4results about How to "Increase surface active sites" patented technology

The invention belongs to the technical field of concrete, and particularly relates to basalt fiber composite modified sprayed concrete and a preparation method thereof. The basalt fiber composite modified sprayed concrete is prepared from the following raw materials in parts by weight: 420 to 470 parts of cement, 200 to 220 parts of water, 830 to 860 parts of sand, 840 to 880 parts of gravel, 40 to 60 parts of admixture, 15 to 30 parts of modified basalt fiber, 2 to 6 parts of polycarboxylate superplasticizer and 5 to 12 parts of alkali-free accelerator. The modified basalt fiber is added into the sprayed concrete to serve as a reinforcing phase, the strength and impact toughness of the concrete can be improved, and the later strength of the concrete is guaranteed. The cerium trifluoride modified fly ash is added into the admixture, so that the rebound rate can be reduced, and the early strength of the concrete is improved.

This invention belongs to the field of reversible proton ceramic battery technology, and relates to an oxygen electrode material for a three-phase heterointerface reversible proton ceramic battery. The three-phase heterointerface reversible proton ceramic battery oxygen electrode material is a three-phase composite containing A-site defects in double perovskite Pr. 1‑α BaCo2O 5+δ1 (PBC) phase, single perovskite BaPrO 3‑δ2 The invention comprises a (BPO) phase and in-situ desoluble praseodymium oxide nanoparticles; with the total mass percentage of PBC phase, BPO phase, and praseodymium oxide nanoparticles being 100%, the PBC phase accounts for 50-65 wt%, the BPO phase accounts for 33-45 wt%, and the praseodymium oxide nanoparticles account for 1-5 wt%. The three-phase heterogeneous interface oxygen electrode material constructed in situ in this invention exhibits tight coupling and synergistic effects among the three phases, resulting in both a low coefficient of thermal expansion and high catalytic activity. This oxygen electrode material demonstrates excellent electrochemical performance in reversible proton ceramic batteries, whether in fuel cell mode or electrolyzer mode.

This invention discloses a hierarchical guanidine resin-based CO2 adsorbent material and its preparation method, belonging to the field of polymer synthesis technology. The adsorbent material prepared by this invention has a composite spherical structure and a hierarchical pore structure, including micropores, mesopores, and macropores. By introducing a hierarchical pore structure, the adsorption capacity of the material for CO2 is effectively improved. The introduction of hierarchical pores can significantly reduce molecular diffusion resistance and increase the contact area between the adsorbent and CO2 molecules, thereby achieving rapid adsorption. Furthermore, pyridyl, polyamino compounds, and guanidine groups have strong basicity and chemical affinity for CO2. Through surface functionalization modification, the number of active sites on the material surface is significantly increased, thereby further improving the CO2 adsorption capacity and selectivity.

The application relates to the field of cement, and particularly discloses an environment-friendly cement based on carbonaceous coal gangue and a manufacturing method thereof. The environment-friendly cement based on carbonaceous coal gangue raw materials comprise modified coal gangue powder 60-80 parts; cement clinker 30-40 parts; slag powder 10-20 parts; desulfurization gypsum 10-15 parts; tourmaline powder 5-10 parts; ammonium sulfate micro powder 5-10 parts; sodium carboxymethyl cellulose 3-7 parts; and the modified coal gangue powder is obtained by calcining and activating coal gangue powder and then treating the coal gangue powder with a beta-alanine aqueous solution. The environment-friendly cement disclosed by the application takes coal gangue as one of main raw materials, converts the coal gangue into environment-friendly cement with high added value through activation and enhancement treatment. This not only reduces the dependence on natural resources, but also realizes the recycling of waste resources and improves the resource utilization rate; and the cement disclosed by the application can maintain good working performance in the construction process.