Disclosed is a high-durability protective layer compound pile. The structure of high-durability protective layer compound pile comprises: the compound pile is composed of a core bearing structure which is wrapped with a high-durability protective layer, the material of the protective layer adopts plastic or other modified products, asphalt and mortar or concrete, alkali activated material and the mortar or the concrete, geopolymer and the mortar or the concrete, reactive powder concrete, fiber reinforcement concrete base material, and resin mortar or concrete; The manufacturing and the construction can adopt six methods: firstly, site-casting can be performed to the protective layer and a core structure simultaneously; secondly, after the site-casting is performed to the protection wall of the protective layer, the site-casting is performed to the site-cast protective wall; thirdly, prefabrication is performed to the sleeve of the protective layer, and site-casting is carried out to the prefabricated sleeve of the site cast core structure of the sunk tube; fourthly, prefabrication is performed to the sleeve of the protective layer, the sleeve is taken as an outer mould plate to prefabricate the prefabricated sleeve of the core structure; fifthly, prefabrication is performed to the core structure, the core structure is taken as an inner mould plate to prefabricate the prefabricated sleeve of the core structure; and sixthly, site-casting is implemented to the protective layer and the core structure simultaneously.