Novel porous foam material and preparation method thereof

A foaming material and a new technology, applied in the field of foamed plastics, can solve the problems of complex preparation process, poor solubility of foaming agent, high price, etc., and achieve the effect of simple production process, environmental protection process and convenient operation

Inactive Publication Date: 2019-12-24
GUANGDONG JUHANG INST FOR ADVANCED MATERIALS CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] 1) The preparation process is complicated and the price is high;
[0006] 2) Need to use a large amount of solvents, causing pollution to the environment;
[0007] 3) Tungsten-based catalysts are often used, which requires strict test conditions;
[0008] 4) The performance of the prepared porous material drops significantly, and the high-strength characteristics of the PDCPD material cannot be highlighted;
[0010] Prior patent applications CN 104327436 A and CN 107722243 A have both announced the preparation method of polydicyclopentadiene foam material, which can reduce the density of the material on the basis of ensuring the high strength of the raw material; both use chemical foaming agent, the method developed The solubility of the foaming agent is relatively poor, and the expansion ratio is not easy to adjust

Method used

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  • Novel porous foam material and preparation method thereof
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Examples

Experimental program
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Effect test

Embodiment 1

[0030] A novel open-cell foaming material and preparation method thereof: dissolve 1% 2,6-di-tert-butyl-4-methylphenol into 1000 mL of dicyclopentadiene monomer, stir for 5 minutes, and dissolve 2,6 - Dissolve 1% UV-531 in the monomer of di-tert-butyl-4-methylphenol, stir for 4min, dissolve in the monomer of 2,6-di-tert-butyl-4-methylphenol and UV-531 Dissolve 1% styrene-butadiene rubber, add 1 / 10000g rubbs catalyst solution (dissolved in dichloromethane or toluene solution), stir evenly for 2 minutes; pour into 50 ℃ mold, extract vacuum, react for 30 minutes, keep warm for 10 minutes, cool and demould Open-cell foamed PDCPD materials are available.

Embodiment 2

[0032] A novel open-cell foaming material and a preparation method thereof. Dissolve 0.5% bis(3,5-di-tert-butyl-4-hydroxyphenyl) sulfide in 1000 mL of dicyclopentadiene monomer, stir for 5 min, Dissolve 1% UV-326 into the monomer dissolved with bis(3,5-di-tert-butyl-4-hydroxyphenyl) sulfide, stir for 3 min, and dissolve in bis(3,5-di-tert-butyl- Dissolve 2% styrene-butadiene rubber into the monomer of 4-hydroxyphenyl) sulfide and UV-326, stir for 9min, add 1 / 10000grubbs catalyst solution (dissolved in dichloromethane or toluene solution), stir evenly for 3min; pour Put it into a mold at 50°C, extract the vacuum, react for 30 minutes, keep it for 10 minutes, and then cool and demold to obtain an open-cell foamed PDCPD material.

Embodiment 3

[0034] A novel open-cell foaming material and a preparation method thereof. Dissolve 0.5% 2,6-di-tert-butyl-4-methylphenol in 1000mL of dicyclopentadiene monomer, stir for 4min, and dissolve 2,6 - Dissolve 2% UV-326 in the monomer of di-tert-butyl-4-methylphenol, stir for 5min, dissolve in the monomer of 2,6-di-tert-butyl-4-methylphenol and UV-326 Dissolve 3% styrene-butadiene rubber in the medium, stir for 8min, add 1 / 10000grubbs catalyst solution (dissolved in dichloromethane or toluene solution), stir evenly for 3min; pour into a 50°C mold, extract vacuum, react for 30min, keep warm for 10min and then cool The open-cell foamed PDCPD material can be obtained by demoulding.

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Abstract

The invention discloses a novel porous foam material and a preparation method thereof. The porous foam material comprises the following raw material components in parts by weight: 100 parts of dicyclopentadiene, 0.1-3 parts of an anti-aging agent, 0.1-3 parts of an ultraviolet absorbent, 0.2-5 parts of a tackifier, and a grubbs catalyst with the molar ratio of the grubbs catalyst to the dicyclopentadiene being 1 / 100000-1 / 500. The preparation method comprises the following steps: dissolving the anti-aging agent into dicyclopentadiene monomer at room temperature; dissolving the ultraviolet absorbent into the dicyclopentadiene monomer in the first step at room temperature; dissolving the tackifier into the dicyclopentadiene monomer obtained in the second step at room temperature; adding a certain proportion of catalyst solution into the dicyclopentadiene monomer; and pouring the obtained mixed solution into a mold, performing suction treatment for a period of time, carrying out vacuum insulation molding, cooling the molded product, and demolding the product to obtain the open-cell foam material. The obtained foam material has the properties of high strength, low density, heat insulation and sound insulation; the production process is simple, environment-friendly and convenient to operate.

Description

technical field [0001] The invention relates to a foamed plastic, in particular to a novel open-cell foamed material and a preparation method thereof. Background technique [0002] At present, the concept of lightweight materials has attracted more and more attention. For polymer materials, a cell structure is usually introduced into the material to replace the original solid polymer part with air bubbles, so as to achieve the purpose of reducing the density of the material. Polymer foam materials refer to microporous materials based on polymers (plastics, rubbers, elastomers or natural polymer materials) with countless bubbles inside them, and can also be regarded as composite materials with gas as filler. Open-celled polymer foam materials have a wide range of applications in biology, medical, environmental engineering and other fields, and can be used in tissue engineering, solvent extraction, thermal insulation, sound absorption, water retention, oil absorption, and dru...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L45/00C08L23/16C08L9/06C08J9/00
CPCC08J9/00C08J9/0061C08J2205/05C08J2345/00C08J2409/06C08J2423/16
Inventor 陈旭东吴浪甄智勇
Owner GUANGDONG JUHANG INST FOR ADVANCED MATERIALS CO LTD
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