72results about How to "Small volume effect" patented technology

The invention relates to a negative pole material for a lithium-ion secondary battery, and the negative pole material comprises composite particles in core-shell structures, conductive additives and an amide type high-temperature-resistant binder, wherein each composite particle in the core-shell structure comprises an inner core and an outer shell layer, each inner core contains at least one of elemental silicon, a silicon oxide and a silicon alloy, and each outer shell layer is coated by one or more of inorganic materials, namely C, Cu, Ni, Fe, Cr, Al2O3, TiO2, LiPO3, Li2Si2O5, Li2SiO3, Li4SiO4, Li8SiO6 and SiO2; and the amide type high-temperature-resistant binder is one or more of polyamide, imide and amide-imide. The invention further relates to a negative pole containing the negative pole material and a preparation method thereof. The invention further relates to a battery containing the negative pole. The battery has the advantages of higher charge-discharge capacity, better cycle property and high safety, and is suitable for various mobile electronic devices or devices requiring mobile energy sources for driving.

The invention discloses a silicon dioxide composite anode material for a lithium ion battery, as well as a preparation method and an application of the silicon dioxide composite anode material. The silicon dioxide composite anode material is prepared from the components of silicon dioxide powder and a conductive carbon layer with the surface of the silicon dioxide powder is uniformly and densely coated. With the adoption of the silicon dioxide composite anode material, the original component structure of an SiO material system is kept, so that the lower volume effect is ensured; the silicon dioxide dense carbon layer coating structure is successfully realized by adopting the technologies of mixing kneading, sheet rolling, press forming and the like, and thus the first coulombic efficiency of the silicon dioxide composite anode material is remarkably increased, and can reach a theoretical value being larger than 77 percent, and the cycle performance and the conductive characteristic are also remarkably improved, so that the silicon dioxide composite anode material is suitable for being charged and discharged with the large rate and can be applied to the power market.

The embodiment of the invention discloses a silicon-based cathode composite material and a preparation method thereof, and belongs to the field of lithium battery cathode materials. An embodiment of the invention is as below: coating nickel hydroxide on the surface of a carbon-nano silicon composite material with a first carbon layer, calcining to remove the first carbon layer, so as to obtain nickel oxide-nano silicon composite material with gaps; then coating a second carbon layer on the surface of the nickel oxide-nano silicon composite material to obtain the silicon-based cathode composite material. The composite material comprises nano silicon particles, a nickel oxide layer arranged outside the nano silicon particles and carbon coating on the nickel oxide; gaps between nickel oxide and nano silicon particles are for containing embedded lithium ions, so as to keep stable structure of the cathode material during lithium deintercalation; and the method reduces the volume effect of the Si-based material and improves specific capacity and cycle performance of the cathode material. The method provided by the embodiment of the invention is safe and environment-friendly, and does not cause environment pollution.

The invention discloses a flexible electrode with carbon fiber wrapped metal oxide for a capacitor and a preparation method. Through surface modification of metal oxide nanoparticles and the like, a flexible membrane that metal oxide nanoparticles are wrapped with a carbon nano fiber (a one-dimensional carbon material) is prepared by using an electrospinning technique, and the flexible membrane can be used in a flexible super-capacitor electrode. Not only is good flexibility achieved, a sufficient buffer space can be provided for volume variation of the metal oxide nanoparticles in operation through the carbon nano fiber, the volume effect of the metal oxide can be reduced, advantages of high specific capacitance, good stability and the like can be achieved, and the properties of a flexible capacitor can be further improved. In addition, methods such as surface chemical deposition or electric deposition are not needed in the production process, and the flexible electrode is simple to operate, controllable in material structure, low in cost and applicable to large-scale industrial production.

The invention provides a silicon-based composite material and a preparation method thereof, a silicon-carbon composite material, and a lithium ion battery containing the materials, belongs to the technical field of lithium ion batteries, and can solve the problem of capacity fading caused by a volume effect of the existing silicon-based composite material and the lithium ion battery prepared by using the silicon-based composite material in the charge and discharge processes. The preparation method of the silicon-based composite material, disclosed by the invention, comprises the steps of: mixing SiOx (x is smaller than or equal to 1.5 and greater than or equal to 0.5) and a conductive carbon substrate to obtain compound powder of the SiOx ( the x is smaller than or equal to 1.5 and greater than or equal to 0.5); and coating the compound powder by a carbon precursor to obtain a coating and carrying out carbonization reaction on the coating. The silicon-based composite material and the silicon-carbon composite material with an excellent cycle performance are obtained by selecting proper technological parameters, and the lithium ion battery containing the materials is prepared. The composite materials disclosed by the invention are prepared by using the method, and the lithium ion battery disclosed by the invention contains the composite materials.

The invention provides a silicon-carbon composite material of a closed cage structure and a preparation method of the silicon-carbon composite material of the closed cage structure. The silicon-carboncomposite material of the closed cage structure is a hollow filled structure material in a closed cage form; the core of the hollow filled structure material is a silicon material-filled porous carbon material; the porous carbon material is filled with a silicon material; the silicon material has the void content of 50-95% in the porous carbon material; and a carbon material coats the outside ofthe silicon material-filled porous carbon material and the specific component of the carbon material is (SiOx)yC, wherein x is smaller than or equal to 2 and greater than or equal to 0 and y is smaller than or equal to 1 and greater than 0. When the silicon-carbon composite material of the closed cage structure is used as a negative electrode of a battery, contact of the silicon material and an electrolyte is isolated, the life of the battery is prolonged and the capacity performance and the cycle performance of the battery are improved.

The invention relates to a nanometer silicon/graphene lithium ion battery cathode material and a preparation method thereof. The cathode material comprises nanometer silicon and graphene, wherein the granularity of nanometer silicon granules is 10-100nm, and the mass ratio of nanometer silicon to graphene is 1:(5-10). The preparation method of the nanometer silicon/graphene lithium ion battery cathode material comprises the following steps of: preparing an electron solution; reducing a silicon tetrachloride liquid phase into nanometer silicon; preparing a graphene oxide glue sample solution; loading the graphene oxide glue sample solution on nanometer silicon; and drying and sintering the semi-finished product of the composite electrode material. According to the preparation method, after the nanometer silicon granules the granularity of which can be controlled are obtained through a liquid phase reducing method; in a mode that a glue body is separated out through replacing a solvent graphene is reduced and a glue layer is formed at the same time, and moreover the glue layer is adsorbed on an existing nanometer silicon glue nucleus; the obtained nanometer silicon has a better size and a better structure, can combine graphene and nanometer silicon efficiently in the term of molecule size; the obtained silicon carbon material has stable circulation performance and excellent electric conducting performance.

The invention relates to a preparation method of a high-capacity anode material, in particular to a method for synthesizing a high-capacity core-shell structure anode material for a lithium-ion battery. The method comprises the following steps: firstly, adding high-capacity nano-particles to raw materials of synthesizing mesocarbon microbeads, and carrying out high-speed stirring and high-temperature polymerization; with the high-capacity nano-particles as a core, generating the mesocarbon microbeads on the surface through polymerization of polycyclic aromatic molecules; and finally obtaining the high-capacity core-shell structure anode material with the high-capacity nano-particles as the core and the mesocarbon microbeads as the shell through high-temperature carbonization. Compared with a traditional synthesis process, the preparation method has the advantages ofachieving uniform coating, simple in process, excellent in electrochemical properties and the like.

The invention discloses a lithium ion battery anode material and a preparation method thereof, and a lithium ion battery. The preparation method comprises the following steps: (1) mixing aluminum and silicon (II) oxide to obtain a mixture, wherein the mass of silicon (II) oxide is greater than that of aluminum; and (2) firing the mixture under an inert atmosphere or vacuum condition at the temperature of 900-1150 DEG C for 2-12h to obtain the lithium ion battery anode material. According to the preparation method, the raw material aluminum is added in the raw material silicon (II) oxide, due to reaction of the raw material aluminum and silicon (II) oxide, the content of active oxygen in the anode material obtained finally is reduced, and the prepared anode material further comprises aluminum oxide. The content of the active oxygen in the anode material is reduced, the charge-discharge first-time efficiency of the anode material is greatly improved, the specific capacity of the anode material is greatly increased; meanwhile, aluminum oxide in the anode material can be used for relieving the volume expansion of silicon in the anode material, so that the volume effect of the whole anode material is reduced.

The invention relates to an iron trioxide monocrystal nanotube/graphene composite electrode material and a preparation method thereof. The composite electrode material of the invention is formed by coating an iron trioxide monocrystal nanotube with graphene via Van der Waals' force, wherein the mass ratio of the graphene and ferric oxide is 1:(1 to 10); the iron trioxide monocrystal nanotube is an alpha-Fe2O3 monocrystal nanotube, and the length thereof is 300 to 500 nm, and the outer diameter is 60 to 90 nm while the inside diameter is 10 to 50 nm. The method designed by the invention is simple in synthetic process and low in cost, and can be applied to lithium ion battery cathode materials. The iron trioxide monocrystal nanotube/graphene composite electrode material has excellent stability and electrochemical performance.

The invention provides a manufacturing method of a temperature-uniforming plate, which comprises the steps of providing a flat first bottom plate with a first bottom surface, wherein the first bottom surface includes at least one cavity region; etching the first bottom plate to form at least two first grooves, and forming a non-etched first post between every two first grooves within the same cavity region; forming a first capillary structure on the surfaces of the first grooves and the first post; filling a working fluid in the first grooves; covering the adhesive on a first surface outside the cavity region; providing a second bottom plate with a second bottom surface, second grooves and a second post; laminating the first bottom plate and the second bottom plate together in the vacuum state to form a closed cavity by the first grooves and the second grooves; and curing the adhesive to obtain the temperature-uniforming plate. The invention also relates to a temperature-uniforming plate manufactured according to the above method.

The invention discloses a preparation method of a high-capacity silicon-carbon composite negative electrode material with a core-shell structure for a lithium-ion battery. The high-capacity silicon-carbon composite negative electrode material with the core-shell structure contains a silicon substance and a carbon substance, and the molar ratio of Si to C is 0.003-0.316. According to the invention,the problems in the prior art are solved, and the negative electrode material not only improves the structural stability of the core material silicon but also can effectively reduce the volume changeand particle fragmentation of an electrode in the lithium intercalation and deintercalation process. Meanwhile, the capacity bottleneck of a shell material carbon is solved, a difference between theresistance and the discharge potential of the core material and the shell material is reduced such that the core material and the shell material can reach a relatively consistent level in the aspect of lithium ion de-intercalation, and the advantage complementation between the core material silicon and the shell material carbon is realized. The coating effect is fully exerted, the structure of thesubstance is stabilized, and the safety stability and the electrochemical performance of the material are improved.

The invention discloses a silicon-containing material and a preparation method thereof. The silicon-containing material comprises silicon oxide particles and a geopolymer, and the geopolymer is dispersed in the silicon oxide particles and on the surfaces of the silicon oxide particles; or the geopolymer is dispersed inside or on the surface of the silicon oxide particles. The preparation method ofthe silicon-containing material comprises the following steps: (1) preparing required raw materials, mixing silicon and silicon dioxide, heating and depositing to obtain sediments, and crushing the sediments to obtain silicon oxide particles; (2) exciting the silicon oxide particles and aluminosilicate under specific conditions to react, thereby obtaining the silicon-containing material. The silicon-containing material has low volume effect and low sensitivity to water, and can effectively improve the first cycle efficiency and safety performance. The preparation method disclosed by the invention is simple in process, simple and convenient to operate, high in productivity and suitable for large-scale industrial production.

The invention relates to a lithium ion battery negative electrode material silicon oxide doped manganese oxide/carbon tube and a preparation method thereof. The material is prepared according to the following method of (1) dispersing a carbon nanotube in a lower alcohol solution of N, N-dimethylformamide to obtain a carbon nanotube dispersion liquid; (2) dissolving a manganese source, a precipitator and a silicon source in the carbon nanotube dispersion liquid, uniformly stirring the mixture, naturally cooling the mixture to a room temperature after hydrothermal reaction, and performing filtering, washing, freezing and drying to obtain black powder; and (3) calcining the black powder in a protective atmosphere, and cooling the product with a furnace to the room temperature so as to obtain the lithium ion battery negative electrode material silicon oxide doped manganese oxide/carbon tube. The material is uniform in morphology and size, and silicon oxide doped manganese oxide particles are grown on a surface of the carbon nanotube; the material has the advantages of high electron conductivity and ion conductivity, short ion diffusion passage, small volume effect during lithium ion intercalation/de-intercalation process and the like; and the material is simple in preparation process, short in period, low in reaction temperature and low in cost, a large amount of materials can be synthesized, and the product yield is high.

The invention discloses an organic material/graphene composite negative electrode. The composite negative electrode is formed by preparation of an organic material, a graphite carbon material and an auxiliary material, wherein the organic material is a mixture selected from one or more of organic acid/anhydride with a conjugate carbonyl structure. The invention also provides a preparation method of the composite negative electrode and a lithium ion battery manufactured by the composite negative electrode. The organic material/graphene composite negative electrode has the characteristics of high capacity, high power and long service lifetime and has a wide application prospect.

The invention provides a carbon-coated silicon-based titanium-niobium composite material and a preparation method thereof, and a lithium ion battery. The preparation method comprises the following steps: with a titanium source and a niobium source as raw materials, carrying out a primary calcination process to obtain a first calcination product, wherein the temperature of the primary calcination process ranges from 800 DEG C to 1200 DEG C; and subjecting a silicon source, the first calcination product and a carbon source to a secondary calcining process so as to obtain the carbon-coated silicon-based titanium-niobium composite material, wherein the temperature of the secondary calcining process is 500-1000 DEG C, the titanium source is one or more selected from the group consisting of anatase titanium dioxide, anatase titanium dioxide hydrate silicon powder and silicon monoxide, the niobium source is niobium pentoxide, the silicon source is silicon powder or silicon monoxide, and the carbon source is hydrocarbon. The carbon-coated silicon-based titanium-niobium composite material prepared by adopting the method has a relatively small volume effect and relatively high cycle performance in the charging and discharging processes; and meanwhile, the preparation method also has the advantages of simple process, no pollution, high repeatability, large-scale production and the like.

The invention discloses a silicon-layered titanium carbide cathode material and a preparation method thereof. A negative electrode material includes silicon particles and layered titanium carbide, wherein the silicon particles are uniformly distributed between a surface of a sheet layer of the layered titanium carbide and the sheet layer. The preparation method comprises steps that Ti3AlC2 or Ti3SiC2 is added to hydrogen fluoride solution to etch to obtain the layered titanium carbide; the layered titanium carbide and the silicon particles are added to solvent for ultrasonic dispersion, afterdrying, the silicon-layered titanium carbide cathode material is obtained. The preparation method of the silicon-layered titanium carbide cathode material is advantaged in that steps are simple, operability is high, the cathode material volume effect is small, and conductive performance and cycle stability are good.

The invention relates to a SnO2 nanorod for a negative electrode of a lithium ion battery, and a preparation method of the SnO2 nanorod. The preparation method comprises the following steps of: adding SnCl2*2H2O into deionized water to obtain milky solution, and performing ultrasonic treatment after adding super P into the milky solution so as to obtain uniform mixed solution; performing microwave hydrothermal reaction of the mixed solution to obtain a SnO2/super P composite material; and sintering the SnO2/super P composite material so as to obtain the SnO2 nanorod. According to the SnO2 nanorod for the negative electrode of the lithium ion battery, and the preparation method of the SnO2 nanorod disclosed by the invention, the super P is used as a template; the structure of a nano material can be controlled to a certain degree, such that aggregation of the nano material is inhibited; compared with the conventional hydrothermal method, a microwave hydrothermal method has the advantages that: microwave is used as a heating tool; stirring in a molecular level is realized; the non-uniform heating disadvantage of a hydrothermal container is overcome; the reaction time is shortened; the working efficiency is increased; and the nano material having complete crystallization and uniform particle size distribution can be prepared; and furthermore, the method is simple to operate, short in period and low in cost, and is suitable for large-scale production.

The invention relates to the field of new energy, and particularly provides a preparation method of the negative electrode of an energy storage device, the negative electrode of the energy storage device, the energy storage device, an energy storage system and electric equipment. The preparation method of the negative electrode of the energy storage device comprises the following steps: carrying out heating pretreatment on dried paper compounded with salt containing a sulfur element in an inert atmosphere to generate a sulfur-containing gas, further heating to realize the carbonization of thepaper and the doping of sulfur, thereby obtaining the negative electrode of the energy storage device. The method is simple in process, low in cost and suitable for industrial production. Based on themethod, the prepared negative electrode of the energy storage device is uniform and stable in structure, high in activity, and low in self weight. Therefore, the specific capacity, the energy densityand the cycle performance of the energy storage device can be improved.

The invention discloses a preparation method of a silicon-based negative electrode material, which comprises the following steps: taking silicon monoxide as a raw material, firstly carrying out surface modification treatment on the silicon monoxide raw material, then combining the silicon monoxide subjected to surface modification treatment with few layers of graphene to prepare a silicon-based capacity unit, and then mixing the silicon-based capacity unit with a carbon-based material to prepare the silicon-based negative electrode material. The invention also discloses the silicon-based negative electrode material of the lithium ion battery prepared by the method, a negative electrode containing the silicon-based negative electrode material, and the lithium ion battery. The reversible capacity and coulombic efficiency of the lithium ion battery can be improved, and volume expansion is reduced.