The invention discloses an all-solid-state sensitized solar cell and a preparation method thereof. The all-solid-state sensitized solar cell sequentially comprises a photo anode, an interface modification layer, a hole transport layer and a counter electrode from bottom to top, wherein the photo anode sequentially comprises a conductive glass layer, a dense film layer, a porous film layer and a sensitizer layer form bottom to top, and the dense film layer and the porous film layer are both made from titanium dioxide; the sensitizer layer is made from CH3NH3PbI3; the inference modification layer is made from aluminum oxide or magnesium oxide; the hole transport layer is made from spiro-MeOTAD or PTAA; the counter electrode is an Au electrode. The preparation method comprises the steps of during a process of preparing the solar cell, enabling a thin film to be immersed in polymeric precursor solution of the aluminum oxide after the sensitizer layer is prepared and before the spin-coating of a hole transport material is carried out, and obtaining an aluminum oxide interface modification material after natural drying, wherein the charge recombination can be prevented by the interface modification material, and the electron injection efficiency can be increased. According to the all-solid-state sensitized solar cell and the preparation method, disclosed by the invention, the cost is low, the photoelectric conversion efficiency of an all-solid-state dye-sensitized solar cell can be obviously increased, and a great significance is obtained for practical application of the all-solid-state dye-sensitized solar cell.