2134 results about "FORMALDEHYDE SOLUTION" patented technology

The invention discloses a micro-crack self-repairing microcapsule, which comprises a capsule core and a capsule wall, wherein the capsule core comprises the following ingredients in part by weight: 10 to 60 parts of isocyanate derivative, 0.1 to 10 parts of capsule core diluent and 2 to 40 parts of cosolvent; and the capsule wall comprises ingredients with the following mol ratio: urea: formaldehyde solution, prepolymer=1: (1.0-4.0): (2.0-6.0), wherein the prepolymer is formed from the ingredients with the mol ratio: isocyanate derivative: cyclohexanone: chain extender=1: (2.0-5.0): (0.3-3.0). The invention also discloses a micro-crack self-repairing anti-corrosion coating utilizing the capsule. The micro-crack self-repairing microcapsule is free from additionally adding a repairing catalyst or an initiator, can realize completely automatic repairing function, can be widely applied to the protection field of a metal surface coating in a wet environment, and solves the problems that the contact probability between functional filling material flowing into cracks in the intelligent anticorrosion coating and the catalyst or the initiator is small.

A method for preparing alkali lignin modified phenol-formaldehyde resin comprises the following steps: phenol, a first batch of formaldehyde solution, alkali lignin, metal oxide and dilution water are added into a reactor; a second batch of formaldehyde solution is added into the reactor; and a third batch of formaldehyde solution and a first batch of alkaline solution are added, formaldehyde trapping agent and a second batch of alkaline solution are added, and then material is discharged after cooling. The invention adopts the copolymerization technique to prepare an alkali lignin phenol formaldehyde adhesive, lignin and the phenol are added simultaneously, obtained hydroxymethylated lignin is reacted with hydroxymethyl phenol, a small part of the obtained hydroxymethylated lignin participates in the polycondensation of the hydroxymethyl phenol to form a main chain, and a large part of the obtained hydroxymethylated lignin forms branch chains through graft copolymerization, therefore, the lignin is introduced into a molecular chain and the aim of modifying phenol-formaldehyde resin is achieved. The invention can replace the use of 30-50 percent of the phenol, realizes stable and easy reaction control and easy industrial production; the bonding strength satisfies the requirements of national I-level plates; formaldehyde release reaches E0 level; therefore, the invention provides a new approach to the development of environment-friendly biomass-based wood adhesive and resource utilization of waste materials.

The present invention provides a fluorylbis-benzoxazoly monomer and a preparation method thereof. In a container with a mixer, a cooling pipe and a thermometer, formaldehyde solution of 37 percent and an organic solvent are added according to a weight ratio of (1 to 4) to 1, primary amine is added into the formaldehyde solution at the temperature between 5 DEG C and 10 DEG C, the reaction solution is continuously mixed for reaction for 1 to 4 hours and heated to be between 70 DEG C and 120 DEG C, an organic solvent with dissolved bisphenol fluorine is added, weight percentage of the bisphenol fluorine in the organic solvent is 20 percent to 50 percent, the molar ratio of the bisphenol fluorine and the primary amine is (1 to 2) to 3; the reaction continues to last for 4 to 10 hours at the temperature between 70 DEG C and 120 DEG C, and ultimately the fluorylbis-benzoxazoly monomer can be acquired through post processing. Because of the fluorine structure, the rigidity of molecular chains of the product can be enhanced, and the glass-transition temperature of resin can be improved; because of the enhanced nonpolarity of molecules, the hygroscopicity of the resin is lowered, thereby improving the wet-hot aging performance of the resin is greatly improved.

The invention relates to a method for preparing nitrogenous graphitized hollow carbon microspheres, which relates to a method for preparing hollow carbon microspheres. The method disclosed by the invention aims to solve the technical problem that in the existing method for preparing nitrogenous graphitized hollow carbon microspheres, because a template agent is utilized, the preparation process is complicated, and the cost is increased. The method comprises the following steps: adding melamine powder and a formaldehyde solution into deionized water, and after heating for reaction, obtaining reaction liquid; then, transferring the reaction liquid into a reaction kettle, and after carrying out hydrothermal reaction on the reaction liquid, obtaining melamine resin microspheres; and putting the melamine resin microspheres into a quartz tube type furnace, and heating the melamine resin microspheres so as to split the melamine resin microspheres, thereby obtaining nitrogenous graphitized hollow carbon microspheres. The average diameter of the nitrogenous graphitized hollow carbon microspheres is 1-5 microns; and by using the method, no template agent and no catalyst are required to be added in the preparation process, the preparation process in a synthesis method is simple, the cost is low, and microspheres are easy to be performed mass production and can be used as electrode materials or carrier materials of active substances of electrodes in the fields of electrochemical super capacitors, lithium ion batteries, fuel cells and the like.

The invention discloses a magnetic phase transition microcapsule and a preparation method thereof. Nanometer magnetic powder is filled in a microcapsule material to form a shell, and a core material is wrapped in the shell. The magnetic phase transition microcapsule is prepared by the following steps: firstly, adding urea to a formaldehyde solution to dissolve or adding melamine to the formaldehyde solution, or adding the urea to the formaldehyde solution and adding melamine after fully dissolving the urea; then, reacting under stirring at a constant temperature to obtain a prepolymer solution; adding the nanometer magnetic powder to the prepolymer solution and dispersing the solution under ultrasound; dissolving an emulsifying agent in the water, adding an organic phase transition material and cutting and emulsifying the organic phase transition material at a high speed to prepare an emulsion; and uniformly mixing the emulsion and the prepolymer solution after ultrasonic dispersion and reacting under stirring at the constant temperature to obtain the magnetic phase transition microcapsule. The magnetic phase transition microcapsule has magnetism and can reach specific parts under the guide of an external magnetic field while the magnetic phase transition microcapsule is applied to a latent heat type functional fluid so as to control the flow of the fluid.

The invention discloses a preparation method of copper-coated tungsten composite powder, belonging to the technical field of powder metallurgy. Corresponding tungsten powder and blue vitriod are employed according to the weight ratio of composite powder to be prepared and the tungsten powder is pre-treated; copper sulphate and seignette sol are dissolved into solution; bipyridine is added and NaOH is used to adjust pH value to 12-14; an appropriate amount of formaldehyde solution and the tungsten powder are added; the mixture is heated and then stirred continuously in constant-temperature bathing at 30-60 DEG C until the tungsten powder is red; the tungsten powder is washed, dried, reduced and annealed, thereby obtaining copper-coated tungsten composite powder. The preparation method of copper-coated tungsten composite powder has wide application range and is applicable to tungsten-powder coating coppers with different finenesses and shapes. The preparation method of copper-coated tungsten composite powder prepares copper-coated tungsten composite powder in different content ratios according to different requirements. The copper-coated tungsten composite powder obtained by the method of the invention has excellent sintering activity, thereby improving the combination property of tungsten copper alloy.

The invention discloses a fluorescent probe for detecting formaldehyde as well as a preparation method and an application of the fluorescent probe. The structure of the fluorescent probe is presented by a formula I (shown in the specification). A kit for detecting formaldehyde comprises a compound represented by the formula I and a solvent. The ''off-on'' type formaldehyde probe for naphthalimide dyes and the specific detection kit have good responses to a formaldehyde solution, can be used for detecting formaldehyde in cells and have the characteristics of being simple and convenient to operate, low in cost, sensitive in response and easy to popularize and apply.

The invention discloses a method for synthesizing dihydroxy diphenyl methane with high 4, 4' site content by one stage process, relates to a method for synthesizing bisphenol F with high 4, 4' site content and provides a method for synthesizing dihydroxy diphenyl methane with high 4, 4' site content by one stage process, which reduces dosage of phenol and production cost and has yield of more than 60 percent. The method comprises the following steps: adding the phenol into a container provided with an electric stirrer, a thermometer and a reflux condensation tube, heating the phenol in water bath, adding phosphoric acid after the phenol is fully melted, stirring the mixture, and fully mixing the phenol and the phosphoric acid to obtain mixed solution; adding formaldehyde solution into the mixed solution, separating acid after reaction, neutralizing an oil phase by sodium bicarbonate, separating water and an organic phase, decompressing and distilling the mixed solution, removing the phenol and the water, and cooling, crystallizing and filtering the mixed solution to obtain products.

The invention discloses a process for producing hexamethylol melamine, belonging to the field of production and preparation of hexamethylol melamine. The process comprises the steps such as mixing, reaction and crystallization, centrifugalization, evaporation and the like, wherein evaporation auxiliary formate is added when in evaporation so as to change the relative volatility of formaldehyde and water. Furthermore, the process for producing the hexamethylol melamine together with a formaldehyde device can also be used for co-production, so that the concentration of the produced formaldehyde solution is improved to 45wt%-55wt%. The produced hexamethylol melamine provided by the invention has the advantages of small amount of waste water and low formaldehyde content, namely, if 1 ton of hexamethylol melamine is produced, 1 ton of waste water containing 0.84wt% of formaldehyde is discharged. After the process provided by the invention and the formaldehyde device are used for co-production, the formaldehyde production cost and transportation cost are reduced, and the comprehensive cost is 10% less than that of other processes.

The invention relates to a method for simultaneously preparing multilevel-structure mesoporous silicon dioxide and a carbon nano material, belonging to the field of mesoporous nano material preparation. The method comprises the following steps: mixing water and alcohols to prepare a reaction solvent; adding a catalyst alkali, a reaction reagent resorcin and a surfactant CTAB (cetyltrimethylammonium bromide) into the reaction solvent; after stirring, adding a reaction reagent formaldehyde solution and TEOS (tetraethyl orthosilicate) to obtain a mixed solution; continuing stirring the mixed solution at room temperature, removing the supernatant to obtain a precipitate, and drying to obtain solid powder; calcining the solid powder at high temperature under inert gas shielding to carbonize the solid powder, thereby obtaining black solid powder; soaking the black solid powder in a hydrogen fluoride water solution or strongly alkaline solution to remove silicon dioxide, thereby obtaining a multilevel-structure mesoporous carbon material; and calcining the solid powder or black solid powder at high temperature in the air to obtain the multilevel-structure mesoporous silicon dioxide material. The method provided by the invention is simple to operate, has the advantage of low cost, and can implement large-scale production.

A preparation method of lignin-modified phenolic resin wood adhesive. The preparation method includes following steps: adding 5-14 parts by mass of industrial alkali lignin, 6-12 parts by mass of a formaldehyde solution with a mass concentration being 35-40%, and 10-19 parts by mass of phenol to a reactor having a stirrer and a condenser pipe, starting a stirring operation, stating a heating operation for increasing a temperature to 80-90 DEG C within 35-45 min, maintaining the temperature and carrying out a reaction for 15-20 min to obtain the lignin-modified phenolic resin wood adhesive.

The present invention relates to a polymerizable macromolecule photoinitiator and a preparation method thereof. The preparation method comprises: adding 4-hydroxybenzophenone and a formaldehyde solution to a three-necked flask filled with an alkali adopted as a catalyst, carrying out heating stirring to a temperature of 95 DEG C, and carrying out a reaction for 2 hours; heating to a temperature of 150 DEG C, carrying out a reaction, and carrying out a reduced pressure suction filtration reaction for 20 minutes; cooling to a temperature of 105 DEG C after completing the reaction, and collecting the product; pouring the product into water to carry out precipitation, and carrying out suction filtration to obtain a benzophenone-containing macromolecule photoinitiator; dissolving the benzophenone-containing macromolecule photoinitiator in an organic solvent, and simultaneously adding the benzophenone-containing macromolecule photoinitiator and a tertiary amine to the three-necked flask to carry out stirring; dissolving acryloyl chloride in an organic solvent, and slowly adding the organic solvent containing the acryloyl chloride to the mixing solution in a dropwise manner, wherein thereaction temperature is 0-5 DEG C; after completing the addition, stirring for 3 hours at a room temperature, and standing overnight; carrying out suction filtration, washing and drying on the resulting solution; and carrying out rotary evaporation to remove the solvent to obtain the polymerizable macromolecule photoinitiator. The photoinitiator prepared by the preparation method of the present invention has characteristics of large molecular weight, relatively small mobility, self-polymerization, and the like.

The invention discloses a cardanol epoxy floor curing agent and a preparation method thereof. Cardanol extracted from cashew shell oil which is a natural product serves as a raw material, and the cardanol with 15 long-chain hydrocarbyl substituents of carbon is reacted with alicyclic amine and a formaldehyde solution to prepare the cardanol epoxy floor curing agent, wherein the molar ratio of the cardanol to the alicyclic amine to the formaldehyde solution is 1:(1-1.5):(1-1.5); in the reaction, the cardanol is firstly added into a reactor, the formaldehyde solution is then added into the reactor for reaction, the alicyclic amine is dropwise added in the reactor, and the cardanol epoxy floor curing agent can be obtained after the material is discharged. In the invention, the synthesis is performed at low temperature; synthetic products have a longer application period; and alicyclics with higher rigidity and better stability are introduced in molecular structures of the products, therefore, an epoxy resin curing product has excellent mechanical properties.

The invention discloses a single-component thread locking epoxy precoated adhesive which is characterized by being prepared from the following components in proportion by weight: 40-70 parts of epoxyresin, 10-80 parts of activated thinner, 20-60 parts of epoxy hardener, 8-20 parts of urea, 30-60 parts of formaldehyde solution, 10-30 parts of hydroxyphenol, 0.5-5 parts of stuffing, 5-15 parts of surfactant, 80-200 parts of distilled water, 0.5-2 parts of membrane material, 0.1-1 part of hydrolysis inhibitor and 5-10 parts of solvent; and a preparation method comprises the steps: firstly, respectively microencapsulating the epoxy resin and the epoxy hardener are and then uniformly mixing with other components in proportion. The single-component thread locking epoxy precoated adhesive has the characteristics of convenient construction, applicable workpiece material diversification, less curing condition restriction, good moisture resistance and high destabilizing moment and average disassembly moment, ensures the locking performance and better guarantees the safe reliability of products.

The present invention discloses a reversible thermochromic microcapsule pigment preparation method, which comprises: weighing 0.08-0.1% by mass of crystal violet lactone, 0.4-0.5% by mass of bisphenol A, 3-6% by mass of hexadecanol, 2-4% by mass of melamine, 4.03-5% by mass of a formaldehyde solution, 0.4-0.6% by mass of sodium dodecyl benzene sulfonate, 0.09-0.11% by mass of sodium dodecyl sulfate ammonium, and 87-90% by mass of distilled water, preparing a complex A, preparing an O/W type emulsion and a melamine-formaldehyde pre-polymerization liquid, and carrying out a condensation polymerization reaction to prepare the pigment. According to the present invention, advantages of high color change sensitivity, low color change temperature and good color change stability are provided when the prepared monomer thermochromic material is adopted as the pigment, and the prepared reversible thermochromic microcapsule pigment can be widely used in the fields of anti-counterfeiting inks, temperature showing materials, and the like.

The present invention is process of preparing cashew nut oil modified phenolic resin. The process includes the following steps: preparing the resin A; mixing the resin A 100 weight portions, formaldehyde solution 80-280 weight portions and alkaline catalyst 0.1-5 weight portions; reaction at 70-100 deg.c for 1-5 hr; vacuum distilling in a vacuum distilling kettle at temperature of 40-80 deg.c and vacuum degree of -0.03 MPa to -0.1 MPa to dewater to water content of 0.5-20 %, cooling to room temperature, and adding solvent while stirring to regulate the solid resin content to 30-70 % and viscosity at 25 deg.c to 40-400 cp to obtain the cashew nut oil modified phenolic resin. The cashew nut oil modified phenolic resin has high heat resistance, flame resistance and high toughness, and may be applied as the base material for copper clad panel.

The invention relates to an adhesive for producing an artificial board having a strong strength and a low formaldehyde release amount, and a preparation method and an application of the adhesive in the artificial board production field. The adhesive comprises the following components, by weight, 200 parts of formaldehyde, 150-170 parts of urea, 1-3 parts of polyvinyl alcohol, 12-15 parts of melamine, 5-8 parts of a formaldehyde catching agent, and 0.5-2 parts of a cross-linking agent, wherein the formaldehyde is an aqueous formaldehyde solution having a mass concentration of 35-40%. The preparation method of the adhesive comprises the following steps: adding urea three times, adding the formaldehyde catching agent and the cross-linking agent in the resin synthesis, and sequentially carrying out reactions in a weak alkaline medium, an acidic medium and a neutral medium. The artificial adhesive-bonded board produced through using the adhesive has a low formaldehyde release amount and a bonding strength reaching requirements of Chinese standard adhesive-bonded boards II.

The present invention relates to a preparation method of a microcapsule aluminum hypophosphite flame retardant. The method comprises the steps of: first reacting melamine, a formaldehyde solution and a resin modifier under reaction conditions of pH of 8-10 and a temperature of 50-80 DEG C for 0.5-2 h to prepare a melamine resin prepolymer; then slowly adding the prepolymer to water with aluminum phosphate dispersed therein, reacting at 65-95 DEG C for 1-5 h, and treating to obtain the microcapsule coated inorganic aluminum phosphate flame retardant. The obtained microcapsule inorganic aluminum hypophosphite flame retardant has greatly improved water resistance, boiling residual rate of 92% to 97% and average particle diameter of 10-35 mum, solves the disadvantage of flammability of inorganic aluminum hypophosphite, and greatly improves the safety of the production and application process.

The invention provides an adhesive for grade-E0 medium density fiberboards. The raw materials of the adhesive include formaldehyde, polyvinyl alcohol, urea and tripolycyanamide. The production process of the adhesive comprises: firstly, adding all formaldehyde into a reaction kettle, regulating the pH value of formaldehyde solution to 7.5 to 8.5 by using sodium hydroxide solution, adding the 40 to 50 percent of polyvinyl alcohol and urea and adding 80 to 90 percent of tripolycyanamide and adding the 10 to 20 percent of urea; secondly, adjusting the pH value to 5 to 6 by using formic acid, reacting for 20 to 30 minutes till a cloud point, regulating the pH value to 705 to 8.5 with caustic soda solution, and adding the 10 to 20 percent of tripolycyanamide and 20 to 30 percent of urea; and finally, adding 10 to 20 percent of urea, regulating the pH value of the adhesive to 6.6 to 7.5, and discharging. The adhesive has the advantages that: the free formaldehyde content is very low, and the manufactured medium density board is of grade E0; the curing time is proper, the storage stability is high, and the normal-temperature storage period is about 1 month; and the manufactured medium density board has high internal combining strength and high waterproof and dampproof performance.

The invention discloses a nonionic self-emulsifying water-based epoxy curing agent with Gemini surfactant structure, of which the molecular general formula is disclosed in the specification. The preparation method comprises the following steps: 1) adding alkyl phenol, polyamine and formalin in a solvent to carry out Mannich reaction, and removing the solvent and byproduct after the reaction finishes, thereby obtaining Mannich amine containing primary amine group; and 2) sufficiently reacting the Mannich amine containing primary amine group with diglycidyl ether, cooling after the reaction finishes, adding water, and sufficiently dispersing to obtain an emulsion, thereby obtaining the product. The synthesis technique is simple and pollution-free; the synthesized curing agent does not need to perform salification reaction to implement self-emulsifying action by using organic acid; the epoxy curing agent has the advantages in the Gemini surfactant and has the characteristics of excellent wettability, excellent emulsibility, excellent stability and the like; and the epoxy curing agent can directly emulsify and cure the liquid epoxy resin, and can also cure an epoxy resin dispersion solution.