The invention discloses a low-expansion
porous silicon carbon material and a preparation method thereof, and relates to the technical field of
lithium ion batteries. According to the low-expansion
porous silicon carbon material and the preparation method thereof, S1,
porous carbon is selected, the specific surface area is 1500-2500m < 2 > / g, the particle size is 2-10mu m, and the aperture is 1-5nm; s2, feeding the
porous carbon particles into a
rotary kiln bed, vacuumizing a deposition area of a
rotary kiln under protective gas, and introducing SiH4 for deposition to obtain a
porous silicon carbon precursor; s3, FEC is selected as a
coating precursor, the FEC and
alkyl lithium oxide are subjected to water bath heating, the temperature is 45-80 DEG C, and the time is 2-4 h; s4, heating the purified
vinylene carbonate to a melting state of 30 DEG C, adding an AIBN initiator, and heating to 50-80 DEG C for 5-10 hours to obtain poly (
vinylene carbonate); and S5, uniformly mixing the obtained
vinylene carbonate and the
silicon carbon precursor, raising the temperature to the highest temperature, and keeping the temperature for 15-24 hours to obtain the porous
silicon carbon coated with the vinylene
carbonate.