36 results about "Grubbs' catalyst" patented technology

The invention discloses a cycloolefin copolymer / carbon nanotube hybrid material modified oil-water separation sponge, relates to the field of high polymer materials, and provides a novel cycloolefin block copolymer which can be obtained by ring-opening metathesis polymerization of cycloolefin and 5-norbornene-2-carboxylic acid methyl ester under the catalysis of a third-generation Grubbs catalyst. The method is simple in process, and the length of the 5-norbornene-2-carboxylic acid methyl ester block can be accurately regulated, so that the nano shish-kebab structure and the surface performance of the nano shish-kebab structure can be regulated. The process for preparing the nano-hybrid shish-kebab from the cycloolefin block copolymer and the carbon nanotubes is simple in technology, the surface of a rough surface material such as polyurethane sponge can be uniformly covered with the nano-hybrid shish-kebab to form a thin film, super-hydrophobicity can be achieved, and meanwhile the nano-hybrid shish-kebab has oleophylic performance; and the oil-water separator has high separation efficiency and good wear resistance in the oil-water separation process.

The invention relates to the technical field of polymer composite materials, in particular to an explosion-proof and impact-resistant polymer coating material for an aircraft shell. The coating is prepared from aliphatic polyurethane acrylate, cycloaliphatic epoxy resin, nano silicon dioxide, polyethylene glycol, polyurea microcapsules, dicyclopentadiene resin, a Grubb catalyst, graphene oxide, polysulfide rubber and the balance of auxiliary materials. According to the invention, aliphatic polyurethane acrylate is used as a flexible matrix, so that the risk of hydrolysis of aromatic isocyanate is avoided. The dicyclopentadiene resin is subjected to in-situ ring opening polymerization in the presence of a Grubbs catalyst and cooperates with the hydrophobic nano silicon dioxide to block water. The polyurea microcapsules are broken by impact to release silicone oil, and cracks are filled immediately to reduce friction. And a water molecule permeation path is prolonged by the mica powder sheet layer. And the epoxy-polyurethane network realizes micro-crack self-repairing through dynamic ester bond exchange, so that the anti-explosion and anti-impact functions of the coating and the structural stability of an aircraft shell in an extreme environment are guaranteed.

The invention discloses a method for synthesizing degradable polyethylene through copolymerization of conjugated lactone and cycloolefin. The preparation method comprises the following steps: catalyzing ring-opening metathesis polymerization of alpha, beta-unsaturated lactone and a cycloolefin monomer by using a Grubbs catalyst, hydrogenating the obtained copolymer to prepare a series of polyethylene-like materials with different densities introduced into ester groups in a main chain, and simultaneously retaining the thermal and mechanical properties of high-density polyethylene; after the polyethylene material is degraded and recycled through alcoholysis, polyethylene-like with high molecular weight and excellent performance can be obtained again through a polycondensation method, and the problem that an existing polyethylene material is difficult to recycle is solved. The synthesis method is simple and convenient to operate, the polymer obtained by copolymerization of conjugated lactone and cyclooctene is high in molecular weight, and ester groups in a main chain are uniformly distributed. Regioselectivity of conjugated lactone polymerization is good, and an AB type monomer obtained after alcoholysis is beneficial to polycondensation to obtain a high-molecular-weight polymer. The hydrogenated product is pure white solid powder, has few metal catalyst residues, and is expected to replace a bulk polyethylene material.

The invention discloses a cycloolefin block copolymer oil-water separation film, relates to the field of high polymer materials, and provides a method for preparing a cycloolefin block copolymer through ring-opening metathesis polymerization of cycloolefin and 5-norbornene-2-carboxylic acid methyl ester under the catalysis of a third-generation Grubbs catalyst. And the hybrid shish-kebab is prepared by using the polymer, so that an oleophylic and hydrophobic film structure can be formed, the prepared film can be effectively hydrophobic and has oleophylic performance, and a new treatment mode is provided for sewage prevention and treatment. The whole preparation process is simple in technology, rapid and batch production can be achieved, and popularization is convenient.

The invention relates to the technical field of ruthenium catalysts, and provides a preparation method of a first-generation Grubbs catalyst. The preparation method comprises the following steps: mixing dichloro bis (2, 2 '-dipyridyl) ruthenium, tricyclohexylphosphine, benzyl dichloride and an alcohol solvent, and carrying out a coordination reaction to obtain a first-generation Grubbs catalyst; the temperature of the coordination reaction is 0-25 DEG C. Dichloro bis (2, 2 '-dipyridyl) ruthenium, tricyclohexylphosphine and benzyl dichloride are adopted as reaction raw materials, alcohol is adopted as a solvent, the reaction is performed through a one-pot method, the reaction condition is mild, operation is easy, environmental pollution is small, cost is low, the requirement for equipment is low, the dosage of reactants can reach the kilogram level, and batch industrial production can be achieved.

The invention relates to the technical field of tire production, in particular to a self-repairing new energy tire and a production method thereof. The production method of the self-repairing new energy tire comprises the following steps: mixing an amino-terminated polyether monomer, a trimerization catalyst, a chain extender, abietic acid, a Grubbs catalyst, self-repairing microcapsules and meta-aramid staple fibers to obtain a component A; pre-polymerizing an amino-terminated polyether monomer, a disulfide bond-containing monomer, a trimerization catalyst and 1, 6-hexamethylene diisocyanate to obtain a component B; the component A and the component B are mixed to obtain the self-repairing adhesive material; the inner surface of a new energy tire body is coated with a self-repairing bonding material, then mute cotton is bonded to the surface of the self-repairing bonding material, and the self-repairing new energy tire is obtained. The self-repairing new energy tire provided by the invention is provided with the high-performance self-repairing bonding material layer, and the self-repairing bonding material has high structural strength, long service life and excellent self-repairing performance, heat resistance, bonding performance and mute performance.

The invention relates to the field of dielectric materials, and discloses a dielectric constant-adjustable cross-linked polymer dielectric film and a preparation method and application thereof, the material components of the cross-linked polymer dielectric film comprise a compound I and a compound II with the following structures (1) and (2): # imgabs0 #, and n represents the number of repetitive structure units. According to the invention, a series of polymer dielectric films with different illumination crosslinking time are obtained by adopting a ring-opening metathesis polymerization reaction initiated by a Grubbs catalyst; when the illumination crosslinking time is prolonged from 0 minute to 7.5 minutes, the dielectric constant of the polymer dielectric can be increased from 3.85 to 4.64, and the glass transition temperature is increased from 255 DEG C to 273 DEG C; under the temperature condition of 150 DEG C, the energy storage density of the optimized cross-linked polymer dielectric film can reach 7.4 J / cm < 3 > on the premise of maintaining 90% of charge-discharge efficiency.

The invention discloses a carbazole derivative embedded with a boron-nitrogen unit, a synthesis method and application. The synthesis method comprises the following steps: respectively carrying out nucleophilic substitution reaction on a raw material 1 or 6 and 4-bromo-1-butene, and separating and purifying to obtain a corresponding intermediate 2 or 7; further adding the intermediate 7, reduced iron powder and ammonium chloride into a solvent for reduction reaction, and quenching, separating and purifying to obtain an intermediate 8; respectively adding the intermediate 2 or 8 and a boronizing reagent into a solvent to carry out electrophilic boronizing reaction, and separating and purifying to obtain a corresponding intermediate 3 or 9; respectively adding the intermediate 3 or 9 and a Grubbs catalyst into a solvent for olefin metathesis reaction, and separating and purifying to obtain a corresponding intermediate 4 or 10; the intermediate 4 or 10, a dehydrogenation reagent and a sacrificial reagent are added into a solvent for an oxidative dehydrogenation reaction, separation and purification are performed to obtain a corresponding compound 5 or 11, and the carbazole derivative embedded with the boron-nitrogen unit has good fluorescence and can be efficiently applied to the fields of OLED and OPD.

The invention discloses a polymer brush with a nanoscale microphase separation structure, a polymer film and a preparation method of the polymer film, the polymer brush comprises a liquid crystal unit, and the preparation method comprises the following steps: reacting the liquid crystal unit with halogenated alcohol to prepare a liquid crystal side chain; reacting the liquid crystal side chain with norbornene dianhydride to prepare a liquid crystal monomer containing carboxyl at the tail end; reacting the liquid crystal monomer containing carboxyl at the tail end with fatty alcohol or difatty glyceride to obtain a block type liquid crystal monomer; and carrying out ring-opening metathesis reaction on the block type liquid crystal monomer under the action of a Grubbs catalyst to prepare the polymer brush. The introduction of the liquid crystal unit provides stronger driving force for microphase separation of the brush polymer, so that the nanoscale microphase separation structure can be directly obtained through an annealing process under the condition of not adding any guide layer.

The invention relates to the technical field of shoe materials, in particular to shoe material sponge applied to shoes easy to wear and take off and a preparation method of the shoe material sponge. The shoe material sponge is prepared from the following raw materials in parts by weight: 70 to 80 parts of polyether polyol, 10 to 17 parts of polyester polyol, 3 to 8 parts of a chain extender, 5 to 12 parts of thiolated nano silicon dioxide, 0.3 to 0.8 part of a Grubbs catalyst, 3 to 10 parts of self-repairing microcapsules, 1 to 3 parts of an oxazolidine crosslinking agent, 1 to 2.5 parts of a foaming agent, 0.05 to 0.2 part of a catalyst, 1 to 2 parts of a foam stabilizer and 40 to 60 parts of isocyanate. The core material of the self-repairing microcapsule is dicyclopentadiene; the method has the advantage that the fatigue resistance of the sponge for the shoe material is improved.

The invention belongs to the technical field of catalyst synthesis, and particularly discloses a preparation method of a first-generation Grubbs catalyst, dichlorophenyl ruthenium (II) dimer is used as a metal source raw material, benzaldehyde and tricyclohexylphosphine are combined to synthesize the first-generation Grubbs catalyst, in the reaction process, a dendritic multi-site di (pentafluorophenyl) boric acid catalyst is introduced, and the first-generation Grubbs catalyst is synthesized by using dichlorophenyl ruthenium (II) dimer as a metal source raw material. A di (pentafluorophenyl) boron group at the tail end forms a superacid center due to a strong electron absorption effect, and benzaldehyde carbonyl can be efficiently activated; the dendritic skeleton provides a multi-site synergistic effect and steric configuration control, enhances the substrate enrichment and transition state stabilization capability, and significantly reduces the activation energy generated by the Ru = CHPh key intermediate, and meanwhile, the key steps of further accelerating aldol condensation, metal-carbon double bond generation and the like are combined with a proper amount of alkaline accelerator, so that the preparation method has the advantages of high yield and high yield. The efficient introduction of a benzaldehyde key C1 construction unit is realized, the reaction condition is mild, and the operation is simple and convenient.

The embodiment of the invention provides an asymmetric brush polymer and a preparation method thereof. The preparation method comprises the following steps: step S1, enabling 5-norbornene-2-exo, 3-exo-dimethanol to react with 2-(dodecyl thiocarbon thio) propionic acid, so as to obtain a norbornene derivative with 2-(dodecyl thiocarbon thio) propyl ester and a hydroxyl unit at the same time; s2, enabling the norbornene derivative to react with caprolactone and methyl acrylate by utilizing a light irradiation reaction system in the presence of a ring-opening polymerization catalyst and a photocatalyst, so as to obtain an asymmetric macromonomer containing polymethyl acrylate and polycaprolactone block units at the same time; s3, enabling the asymmetric macromonomer to react in the presence of a Grubbs catalyst, so as to obtain the asymmetric brush type polymer. By applying the technical scheme provided by the invention, the technical problems that in the prior art, the synthesis steps of the asymmetric brush type polymer are tedious, multiple purification is needed, and the molecular weight and distribution of the polymer are difficult to effectively control can be effectively solved.

The invention relates to a preparation method of an integrated nonmetal spin-vibration screen frame, an upper screen frame structure of spin-vibration screen equipment adopts a screen frame and multiple layers of screen meshes which are integrally formed through plastic injection, and the preparation method of the screen frame structure comprises the following steps: S1, mixing epsilon-caprolactam, diisocyanate, an antioxidant and glass fibers to obtain a component A; mixing a Grubbs catalyst with water to form a catalyst solution as a component B; s2, the component A and the component B are contained in a storage tank of an RIM forming machine, and then injection reaction forming is conducted through the RIM forming machine; and S3, the upper surface of the screen and the inner walls of the meshes are subjected to plasma roughing treatment, and then molten plastic with the component C containing metal particles is sprayed for crystallization attachment. The invention has the beneficial effects of light weight, long service life and avoidance of non-metal foreign matters.

The invention discloses a compound, polydicyclopentadiene resin and a preparation method thereof, and the preparation method of the polydicyclopentadiene resin comprises the following steps: mixing dicyclopentadiene, a regulator, a Grubbs catalyst and a compound of formula (I), and reacting at a first temperature to obtain a product. The preparation method comprises the following steps: mixing a compound shown as a formula (I) with DCPD, a Grubbs catalyst and a regulator to form a composition, and controlling a polymerization process to prepare a material which has excellent mechanical strength and can be controllably degraded under the conditions of acid or alkali and the like. The phosphate group contained in the hydrogel can generate inorganic phosphate after being hydrolyzed, the hydrogel has good biocompatibility, pollution which cannot be degraded by traditional cross-linked macromolecules can be relieved, and degradation products still have good environment-friendly properties.

The invention relates to the technical field of fused deposition 3D printing wire preparation, in particular to a cycloolefin polymer-based flexible printing wire material, a preparation method and a solar interface evaporator. The method comprises the following steps: catalyzing a cycloolefin monomer to generate olefin metathesis ring-opening polymerization reaction by utilizing a Grubby catalyst to form a cycloolefin polymer; under the action of a photoinitiator, a mixture formed by the cycloolefin polymer and a filling material is subjected to ultraviolet light curing, and a cycloolefin compound is obtained; and extruding the cycloolefin compound through a screw to prepare the cycloolefin polymer-based flexible printing wire material. By regulating the crosslinking density of the cycloolefin compound, on the basis of keeping flexibility, the mechanical property is improved, and the problem of contradiction between high elasticity and dimensional stability of a flexible device material is solved. The solar interface evaporator with high water evaporation efficiency is prepared by developing a cycloolefin polymer material capable of FDM printing and constructing a bionic gradient pore structure.

The present application relates to the field of biotechnology, and particularly to an enzyme composition and its application in preparing ceramide NP. The present application provides a new method for synergistically catalyzing the synthesis of ceramide NP by multiple enzymes; the method is based on enzyme directed evolution, and uses propenal and glycine as starting substrates, and under the action of mutant glycine aldolase, enaminoketol reductase, pentenoate ligase, olefin reductase, phosphite dehydrogenase and polyphosphate kinase, and in cooperation with a metal catalyst Grubbs Catalyst, to realize the synthesis of high-efficiency and high-purity ceramide NP; compared with the traditional microbial fermentation method, the synthesis path of the present application has the advantages of mild reaction condition, convenience for continuous production, short conversion period (<8h), low cost and high product purity (byproduct content <0.5%), and is suitable for the demand of industrial large-scale production.

The present invention relates to a method for synthesizing a phosphoniamidate derivative in a single step or directly through ultrasonic irradiation and portionwise addition of the Hovayda-Grubbs catalyst.

The invention discloses a atractylenolide synthesis intermediate and a synthesis method of atractylenolide and a derivative thereof, and the method comprises the following steps: oxidizing methyl in a compound 17 to prepare a compound 18; preparing a compound 19 from the compound 18 under the action of a Grubbs catalyst; carrying out hydrogenation reduction on the compound 19 to prepare a compound 20; dehydrating and eliminating the compound 20 to obtain a compound 21; hydrolyzing the compound 21 to obtain a compound 22; according to the invention, asymmetric total synthesis of atractylone, 13 kinds of eudecane atractylenolides and lactam natural products is finally realized, the technical bottleneck of chiral control of the compounds is broken through for the first time, the convergent design has both step economy and derivative universality, and especially, the type of a nucleophilic reagent is changed by a system, so that the method is suitable for industrial production. And derivative libraries with various structures are successfully constructed.

The invention provides a high-sensitivity ethylene fluorescent probe based on carbon dots as well as a preparation method and application of the high-sensitivity ethylene fluorescent probe, and belongs to the technical field of nano materials and gas sensing. The preparation method comprises the following steps: pre-reacting a Grubbs catalyst with a compound of which the terminal is alkenyl to obtain a precursor, and reacting the precursor with an aromatic amine compound and a carboxylic acid compound under a heating condition to obtain the high-sensitivity ethylene fluorescent probe based on the carbon dots. The high-sensitivity ethylene fluorescent probe based on the carbon dots has good specific recognition and fluorescence enhancement response to non-polar ethylene molecules, ethylene in a complex biological matrix can be rapidly and highly selectively detected within 3 minutes, and the detection limit is as low as 0.12 ppm. In addition, the carbon dot fluorescent probe can also realize spatial resolution fluorescence imaging of ethylene in plant tissues, and has wide application prospects in the fields of agricultural production, food preservation, plant physiology research and the like.

This invention discloses a modified bamboo-based fiber composite material and its preparation method. Specifically, it relates to a modified bamboo-based fiber composite material, characterized by comprising the following components in parts by weight: 80-100 parts modified bamboo fiber, 70-90 parts epoxy resin, and 2-5 parts curing agent. The modified bamboo fiber is prepared through the following steps: Step 1: Immersing the bamboo fiber in a 10-15% sodium hydroxide solution at 70°C for 3-6 hours, then washing with water until neutral and drying; Step 2: Immersing the bamboo fiber treated in Step 1 in an aqueous mixture containing 0.6%-1.4% Grubbs catalyst, stirring and soaking for 12-24 hours; Step 3: Mixing the dried bamboo fiber treated in Step 2 with dicyclopentadiene microcapsule powder at a mass ratio of 30-50:1 until homogeneous. The modified bamboo-based fiber composite material prepared by this invention exhibits good mechanical properties.

A method for modifying a material through rapid surface grafting, and a use thereof are provided. In the method, with an olefin-functionalized nanomaterial as a model matrix, a cycloolefin as a polymerization monomer, a Grubbs catalyst as an initiator, and ethyl vinyl ether as a terminator, surface olefin cross-metathesis is conducted to prepare a polyolefin-grafted nanomaterial. In the use, with a thermoplastic resin as a matrix and the surface-polyolefin-grafted nanomaterial as a reinforcing material, a composite is prepared. The compatibility between the reinforcing material and the thermoplastic resin matrix is evaluated through cross-sectional morphology and mechanical performance characterization. A chain-transfer reaction is adopted as an alternative approach for surface-initiated ring-opening metathesis polymerization to avoid the growth of polymer chains from the surface. This alternative approach can significantly improve a reaction rate, shorten a reaction time, and simplify a technical flow, and demonstrates a promising industrialization prospect.

The invention relates to a crosslinkable cycloolefin copolymer as well as a preparation method and application thereof. The preparation method comprises the following steps: copolymerizing norbornene and derivatives thereof with dicyclopentadiene, preparing a film from the obtained polymer in a solution casting manner, and finally initiating formation of a polymer cross-linked structure through heat treatment. The polymer is prepared by initiating monomers to perform ring-opening metathesis polymerization by a second-generation Grubbs catalyst, norbornene and derivatives thereof in the polymer can adjust the polarization intensity of the polymer in a high electric field, and dicyclopentadiene can provide crosslinking sites, so that a crosslinking structure is formed in a polymer film. The dielectric film prepared by the invention has excellent thermal stability and energy storage performance, still keeps high breakdown strength, high energy storage density, high charge-discharge efficiency and good structural stability at 150 DEG C, and is suitable for electronic devices such as energy storage capacitors working in a high-temperature environment.

The application relates to the fields of dielectric materials and energy storage materials, and discloses a high-temperature dielectric polymer as well as a preparation method and application thereof, the preparation method comprising the following steps: subjecting 5-norbornene-2,3-diformamide to a reduction reaction through lithium aluminum hydride to obtain a 5-norbornene-pyrrolidine intermediate; placing the intermediate and p-toluenesulfonyl chloride in a chloroform solution, and adding triethylamine dropwise to react; obtaining norbornene pyrrolidine benzene sulfone monomers; subjecting the monomers to ring-opening metathesis polymerization reaction through Grubbs catalyst to obtain poly-norbornene pyrrolidine benzene sulfone; placing the poly-norbornene pyrrolidine benzene sulfone and p-methylbenzenesulfonyl hydrazide in a toluene solution, and subjecting to hydrogenation reaction to obtain the target polymer. The polymer of the application only needs to be applied with a low electric field intensity of 350 MV / m at 150 DEG C, and the electric polarization energy storage density (charge and discharge efficiency > 90%) of about 10.8 J / cm 3 can be obtained, which exceeds existing high-temperature polymer dielectric materials.

The invention discloses a high-impact-resistance self-repairing polyurea-nano composite coating as well as a preparation method and application thereof in nuclear power plant protection, and belongs to the technical field of coating materials. The water-based polyurethane adhesive is prepared from the following raw materials in parts by weight: 20 to 30 parts of modified isocyanate, 30 to 40 parts of hydroxyl-terminated polybutadiene, 5 to 10 parts of nano silicon dioxide, 8 to 15 parts of microencapsulated dicyclopentadiene, 0.1 to 0.5 part of a Grubbs catalyst, 3 to 8 parts of an aminated carbon nanotube, 0.5 to 1.5 parts of a TEDA catalyst and 20 to 30 parts of a DMF (Dimethyl Formamide) solvent. The composite coating prepared by the invention has high impact resistance, self-repairing capability, electromagnetic shielding function and radiation resistance, is suitable for protecting key equipment and structures of the nuclear power station, and effectively improves the safety and durability of facilities of the nuclear power station.

The invention provides an efficient ring-opening metathesis polymerization method based on a ruthenium catalyst, belongs to the technical field of polymer synthesis, and solves the problems of low polymerization efficiency, complex process and tedious operation of the existing method. The preparation method comprises the following steps: mixing and dissolving a large steric hindrance monomer, a Grubbs catalyst and an ionic liquid in an organic solvent for reaction, and finally adding a terminator for quenching reaction to obtain a target compound. According to the invention, the ionic liquid is used as an additive for the ring-opening metathesis polymerization reaction, and the ring-opening metathesis polymerization reaction activity of the large-steric-hindrance cycloolefin monomer is remarkably improved through a multi-synergistic effect mechanism generated between the specific anion-cation structure and the monomer and the ruthenium catalyst.

[Problem] To easily produce an oxypropylene group-containing glycol ether that substantially contains no allyl group-containing impurity and does not adversely affect a polymerization reaction of a polyether-polysiloxane block copolymer when used as a reaction solvent or a diluent, by easily separating the oxypropylene group-containing glycol ether by distillation or the like in a facility and a reaction process that are industrially relatively easy and simple. [Solution] An oxypropylene group-containing glycol ether production method which includes a step for isomerizing an allyl group-containing impurity contained in an oxypropylene group-containing glycol ether by using a ruthenium carbene complex that is known as a Grubbs catalyst, and preferably further includes a purification step for separating the oxypropylene group-containing glycol ether by using a means such as distillation.

The present invention discloses a method for repairing damage to cellulose insulating paper based on mechanically enhanced microcapsules, and relates to the field of high voltage and insulation technology. The repair method of the present invention is to use cellulose insulating paper based on mechanically enhanced microcapsules for damage repair, wherein the mechanically enhanced microcapsules are mainly made of capsule walls and core materials, wherein the capsule walls include polyurethane and nano-silica, and the core materials include DCPD and Hoveyda-Grubbs catalyst. The present invention solves the problem that microcapsules in traditional insulating paper are prone to premature rupture under external stress, resulting in premature leakage of the repair agent and low repair efficiency. Using insulating paper containing the microcapsules of the present invention for damage repair can improve the efficiency and accuracy of the repair process.

A prepolymer and a resin composition containing the prepolymer are provided. The prepolymer is obtained from a prepolymerization reaction of a mixture, the mixture including 100 parts by weight of a compound of Formula (1) and 0.01 to 0.09 part by weight of a Grubbs catalyst. The resin composition may be used to make various articles, including a prepreg, a resin film, a laminate or a printed circuit board, and at least one of the following properties can be improved, including copper foil peeling strength and passive intermodulation.

The application discloses a preparation method of bottle brush polymer, comprising the following steps: heating norbornene-terminated polyester macromonomer to a molten state, adding a ROMP catalyst under the condition of containing a ligand to initiate a ring-opening metathesis polymerization reaction, and obtaining the bottle brush polymer; wherein the ligand is used for adjusting the activity of the ROMP catalyst, the polymerization reaction is carried out in a bulk system, and the content of the organic solvent in the bulk system is less than 8 wt%; and the ligand is pyridine. By adding the ligand (such as pyridine) into the reaction system, the initial activity of the Grubbs catalyst (such as G3) is effectively controlled, the catalyst is uniformly dispersed in the melt, then the norbornene-terminated polyester macromonomer is smoothly and controllably subjected to bulk ring-opening metathesis polymerization (ROMP) in a molten state, and the large amount of organic solvent required in traditional solution polymerization and the subsequent cumbersome removal process are avoided.

The invention relates to the technical field of polymer synthesis, and discloses a polyolefin-polycarbonate grafted copolymer and a preparation method thereof. A metalloporphyrin complex, quaternary ammonium salt and a Grubbs catalyst are adopted as a composite catalytic system, and CO2, an epoxy monomer and a cycloolefin monomer are copolymerized through a one-step method to prepare the polyolefin-polycarbonate grafted copolymer. The preparation method disclosed by the invention has the beneficial effects that the graft copolymer is obtained by adopting one-step polymerization, so that compared with a traditional two-step method, the preparation efficiency is improved, and meanwhile, the preparation cost is reduced; polyolefin and polycarbonate are prepared into a grafted copolymer, so that the mechanical property of polycarbonate can be greatly improved.