The invention relates to a
resource utilization and alkali liquor regeneration cycle method for
silicon-rich alkali liquor in a two-step alkali-process aluminum extraction process of high-
alumina fly ash. The method comprises the following steps: firstly, introducing a gas containing
carbon dioxide into the
silicon-rich alkali liquor, enabling
silicate in the
silicon-rich alkali liquor to react to generate a hydrated
silicon dioxide precipitate, and then carrying out
solid-liquid separation to obtain a hydrated
silicon dioxide product and a
sodium carbonate solution; adding
calcium-based alkali into the
sodium carbonate solution for reaction to generate a
sodium hydroxide solution and
calcium carbonate precipitate, and then performing
solid-liquid separation to obtain a regenerated
sodium hydroxide solution; and finally, returning the obtained regenerated
sodium hydroxide solution for the pre-desilicication process of the high-
alumina fly ash. According to the method, waste silicon resources are converted into high-value products, closed-loop circulation of the alkali liquor is achieved, the silicon
recovery rate can reach 98% or above, the alkali regeneration efficiency exceeds 90%, the consumption of fresh alkali and
discharge of alkali
wastewater are remarkably reduced, and the overall
economic benefits and environmental friendliness of the technology for extracting aluminum from high-
alumina fly ash are improved.