1131 results about "Ether solvent" patented technology

Disclosed are compositions for an organic electroluminescent device favorably used for forming a hole injection layer and a hole transport layer of the organic electroluminescent device by a wet film forming method. The compositions for the organic electroluminescent device, which are composite solutions prepared by dissolving hole transport materials such as aromatic diamine compounds and an electron acceptor such as tri(pentafluorophenyl)boron in a solvent that contains an ether solvent and / or an ester solvent whose water solubility at 25° C. is 1 weight % or less in the solvent, with a concentration of 10 weight % or higher in the compositions.

Improved methods for synthesis of oligonucleotides and other phosphorus-linked oligomers are disclosed. The methods include the use of aromatic solvents, alkyl aromatic solvents, halogenated aromatic solvents, halogenated alkyl aromatic solvents, or aromatic ether solvents to achieve deprotection of protected hydroxyl groups.

The invention provides a power battery and a lithium ion electrolyte thereof. The lithium ion electrolyte comprises a non-aqueous organic solvent, lithium salt and an additive, wherein the additive comprises a first additive and a second additive, and the first additive comprises silane sulfate; the first additive accounts for 0.05 to 10% of the total weight of the electrolyte, and the second additive is an auxiliary additive and comprises one or more of vinylene carbonate, propane sultone, fluoroethylene carbonate, vinyl ethylene carbonate, ethylene sulfite, adiponitrile, and succinic anhydride in any proportion; the second additive accounts for 0.1-5wt% of the total weight of the electrolyte, and the non-aqueous organic solvent is a carbonic ester solvent, a carboxylic ester solvent, an ether solvent or a ketone solvent; and the lithium salt comprises primary lithium salt and secondary lithium salt.

The invention relates to an environment-friendly safe solvent cleaning agent which specifically comprises the following components in parts by weight: 0-97 parts of C10-C12 alkanes, 3-100 parts of alcohol ether solvent, 0.00-0.01 part of antioxidant and 0.00-0.01 part of corrosion inhibitor. The environment-friendly safe solvent cleaning agent provided by the invention is narrow in boiling range and the distillation recovery rate of the environment-friendly safe solvent cleaning agent can be above 95%; the environment-friendly safe solvent cleaning agent is also high in clearing ability, and has strong cleaning ability for polar dirt and nonpolar dirt; especially, the environment-friendly safe solvent cleaning agent can be used for thoroughly cleaning various metal working fluids, and oil-based and water-based cutting fluids without any residual and corrosion on metals; moreover, the shortcoming that the previous hydrocarbon type cleaning agents are wide in boiling range and only capable of dissolving and cleaning the nonpolar dirt are overcome. The cleaning agent is perfect in balance of cleaning ability, safety, dryness and reproducibility.

The invention relates to a method for obtaining high pure dicarboxylic acid. The method comprises the steps of I. heating a termination fermentation broth for inactivation; II. acidizing to make dicarboxylic acid crystallized and precipitated, and filtering to obtain a filter cake of dicarboxylic acid; III. mixing the filter cake of dicarboxylic acid and an ether solvent to make the dicarboxylic acid dissolved, separating an organic phase and a water phase, wherein the ether solvent is ether, n-propyl ether, iso-propyl ether, butyl ether, amyl ether or hexyl ether; IV. adding organic an adsorbent to the organic phase obtained from the step III, and filtering to remove solid materials; and V. cooling the organic phase obtained from the step IV until dicarboxylic acid is crystallized and precipitated, filtering to obtain a filter cake of crystallized dicarboxylic acid, and drying the filter cake of crystallized dicarboxylic acid to obtain a dicarboxylic acid product with a purity, by weight, higher than 98.5%. The method overcomes the shortages of complex operation, high production cost, low product purity, high colourity, high equipment investment and the like in a conventional refining method.

The invention discloses a method for preparing water-soluble solid styrene / acrylic resin and application thereof. The method prepares the required resin by simultaneously performing free radical polymerization reaction and esterification reaction on an aromatic vinyl unsaturated monomer, an aliphatic vinyl unsaturated monomer, an unsaturated carboxylic acid monomer, fat alkanol, an initiating agent and an alpha-methyl styrene dimer in a reactor. In the method, the alpha-methyl styrene dimer is added as a chain transfer agent to reduce the branching degree and avoid the generation of gel and the blockage of the reactor; and simultaneously, the added fat alkanol performs esterification reaction with acroleic acid to inhibit the esterification reaction between an alcohol ether solvent and the acroleic acid, thus the viscosity of the reaction mixture is controlled effectively, and the finally prepared resin has narrow molecular weight distribution (Mw / Mn is less than 2.0), low molecular weight (Mw is less than 10,000), few organic volatile matters, and good wetting dispersion of pigment, and can be applied to preparing water color ink, coating or oil polish.

The invention discloses a pyroxylin lacquer with low smell, wherein the pyroxylin lacquer has no benzene hydrocarbon, and the lacquer formula includes 10 percent-25 percent by weight of at least one resin, 25 percent-55 percent by weight of at least one of alcohol ether solvent, ester solvent or alcoholic solvent, , 20 percent-50 percent by weight of at least one curing agent, plasticizer and additive, the pyroxylin lacquer of the invention uses non-benzene solvent, and ensure the superiority of pyroxylin lacquer per se, so as to effectively avoid environmental pollution produced in production, construction and using process of the benzene hydrocarbon, and health hazard to production operator and constructer.

The invention provides a method for preparing an intermediate of vitamin A, namely C14-aldehyde, and an intermediate of the C14-aldehyde, namely C14 enol ether, which comprises the following steps of: (1) under the protection of inert gas, performing rearrangement dissociation reaction on C4 phosphonate at the temperature of between -40 and 30DEG C in the presence of alkali in an ether solvent ora dipolar aprotic solvent; (2) adding beta-cyclocitral, and performing Wittig-Homer condensation reaction at the temperature of between -40 and 30DEG C in the presence of alkali in the ether solvent or the dipolar aprotic solvent to obtain the C14 enol ether; and (3) under the protection of inert gas, mixing the C14 enol ether, an acid catalyst, water and a homogenous phase solvent, and performing hydrolysis reaction at the temperature of between 10 and 35DEG C with stirring to obtain the C14-aldehyde. The method has the advantages of simple process, readily available raw materials and low cost, and has great industrial value.

The invention discloses a metal cyanide coordination catalyst and a preparation method and application thereof. The catalyst has the structural formula of M1a[M2(CN)bL1c]d(X)m(L2)n.xSu.yL3.zH2O. The method for preparing the metal cyanide coordination catalyst comprises the following steps of: regulating mixed solution I' which consists of L3, M3e[M2(CN)bL1c]f, deionized water I, alcohol and / or an ether solvent to have a pH value of less than 7; and adding the solution I' into mixed solution II' which consists of M1(X)g salt, Su or a Su precursor, and deionized water II, and stirring for reaction at the temperature of between 20 and 120 DEG C for 0.5 to 200 hours; and separating, drying, the repeatedly dispersing to form slurry in an anhydrous organic solvent in which L2 is dissolved, distilling, separating and drying to prepare the metal cyanide coordination catalyst. The catalyst has the advantages of porous structure of less than 100nm, presence of coordination of M1 and L2 on a chemical structure, and obvious alternative selectivity in the process of catalyzing the copolymerization of epoxide and carbon dioxide.

An electrochemical device, having an anode containing magnesium; a cathode stable to a voltage of at least 3.2 V relative to a magnesium reference; and an electrolyte obtained by admixture of a magnesium salt of a non-nucleophilic base comprising nitrogen and aluminum trichloride in an ether solvent is provided. As sulfur is stable to a voltage of at least 3.2 V relative to a magnesium reference, a magnesium-sulfur electrochemical device is specifically provided.

The invention discloses a preparation method of a sofosbuvir intermediate, which comprises the following step: in an anhydrous non-protonic solvent, carrying out dynamic kinetic resolution on a compound disclosed as Formula (II) under the action of an organic alkali and / or inorganic alkali to prepare a compound disclosed as Formula (I), wherein the non-protonic solvent is one or more of ester solvent, ketone solvent and ether solvent, the organic alkali and / or inorganic alkali account / accounts for 0.1-10 wt% of the compound disclosed as Formula (II), the temperature of the dynamic kinetic resolution is 10-30 DEG C, and the time of the dynamic kinetic resolution is 5-10 hours. The preparation method has the advantages of high conversion rate, high product purity and low cost, and is environment-friendly.

The present invention discloses a method for preparing 3-aminomethyl-3,5,5-trimethyl cyclohexylamine(isophorone diamine, IPDA) from 3-cyan-3,5,5-trimethyl cyclohexanone(IPN). The method comprises the following steps 3-cyan-3,5,5-trimethyl cyclohexanone, ammonia, an alcohol and / or ether solvent, a hydrogenation catalyst and a promoter are reacted at a temperature of between 50 and 120 DEG C and a hydrogen pressure of between 5 and 15 MPa so as to obtain 3-aminomethyl-3,3,3-trimethyl cyclohexylamine. The method simplifies the prior process for preparing IPDA from IPN, is low in equipment cost, mild in reaction conditions and high in offspring yield.

The present invention relates to monocyclopentadienyl phenoxyl substituted cyclopentadienyl metallocene compound serving as olefin polymerizing catalyst and its preparation process and application. The preparation process includes the following steps: 1. reaction of cyclopentadienyl derivative and MCl4 in the molar ratio of 2 to 1 in ether solvent to produce cyclopentadienyl metal chloride; 2. reaction of strong alkali compound and ligand derivative containing phenoxyl side chain in the equal molar ratio in ether solvent to produce metal salt of the corresponding ligand derivative; and 3. reaction of the ligand derivative containing phenoxyl side chain and the cyclopentadienyl metal chloride in the equal molar ratio in organic solvent to obtain the catalyst. The catalyst has excellent olefin polymerizing catalyzing effect.

The invention discloses a mothproof fabric and a preparation method thereof. The preparation method of the mothproof fabric comprises the following steps: weaving natural fibers into an inner layer, synthetic multifilament yarn into a surface course, and polypropylene fiber filament or polyethylene fiber filament fabric into a lapping layer, wherein the inner layer and the surface course are in grid shape; dying in dying liquid at a temperature of 60-105 DEG C for 10-120 minutes; washing with water; drying; and forming, wherein the dying liquid is a missible-oil aqueous solution, missible oil is formed by mixing pyrethroid and ether solvent in a mass ratio of 1:5 to 1:20; the mass ratio of the fabric to the dying liquid is 1:7 to 1:20; and the amount of the missible oil is 5-10% of the fabric weight. The method has short production flows, convenient operation, small consumption of a pyrethroid pesticide and low requirements for fiber material by adopting dying and the additional pyrethroid pesticide; and the fabric prepared by the method has favorable permeability, strong capability of resisting insect invasion and long anti-mosquito effect.

The invention relates to an electrolyte for an aluminium electrolytic capacitor and a preparation method of a core solute thereof, in particular to an electrolyte for a medium-high voltage aluminium electrolytic capacitor, which has high heat stability. The electrolyte for the medium-high voltage aluminium electrolytic capacitor comprises a solute and a solvent and is characterized in that the solute comprises alpha position dicarboxylic acid which contains branched chains or binary carboxylic salt, the solvent is one of an alcohol solvent, an alcohol ether solvent, an acid amide solvent, a sulphone solvent, a sulphoxide solvent and an ester solvent or is a mixed solvent formed by more than one of the alcohol solvent, the alcohol ether solvent, the acid amide solvent, the sulphone solvent, the sulphoxide solvent and the ester solvent, wherein the content of the alpha position dicarboxylic acid which contains the branched chains or the binary carboxylic salt is 0.1-30 percent by weight, and the preferable content is 2.5-15 percent by weight. Besides, the invention also provides a preparation method of the alpha position dicarboxylic acid which contains the branched chains and dicarboxylic acid ammonium salt. Due to the alpha position dicarboxylic acid which contains the branched chains and the binary carboxylic salt, the electrolyte inside glycol has better solubility and heat stability, and the obtained capacitor has long service life and good low-temperature property.

The present invention is one kind of water soluble anticorrosive paint and its preparation process, and belongs to the field of paint technology. The water soluble anticorrosive paint consists of two components, including the component A comprising chitin-epoxy resin emulstion 45-50 weight portions, ferric oxide red 20-22 weight portions, antirust pigment 8-10 weight portions, talcum powder 8-10 weight portions, defoaming agent 0.25-0.35 weight portions, leveling agent 0.25-0.35 weight portions, flash rust resistant 0.35-0.45 weight portions and deionized water 8-10 weight portions; and the component B comprising polyamide 650 58-62 weight portions and alcohol ether solvent 38-42 weight portions. The water soluble anticorrosive paint has excellent emulsifying performance, high protecting performance, good antisepsis and anti-mildew performance, high weather resistance and high alkali tolerance.

The invention discloses an environment-friendly water-based metal cleaner and a preparation method thereof. The environment-friendly water-based metal cleaner is composed of the following components of, by mass, 5-30% of a nonionic surfactant without APEO, 0.1-5% of a cationic surfactant, 0.1-15% of an inorganic washing assistant, 0.3-5% of a chelating agent, 0.5-6% of a corrosion inhibitor, 0.5-7% of an anti-redeposition agent, 0.5-3% of a penetrating agent, 0.1-8% of an alcohol ether solvent, and the balance water. The preparation method of the environment-friendly water-based metal cleanercomprises the following steps that the inorganic washing assistant and the chelating agent are added in the water and evenly mixed; then the nonionic surfactant without the APEO, the cationic surfactant, the corrosion inhibitor, the anti-redeposition agent, the penetrating agent and the alcohol ether solvent are added and evenly mixed; and the environment-friendly water-based metal cleaner is obtained. The environment-friendly water-based metal cleaner is free of phosphorus, nitrite and the APEO, good in anti-rust performance, good in stability, free of stimulation, safe, environmentally friendly and simple in preparation technology.

A liquid / liquid extraction method is used for separating a perfluorinated polyether (PFPE) into two molecular-weight distributions using an alcohol or cyclic ether as one solvent and a fluorinated solvent as the other solvent. The more polar alcohol or cyclic ether solvent extracts the lower molecular weight PFPE and the less polar fluorinated solvent extracts the higher molecular weight PFPE. In addition, when the PFPE is a mixture of PFPEs with different end groups, such as a mixture of predominantly Z-Tetraol but with other PFPEs with Z-Dol end groups, there is an enrichment of the Z-Tetraol in the more polar solvent. The preferred PFPE is a mixture of PFPEs in as-purchased Z-Tetraol and the preferred solvents are methanol or trifluoroethanol as one solvent and a perfluorinated hydrocarbon, such as perfluorohexane, as the other solvent.

The invention discloses a preparation method of a ribofuranose phosphate derivative. The preparation method comprises preparation steps as follows: L-alanine isopropyl ester hydrochloride, phenol dichlorophosphate and substituted phenol are taken as starting materials and have a docking reaction under the action of alkali; (2R)-2-deoxy-2-difluoro-2-methyl-D-erythropentonic acid GAMMA-lactone and 3,5-dibenzoate reduce carbonyl in a dichloromethane or ether solvent into an alcoholic hydroxyl group under the action of a strong reducing agent; an intermediate with a formula 2-1 has a reaction with paratoluensulfonyl chloride under the action of alkali to obtain p-toluenesulfonates; an intermediate with a formula 2-2 and a benzoyl cytosine derivative have a docking reaction under the action of a condensing agent; an intermediate with a formula 2-3 converts cytosine into uracil under the action of organic acid; benzoyl protection for an intermediate with a formula 2-4 is released under the action of an alkaline agent; an intermediate with a formula 2-5 and an intermediate with a formula 1 are docked under the action of a Grignard reagent to obtain Sofosbuvir.

The invention relates to a cleaning agent for clearing away resins and soldering, comprising the following components in weight ratios: 20-60% alcohol-ether solvent, 0-5% rosin solvent, 0.001-0.01% corrosion inhibitor, 0.001-0.01% antioxidant, and a hydrocarbon solvent added to 100%. The cleaning agent has strong capability of dissolving resins, soldering and oil contaminations, and short in cleaning time, which only needs 10-15 min, and has no corrosion on an integrated circuit board; the used cleaning agent can be recycled through distillation; and more importantly, such an environment-friendly resin and soldering cleaning agent contains no halogenated hydrocarbons which are strong in toxicity and have damage influence on the atmosphere; therefore, the cleaning agent is a substitute product for the halogenated hydrocarbon cleaning agents.

The invention discloses a liquid metal anode material, a room-temperature liquid metal battery, and a preparation method and an application. The anode material is a black green liquid which is formed by mixing alkali metal, an aromatic compound and an ether solvent, wherein the alkali metal is any one of metal sodium, metal lithium or metal potassium; and the aromatic compound is any one of biphenyl, derivatives of the biphenyl, naphthaline, derivatives of the naphthaline and anthracene or derivatives of the anthracene; and the ether solvent comprises one or more of glycol dimethyl ether, diethylene glycol dimethyl ether or tetraethylene glycol dimethylether and the like.

An electrochemical device, having an anode containing magnesium; a cathode stable to a voltage of at least 3.2 V relative to a magnesium reference; and an electrolyte containing an electrochemically active magnesium salt obtained by mixing an organic magnesium compound with an aluminum compound in an ether solvent and separation of the electrochemically active salt from the reaction mixture is provided. The separated electrochemically active salt is stable and safe to handle in comparison to conventional Grignard based electrolyte systems.

The invention relates to the technical field of the surface treatment of metal powder, in particular to a preparation method of coated aluminum powder, comprising the following steps of: mixing and stirring aluminum powder and an alcohol / ether solvent; then, respectively adding organosiloxane, water and a pH regulating agent; reacting and mixing; and pumping and filtering to prepare coated sheet aluminum powder. The preparation method can complete a coating process at normal temperature, has simple manufacturing technology and can better coat aluminum powder paint. The prepared aluminum powder paint has better acid-base resistance, glossiness and good dispersivity in a water paint system and solves the problem of hydrogen liberation of aluminum powder in chromium-free aqueous Dacromet paint.

The invention relates to a water-based primer-topcoat synthetic anti-corrosive paint for coating automobile spare parts and a preparation method thereof. Most of the traditional water-based anti-corrosive paints have the shortcomings of poorer outdoor durability, self-drying performance and anti-corrosive performance. The water-based primer-topcoat synthetic anti-corrosive paint for coating the automobile spare parts comprises the following components in percentage by weight: 39.5-59.5% of water-based epoxy-ester modified acrylic resin, 25-35% of anti-corrosive pigment and filler, 0.15-0.4% of water-based deforming agent, 0.3-0.6% of water-based wetting dispersant, 0.15-0.4 of water-based substrate wetting agent, 5-8% of alcohol ether solvent, 15-20% of water, 0.5-0.8% of water-based drying agent, 1.0-1.5% of anti-corrosive agent, 0.2-0.5% of thickening agent and 0.05-0.2% of organic amine neutralizing agent. The water-based primer-topcoat synthetic anti-corrosive paint provided by the invention can dry by per se under a normal temperature; and the weather resistance property and the non-corrosive property of paint films are good.

The invention discloses an electrolyte and a lithium secondary battery comprising the same. The lithium secondary battery includes the components of: a positive electrode including an overlithiated lithium transition metal oxide with a layered structure; a negative electrode including a silicon-based negative active material; and an electrolyte that is interposed between the positive electrode and the negative electrode and includes a fluoride-based ether solvent in an amount of 3 vol% or more based on a total volume of a non-aqueous electrolytic solution.

The invention discloses an aqueous finish paint used for coiled material. For a present aqueous paint used for steel band, in the preparation of epoxy modified polyester resin in the paint, it becomes aqueous must after amine neutralization, thereby, the steel band coated by the paint has the disadvantage of poor coating film water resistance. The aqueous finish painting in the invention comprises the following components: water soluble saturated polyester resin 45-50%, pigment 25-35%, aqueous defoaming agent 0.2-0.5%, aqueous wetting and dispersing agent 0.5-0.8%, aqueous leveling agent 0.3-1.0%, ethers solvent 2-5%, water 5-10%, water soluble amino resin 5-8%baking vanish cooling catalyst 0.2-0.8%, delustering powder 0-1.0% and aqueous anti-scratch agent 0-0.1%. The invention realizes water solubility of polyester resin by dicarboxybenzenesulfonic acid sodium salt, does not need amine neutralization, and achieves coating film with good water resistance.

The invention discloses an aqueous bronze powder preparation method. The method comprises the following steps: cleaning sheet bronze powder ball-milled in a ball mill with a ketone solvent in a cleaning tank, press-filtering, and carrying out solid-liquid separation to obtain a filter cake; adding the filter cake, an alcoholic solvent and a titanate coupling agent to a reaction container, and stirring; taking ammonia water and distilled water, and mixing ammonia water with distilled water for dilution; taking ethyl orthosilicate, and diluting with the alcoholic solvent; simultaneously adding to the reaction container in a dropwise manner; ageing for 6-10h, taking out, press-filtering, and carrying out solid-liquid separation to obtain inorganic silicon coated bronze powder; taking the inorganic silicon coated bronze powder and an ether solvent, and uniformly dispersing the inorganic silicon coated bronze powder in the ether solvent; and taking a hydrophilic ester monomer and an azo initiator, adding to the reactor, coating, taking out, press-filtering, and carrying out solid-liquid separation to obtain aqueous bronze powder. The method adopts an organic-inorganic double layer coating modifying treatment process to prepare the aqueous bronze powder, so the aqueous bronze powder has a high controlled release efficiency and does not change its color for a long time in alkaline printing ink.

The invention provides manufacturing of a carbon deposition cleaning agent for an automobile engine, and is characterized in that the carbon deposition cleaning agent consists of anionic surfactant alkyl benzenesulfonic acid triethanolamine serving as the cleaning agent, anionic surfactant oleic acid triethanolamine serving as the cleaning agent, a nonionic surfactant nonylphenol polyoxyethylene ether serving as the cleaning agent, a nonionic surfactant lauryl amine polyoxyethylene ether serving as the cleaning agent, triethanolamine serving as a metal antirust agent, benzotriazole serving as a corrosion inhibitor, a propylene glycol monoethyl ether solvent, a butyl cellosolve solvent, a trichloromethane solvent and a 97# gasoline solvent. The carbon deposition cleaning agent is mainly suitable for performing rapid infiltration and powerful cleaning on deposited carbon on the automobile engines, the top of pistons, gasoline nozzles, air valves, air valve conduits and the inner walls of exhaustion pipe silencers. The carbon deposition cleaning agent is faint yellow and transparent liquid and has no corrosiveness against the metals, and a pH value is 7-9; and the cleaning agent can be directly used in the gasoline, and the using amount is 0.5-3 percent.

The invention discloses a nitrocellulose transparent primer and an application thereof. The primer is prepared by mixing main lacquers and diluents based on a mass ratio of 1: (0.4-0.6), the main lacquers are obtained by evenly mixing 21.0-25.0% of alkyd resins, 6.0-8.0% of inflexible resins, 0.2% of dispersing agents, 45.0-50.0% of nitrocotton liquids, 3.0-5.0% of plasticizers, 8.0-10.0% of extender pigments, 4.0-6.0% of grinding aids, 0.5% of anti-setting agents, 0.2% of defoaming agents, 0.1% of anti-yellowing agents and 5.5% of main lacquer solvents, the extender pigments are mixtures of more than two of a talcum powder, a transparent powder or a silica micropowder, and the diluents are prepared by mixing and uniformly stirring 42% of ester solvents, 33% of aromatic hydrocarbon solvents, 13% of solvent oil and 12% of alcohol ether solvents. According to the nitrocellulose transparent primer, the repainting transparency is high, the drying is quick, the film filling capability is good, the grinding capability is good, the fullness degree is high, construction times are effectively reduced, and each of the components has not any benzene-containing solvent, thereby the health of a constructor is greatly guaranteed, the environmental pollution is effectively reduced, and the nitrocellulose transparent primer can be widely applied to aspects of home decoration, furniture and the like.