulfur autotrophic denitrification filter material as well as a preparation method and application thereof, and relates to the technical field of denitrification filter material preparation. The sulfur autotrophic denitrification filter material is prepared from polyethylene glycol, polyvinyl alcohol, sodium alginate, water, a sulfur autotrophic denitrification bacteria solution, elemental sulfur, biogas residue activated carbon, sodium thiosulfate, calcium chloride and boric acid. The invention also comprises a preparation method of the sulfur-based autotrophic denitrification filter material. According to the invention, a composite material based on nano modified graphene oxide is developed, a calcium carbonate material, pyrite, graphene oxide and denitrifying bacteria are adopted to prepare a granular composite autotrophic denitrification filter material with photocatalytic characteristics, and zero-valent iron and a biogas residue carbon micro-electrolysis material are combined; the GO + ZVI + biogas residue carbon + efficient denitrifying bacteria + photocatalysis five-in-one composite artificial wetland imitating type denitrification deep denitrification filter tank is constructed, the material cost is low, and the environmental pollution degree is small.

The invention discloses a salt-tolerant denitrifying bacterium and application of the salt-tolerant denitrifying bacterium, the salt-tolerant denitrifying bacterium is specifically Stutzerimonas degrandans and is named as Stutzerimonas degrandans BP, the preservation number of the salt-tolerant denitrifying bacterium is GDMCC No.64297, and the salt-tolerant denitrifying bacterium is preserved in the Guangdong Microbial Culture Collection Center on January 19, 2024. When the Stutzerimonas degrandans BP provided by the invention is used for biological nitrogen removal of high-salinity wastewater, the Stutzerimonas degrandans BP has relatively strong salt-tolerant denitrification capability, NO3 <->-N in a high-salinity water body can be effectively removed, no by-products such as NO2 <->-N and NH4 < + >-N are accumulated, and secondary pollution cannot be caused. Experimental results show that the Stutzerimonas degrandans BP provided by the invention is a facultative anaerobic bacterium, and is suitable for biological nitrogen removal in an anaerobic or anoxic environment. Under an anaerobic condition, high-efficiency salt-tolerant denitrification can be realized by virtue of relatively small biomass (OD600 = 0.15-0.25), so that the yield of sludge can be reduced while the operation cost of the process is reduced.

The invention relates to the field of municipal wastewater treatment, in particular to an expressway service area wastewater treatment device and method based on an AOOA-MBBR technology. The device comprises a first anoxic tank, a first aerobic tank, a second aerobic tank and a second anoxic tank which are communicated in sequence and are respectively filled with MBBR (Moving Bed Biofilm Reactor) filler, and the volume of the filled MBBR filler is used as an effective volume; aeration devices are respectively arranged in the first aerobic tank and the second aerobic tank; the first anoxic tank is used for inoculating hydrolytic bacteria and denitrifying bacteria; the first aerobic tank is used for inoculating hydrolytic bacteria, nitrifying bacteria and denitrifying bacteria; the second aerobic tank is used for inoculating nitrifying bacteria, and the second anoxic tank is used for inoculating hydrolytic bacteria and denitrifying bacteria; the second aerobic tank is communicated with the first anoxic tank through a return pipe, and the return pipe is provided with a return power assembly. The invention solves the problems of high operation cost, poor denitrification effect and high sludge yield due to the need of an external carbon source / electron donor in the existing treatment of the expressway service wastewater with the extremely low carbon-nitrogen ratio.

The invention belongs to the field of industrial wastewater treatment, and relates to an iron autotrophic denitrification coupling anaerobic ammonia oxidation combined enrichment culture device and method. Comprising a water inlet tank, a No.1 anoxic reactor, an intermediate tank and a No.2 anaerobic reactor, the water inlet tank is provided with a water outlet pipeline of the water inlet tank, and the water outlet pipeline of the water inlet tank is connected with the No.1 anoxic reactor; the anoxic reactor I is provided with a water outlet pipeline of the anoxic reactor I, and the water outlet pipeline of the anoxic reactor I is connected with the intermediate tank; the intermediate tank is provided with an intermediate tank water outlet pipeline, and the intermediate tank water outlet pipeline is connected with the No.2 anaerobic reactor; the No.2 anaerobic reactor is provided with a No.2 anaerobic reactor water outlet pipeline; the No.2 anaerobic reactor water outlet pipeline is connected with the No.1 anoxic reactor. According to the invention, collaborative culture of autotrophic denitrification bacteria and anaerobic ammonium oxidation bacteria can be realized, an autotrophic denitrification effect provides a certain amount of nitrite and iron ions to promote anaerobic ammonium oxidation reaction, and an anaerobic ammonium oxidation effect can effectively prevent an autotrophic denitrification tank body from being mineralized.

The present invention proposes a MABR membrane assembly, a MABR reactor, a MABR reactor operation method and a MABR biofilm optimization control method, which adopts a cross-flow working mode between horizontal membrane filaments and water flow to improve the mass transfer efficiency of the matrix and metabolites in the MABR biofilm; the composite structure membrane assembly is used to promote the complementarity and symbiosis of various microorganisms such as carbon removal aerobic bacteria, nitrifying bacteria, denitrifying bacteria and anaerobic ammonia oxidizing bacteria; different areas such as MABR membrane reaction area, pre-reaction area and water distribution and gas distribution area are constructed in the same reactor to complete short-range nitrification or partial short-range nitrification reaction, short-range denitrification reaction and anaerobic ammonia oxidation reaction respectively, so as to achieve efficient biological denitrification of sewage with low carbon-nitrogen ratio in a single-stage MABR reactor. At the same time, the optimization control method of the MABR biofilm solves the problems that the overly thick biofilm in the MABR reactor is not easy to be effectively washed, and the fixed gas washing frequency and intensity are difficult to simultaneously adapt to the biofilm washing and film removal requirements of membrane filaments in different parts.

The application discloses a method for efficient denitrification and decarburization of kitchen waste and sludge co-fermentation anaerobic digestion effluent, which removes part of COD and ammonia nitrogen in the influent sludge by using a first SNAD, and maintains a certain amount of free ammonia of a certain concentration due to the high concentration of ammonia nitrogen and the high pH of the influent, so as to maintain the inhibition effect on nitrifying bacteria and ensure the conversion of part of the ammonia nitrogen into nitrite nitrogen, and the high activity of anaerobic ammonia oxidation bacteria is ensured in the first SNAD by limiting the aeration amount, so that the ammonia nitrogen and nitrite can be further removed; the effluent enters a nitrification tank, and the ammonia nitrogen is nitrified into nitrate nitrogen under the condition of nitrifying bacteria and sufficient aeration amount, and then enters a denitrification tank, and the denitrification process is carried out under the condition of heterotrophic denitrifying bacteria and sufficient carbon source, so that most of the nitrate nitrogen in the system is converted into nitrogen gas and removed, finally, the clear liquid is discharged after being filtered by an MBR membrane in a membrane tank, so as to achieve the purpose of efficient denitrification and decarburization of kitchen waste anaerobic digestion effluent.

The invention discloses a device and a method for realizing double short-range coupling anammox deep denitrification and phosphorus recovery by using in-situ sludge fermentation. The method comprises the following steps: adding a calcium chloride solution into a rear-end anammox reactor of a two-stage PNA process to form recyclable phosphorus crystal substances such as Ca-P precipitate, and enabling anaerobic ammonium oxidation bacteria to be attached to the surface of the precipitate and to be enriched and intercepted in the anammox reactor; in the continuous forming process of anaerobic ammonia oxidation particles, unfermented waste activated sludge is added into the PNA technology, a carbon source is provided for short-cut denitrifying bacteria by means of slow hydrolysis and acidification of the waste activated sludge, and conversion from single-stage PNA autotrophic nitrogen removal to double short-cut coupling anammox synergistic nitrogen removal is completed. The anaerobic ammonium oxidation bacteria in the operated granular sludge can reach 12%, 73% of the sludge has the sludge particle size of 200 [mu] m or above, the total nitrogen removal rate is kept to be 90% or above, and most phosphorus exists in a recyclable form of Ca-P crystal substances.

The invention relates to the technical field of microorganisms and particularly discloses paenibacillus mucilaginosus as well as a microbial agent and application thereof. The preservation number of the paenibacillus mucilaginosus N-002 is CGMCC (China General Microbiological Culture Collection Center) No.32752, and the preservation number of the paenibacillus mucilaginosus N-002 is CGMCC No.32752. The paenibacillus mucilaginosus N-002 provided by the invention can produce a urease inhibitor and indoleacetic acid at high yield and has no denitrification effect, the urease inhibitor produced by the paenibacillus mucilaginosus N-002 can reduce the urease activity of soil, significantly reduce the ammonia emission and nitrous oxide emission of the soil, especially after a nitrogen fertilizer is applied, is beneficial to soil nitrogen element maintenance, improves the fertilizer efficiency of the nitrogen fertilizer, and has a good application prospect. Meanwhile, the influence of emission of ammonia and nitrous oxide on the environment is reduced; the strain has no denitrification effect, and can increase the proportion of non-denitrifying bacteria in soil and reduce the denitrification effect of the soil after being applied to the soil, so that the emission of nitrous oxide in the soil is reduced, and environmental protection is facilitated.

The present invention relates to the field of urban sewage treatment, and particularly relates to an urban sewage carbon-nitrogen-phosphorus synergistic deep treatment method based on a biological manganese oxide. The method comprises: S1, configuring an upward flow denitrification filter tank; S2, a starting stage, involving: taking a mixed solution of a secondary effluent and a secondary influent of an actual urban sewage treatment plant and manganese sulfate as the influent of the denitrification filter tank, with the manganese concentration being 3.0 mg / L, inoculating hydrolytic acidification bacteria, denitrifying bacteria, anaerobic ammonium oxidation bacteria and manganese oxidation bacteria into the denitrification filter tank, and gradually increasing the ratio value of the secondary influent to the secondary effluent in the mixed solution to 3%; and S3, a stable stage, involving: taking a mixed solution of the secondary effluent and the secondary influent of the actual urban sewage treatment plant and manganese sulfate as the influent of the denitrification filter tank, wherein the manganese concentration is 3.0 mg / L, the hydraulic retention time is 3-4 hours, and the backwashing period is 9-11 days. The present invention can synchronously and efficiently remove carbon, nitrogen and phosphorus from the secondary effluent of an actual urban sewage treatment plant at a low cost.

The invention discloses an enzyme source particle carrier and a preparation method and application thereof, and relates to the technical field of microbial carriers, the enzyme source particle carrier comprises denitrification inner layer particles, a nitride, activated carbon, water, a polyurethane prepolymer, an initiator and a catalyst; the denitrification inner layer particles comprise the following components: a denitrifying substance, activated carbon, a polyurethane prepolymer, an initiator and a catalyst. The enzyme source particle carrier provided by the invention enriches denitrifying bacteria and nitrifying bacteria at the same time, and adopts activated carbon to increase bacterial attachment sites in the particle carrier, so that the enzyme source particle carrier has better biological activity, mechanical strength and service life, and can better adapt to impact of complex water bodies, water quality and water quantity; and the nitrifying bacteria and the denitrifying bacteria are reasonably distributed in the enzyme source particle carrier, so that synchronous nitrification and denitrification are easily realized, and an efficient, energy-saving and carbon-source-saving denitrification process is achieved.

The invention discloses an autotrophic nitrogen removal and detoxification device and method for treating coking wastewater through two-stage low-oxygen short-cut nitrification, sulfur autotrophic denitrification and anaerobic ammonia oxidation, and belongs to the field of sewage treatment. The device comprises a water inlet tank, a sequencing batch reactor, a middle water tank and an up-flow anaerobic sludge blanket reactor. The method comprises the following steps: enabling the coking wastewater which is subjected to carbon capture and contains ammonia nitrogen and thiocyanate to enter a sequencing batch reactor, oxidizing the ammonia nitrogen into nitrite under a limited oxygen condition, and generating nitrogen, sulfate and ammonia nitrogen from the thiocyanate and the nitrite by autotrophic denitrifying bacteria; reaction effluent mixed with coking wastewater enters an upflow anaerobic sludge blanket, and anaerobic ammonium oxidation bacteria convert ammonia nitrogen and nitrite into nitrogen and generate a small amount of nitrate; and the residual nitrate, nitrite and thiocyanate are continuously and thoroughly removed through the sulfur autotrophic denitrification effect. The method provides a new idea for economical and efficient autotrophic nitrogen removal and detoxification of the coking wastewater containing thiocyanate and ammonia nitrogen.

The present invention provides an autotrophic denitrification filter material, comprising three types of materials A, B, and C, and the weight ratio of each material is A: B: C = (10-15): (1-2): 1, wherein A is a composite denitrification ingredient, including ferrous sulfide, sulfur, sodium thiosulfate and iron powder; B is an adhesive; and C is a molecular sieve treated with a microbial culture solution. The high efficiency of the autotrophic denitrification filter material with high efficiency denitrification provided by the present invention is mainly based on the following two options: first, the filter material belongs to a multivalent composite sulfide-iron coupling denitrification scheme, and the diverse electron donors of the autotrophic denitrifying bacteria have synergistic synergy; second, the autotrophic denitrifying bacteria culture solution is pre-placed in the gap of the molecular sieve, which can be slowly released, ensuring that the autotrophic denitrifying bacteria can still maintain growth when the environment is subjected to various shocks. The autotrophic denitrification filter material provided by the present invention has a simple preparation process, is easy to operate during application, and can maintain high efficiency in denitrification capacity.

The invention relates to the field of sewage treatment, and discloses a sewage treatment method based on desulfurization and denitrification, which comprises the following steps: S1, magnetic flocculation-electro-catalysis pretreatment: adding a polyaluminum chloride-magnetic powder composite flocculant into sewage through a magnetic flocculation reactor to form a magnetic floc, removing suspended matters through a permanent magnetic separation device, and then entering an electro-catalysis oxidation pond, carrying out electrolysis by taking titanium-based lead dioxide as an anode and active carbon fiber as a cathode; and S2, performing synchronous desulfurization and denitrification on the three-dimensional electrode fluidized bed, feeding pretreated effluent into a three-dimensional electrode fluidized bed reactor, filling activated carbon particles as a third electrode, and adding a composite flora of thiobacillus and denitrifying bacteria. The efficient removal of sulfides, total nitrogen, total phosphorus and chemical oxygen demand in the sewage is realized through a multi-stage synergistic process of magnetic flocculation-electrocatalysis pretreatment, synchronous desulfurization and denitrification of a three-dimensional electrode fluidized bed, deep denitrification and dephosphorization of a denitrification filter tank and catalytic ozonation-membrane separation combined deep treatment.

The invention belongs to the technical field of sewage treatment, and particularly relates to a low-carbon-nitrogen-ratio sewage short-process nitrogen and phosphorus removal system and method. The method comprises the following steps: S1, capturing a carbon source and synthesizing an internal carbon source; s2, synchronous denitrification phosphorus removal; S3, layered nitrification treatment and internal carbon source reutilization; and S4, material circulation. According to the invention, denitrifying phosphorus-accumulating bacteria are used as an active carbon source carrier, and soluble VFAs which is easily fight for by common heterotrophic denitrifying bacteria is converted into solid PHA in the bacteria in a carbon source capture and internal carbon source synthesis tank; according to the method, the total nitrogen and the total phosphorus in the sewage with the low carbon-nitrogen ratio can be efficiently and deeply removed, and meanwhile, the method has the outstanding advantages of being low in energy consumption, small in sludge yield and small in occupied area.

The invention discloses a kitchen waste wastewater resourceful treatment process, and belongs to the technical field of kitchen waste resourceful utilization. The treatment process provided by the invention comprises the following steps: adding a ferrate composite oxidant into the kitchen waste wastewater to carry out alkali adjustment and oxidation synchronous treatment, adding biological iron or chemical polyferric sulfate to react, and then adding denitrifying bacteria to carry out denitrification treatment. The treatment process provided by the invention is simple in operation steps and low in treatment cost, and is a kitchen waste resourceful treatment process capable of turning waste into wealth. The COD (Chemical Oxygen Demand) of the treated kitchen waste wastewater is greater than or equal to 50000 mg / L, the content of total nitrogen and total phosphorus is obviously reduced, the content of small molecular organic matters in water is increased, the biodegradability is improved, the requirement of a sewage treatment plant for supplementing a carbon source is met, and the treated kitchen waste wastewater can be used as a carbon source for supplementing the carbon source for the sewage treatment plant.

The invention belongs to the technical field of biological filters, and relates to an anaerobic denitrification reactor and a method for accelerating degradation of nitrate nitrogen in micro-polluted water, and the reactor mainly comprises a biological filter, a water inlet tank, a peristaltic pump and a water outlet tank. The biological filter is composed of a filler composed of a modified polyvinylidene fluoride hollow fiber membrane and a high-temperature treatment iron wire, and the wastewater treatment process of the biological filter comprises a biofilm culturing stage and a domestication stage. In the biofilm culturing stage, the activated sludge enters the biofilter along with inlet water, and is loaded on the surface of membrane filaments to form a layer of biofilm; in the domestication stage, the wastewater slowly enters a biological filter and stays in a reactor, iron and nitrate nitrogen in the wastewater are subjected to denitrification reaction under the action of denitrifying bacteria, and the purpose of rapidly removing the nitrate nitrogen is achieved. According to the method, nitrate nitrogen in the wastewater can be rapidly reduced under the condition of not additionally adding a carbon source, so that the treatment process is low-carbon, aeration is not needed, energy is saved, and the method is suitable for industrial popularization.

The invention relates to a composite ecological filler for enhancing in-situ denitrification of a river water body, a percolation system and application. The composite ecological filler is composed of an anoxic denitrification filler and a transition regulation filler or composed of an aerobic nitrification filler, an anoxic denitrification filler and a transition regulation filler; the aerobic nitrification filler comprises an inorganic mineral matrix denitrification filler, biological ceramsite, a mineral-based slow-release functional material and a microbial immobilization functional carrier; the anoxic denitrification filler comprises a sulfur-based composite electron donor material, a slow-release organic carbon source material, a zero-valent iron-based environmental remediation material and denitrifying bacterium embedding gel; the transition regulation and control filler comprises a multifunctional water treatment filter material, activated carbon and an environment response type functional microbial carrier. The invention also provides application of the composite ecological filler and a percolation system, solves the problem that the traditional denitrification filler cannot cooperatively support nitrification / denitrification due to single function, and also solves the problem that the fixed ratio of the traditional denitrification filler is difficult to adapt to dynamic fluctuation of water quality.