5results about How to "High theoretical capacity" patented technology

The application discloses an aluminum ion battery positive electrode material and a preparation method and application thereof. x Al y MnO2.nH2O, wherein, 0<=x<=0.3, 1 / 3<=y<2 / 3, 0<=n<=2, and x and n are not 0 at the same time; the preparation method comprises the following steps: mixing an aluminum salt solution and a precursor K z MnO2.mH2O, performing a heating reaction, and obtaining the aluminum ion positive electrode material through heat treatment of a reaction product. The aluminum ion battery positive electrode material has the advantages of high specific capacity, excellent cycle performance and rate performance, low cost, and the like, is beneficial to promoting commercial application of the aluminum ion battery, and has a very wide application prospect.

The present application relates to the technical field of sodium ion battery negative electrode material, and specifically to modified hard carbon negative electrode material and its preparation method and application, the present application takes biomass waste oil tea shell as raw material, adopts sulfuric acid and phosphoric acid as dopant, carries out porosification and activation, obtains P, S double atom doping pre-carbonization porous carbon material after carbonization, takes tetraethyl orthosilicate as raw material to prepare nano SiO2 microspheres under catalysis, carries out carbonization after blending nano SiO2 microspheres and P, S double atom doping pre-carbonization porous carbon material, obtains modified hard carbon negative electrode material through pyrolysis reaction with magnesium powder at the same time of carbonization, the element doping in modified hard carbon negative electrode material provides more active sites for sodium ion storage, improves the theoretical capacity and conductivity of the material, and the nanoscale silicon powder reduces the pulverization phenomenon caused by volume expansion when silicon is used as the negative electrode material of sodium ion battery due to the special size effect, reduces the attenuation of battery capacity.

This invention discloses a lithium-rich manganese-based layered oxide composite cathode material and its preparation method, belonging to the field of lithium-ion battery technology. The method includes: adding water to a nickel source, a cobalt source, and a manganese source to obtain a mixed solution; adding sodium carbonate solution to adjust the pH; washing with deionized water and centrifuging; drying; mixing with lithium salt; and pre-calcining to obtain Li. 1.2 Ni 0.13 Co 0.13 Mn 0.54 O 1.8 F 0.2 The material was then subjected to a process involving the sequential addition of a carbon source and an organic solvent. The resulting mixture was heated under a mixed atmosphere to obtain a lithium-rich manganese-based basal oxide material. Na₂WO₄ and pyrrole were then added, and the mixture was dissolved in deionized water to obtain a composite cathode material, Li. 1.2 Ni 0.13 Co 0.13 Mn 0.54 O 1.8 F 0.2 @N,S-C@Na2WO4@PPy. The composite cathode material of this invention has uniform particles, stable structure, and exhibits considerable wide potential window reversible capacity, excellent rate performance, and stable cycle life.

The present invention relates to a lithium secondary battery which includes a positive electrode including an overlithiated manganese-based oxide, in which an amount of manganese among total metals excluding lithium is greater than 50 mol% and a ratio (Li / Me) of the number of moles of the lithium to the number of moles of the total metals excluding the lithium is greater than 1, as a positive electrode active material; a negative electrode including a silicon-based negative electrode active material; a separator disposed between the positive electrode and the negative electrode; and an electrolyte, and satisfies Equation (1). 0.25A≤B≤0.6A In Equation (1), A is a discharge curve area in a voltage range of 2.0 V to 4.6 V of a dQ / dV graph obtained by differentiating a graph of battery discharge capacity Q and voltage V after one cycle which are measured while charging the lithium secondary battery at 0.1 C to 4.6 V and then discharging the lithium secondary battery at 0.1 C to 2.0 V, and B is a discharge curve area in a voltage range of 2.0 V to 3.5 V of the dQ / dV graph.

The present disclosure provides a sodium battery cathode electrode material, which has a chemical formula as follows:xNaMBO3.yNa2Ti3O7.zNa3V2(BO3)3 / C, wherein the mole number ratio of x to y to z is 0.94-0.96:0.02-0.03:0.02-0.03; M is Fe and Mn, and the mole number ratio of Fe to Mn is 8-9:1-2; and the mass fraction of carbon in the sodium battery cathode electrode material is 1.2% to 1.5%. The sodium battery cathode electrode material provided by the present disclosure is high in capacity, high in voltage platform, stable in structure and high in cycle performance, and the preparation method is simple, low in cost and short in process flow.