413 results about "Electron acceptor" patented technology

The invention provides a low C / N sewage nitrogen and phosphorus removal method based on MABR-DPR-anaerobic ammonia oxidation, which couples anaerobic, membrane aeration anoxic and anaerobic ammonia oxidation processes, forms an anoxic environment in a water phase of a membrane aeration reactor, and enriches denitrifying phosphorus-accumulating bacteria. And the anaerobic phosphorus release and anoxic denitrification nitrogen and phosphorus removal processes of the denitrifying phosphorus-accumulating bacteria are realized through the backflow of the sludge between the anaerobic tank and the membrane aeration reactor. Nitrite accumulated in effluent of the membrane aeration reactor supplements an electron acceptor for a subsequent anaerobic ammonia oxidation deep denitrification process, and meanwhile, a carbon source is obviously consumed in an anoxic denitrification nitrogen and phosphorus removal process of the membrane aeration reactor, so that inhibition of influent organic matters on an anaerobic ammonia oxidation process is effectively weakened. The process solves the problem that the carbon source is seriously insufficient in the nitrogen and phosphorus removal process of the low C / N sewage, and the stable and efficient nitrogen and phosphorus removal effect can still be maintained under the condition that an external carbon source is not needed.

The invention relates to a method for quantitatively evaluating the anti-oxidation effect of a skin surface in real time. The method comprises the following steps: applying a reaction medium with a standard potential window on the skin surface; the reducing capacity of skin antioxidant molecules is indirectly reflected through real-time potential drift of electron concentration change in the reaction process; constructing a surface electron acceptor reaction relation framework taking the skin as a reaction main body; deploying the modified electrode array on the skin surface; each pair of electrode sites responds to corresponding reactive oxygen species (ROS); collecting a transient response current and time curve and generating a characteristic curve combination map; an anti-oxidation response electrochemical space fingerprint is established through the pattern form and the response gradient; dividing the electrochemical response signal into a plurality of reaction micro windows; establishing a biophysical state vector of the individual skin by detecting basic conductivity, moisture capacitance and micro-temperature change of the skin surface; the vectors are used for conducting numerical value normalization and response range calibration on the response curve, and a unified standardized anti-oxidation response value is output.

A long-persistent luminescence emitter containing a polymer that contains, relative to the total molar amount of an electron donor structural unit and an electron acceptor structural unit therein, 70 mol % or more of an electron donor structural unit and less than 30 mol % of an electron acceptor structural unit, or containing a polymer that contains, relative to the total molar amount of an electron donor structural unit and an electron acceptor structural unit therein. 70 mol % or more of an electron acceptor structural unit and less than 30 mol % of an electron donor structural unit. The emission decay after stopping light irradiation to the emitter is power law decay.

The invention relates to the technical field of biological denitrification, in particular to a nitrogen-doped carbon dot-based microbial electronic control denitrification system and application thereof. The system comprises electron donor microorganisms, electron acceptor microorganisms and nitrogen-doped carbon dots, the nitrogen-doped carbon dots serve as electron mediators outside cells, an efficient extracellular electron transfer network is constructed, and interspecific electron transfer resistance is reduced; meanwhile, the nitrogen-doped carbon dots can regulate and control intracellular electron transport chains and the energy metabolism process, the improvement of the reducing power and the energy level is promoted, and the metabolism mode optimization is realized. By cooperatively regulating and controlling generation, transmission and utilization of electrons under an extreme electron donor limited oligotrophic condition, the system disclosed by the invention can realize efficient denitrification, avoid nitrite accumulation, remarkably inhibit generation of nitrous oxide (N2O), reduce dependence on an external organic carbon source and an electron source, and improve the denitrification efficiency. And a new technical approach is provided for improving the deep denitrification efficiency under the low-carbon condition.

The invention relates to the technical field of flash fire lifting agents, and discloses a flash fire lifting agent of an electrolyte of a boron-free aluminum electrolytic capacitor and a preparation method of the flash fire lifting agent, and the flash fire lifting agent comprises the following components in percentage by mass: 10-30% of organic ammonium carboxylate; 5%-15% of a nitro compound; 3%-10% of a phosphate ester compound; 2%-8% of a polyethylene glycol derivative; 0.5%-3% of organic siloxane; and the balance of deionized water. Through the synergistic effect of the organic ammonium carboxylate, the nitro compound, the phosphate ester substance and the organosiloxane in a specific proportion, the sparking voltage of the electrolyte is remarkably improved, and the negative effects of boron elements on the environment and the performance of a capacitor are avoided; a nitro compound is used as an electron acceptor to inhibit hydrogen precipitation, and cooperates with phosphate to fill oxide film micropores and block current concentration; the organic siloxane forms a hydrophobic barrier on an electrode interface, electrolyte decomposition is delayed, the organic carboxylic acid ammonium salt accurately controls the free acid concentration, and the conductivity rise caused by hydrogen ion migration is avoided.

The invention discloses an acridine-derived thermally activated delayed fluorescent material and an electroluminescent device thereof, and belongs to the technical field of organic luminescent materials. According to the fluorescent material, any electron withdrawing group is used as a receptor, an acridine derivative is used as a donor, nitrogen atoms of the acridine derivative are directly connected with the receptor, a dihedral angle between an electron donor and the electron receptor is increased, the dihedral angle is kept at an angle close to 90 degrees, meanwhile, the large-rigidity donor structure further reduces intramolecular vibration relaxation, and the fluorescence intensity is improved. In addition, HOMO delocalization can be further realized through side conjugation modification of acridine, so that large antiintersystem crossing rate and radiation decay rate are realized, the luminescence property of molecules is further improved, and the efficiency roll-off is reduced. The material provided by the invention can be used as an active material to be applied to organic electroluminescent devices.

The invention discloses a molecular assembly method of a D-A type blending system, which comprises the following steps: by taking indolo [3, 2-B] carbazole as an electron donor (D) and N, N '-bis (4-pyridyl)-1, 4, 5, 8-naphthalene tetraformyl diimide as an electron acceptor (A), dispersing the electron donor (D) and the electron acceptor (A) in an organic solvent, heating, and carrying out ultrasonic treatment to dissolve the electron donor (D) and the electron acceptor (A) to obtain clear and transparent D-A type blending system assembly liquid; vertically inserting a cleaned conductive substrate into the D-A type blending system assembly liquid, soaking for a period of time, lifting the conductive substrate at a constant speed by using a lifting instrument until the conductive substrate is completely separated from the liquid level, horizontally placing, and naturally volatilizing the solvent until the conductive substrate is completely dried to obtain a completely assembled D-A type assembly film; the invention also provides an application of the D-A type assembled film as multi-system information storage. The micromolecule blending assembly system provided by the invention can realize an ultrahigh-density information storage function.

Compounds of Formula Ia and Ib: (Ia) (Ib) wherein R, R1 and R2 are each independently a linear or branched C6-15-alkyl; X1, X2, X3 and X4 are each independently H, F, Cl or Br; and T1 and T2 are each independently ═O, ═C(CN)2, or ═CHCN, are disclosed herein. Organic photovoltaics (OPVs) based on binary and ternary compositions comprising a compound of Formula Ia and / or Ib are also disclosed. In an aspect, a compound of Formula Ia (electron acceptor material A1) was combined with PTB7-Th (electron donor material D1) to afford binary bulk heterojunction blends. In an aspect, a pair of compounds of Formula Ia (electron acceptor materials A1) were combined with PTB7-Th (electron donor material D1) to afford ternary bulk heterojunction blends. In a further aspect, a compound of Formula Ib (electron acceptor material A1) was combined with P3HT (electron donor material D1) to afford binary bulk heterojunction blends.

The invention is applicable to the technical field of solid-state charge transfer compounds, and provides a solid-state charge transfer compound and a preparation method and application thereof, the solid-state charge transfer compound is EtLP6 alpha-TFTN, ethyl oblique [6] arene EtLP6 is used as an electron donor, and electron-deficient aromatic tetrafluoroterephthalonitrile is used as an electron acceptor. According to the embodiment of the invention, a solid-state charge transfer (CT) compound formed by ethyl oblique [6] arene (EtLP6) and an electron-deficient aromatic receptor (Tetrafluoro-terephthalonitrile-TFTN) is constructed, and the switching type gasochromic property of the solid-state charge transfer (CT) compound on 1, 3-dioxane and 1, 4-dioxane isomer steam is utilized, so that the solid-state charge transfer (CT) compound can be used for realizing the conversion of 1, 3-dioxane and 1, 4-dioxane isomer steam, and the conversion efficiency of 1, 3-dioxane and 1, 4-dioxane isomer steam is improved. The 2, 4-dioxane isomer can be quickly and visually distinguished and detected; according to the embodiment of the invention, the solid-state charge transfer compound can be obtained through simple mechanical grinding, and a complex solvent crystallization process is not involved.

The invention discloses a water-soluble near-infrared two-region aggregation-induced emission material and a preparation method and application thereof, and belongs to the technical field of aggregation-induced emission materials.Benzobithiadiazole is used as an electron acceptor group, dithieno-cyclopentadiene and derivatives thereof are used as electron donor units, and benzobithiadiazole and dithieno-cyclopentadiene and derivatives thereof are coupled to form the water-soluble near-infrared two-region aggregation-induced emission material. The organic near-infrared second-region molecule with the intramolecular charge transfer characteristic is constructed. According to the invention, the positively charged quaternary ammonium salt group is introduced into the electron donor group, and the positively charged quaternary ammonium salt group has good hydrophilicity, so that the water solubility of molecules can be effectively improved. Moreover, the water-soluble near-infrared two-region aggregation-induced emission material has excellent photodynamic and photothermal activity, and realizes efficient killing of bacteria (especially propionibacterium acnes) through the synergistic effect of photodynamic and photothermal effects.

The invention discloses a calcium nitrate slow-release filler for strengthening restoration of black and odorous bottom mud of a river channel and a preparation method of the calcium nitrate slow-release filler. The calcium nitrate slow-release filler is prepared by physically mixing Ca (NO3) 2.4 H2O, PVA (Polyvinyl Alcohol) and sodium carboxymethyl cellulose. The calcium nitrate slow-release filler disclosed by the invention not only can controllably slowly release calcium nitrate and prevent the calcium nitrate from quickly escaping to overlying water to cause secondary pollution after being put into the bottom mud, but also can provide an electron acceptor for the bottom mud, effectively remove sulfide and ferrous ions in the black and odorous bottom mud and relieve the black and odorous phenomenon of the bottom mud in urban river channels; the method has a wide application prospect in the restoration of the black and odorous bottom mud of the river channel.

The invention discloses a biological agent for preventing and treating panax notoginseng root rot, and relates to the technical field of biological prevention and treatment, the biological agent is composed of four layers of functional florae: an A layer of sentinel-decoding flora is used for identifying a pathogen quorum sensing signal and is used as an event trigger source, a B layer of metabolic countering flora is used for decoupling conversion of disease-promoting saponin and controllable release of a metabolic false substrate, and a C layer of functional florae is used for controlling root rot of panax notoginseng. The C-layer self-healing conductive biological membrane construction flora forms a biological membrane with conductivity and self-healing capability on the root surface, and the D-layer electrically-enabled flora constructs stable biological micro-current at the rhizosphere by using ferric oxide particles as external electron acceptors. The layer A triggers to cause controlled release of the layer B, a conversion product of the layer B provides a carbon source and a structural unit for the layer C, and a conductive network of the layer C and the layer D form an electronic path. The biological agent is used for early recognition and continuous inhibition of pathogens in panax notoginseng planting soil, can start defense response in the early stage of quorum sensing signal occurrence, and keeps action stability under complex environmental conditions.

The invention discloses a TADF luminescent material and a preparation method thereof, and relates to the technical field of organic optoelectronics, the molecular structure of the material comprises a phenyl triazine derivative electron-deficient core as an electron acceptor and a carbazole or tert-butyl carbazole electron-rich group as an electron donor; an aggregation-induced emission mechanism is introduced into the thermally activated delayed fluorescence material, so that the aggregation-induced quenching problem of a traditional thermally activated delayed fluorescence material and the exciton annihilation effect under high brightness are effectively solved, and meanwhile, the defect that a traditional aggregation-induced emission molecule is low in electroluminescence efficiency is overcome; the material can be used for preparing a non-doped organic electroluminescent device, the process is simplified, the cost is reduced, and the material has application potential in the field of intelligent response materials.

This invention relates to the field of wastewater treatment technology, and more particularly to a method for anaerobic ammonia oxidation denitrification in a conductive membrane bioreactor for wastewater with low concentrations of nitrite. Anaerobic ammonia-oxidizing bacteria are inoculated into a conductive membrane bioreactor; the bioreactor is connected to a DC power supply, with a conductive membrane assembly as the cathode and a three-dimensional porous or fibrous conductive carbon material with a high specific surface area as the anode, and a positive bias is applied to the anode; nitrogen-containing wastewater with a nitrite to ammonia nitrogen molar ratio of 1:1.5 to 1:5 is introduced into the electro-enhanced membrane bioreactor, where the anaerobic ammonia-oxidizing bacteria use the conductive carbon material at the anode as an extracellular electron acceptor for biological denitrification. This invention, based on a conductive membrane bioreactor, achieves efficient denitrification even under nitrite-deficient conditions through a dual approach of "electroadsorption enrichment + electrostimulation enhancement." This method is simple to operate, energy-saving, and has broad application prospects.

The invention discloses a method and a device for preparing a D-A type thermally activated delayed fluorescent material through continuous flow. A two-section type continuous flow reaction system is adopted, wherein the first continuous flow reaction system is connected with a tubular reactor in series through a micro-channel reactor, and efficient nucleophilic substitution reaction of an electron acceptor halide and an electron donor is achieved under palladium catalysis; the second continuous flow reaction system is driven by double feeding pumps, so that a D-A type compound prepared from a precursor and nonaphenyl tertiary alcohol are subjected to Friedel-Crafts alkylation modification under the catalysis of acid, the reaction time of the two steps is greatly shortened, and the yields of the two steps are both 88% or above. Through flow rate limitation, solvent concentration, solid content and temperature-pressure cooperative control, the problems of palladium-containing catalyst slurry transmission and side reaction inhibition are solved. According to the method, continuous kilogram-level production of the TADF material is achieved, compared with a traditional process, energy consumption is reduced, intermediate separation is not needed, and a new normal form is provided for industrial preparation of the OLED material.

The invention discloses a synthesis method and application of a non-condensed ring electron acceptor, which are different from a traditional condensed ring structure or a single alkyl chain side chain, and a dichlorobenzene unit is introduced as a conformation regulating group. As chlorine atoms have strong electronegativity and proper atomic radius, remarkable non-covalent interaction such as Cl-S and Cl-pi can be generated among molecules. The interaction is similar to a set of precise molecular guide rails, molecules are guided to perform highly ordered pi-pi accumulation, so that electron cloud overlapping is remarkably enhanced, and an efficient electron transmission channel is constructed. According to the organic solar cell prepared based on the non-condensed ring electron acceptor material designed by the invention, the electron mobility is remarkably improved, and meanwhile, the charge recombination loss of a device is effectively reduced.

The invention discloses a water-soluble stable anion free radical compound and a preparation method and application thereof, the anion free radical compound comprises an electron donor and an electron acceptor, the electron donor is an alkali metal compound, and anions of the alkali metal compound are halide ions; moreover, electrons of halide ions are delocalized from an electron donor to an electron acceptor to form an anion free radical compound. An electron donor and an electron acceptor form a charge transfer compound, and the charge transfer compound is self-assembled to form a stable anion free radical compound. The free radical compound takes alkali metal halide salt as an electron donor, on one hand, integer charge transfer between halogen anions and an electron acceptor can be met, and F4TCNQ.-anion free radicals are rapidly generated; on the other hand, coordination bonds with moderate strength are formed between alkali metal cations and F4TCNQ.-. Therefore, the composition has excellent water solubility and stability.

Fullerene-functionalized vinyl polymer having general formula (I):wherein:x is a fractional number comprised between 0 and 0.89;y is a fractional number comprised between 0.01 and 0.9;z is a fractional number comprised between 0.1 and 0.99;provided that the sum of x+y+z is equal to 1;p is an integer comprised between 10 and 10000;w is an integer comprised between 50 and 250;n is an integer comprised between 1 and 12;R represents a hydrogen atom; or is selected from C1-C20, linear or branched, saturated or unsaturated, alkyl groups, optionally containing heteroatoms, optionally substituted aryl groups, optionally substituted heteroaryl groups, optionally substituted cycloalkyl groups, optionally substituted heterocyclic groups.Said fullerene-functionalized vinyl polymer having general formula (I) can advantageously be used as an electron acceptor compound in organic photovoltaic devices (or solar devices).

To provide a novel light-emitting device. A light-emitting device with high emission efficiency is provided. A light-emitting device with a long lifetime is provided. A light-emitting device with low driving voltage is provided.SOLUTION: The EL layer includes a first layer, a second layer, a third layer, a light-emitting layer, and a fourth layer in this order from the anode side, the first layer includes a first organic compound and a second organic compound, the fourth layer includes a seventh organic compound, and the first organic compound has an electron-accepting property with respect to the second organic compound; HOMO levels of the second organic compounds are greater than or equal to - 5. 7eV and less than or equal to - 5. 2eV, and electron mobilities of the seventh organic compounds are greater than or equal to 1 * 10 - 7cm2 / Vs and less than or equal to 5 * 10 - 5cm2 / Vs when a square root of an electric field intensity [V / cm] is 600.SELECTED DRAWING: Figure 1

Provided is a heat-sensitive recording body which is environmentally friendly and has excellent water resistance and oil resistance as well as excellent color developing performance.　The heat-sensitive recording body has a heat-sensitive recording layer containing a colorless or light-colored electron-donating leuco dye and an electron-accepting developer on a support, wherein the electron-accepting developer is an isolated lignin, and the heat-sensitive recording layer contains toluenesulfonamide as a sensitizer.

The invention discloses a pure organic room-temperature phosphorescent material and a preparation method thereof, and relates to the technical field of organic phosphorescent materials. The structural formula of the pure organic room-temperature phosphorescent material is as follows: R1 and R2 are independently selected from substituted or non-substituted alkyl, and R3 and R4 are independently selected from hydrogen, substituted alkoxy or non-substituted alkoxy. According to the present invention, the rotation resistance covalent bond is introduced between the electron donor and the electron acceptor, such that the electron donor and the electron acceptor cannot be coplanar so as to achieve stable ground state-excited state molecular orbital separation; an ester group with lone pair electrons is introduced to a proper position on an electron acceptor, so that the ester group is overlapped with a molecular orbit of an electron donor through the lone pair electrons, thereby providing an n-pi transition path in a triple excited state, and further greatly improving kP. Compared with the existing pure organic room-temperature phosphorescent material, the kP of the pure organic room-temperature phosphorescent material provided by the invention is improved by one order of magnitude, and stable phosphorescent emission can be realized in air.

The invention discloses a perovskite solar cell with significantly improved efficiency and a preparation method thereof, and the interface of a perovskite light absorption layer / hole transport layer is modified by using an organic molecular material 1, 4, 5, 8-tetrafluoronaphthalene-2, 3-dinitrile with a strong electron acceptor. Tests show that the perovskite solar cell modified by a proper amount of 1, 4, 5, 8-tetrafluoronaphthalene-2, 3-dinitrile effectively promotes the separation of current carriers, increases the extraction and transmission of the current carriers, reduces the defect state density of the perovskite surface, prolongs the service life of the current carriers, improves the long-term stability and humidity stability of a device, and improves the performance of the device. And the photoelectric conversion efficiency of the cell is improved. The photoelectric conversion efficiency (PCE) of the perovskite solar cell device modified by the 1, 4, 5, 8-tetrafluoronaphthalene-2, 3-dinitrile reaches 22.82%, and after the photovoltaic performance of the perovskite solar cell device is continuously monitored in a dark box nitrogen environment at room temperature for 1400 hours, 90.6% of the initial efficiency of the perovskite solar cell device is still maintained. 80.3% of the initial efficiency is still maintained under the air environment condition that the relative humidity is 45% at room temperature. According to the invention, the strong electron acceptor material is utilized to perform interface modification on perovskite, the cell performance is significantly improved, and an important reference is provided for industrialization of perovskite solar cells.

Disclosed is a composition for forming a hole transport layer, the composition containing a charge transport polymer having a unit which is represented by a specific structural formula, tetraaryl borate ions, a first solvent that is an aromatic compound containing an oxygen atom, and a second solvent that does not contain an oxygen atom.　The present invention can provide: a composition which contains a polymer having an aromatic amine structural unit and an electron-accepting compound that improves conductivity, contains a mixed solvent that sufficiently dissolves the polymer and the electron-accepting compound, and can be suitably applied to the formation of a hole transport layer; and a photoelectric conversion element which has a hole transport layer that is formed using the composition.

The invention discloses a phenanthroimidazole-based Fe < 3 + > specific recognition fluorescent probe and application thereof. The fluorescent probe takes a phenanthroimidazole group as an electron donor unit and takes a benzene ring and a fluorine atom substituted benzene ring as an electron acceptor unit. An imidazole group and a fluorine atom are respectively introduced in the directions of a short axis and a long axis of a molecule, so that fine regulation and control of excited state properties are realized, vibration coupling in a first singlet excited state is effectively inhibited, high-purity blue light emission is obtained, and the photophysical properties of the material are remarkably improved. The fluorescent material is simple and convenient in synthesis method, easy to purify, excellent in thermal stability and remarkable in signal response, and has a wide application prospect in detection of Fe < 3 + > in a high-temperature industrial environment.

The present application belongs to the technical field of soil environment regulation, and particularly relates to a paddy soil carbon fixation and emission reduction regulation method based on a ferrihydrite-organic matter complex. The ferrihydrite-organic matter complex is prepared through coprecipitation, the mineral combination degree of organic carbon in soil is improved, and the biological availability thereof is reduced, so as to alleviate the process of organic carbon decomposition and greenhouse gas emission mediated by microorganisms. Under the condition of redox fluctuation, the complex can maintain good structural stability, slow down the process of iron reduction and dissolution and the process of organic carbon release accompanying the same. In addition, the ferrihydrite as an electron acceptor can participate in the electron competition process under anaerobic conditions, so as to inhibit the production of methane to a certain extent. Therefore, the ferrihydrite-organic matter complex can realize the synergistic regulation of organic carbon stabilization and greenhouse gas emission reduction in paddy soil.

The invention relates to a eutectic material, a hydrate physical mixture as well as preparation and application thereof. The eutectic material comprises an electron donor and an electron acceptor, wherein the electron donor is a bidentate benzimidazole compound with V-type conformation, and the electron acceptor is an aromatic compound containing a strong electron withdrawing group. The material can be widely applied to the fields of multiple anti-counterfeit labels, visual temperature sensing, polar solvent recognizers, nitrobenzene toxic compound detection and the like, and has important practical application value.

The invention discloses a method for rapidly constructing denitrification type anaerobic methane oxidation through hydrogen type methanogens, and relates to the technical field of sewage treatment. According to the method, anaerobic digestion sludge of a sewage treatment plant is taken for inoculation, and a methanogen-mediated denitrification type anaerobic methane oxidation process is constructed. Hydrogen-type methanogens in the anaerobic digestion system excite a reverse methanogenesis function under the condition that organic matters are deficient, and denitrification anaerobic methane oxidation is realized by coupling sulfate and nitrate with nitrogen and sulfur circulating microorganisms. Sulfate is used as a potential electron acceptor in sewage, and dissoluble methane is removed while sulfate is indirectly utilized through recessive biological sulfur cycle catalytic bridging anaerobic methane oxidation and denitrification. In addition, the anaerobic digestion sludge can be continuously inoculated with hydrogen-type methanogens, and compared with traditional denitrification type anaerobic methane oxidation archaea culture, the method is more convenient. Therefore, the denitrifying anaerobic methane oxidation rapidly constructed by the hydrogen-type methanogens is an effective measure for breaking through the deep denitrification of the sewage treatment plant and synchronously controlling and discharging the greenhouse gas.

In certain embodiments, the present disclosure provides methods of treating diseased or damaged tissue in a patient. In some forms the methods comprise introducing a photocurable composition to the diseased or damaged tissue, the photocurable composition comprising a photoactivatable metal ligand complex, a matrix forming polymer, and an electron acceptor. Such methods may further comprise irradiating the photocurable composition through a tissue portion to induce a photocrosslinking reaction forming crosslinks between individual polymers of the matrix forming polymer within the photocurable composition.

The application belongs to the field of photodynamic therapy, and specifically discloses a vitamin K co-crystal material for photodynamic therapy and a preparation method thereof. The vitamin K co-crystal material takes vitamin K as an electron acceptor, and the two carbonyl groups at the para positions of the vitamin K quinoid six-membered ring make the vitamin K exhibit electron deficiency, form an organic charge transfer complex with the electron acceptor, and self-assemble to form a co-crystal, so that the absorption spectrum of the system is widened, a wider wave band of light is more effectively utilized, the photodynamic therapy response wavelength of the vitamin K is adjusted from the ultraviolet region to the visible region and the near infrared region, the problem of low penetration depth and light damage caused by photodynamic therapy using light in the ultraviolet region is avoided, and the vitamin K has excellent photodynamic performance and good application prospects in surface sterilization and disinfection, treatment of body surface infection, and directional cancer treatment based on visible light or near infrared light.

The application belongs to the technical field of fluorescent probe, and particularly relates to a near-infrared selenium rhodamine photodynamic photosensitizer as well as a preparation method and application thereof. In order to provide a selenium rhodamine photosensitizer with an excitation light wavelength in a near-infrared region, a selenium rhodamine dye is used as a parent chromophore and an electron acceptor, anthracene is used as an electron donor, and a non-heavy atom photodynamic photosensitizer AN-SeR is designed and synthesized. The photosensitizer exists in a monomer and a J-aggregate in an aqueous solution. The J-aggregate can not only improve the singlet oxygen quantum yield by reducing the energy level gap between the singlet state and the triplet state, but also more importantly expand the excitation light wavelength of AN-SeR from the visible region to the near-infrared region which is more suitable for biological application. Under near-infrared light (650 nm) irradiation, the half lethal concentration of AN-SeR to cancer cells is 0.052 muM, and AN-SeR has potential biological application value.