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85results about How to "Increase surface active sites" patented technology

Electrode Ce doped PbO2 used for treating waste water and its preparation method

The invention relates to an electrode Ce doped PbO2 used for treating waste water and its preparation method. The electrode is a F-PbO2-CeO2 / TiO2-NTs / Ti electrode. The method for producing the electrode comprises that: obtaining a titania nano-tubes array (TiO2-NTs / Ti) matrix prepared by an anodization processing, doping rare earth Ce, preparing a doped-type F-PbO2-CeO2 / TiO2-NTs / Ti electrode by using an electrodeposition method. Compared with the prior art, the PbO2 electrode by the present invention has the advantages of high oxygen evolution potential, strong catalytic activity, stable electrode electrochemical performance and long service life. Compared with the traditional PbO2 electrode, the oxygen evolution potential of the electrode is higher than 2.4 V, and accelerated and strengthen life is more than 400 hours, the service life can reach about 40 years. The electrode has the advantages of simple preparation technology and low manufacturing cost, and can be effectively used for an electrochemical oxidation treatment of organic waste water which has high density and is difficult to degrade, the electrode also has a wide economic and social benefit.
Owner:TONGJI UNIV

Multifunctional composite material with heterostructure and preparation method thereof

The invention relates to a multifunctional composite material with a heterostructure as well as a preparation method and application of the multifunctional composite material with the heterostructure, and belongs to the technical field of photocatalysis. The preparation method comprises the following steps of: dissolving an graphene oxide in water, carrying out ultrasonic processing to obtain a graphene oxide dispersion liquid, and dripping a silver nitrate solution into the graphene oxide dispersion liquid while stirring, so as to obtain a mixed solution A; slowly dripping ammonia water into the mixed solution A to obtain a mixed solution B; stirring the mixed solution B, and slowly dripping a disodium hydrogen phosphate solution into the mixed solution B to obtain a mixed solution C; then slowly dripping a P25 solution into the mixed solution C under the magnetic stirring condition to be continuously stirred, transferring the obtained mixed solution C into a hydrothermal reaction kettle, and cooling the obtained mixed solution C till the temperature of the obtained mixed solution C drops to the room temperature after the hydrothermal reaction; and carrying out the vacuum drying on a resultant to obtain a composite material after the resultant is centrifuged and rinsed. The prepared composite material can not only absorb pollutants in water, but can also rapidly degrade organic pollutants of certain concentration under the irradiation of visible light. Moreover, the prepared composite material has efficient broad spectrum sterilization activity to various common bacteria.
Owner:JIANGSU UNIV

Ruthenium complex catalyzer for acetylene hydrochlorinate and preparation method and application thereof

The invention discloses a ruthenium complex catalyzer for acetylene hydrochlorinate and a preparation method and application thereof. The catalyzer is characterized in that active carbon serves as catalyst support, and is loaded with ruthenium chloride and an organic ligand; the molar ratio of the ruthenium chloride and organic ligand is 1:1-6, and ruthenium accounts for 0.1-5.0% of the total weight of the catalyzer; the organic ligand is one or more of triphenylphosphine, pyridine, 2,2'-dipyridyl, acetylacetone, chlorodiphenylphosphine, chlorobenzene, cyclopentadiene, 4-methyl isopropyl benzene and 1,5-cyclooctadiene. The ruthenium complex catalyzer for the acetylene hydrochlorinate and the preparation method and application thereof have the advantages that the preparation process is simple, the catalytic activity and stability of the catalyzer are greatly improved, the catalyzer is more environmentally friendly, and the economy is high.
Owner:浙江天麟环境工程有限公司

Preparation method of reed-based biochar adsorption material

InactiveCN108970583AStrong pollutant adsorption capacityRealize the utilization of waste resourcesOther chemical processesAlkali metal oxides/hydroxidesChemistryNitrogen gas
The invention relates to a preparation method of a reed-based biochar adsorption material. The preparation method is technically characterized by comprising the following steps of cleaning the reed stalk, drying and crushing; soaking the crushed reed stalk into a KOH (potassium hydroxide) solution to activate, and drying; putting the dried crushed reed stalk into an atmosphere furnace, and performing oxygen-free high-temperature cracking under the nitrogen or inert gas protection atmosphere; after high-temperature cracking treatment, cooling to room temperature, and cleaning the cracked material to be neutral by an acid solution, so as to prepare the reed-based biochar adsorption material. The preparation method has the advantages that the problems of pollution to environment and waste ofresources due to irresponsible disposal of the wetland plant wastes are solved; compared with the prior art, the specific surface area is large, the pollutant adsorption ability is strong, the environment-friendly value is greatly increased, and the resource utilization of the wastes is realized.
Owner:SHENYANG ACAD OF ENVIRONMENTAL SCI

Method for preparing nitrogen-doped carbon-coated metal nanoparticle composite material by utilizing carbon fibers

The invention discloses a method for preparing a nitrogen-doped carbon-coated metal nanoparticle composite material by utilizing carbon fibers. The method comprises the following steps: firstly, uniformly mixing and stirring water-soluble transition metal salt and a solution of tannic acid to obtain a metal ion tannic acid viscous composite material; then adding the carbon fibers treated through nitric acid and continually stirring and drying; finally, adding a cyanamide type compound and carrying out calcination and pyrolysis in inert gas, so as to obtain a target product. According to the method disclosed by the invention, a preparation technology is simple in flow, controllable in operation and low in cost; the method has the advantages of safety, high efficiency, greenness and environment protection and the like and is suitable for large-scale production.
Owner:HEFEI UNIV OF TECH

Photo-Fenton desulfurization-denitration catalyst and preparation method thereof

The invention discloses a photo-Fenton desulfurization-denitration catalyst and a preparation method thereof. The photo-Fenton desulfurization-denitration catalyst includes a catalyst carrier and photo-Fenton active components which are loaded on the catalyst carrier through a binder, wherein the photo-Fenton active components include tubular manganese-doped graphite phase carbon nitride and ferric molybdate which is loaded on the tubular manganese-doped graphite phase carbon nitride; and the catalyst comprises, in parts by weight, 70-85 parts of the catalyst carrier, 10-30 parts of the binder, 0.5-2.0 parts of the tubular manganese-doped graphite phase carbon nitride and 0.5-2.0 parts of ferric molybdate. The constructed tubular Mn-g-C3N4 / Fe2(MoO4)3 has three functions of photocatalysis,ozone catalysis and Fenton catalysis, different catalytic systems can depend on each other, and can be promoted by each other, the content of reactive free radicals is increased, and the desulfurization and denitration efficiency of vacuum ultraviolet light catalysis in cooperation with a H2O2 oxidation absorption system is improved. The catalyst can be widely applied to purification treatment offlue gas, ultra-low emission of SO2 and NOx can be achieved, and the catalyst has the characteristics of low cost, simple synthesis, environmental protection and the like.
Owner:OCEAN UNIV OF CHINA

Electrochemical sensor for detecting lead ion and/or cadmium ion, and preparation method and application thereof

The invention discloses an electrochemical sensor for detecting lead ions and / or cadmium ions, and a preparation method and an application thereof. The electrochemical sensor includes a glassy carbonelectrode, of which the surface of a reaction terminal is modified by ordered mesoporous carbon supporting hollow spherical bismuth oxide, which is formed with the ordered mesoporous carbon as a carrier, of which the surface supports the hollow spherical bismuth oxide. The preparation method includes a step of modifying the ordered mesoporous carbon supporting hollow spherical bismuth oxide onto the surface of the reaction terminal of the glassy carbon electrode. The electrochemical sensor has advantages of good stability, long service life, wide detection range, low detection limit, good selectivity and strong anti-interference capability. The preparation method has simple processes, low cost and convenient operations, is pollution-free and has extensive application range. The electrochemical sensor is used for detecting lead ions and / or cadmium ions, has simple operation, low cost, short responsive time and high sensitivity, and has great application prospect.
Owner:HUNAN UNIV

Silicon nano-wire-polypyrrole composite material preparation method

The invention discloses a silicon nano-wire-polypyrrole composite material preparation method, which comprises: carrying out metal assisted chemical etching on a single crystal silicon wafer by usingsilver nitrate and hydrofluoric acid to form silicon nano-wires positioned on the single crystal silicon wafer and perpendicular to the surface, coating the surface of the single crystal silicon waferwith the mixed solution of dodecyl benzenesulfonic acid and ammonium persulfate in a spin-coated manner, placing into a closed polymerization device, suspending the wafer above a pyrrole monomer solution, pumping to form a negative pressure, and polymerizing to obtain the silicon nano-wire-polypyrrole composite material. According to the present invention, the preparation method overcomes the disadvantages of the traditional liquid phase chemical polymerization method and the electrochemical preparation method, and has characteristics of simpleness, low cost and low power consumption; the synthesized polypyrrole film is dense and uniform; and the polypyrrole surface modified one-dimensional silicon-based gas sensitive material constructed by the method has high room temperature sensitivity and fast response recovery performance to specific gases.
Owner:TIANJIN UNIV

Carbon nano-tube plastic electric-conduction composite material and wet preparation process thereof

ActiveCN110467782AEasy to processSmooth surface without pittingEmulsionCarbon nanotube
The invention relates to the technical field of electric-conduction composite materials, particularly to a carbon nano-tube plastic electric-conduction composite material and a wet preparation processthereof, wherein the raw materials comprise plastic emulsion, amino acids, carbon nano-tubes and an electric-conduction filler, and the amino acids can produce pi-pi action with the carbon nano-tubes. The process comprises: preparing an amino acid aqueous solution; adding carbon nano-tubes and an electric-conduction filler to the amino acid aqueous solution; adding the carbon nano-tube amino aciddispersion liquid to a plastic emulsion, and carrying out uniformly demulsification mixing; filtering, and drying; mixing with an auxiliary material; and mixing, extruding, and granulating. Accordingto the present invention, carbon nano-tubes are subjected to surface modification by using the biological amino acid capable of producing pi-pi action with the carbon nano-tubes to improve the dispersion performance of the carbon nano-tubes, and the carbon nano-tubes and the plastic emulsion are subjected to wet mixing so as to obtain the uniformly dispersed carbon nano-tube plastic electric-conduction composite material.
Owner:SHANDONG DAZHAN NANO MATERIALS +1

MgO/MgCO3 compound adopting micro-nano hierarchical structure and application of MgO/MgCO3 compound serving as fluorine remover

The invention discloses an MgO / MgCO3 compound adopting a micro-nano hierarchical structure and an application of the MgO / MgCO3 compound serving as a fluorine remover. According to the MgO / MgCO3 compound adopting the micro-nano hierarchical structure, characteristics of low energy consumption, simplicity, easiness in operation and the like of a water bath device lower than 100 DEG C are used and chip inorganic salt is taken as the raw material for preparation of the MgO / MgCO3 compound adopting the uniform micro-nano hierarchical structure and serving as the fluorine remover to be uniformly dispersed in water so as to absorb fluorinions in water. According to the micro-nano hierarchical structure of the MgO / MgCO3 compound, the specific surface area of the material is increased, the fluorine absorbing surface active sites of the material are increased, so that the fluorine absorbing effect of the adsorbent is improved greatly. The MgO / MgCO3 compound fluorine remover adopting the micro-nano hierarchical structure has a wide apparition range for the pH value in water and has remarkable application effect on treatment of fluorine-containing water.
Owner:HEFEI INSTITUTES OF PHYSICAL SCIENCE - CHINESE ACAD OF SCI

Preparation method and application of acid pickled ZVI (zero-valent iron) modified charcoal

The invention provides a preparation method and application of acid pickled ZVI (zero-valent iron) modified charcoal. The preparation method comprises the following steps: 1) crushing, grinding and drying a biomass raw material; 2) carrying out soaking treatment on the dried biomass into a blended soaking solution, and carrying out centrifugal dehydration drying; 3) putting charcoal into an acid solution, carrying out stirring at a uniform speed at the room temperature, and carrying out centrifugal dehydration drying so as to obtain acid pickled charcoal; 5) under protection of an argon environment, putting the acid pickled charcoal into an iron solution, carrying out stirring for 1 hour at the room temperature, and dropping a NaBH4 solution to carry out a reaction; and 6) after the reaction is completed, carrying out centrifugal dehydration drying, so as to obtain the acid pickled ZVI modified charcoal. The acid pickled ZVI modified charcoal prepared by using the preparation method has a remarkable repairing effect on heavy metal Cr (VI) polluted soil, is capable of effectively reducing the content of Cr (VI) in the soil, and in addition is capable of effectively degrading bio-availability and migration of chromium in the soil.
Owner:CHINA CITY ENVIRONMENT PROTECTION ENGINEERING LIMITED COMPANY

Graphite loaded tin dioxide electrode and preparation method

The invention discloses a graphite loaded tin dioxide electrode and a preparation method. The preparation method comprises the following steps of (1) grinding a graphite sheet with abrasive paper so as to remove a surface inert layer, and then performing oxygen terminal treatment; putting a graphite electrode obtained after treatment in a muffle furnace, and performing heat treatment by adopting temperature programming in carbon dioxide atmosphere, so that a standby graphite sheet is obtained; (2) preparing sol-gel deposition liquid; and (3) repeating impregnation-deposition, drying and calcining processes for many times, so that an SnO2-Mn / Graphite electrode is prepared. According to the preparation method, the surface structure of an SnO2 coating is reformed by utilizing manganese as a metal element, so that an Mn doped SnO2 modified layer with small particle size and compact arrangement is obtained, and the electrode performance is improved; compared with the graphite sheet which isnot modified, the obtained electrode has high oxygen evolution potential and electrocatalytic activity, and the stability of the graphite electrode can be effectively kept.
Owner:SHANGHAI BODAN ENVIRONMENTAL ENG TECH

g-C3N4 nanosheet/graphene oxide composite material and preparation method and application thereof

The invention relates to a g-C3N4 nanosheet / graphene oxide composite material and a preparation method and application thereof. According to the composite material, Bulk-g-C3N4 is synthesized througha pyrolysis method, then g-C3N4 nanosheets are synthesized through an ultrasonic-assisted method and finally the g-C3N4 nanosheets are fixed on the surface of graphene oxide through an ultrasonic method to obtain the composite material. The composite material is modified on the surface of a glassy carbon electrode to prepare a novel sensor for simultaneous, rapid and real-time detection of acetaminophen and levofloxacin. Results show that the sensor has a wide linear range, a low detection limit and high sensitivity for detection of two substances. High-sensitivity detection and analysis of acetaminophen and levofloxacin can be realized and high selectivity can be obtained in the complex environment medium. Meanwhile, the composite material has the advantages of being simple in instrumentand equipment, low in analysis cost, rapid, simple, convenient and the like, and a new detection method can be provided for evaluating residual pollution of acetaminophen and levofloxacin in the environment.
Owner:SHANXI UNIV

Production method of superfine glass microfibers

The invention discloses a production method of superfine glass microfibers. The production method comprises the following steps: weighing raw materials, preprocessing quartz sand, feldspar powder, dolomite powder, calcite powder and fluorite powder; uniformly mixing the raw materials with borax, sodium carbonate, sodium nitrate, potassium carbonate and a clarifying agent to obtain a batch, meltingthe batch to obtain molten glass, feeding the molten glass into a centrifugal fiber forming machine, throwing out the molten glass through a centrifugal head of the centrifugal fiber forming machine,and forming ultrafine glass microfibers under the action of blowing airflow. According to the invention, the tensile strength of the glass microfibers can be effectively improved, the produced microfiber glass has the advantages of less slag balls and uniform fiber diameter, and the quality of microfiber glass wool is improved.
Owner:BENGBU RONGQIANG COMPRESSOR MFG CO LTD +2

Resin graphene composite material, preparation method and application thereof

The invention provides a resin graphene composite material, a preparation method and an application thereof, which belong to the technical field of the graphene composite material. The preparation method comprises the following steps: 1) mixing a metal auxiliary agent, a graphene material and water and stirring a mixture to obtain a slurry; 2) drying the slurry to obtain metal graphene; and 3) heating the metal graphene and thermoplastic resin and heating the materials under inert gas atmosphere to the temperature of 50-300 DEG C for a reaction. The preparation method composites the graphene material and the thermoplastic resin, through a Pi bond electron cloud of the graphene material, free electron transmission is carried out, the obtained resin graphene composite material has good conductivity and thermal conductivity, and can be used as a novel electric conduction and heat conduction composite material.
Owner:北京北方国能科技有限公司

Mn (VO3) 2/V2O5 catalyst as well as preparation method and application thereof

The invention relates to a Mn (VO3) 2 / V2O5 catalyst and a preparation method and application thereof, and the preparation method comprises the following steps: (1) dissolving a vanadium salt in a polyhydroxy compound aqueous solution, adding a manganese salt, uniformly mixing to obtain a precursor solution, then carrying out a hydrothermal reaction, and collecting a precipitation product after the reaction is finished; and (2) cleaning the precipitation product for multiple times, drying, carrying out pre-oxidation treatment in an oxidation atmosphere, and then carrying out carbonization treatment in a nitrogen atmosphere to prepare the Mn (VO3) 2 / V2O5 catalyst. The second metal is doped in the vanadium-based catalyst to form the doped composite catalyst, the doped composite catalyst has good catalytic oxidation activity, the catalytic oxidation efficiency of the catalyst on CBs can be improved, and the reaction temperature can be reduced.
Owner:JIANGSU UNIV OF TECH

Iridium-based multi-component nano-porous catalyst as well as preparation method and application thereof

The invention provides an iridium-based multi-component nano-porous catalyst as well as a preparation method and application thereof, belongs to the technical field of catalytic materials, and solves the defects of low anode electrolysis efficiency, large use amount of noble metal in the catalyst and relatively high cost of a water electrolysis hydrogen production catalyst in the prior art. The iridium-based multi-element composite nano-porous catalyst comprises iridium and / or iridium oxide and further comprises an oxide compounded with the iridium and / or iridium oxide, the oxide has conductivity, and the dielectric constant of the oxide is smaller than 80 F / m. The catalyst provided by the invention has low overpotential and high mass activity, the use amount of precious metal iridium can be reduced, and the energy consumed by oxygen evolution reaction is less.
Owner:CHINA THREE GORGES CORPORATION

Hollow spherical bismuth oxide supported ordered mesoporous carbon as well as preparation method and application thereof

The invention discloses a hollow spherical bismuth oxide supported ordered mesoporous carbon as well as a preparation method and application thereof. According to the hollow spherical bismuth oxide supported ordered mesoporous carbon, ordered mesoporous carbon serves as a carrier, and hollow spherical bismuth oxide is supported on the surface of the ordered mesoporous carbon. The preparation method comprises the steps: preparing ordered mesoporous carbon on the surface of which bismuth oxide is supported and calcining the ordered mesoporous carbon on the surface of which bismuth oxide is supported. The hollow spherical bismuth oxide supported ordered mesoporous carbon disclosed by the invention has the advantages of being large in specific surface area, neat and ordered in pore diameter, excellent in dispersion property, high in thermal stability, high in conductivity and the like, the preparation method has the advantages of being simple in preparation process, low in cost and the like, the ordered mesoporous carbon serving as a functional nanometer material can be used for detecting and treating environmental pollutants, and the prepared electrochemical sensor is capable of realizing detection of the environmental pollutants and has the advantages of being high in stability, long in service life, wide in detection range, low in detection limit, excellent in interference resistance and the like.
Owner:HUNAN UNIV

Preparation method of small-grain-size cobalt-based aluminum oxide catalyst

The invention discloses a preparation method of a small-grain-size cobalt-based aluminum oxide catalyst. The method comprises the steps that by adopting a sol-gel method, hydrochloric acid is adoptedas an acidity regulator, acetic acid is adopted as an interface protective agent to synthesize an alumna supporter, then, cobaltous acetate is adopted as a cobalt source, diglycol is adopted as a complexing agent, and a dipping method is adopted for manufacturing the small-grain-size cobalt-based aluminum oxide catalyst. Compared with existing cobalt-based aluminum oxide synthesized by adopting glycine and urea as complexing agents, the grain size of cobaltosic oxide in synthesized cobalt-based aluminum oxide is smaller, the number of catalyst surface active loci is increased, and the interaction strength between the supporter and active ingredients is enhanced. In addition, the cobalt-based aluminum oxide is good in thermal stability, generation of a CoAl2O4 non-active phase can be restrained within the certain temperature range, and the activity of the catalyst in the methane catalyst combustion reaction is improved. The method is easy to implement, the synthesized cobalt-based aluminum oxide can be adopted as a catalyst carrier and can also be adopted as a catalyst obtained after a methane catalysis combustion reaction, and the good application prospect is achieved.
Owner:FUJIAN NORMAL UNIV

Large-size sea urchin spherical magnesium carbonate trihydrate and porous magnesium oxide assembled by nanorod arrays and preparation method thereof

The invention belongs to the technical field of mineral processing, and particularly relates to large-size sea urchin spherical magnesium carbonate trihydrate and porous magnesium oxide assembled by nanorod arrays and a preparation method of the large-size sea urchin spherical magnesium carbonate trihydrate and porous magnesium oxide. The large-size sea urchin spherical magnesium carbonate trihydrate and the porous magnesium oxide are formed by assembling nanorod arrays, the diameters of the large-size sea urchin spherical magnesium carbonate trihydrate and the porous magnesium oxide are 60-150 microns, and the diameter of each nanorod is 50-200 nm; the porous magnesium oxide is prepared by pyrolyzing and calcining the large-size sea urchin spherical magnesium carbonate trihydrate and is of a hierarchical pore structure, that is, the material contains micropores, mesopores and macropores at the same time, and the specific surface area is 110-170m2 / g. The reaction conditions are mild and easy to regulate and control, the magnesium carbonate trihydrate and the porous magnesium oxide crystal have a three-dimensional complex multilevel structure, the particle size is large, the morphology order degree is high, and the porous magnesium oxide has a large number of micropores, mesopores and macropores at the same time.
Owner:SHANDONG UNIV OF TECH

Preparation method of polyethylene film for degradable shopping bag

The invention discloses a preparation method of a polyethylene film for a degradable shopping bag, and particularly relates to the technical field of packaging materials; the polyethylene film prepared by the preparation method disclosed by the embodiment of the invention has good mechanical properties, and meanwhile, after the polyethylene film is accelerated to age by ultraviolet light for 10 days, the tensile strength and the elongation at break are obviously reduced, and the degradation degree is high; manganese dioxide, ferric chloride and nano titanium dioxide are doped, ammonia water and beta-cyclodextrin are used for preparing a composite catalyst, and the catalytic efficiency is high; meanwhile, under the action of beta-cyclodextrin, the composite catalyst is in a porous form, andthe catalytic efficiency of the composite catalyst is further improved.
Owner:刘丹丹

One-dimensional molybdenum phosphide nanorod and preparation method and application thereof

The invention provides a one-dimensional molybdenum phosphide nanorod and a preparation method and application thereof. The preparation method comprises the following steps: uniformly dispersing molybdenum trioxide powder and adenine in deionized water to obtain a dispersion liquid, subjecting the obtained dispersion liquid to a hydrothermal reaction, naturally cooling the dispersion liquid to room temperature after the reaction is completed, and successively conducting centrifugation, washing and drying to obtain a molybdenum trioxide-adenine strip-shaped precursor; and carrying out a phosphating reaction on the obtained molybdenum trioxide-adenine strip-shaped precursor and sodium dihydrogen hypophosphite, and carrying out natural cooling to room temperature to obtain the one-dimensional molybdenum phosphide nanorod. The molybdenum phosphide nanorod composed of uniform nitrogen-doped nanoparticles is obtained; meanwhile, the molybdenum phosphide nanorod has different crystal faces,so a large number of surface active sites are provided, and the catalytic activity of molybdenum phosphide is remarkably improved. The preparation method has the advantages of low cost, simple operation, usage of green, pollution-free and non-toxic raw materials, and safe and simple production flow, is suitable for industrial production, and has potential application value in the field of molybdenum phosphide and transition metal phosphide.
Owner:SHANDONG UNIV

Preparation method of micro-foaming denitration catalyst carrier

The invention provides a preparation method of a micro-foaming denitration catalyst carrier. The method is characterized by comprising the following steps: grafting an unsaturated carboxylic acid ammonium salt on the surface of industrial-grade anatase-type titanium dioxide; and enabling titanium hydride taken as a combustion explosion agent on the surface of a titanium dioxide particle to perform combustion explosion at a high temperature under the action of an initiator so as to form open micropores, thereby further obtaining the micro-foaming denitration catalyst carrier. The denitration catalyst carrier has the obvious performance that the open micropores are formed through the combustion explosion of the surfaces of the titanium dioxide fineparticles, so that the surface active sites of the denitration catalyst carrier are increased, i.e., active substances carried by the denitration catalyst carrier can be in full contact with nitric oxides so as to perform a catalytic reaction. Thus, the utilization rate of the active substances is greatly increased. The preparation process of the denitration catalyst carrier is easy to control, avoids pollutant discharge and is small in production investment, thereby being suitable for large-scale industrial production. As a result, the denitration catalyst carrier provided by the invention can be widely applied to the denitration of the nitric oxides in a flue gas.
Owner:SHANDONG DESHI CHEM IND CO LTD

High-activity electrochemical self-doped TiO2 nanotube-based material as well as preparation and application thereof

The invention discloses a high-activity electrochemical self-doped TiO2 nanotube-based material as well as preparation and application thereof, and belongs to the field of gas-phase photoelectric catalytic materials. The TiO2 nanotube is reduced to increase Ti < 3 + > and oxygen vacancy defects, so that the conductivity of the TiO2 nanotube is greatly improved, metal is further loaded by adopting a square wave pulse deposition method, active sites on the surface of the material are increased, and photo-induced electron-hole recombination is reduced, so that the TiO2 nanotube-based material with both conductivity and catalytic activity is obtained. The material is used for constructing a gas-phase photoelectrocatalysis system, CO2 is reduced into an alkane energy substance, photon-generated carriers are forcibly separated by applying tiny voltage, and compared with photocatalysis, higher photo-generated electron-hole separation efficiency and catalytic activity are shown, the defects that electrolyte needs to be added, CO2 solubility is low, products are difficult to separate and the like in traditional liquid-phase photoelectrocatalysis are overcome, and the generated products are gaseous alkane hydrocarbon and oxygen mixtures and are easy to separate.
Owner:HUAZHONG UNIV OF SCI & TECH

Hydrogen peroxide modified graphite phase carbon nitride nanosheet and preparation method thereof

The invention discloses a hydrogen peroxide modified graphite phase carbon nitride nanosheet and a preparation method thereof, and belongs to the technical field of photocatalysis. The preparation method of the H2O2 g-C3N4 nanosheet comprises the following steps: (1) adding Urea g-C3N4 powder into a mixed solvent of H2O2 and ethanol, performing stirring, and then carrying out ultrasonic treatmentto uniformly disperse the solution to obtain a mixed solution; (2) centrifuging and drying the mixed solution obtained in the step (1) to obtain a solid; and (3) grinding the solid obtained in the step (2) into fine powder, putting the fine powder into a crucible, and carrying out high-temperature calcination to obtain the hydrogen peroxide modified graphite phase carbon nitride H2O2 g-C3N4, called HCN for short. Compared with UCN, the modified HCN photocatalyst disclosed by the invention has the advantage that the photocatalytic activity is obviously improved.
Owner:CHANGZHOU INST OF TECH

Preparation method of alpha-Fe2O3 nano laminated material and method for preparing benzaldehyde from material

The invention discloses a preparation method of an alpha-Fe2O3 nano laminated material. The preparation method comprises the steps as follows: (a) premixing; (b) concentration; (c) hydrothermal synthesis. The invention further discloses a method for preparing benzaldehyde from the material. The preparation method of the alpha-Fe2O3 nano laminated material has the advantages of simple process, low cost and environment friendliness, the obtained alpha-Fe2O3 nano laminated material catalyzes styrene oxide for preparation of the benzaldehyde, and the method has the advantages of high conversion rate and good selectivity.
Owner:QUZHOU UNIV

Zero-valent iron composite material and preparation method and application thereof

The invention provides a zero-valent iron composite material and a preparation method and application thereof. According to the zero-valent iron composite material, the technical defects that traditional zero-valent iron is prone to agglomeration and unstable can be overcome, surface active sites are increased, meanwhile, a porous material is further adopted for coating, and therefore the activity of boric acid zero-valent iron is kept. The zero-valent iron composite material can be prepared by adopting a ball milling method, the reaction condition is simple, operation is easy, and industrialization is convenient. The zero-valent iron composite material is applied to soil remediation, soil with pollutants being polybrominated diphenyl ethers and / or heavy metal and different pollution degrees can be treated and remedied, and the zero-valent iron composite material has good development prospects.
Owner:SOUTH CHINA NORMAL UNIVERSITY
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