3841results about How to "Will not cause secondary pollution" patented technology

The invention discloses a super-hydrophilic and underwater-super-oleophobic oil-water separation mesh membrane, and a preparation method and an application thereof. According to the method, fabric mesh with a specification of 100-300 meshes is subjected to ultrasonic cleaning, and is air-dried under normal temperature; a hydrophilic polymer water-sensitive agent and a cross-linking agent are dissolved in water according to a ratio of 1:9-9:1; the mixture is well mixed by magnetic stirring, such that a solution with a concentration of 1-99% is prepared; nano-sol is prepared with a sol-gel method; the solution and the nano-sol are prepared into a mixed solution with a concentration of 1-99%, and the solution is well dispersed through ultrasonic dispersion; the mesh is soaked in the mixed solution and is vertically lifted, or the mesh is directly sprayed by using a high-pressure spraying gun; and the mesh is bake-dried, such that the super-hydrophilic and underwater-super-oleophobic oil-water separation mesh membrane is obtained. Contact angles of the super-hydrophilic and underwater-super-oleophobic oil-water separation mesh membrane with water and oil in air are both 0 DEG, and the membrane is super-hydrophilic. Under water, the contact angle of the membrane with oil drops is larger than 150 DEG, and the membrane has an oil drop low adhesion characteristic. The mesh membrane provided by the invention can be used in oil-water mixture separation and oil-containing sewage processing.

The invention discloses a heavy metal absorbent and a preparation method and use thereof. The heavy metal absorbent is prepared by using an inorganic mineral modified by a surfactant as a carrier and loading organic complexing agent on the carrier, wherein the inorganic mineral is bentonite, kaolin, kieselguhr, zeolite, aluminum oxide or iron oxide; the surfactant is cationic surfactant or nonionic surfactant; and the organic complexing agent is a compound containing a sulfydryl and an amino. The heavy metal absorbent has the advantages of stable performance, environment friendliness, high absorption capacity, high selectivity, convenient post-recovery treatment and the like. The absorption capacities of cadmium, mercury lead and other heavy metals all exceed 100mg/g, and the heavy metal absorbent can achieve good treatment effect in treatment of water and soil environments polluted by heavy metals.

The invention discloses an oxidized graphene-modified super-hydrophilic super-oleophobic oil-water separation film and a preparation method and application thereof. The method comprises the following steps: mixing a hydrophilic polymer water-sensitive agent and a cross-linking film-forming agent according to a ratio of 1:9-9:1, dissolving the mixture and nano-silica sol in water according to a mass ratio of 1:9-9:1, magnetically stirring uniformly to prepare a 1-99% solution, adding 0.5-1 percent of oxidized graphen as an inorganic cross-linking agent, and ultrasonically and uniformly dispersing; ultrasonically cleaning a fabric silk screen with the particle size of 100-300 meshes, drying at normal temperature, forming a film on the silk screen in a spraying, dip-coating or spinning manner, drying and cross-linking, thus obtaining the hydrophilic and underwater super-oleophobic oil-water separation film. The oil-water separation film has excellent swelling resistance and mechanical property after graphene cross-linking modification, has a contact angle of 0 degree with both water and oil in air and has high super-hydrophilic property; the film has a contact angle of 150 degrees with oil drops under the water and has the low-adhesion characteristic to oil drops. The film can be applied to separation of oil-water mixtures and treatment of oil-containing sewage.

The invention relates to a carbon supported catalyst for ozone oxidation, and a preparation method and a use thereof. The carbon supported catalyst is composed of an active carbon supported Fe, Cu, Ni or Mg transition metal active component and a Ce, La or K cocatalyst. The catalyst has a very high catalysis activity against non-degradable organic wastewater, allows the COD removal rate to reach above 55% and the biodegradability of the wastewater to be improved to above 0.30, has the advantages of long service life, simple preparation, no secondary pollution, containing of no precious metals, and low production cost, and is very suitable for the use in the industrialized production.

The invention discloses a liquid compound microbial fertilizer containing polyglutamic acid, and a preparation method and an application thereof, and belongs to the field of compound microbial fertilizers. Bacillus megaterium, bacillus thuringiensis and bacillus amyloliquefaciens are prepared into a bacteria liquid by liquid fermentation, and then the bacteria liquid is mixed with compound nutrients and a gamma-polyglutamic acid according to the mass ratio of 1:1:0.05-0.1 to be prepared into the efficient liquid compound microbial fertilizer. On the basis of good phosphorus dissolving capability of the bacillus megaterium, good insect resistance of the bacillus amyloliquefaciens and good organic matter degrading capability of the bacillus amyloliquefaciens, the purposes of more excellent fertilizer efficiency and lower water consumption are achieved under the characteristics of water retention, fertilizer preservation, and no environmental pollution of the gamma-polyglutamic acid, therefore, the scientific and reasonable matching of the compound fertilizers is formed.

The invention relates to an alkali activated solidification and stabilization treatment method of refuse incineration fly ash. The method comprises the following steps of: A: carrying out a pretreatment on the refuse incineration fly ash; B, then adding water and heavy metal stabilizing agents and fully stirring so as to fully integrate soluble heavy metals in the fly ash with the heavy metal stabilizing agents and then realizing a mineralization stability; C, adding alkali activating agents into fly ash slurry after finishing the B step and fully stirring; D, carrying out a heating treatment on a water bath after finishing the C sep, controlling a heating temperature and a heating time, and aperiodically stirring so as to uniformly heat the fly ash slurry materials; and E, finally shaping and maintaining the mixed materials so as to further blockade mineralized heavy metals in the fly ash and simultaneously solidify dioxin in the fly ash, and finally realizing the harmless solidification and stabilization of the fly ash. According to the method provided by the invention, the gelling reaction of the fly ash is generated by using the alkali activating agents to activate the fly ash activity only on a base of regulating the fly ash activity, and the double-effect stabilization of the fly ash is obtained by simultaneously supplementing the heavy metal stabilizing agents; moreover, the method has the advantages of low cost, good effect, low increase-volume rate and no secondary pollution.

The invention discloses a removing method of ammonia nitrogen from water through ozone catalytic oxidation, which comprises the following steps: one, arranging activator in reactor; two, proceeding ozone disperse-gas in the reactor; three, controlling contacted time of ozone and waste water and activator and waste water with full of ozone; leading the disposing water out of reactor; getting yielding water. This invention can either dispose high concentrate ammonia nitrogen waste water, or low concentrate ammonia nitrogen waste water, and non-cause twice pollution.

The invention provides a self-cleaning device of a full-automatic washing machine, which is used for solving the problem of secondary contamination on clothes caused by clustered dirt in the interlayer between the water storage tank and the dehydration tank, and in the interlayer between the dehydration tank bottom and the impeller bottom of the washing machine. The interlayer between the water storage tank and the dehydration tank is provided with a plurality of clean balls 3, and a plurality of clean balls 5 are arranged between the dehydration tank bottom and the impeller bottom. When the washing machine washes or rinses, the clean balls perform friction with the water storage tank wall, the dehydration tank wall, the impeller bottom and the dehydration tank bottom to clean the dirt inthe positions, and simultaneously the clean balls are self cleaned through mutual collision and friction. By adopting the way in which the water storage tank rotates along with the dehydration tank when dehydrating and the storage tank wall or bottom is provided with a groove or a piston cylinder (to lead the clean balls to drop into the groove or the piston cylinder when dehydrating), the clean balls do not generate friction with the dehydration tank, thus prolonging the service life of the clean balls and saving energy; and the adoption of the way in which the water storage tank rotates along with the dehydration tank when dehydrating can decrease the width of the interlayer between the water storage tank and the dehydration tank to save water.

The present invention relates to environmental protection engineering technology, and is especially sludge drying and incinerating treatment process. The present invention has effective utilization of heat energy, no exhaust of harmful gas and bad smell, no exhaust of dangerous clinker, simple structure and high burning efficiency of the sludge incinerating system, no need of auxiliary fuel and other advantages.

The invention relates to a method for preparing a chitosan/organo montmorillonite nanometer composite material, belonging to the technical field of new technologies and new materials. The method comprises the following steps: organo montmorillonite is added according to a certain proportion to a chitosan solution with a mass percentage of 0.05 percent to 0.4 percent and a pH value of 4.5 to 5.5; the organo montmorillonite and the chitosan solution are stirred and react at 50 DEG C to 60 DEG C for 10 hours to 16 hours; the reacted solution is evaporated under a water-bath condition of 80 DEG C to 95 DEG C until no obvious liquid exists; the obtained solid is deuibuzed, dispersed, filtered and washed to be neutral; and the obtained solid is dried, ground and screened at 80 DEG C to 95 DEG C so as to obtain the chitosan/organo montmorillonite nanometer composite material. The invention has the advantages of little water consumption and wild reaction condition, and the prepared chitosan/organo montmorillonite nanometer composite material is easy to recycle after being used as an adsorbent, has no secondary pollution, is beneficial to environmental protection and can be applied in fields, such as water treatment, preservatives, antibacterial agents, and the like.

The invention relates to a method for comprehensively recovering valuable metals from electroplating waste mud. The method comprises the following steps of: leaching valuable metals contained in the electroplating waste mud by dilute sulphuric acid, and filtering and separating out acid-leaching slag and a filtrate; replacing copper ions in the filtrate by metallic iron, and filtering and separating copper powder and a filtrate; adding an alkali solution in the filtrate, adding a polymeric flocculant, controlling the pH value of the solution and reacting, and filtering and separating ferric hydroxide and a filtrate; adding the alkali solution in the filtrate, controlling the pH value of the solution and reacting, and filtering to obtain a chromium precipitate and a filtrate; adding the alkali solution in the filtrate, controlling the pH value of the solution, and converting zinc and nickel in the solution to nickel carbonate and zinc carbonate; and dissolving a nickel-zinc coprecipitate by the alkali solution, and filtering and separating out nickel carbonate and a sodium zincate solution, and concentrating and crystallizing the sodium zincate solution to obtain sodium zincate. The method disclosed by the invention is easy to control process conditions, low in treatment cost, and easy to realize large-scale production; the purpose of comprehensively recovering valuable metals is achieved by implementing harmless and resourceful treatment for the electroplating waste mud; and the recovery rate of copper is greater than 95%.

The invention discloses a carbon-based composite material for arsenic and cadmium polluted soil remediation and application of the composite material. The carbon-based composite material disclosed by the invention is prepared by the steps: taking crop straws as raw materials, and charring to prepare charcoal; mixing with an iron salt solution according to a certain solid-liquid ratio, regulating the pH value of the solution in the process so as to realize coprecipitation of the two materials; performing pyrolysis, thereby obtaining the carbon-based composite material. The carbon-based composite material prepared in the invention is applied to arsenic and cadmium compound polluted soil, and methods such as turning over, watering and the like are combined, so that the content of arsenic and cadmium in an effective state can be obviously reduced; therefore, the arsenic and cadmium in the soil can be transferred to a direction with low biotoxicity and migration, the physicochemical properties of the soil can be improved to a certain degree, and the composite material is suitable to be applied to multiple types of soil. The arsenic and cadmium ions in a water body can be effectively removed, the preparation process is simple in operating steps, and the material is wide in source, low in production cost and environment-friendly.

The invention discloses a microorganism deodorant and a preparation method thereof. The microorganism deodorant has the following strain composition: 106-109/mL of Lactobacillus acidophilus, 106-109/mL of Bacillus pumilus, 106-109/mL of Bacillus subtilis, 105-107/mL of Pseudomonas fluorescens, 105-107/mL of Rhodopseudomonas palustris, 104-106/mL of Bantu Brettanomyces, 104-106/mL of common Candida albican, 104-106/mL of Penicillium expansum, 104-106/mL of Rhizopus oryzae, 104-106/mL of Trichoderma viride, 104-106/mL of Streptomyces Microflavus and 104-106/mL of Streptomyces griseus. Accordingto the microorganism deodorant, the release amount of obnoxious gas can be effectively lowered, and the technical support is provided for effectively processing fetor in livestock and poultry farms and protecting environment.

The invention belongs to the technical field of separating film materials, and discloses an adjustable and controllable ultrathin two-dimensional nano g-C3N4 film, and a preparation method and application thereof. The preparation method comprises the following steps of performing heat treatment on dicyandiamide or cyanurtriamide under an inert atmosphere to obtain caked g-C3N4; pulverizing the caked g-C3N4 and calcining under an air atmosphere to obtain g-C3N4 powder; dispersing the g-C3N4 powder in solvent to obtain g-C3N4 two-dimensional nanosheet solution; adding electrolyte solution for modifying; depositing a g-C3N4 two-dimensional nanosheet on a porous carrier of which the pore diameter is greater than 200 nanometers to form a two-dimensional g-C3N4 ultrathin film; and drying to remove the solvent so as to obtain the adjustable and controllable ultrathin two-dimensional nano g-C3N4 film loaded on the porous carrier. The g-C3N4 film is high in water permeability and high in separation efficiency, and has a wide application prospect.

The invention relates to a method for processing reverse osmosis concentrated water, which comprises the steps of: adding oxidant into reverse osmosis concentrated water to be processed to perform an oxidizing reaction to oxidize organic matters in the concentrated water into carbon dioxide and water, and directly. discharging wastewater after oxidation Compared with the prior art, the method is simple in processing, easy to implement, low in investment and cost of processing facilities, lower in raw water COD, small in dosage of the oxidant and low in processing cost; and in addition, the method is green and environmentally-friendly and does not cause secondary pollution.

The invention provides a modification method of a ceramic membrane and a modified ceramic membrane. The modification method of the ceramic membrane comprises the following steps: performing surface treatment on the ceramic membrane to obtain a fresh ceramic membrane; coating the surface of the ceramic membrane with a silane compound through an impregnation method or a sedimentation method; performing thermal treatment on the coated ceramic membrane under a protective atmosphere, naturally cooling to obtain the modified ceramic membrane after the modification. The modification method of the ceramic membrane provided by the invention has advantages that the modification process is simple, the raw material cost is low, and secondary pollution on the environment can be avoided in the modification process; compared with the common organic modification material, the modified ceramic membrane prepared through modification has the features of high long-term stability, strong acid-base resistance, and strong hydrophobic property; and the modified ceramic membrane can be extensively applied to sea water desalinization, oil-water separation, wastewater treatment and other fields.

The invention provides a high-efficiency denitrification mixed bacterial agent and application thereof, and a novel bacterial strain capable of efficiently denitrifying obtained by screening. The high-efficiency denitrification mixed bacterial agent consists of CCTCC No:M 2010001 and nitrosobacteria CCTCC No:M 2010002. The invention mainly has the advantages of providing a high-efficiency denitrification mixed bacterial agent, greatly improving the efficiency for treating sewage, not causing secondary pollution, and having significance for improving ecological environment.

The invention discloses simultaneous removing device and method of various pollutants by an electrocatalytical oxidation combining lime-gypsum method. The device comprises a spraying and cooling device, an electrostatic enhancement reactor, a Venturi device, a double-circulation integrated absorption tower of various pollutants and a wet type electrostatic defroster, wherein after smoke is cooled by the spraying and cooling device, the smoke enters the electrostatic enhancement reactor and is subjected to corona discharge processing in a corona discharge area formed in the electrostatic enhancement reactor; the processed smoke enters the double-circulation integrated absorption tower of various pollutants and is sprayed to remove dust and absorb in the absorption tower; and the purified smoke sequentially enters a corrugated plate defroster and the electrostatic defroster on the upper part of a spraying tower so as to remove aerosol in the smoke. The invention has the advantages that various pollutants can be simultaneously removed, and meanwhile, the pollution of fine granules and the aerosol can be effectively controlled; various pollutants can have higher removal efficiency; and the removal and the absorption of by-products cannot cause secondary pollution to environment.

The invention relates to flame-retardant synthetic paper. The flame-retardant synthetic paper comprises polypropylene resin, polyethylene resin, an inorganic filler, a coupling agent, an antistatic agent, a lubricant and a coloring agent. The flame-retardant synthetic paper is characterized in that the flame-retardant synthetic paper further comprises a flame retardant. Raw materials and the partsby weight thereof are as follows: 100PHR of polypropylene resin, 20-90PHR of polyethylene resin, 50-300PHR of inorganic filler, 1-8PHR of coupling agent, 1-5PHR of antistatic agent, 0.5-5PHR of lubricant, 5-20PHR of coloring agent and 5-35PHR of flame retardant. Blending, mixing, rubberizing, molding by a calendar, leading out by a leading roller, embossing, cooling, corona treatment and windingare carried out on all the raw materials of the flame-retardant synthetic paper for preparing a product. The flame-retardant synthetic paper has the flame-retardant function and is difficult to burn.Even the flame-retardant synthetic paper is incinerated in a high-temperature incinerator, the flame-retardant synthetic paper can not produce harmful gas, not cause secondary pollution to society andhuman beings and be in line with the requirements of environmental protection.

The invention discloses a dejecta treating method and system containing following steps: firstly liquid-solid separation processing to the dejecta by liquid-solid separation device; entering the separated dejecta to an adjusting pool with a wind blending system, then discharging the dejecta in adjusting pool by sewage feeding system of underground pump room, then flocculating-dehydrating treatment of transported dejecta from adjusting pool by flocculating-dehydrating apparatus. Setting a wind blending system in the adjusting pool to make the dejecta fluid always in blending state by forming multiple-point shocks, shaking and agitating effectly overcomes the deposition of the loam, stacking and dejecta fluid surface scab. The flocculating injecting medicine mixing process can greatly improve the use life of pump. It achieves the recovery of resource by anaerobic/biochemical treatment of filter solution generated by flocculating-dehydrating treatment. It reduces the secondary pollution and achieves the harmless treatment of dejecta.

The invention discloses a clay-based heavy metal thermal curing agent and its method for curing heavy metal. The clay-based heavy metal thermal curing agent comprises, by weight, 40-60% of clay, 5-15% of iron oxide, 20-30% of fly ash and 15-25% of stone flour. The method provided by the invention comprises the following steps of: uniformly mixing the clay-based heavy metal thermal curing agent and a heavy metal pollutant according to the mass ratio of 1: 5-10: 1, carrying out extrusion moulding on the mixed sample at the pressure of 300-1000Mpa, and sintering the molded sample at the temperature of more than 800 DEG C for 2-5 h to obtain a recycled material. According to the invention, heavy metal is coalesced by absorption of clay to heavy metal; fly ash and stone flour are used to fully mix heavy metal with the clay-based heavy metal thermal curing agent during the mixing process; iron oxide and alumina components in the clay-based heavy metal thermal curing agent react with heavy metal at the temperature of more than 800 DEG C for high-temperature fusion glass transition so as to form a spinel structure; and heavy metal in the form of spinel and feldspar crystal structural components is fixed in the heavy metal thermal curing agent to form the recycled material.