1202 results about "Solvent extraction" patented technology

The invention discloses a method for extracting and purifying flavone in litsea coreana through an ultrasonic-assisted eutectic solvent, and belongs to the technical field of green processing of natural products. The invention provides a method for efficiently preparing litsea coreana flavone by integrating computer prediction, green solvent extraction and resin purification technologies. The method comprises the following steps: firstly, calculating and screening a deep eutectic solvent system with the highest affinity with the litsea coreana flavone on the basis of a COSMO-RS theoretical model, then coupling the optimized DES with an ultrasonic-assisted extraction (UAE) technology, and through the synergistic effect of the DES and the UAE technology, remarkably improving the extraction rate of the litsea coreana flavone and furthest keeping the biological activity of a target component; then, a macroporous resin dynamic adsorption-desorption purification process is linked, so that high-selectivity enrichment and impurity removal of the flavonoid compounds in the crude extract are realized, a high-purity product is obtained, and a complete process route from intelligent screening, efficient extraction to precise purification is finally formed.

The invention discloses a composition with high ultraviolet damage resistance as well as a preparation method and application thereof, and particularly belongs to the technical field of skin care product raw materials. The composition with high ultraviolet damage resistance is prepared by performing solid-state fermentation on radix scutellariae roots, radix ligustici sinensis and radix puerariae through compound bacteria consisting of bacillus subtilis, lactobacillus bulgaricus and bacillus coagulans and then performing solvent extraction. The composition with high ultraviolet damage resistance has excellent effects of resisting oxidative damage and inhibiting inflammatory factors, and can achieve the effects of repairing skin barriers, resisting inflammation, relieving, efficiently promoting repair of after-sun skin and the like.

The invention discloses a component detection method suitable for a plant extract, and relates to the technical field of plant extract detection, and the component detection method comprises the following steps: S1, carrying out enrichment treatment on a target component by using two-phase liquid-liquid extraction; s2, performing multi-dimensional attribute mapping and component factor construction by using the initial enrichment liquid; s3, performing correlation feature constraint calculation by using the target component response tensor; s4, performing ideal spectrum construction and response difference analysis by using the to-be-compared spectrum feature set; s5, performing mapping analysis by using ideal and actual spectrum residual signals; s6, performing spectrum correction by using the standard comparison spectrum set; the selectivity of target component enrichment is improved by setting biphasic solvent-liquid-liquid extraction, efficient extraction of target components in a plant extract complex system is achieved, compared with existing single solvent extraction or solid-phase extraction, the method has the advantages that the target components are optimally distributed among liquid phases by regulating and controlling interaction among solvents, and the extraction efficiency is improved. And co-extraction of non-target components is reduced.

The invention discloses a superconducting carbon black co-production method based on directional refining of catalytic slurry oil and a product thereof, and belongs to the technical field of carbon black preparation, and the method comprises the following steps: mixing the catalytic slurry oil and catalytic circulating oil to obtain mixed slurry oil, and adding a deliming agent for settling separation to obtain purified slurry oil; carrying out continuous solvent extraction on the obtained purified oil slurry to respectively obtain an aromatic component and a heavy component; carrying out thermal polycondensation reaction on the obtained aromatic component in a magnetic field environment in the presence of a catalyst and a cross-linking agent, and then carrying out supercritical fluid extraction to obtain spinnable mesophase pitch; carrying out slurry reactor hydrogenation deconstruction on the obtained heavy component to obtain stable micromolecular carbon black raw oil, mixing the carbon black raw oil with a nitrogen source and a template precursor, carbonizing, and carrying out acid pickling to obtain the superconducting carbon black; through a heavy oil slurry reactor hydrogenation deconstruction'doping-template 'synergistic carbonization strategy, the superconductive carbon black with nitrogen / phosphorus co-doped and developed hierarchical porous structure is constructed in situ by a one-step method.

The invention discloses a process for producing oligosaccharide from lignocellulose and performing acid circulation, which comprises the following steps of: (1) performing swelling reaction on the lignocellulose by using more than 70wt% of inorganic acid solution to obtain high-acid biomass candy pomace; (2) extracting the high-acid biomass candy pomace with an organic solvent to obtain low-acid biomass candy pomace and an acid-containing organic phase; (3) removing insoluble substances of the low-acid biomass candy pomace to obtain an oligosaccharide solution; and (4) adding water into the acid-containing liquid obtained in the step (2) for reverse extraction, standing and layering to obtain an acid solution and an organic phase. According to the method, the acid in the high-acid and solid biomass candy pomace is effectively recycled, the process is efficient and mild, energy does not need to be additionally provided, and all used reagents can be recycled and reused.

The invention discloses a supercritical entrainment extraction device for total flavonoids in folium cortex eucommiae, and relates to the technical field of pharmaceutical production. Comprising a fluid supply mechanism and an extraction mechanism, the fluid supply mechanism comprises a material mixing tank, a stirring pipe is rotatably arranged in the material mixing tank, a plurality of strip-shaped shells are fixedly arranged on the surface of the stirring pipe, and a plurality of nozzles are fixedly embedded in the surfaces of the strip-shaped shells. A dispersing disc and a grinding roller are arranged in the extraction tank, eucommia ulmoides leaves on the surface of the dispersing disc can be ground and smashed, and meanwhile, supercritical carbon dioxide mixed fluid is sprayed to the surfaces of the eucommia ulmoides leaves on the surface of the dispersing disc through a spray head on the surface of a rotating arm, so that the mixed fluid and the eucommia ulmoides leaves fully react; by utilizing the dissolving capacity of the supercritical carbon dioxide mixed fluid, a worker can conveniently extract the total flavonoids from the folium cortex eucommiae dissolved solution, so that the residual of solvent toxicity under the traditional solvent extraction condition can be effectively avoided, and meanwhile, the poison to a human body and the pollution to the environment in the extraction process are also prevented.

The invention discloses a preparation method of a crocodile hydrolyzed protein zinc skin care product, and relates to the technical field of skin care. The method comprises the following steps: step a, pretreating raw materials: taking fresh crocodile meat and bones, cleaning, mechanically crushing until the particle size is less than 5mm, and adding water according to the ratio of 1: (3-5) to prepare homogenate; step b, performing three-step enzymolysis, namely performing enzymolysis by adopting alkaline protease, flavourzyme and zinc chelating enzyme in sequence; according to the constructed technology of three-step enzymolysis and three-stage membrane separation, accurate preparation of crocodile protein zinc is achieved, and the zinc chelating rate is increased to 90% or above through the gradient effect of alkaline protease, flavourzyme and zinc chelating enzyme and directional release of zinc binding sites and is remarkably higher than that of a traditional single-enzyme hydrolysis technology; meanwhile, a combined purification technology of a ceramic membrane, an ultrafiltration membrane and a nanofiltration membrane is adopted to replace chemical precipitation and organic solvent extraction, so that the completeness of active ingredients is reserved, the risk of environmental pollution is reduced, and the method conforms to the green manufacturing trend of food industry.

The invention belongs to the field of waste residue oil hydrogenation catalyst recovery, and particularly relates to a method for preparing vanadyl sulfate electrolyte by using a waste residue oil hydrogenation catalyst. According to the method, the waste residue oil hydrogenation catalyst is used as a raw material, the high-purity vanadyl sulfate solution is prepared through the preparation procedures of roasting, leaching, impurity removal, reduction, extraction and reverse extraction, on one hand, the problem of solid waste treatment is solved, on the other hand, vanadium is selectively recycled from the high-concentration vanadium-containing solution through a solvent extraction method, and the production cost is greatly reduced. And the obtained vanadyl sulfate solution is high in purity, few in impurities and high in production efficiency.

The invention relates to a method for preparing spinnable mesophase pitch and carbon fibers from coal tar fractions, and belongs to the technical field of carbon materials. The method comprises the following steps: distilling and extracting aromatic hydrocarbon fractions in different distillation ranges from coal tar, activating the aromatic hydrocarbon fractions in one or more distillation ranges as raw materials, and carrying out non-catalytic polymerization reaction on one or more activated coal tar fractions and one or more non-activated coal tar fractions at a low temperature, and performing high-temperature polymerization reaction to obtain matrix asphalt, and performing reduced pressure distillation treatment, solvent extraction or inert gas purging to obtain the spinnable mesophase asphalt. The spinnable mesophase pitch has wide-area streamline optical texture distribution, good directional arrangement and orderliness, the mesophase content can reach 100%, the softening point is low, the coking value is high, the ash content is low, and the structure is controllable. The carbon fiber prepared based on the mesophase pitch is short in required oxidation time and has excellent performance.

This disclosure relates to an annular centrifugal extractor with Solid Separation Part to Separate Solid Particles Present in Solvent Extraction Fluid. In order to remove solid particles from the solution, a solid separation part / rotating bowl is attached to rotating bowl in such a way that solid particles settle inside the solid separation part. This solid separating centrifugal extractor contains two parts: (I) upper part which acts as a liquid-liquid separator to separate aqueous and organic solution used in solvent extraction operation and (II) bottom part which acts as a solid separator to separate solid particle present in solvent extraction liquids. The bottom rotating rotor is coupled with upper rotating rotor by threading arrangement. Both the rotating rotors are confined within a stationary cylinder. Dispersion with solid particles entering inside the rotating bowl is deflected towards the wall of the rotating cylinder by deflecting baffle by centrifugal sedimentation.

The invention discloses a method for improving in-vivo and in-vitro antioxidant activity of pomegranate peel polyphenol extract through combined enzymolysis of tannase and beta-glucosidase, and relates to the technical field of food science and biology. The pomegranate peel polyphenol extract provided by the invention is obtained from pomegranate peel powder through solvent extraction. According to the present invention, tannase and beta-glucosidase are adopted to perform single or combined enzymolysis on the pomegranate peel polyphenol extract, and the determination on the in vitro antioxidant activity of the pomegranate peel polyphenol extract shows that the antioxidant activities of DPPH and ABTS after the combined enzymolysis are improved by 29.84% and 29.30% compared with the antioxidant activities of the untreated polyphenol extract; the UPLC-ESI-QTOF-MS is used for identifying and analyzing the components of the enzymatic hydrolysate, the content of macromolecular ellagic tannin is obviously reduced, and the content of micromolecular ellagic acid and gallic acid is increased. The enzymolysis polyphenol is applied to D-galactose induced oxidative stress mice, and the result shows that the oxidative damage relieving effect of the enzymolysis polyphenol on the mice is better than that of untreated polyphenol.

The invention belongs to the technical field of inorganic salt chemical industry. The invention provides a method for preparing anhydrous lithium chloride by using salt lake brine with low magnesium-lithium ratio, which comprises the following steps: pumping clear salt lake brine with low magnesium-lithium ratio into a plate-and-frame filter press for filtration, and sequentially performing microporous filtration and ultrafiltration on filtrate to obtain primary refined brine; filtering the primary refined brine through a nanofiltration membrane device to obtain secondary refined brine; allowing the secondary refined brine to pass through chelating resin to obtain magnesium-removed brine; mixing the magnesium-removed brine with an alkali solution, adjusting the pH value of the mixed solution, and pumping the mixed solution into a continuous extraction device for solvent extraction to obtain a lithium chloride solution; and evaporating and drying the lithium chloride solution in sequence to obtain an anhydrous lithium chloride product. The anhydrous lithium chloride product is prepared by adopting a nanofiltration membrane separation and solvent extraction combined process, the recovery rate of lithium ions is higher than 80%, the fresh water consumption of 1 ton of lithium chloride product is less than 50 cubic meters, the production cost is low, the chemical units are few, and the automation degree is high.

The invention provides a method for leaching neodymium-iron-boron waste, and particularly relates to a method for extracting and separating iron and neodymium from leachate. According to the leaching method disclosed by the invention, the degradable citric acid is used for replacing hydrochloric acid or sulfuric acid which is heavily polluted to be used as a leaching agent, so that an excellent leaching effect is achieved, and the pollution problem of acid wastewater is greatly controlled; the lixivium is directly used for solvent extraction and separation of iron and neodymium in the lixivium, and an excellent separation effect is achieved; the leaching efficiency of iron and neodymium can reach 99% or above; according to the method for extracting and separating the iron and the neodymium from the leachate, the leachate serves as a water phase for extraction, the selectivity of N235 and the high efficiency of P350 are integrated, the iron is efficiently extracted from the mixed solution, the single-stage extraction efficiency of the iron in the leachate is higher than 99%, the extraction efficiency of the neodymium is lower than 10%, and the separation coefficient of the iron and the neodymium can reach 13000; meanwhile, the single-stage reverse extraction efficiency of iron can reach 80% or above, and deep separation of iron and neodymium is achieved.

The invention relates to a green preparation method and application of an anti-saccharification tea extract, and belongs to the technical field of biology. The preparation method of the tea extract comprises the following steps: extracting tea by using a deep eutectic solvent to obtain the tea extract, and carrying out deproteinization and decoloration to obtain the tea extract. The hydrogen bond acceptor of the deep eutectic solvent comprises proline or betaine, and the hydrogen bond donor of the deep eutectic solvent comprises xylitol or glycerol. By utilizing the NaDES extraction technology, effective components can flow out by efficiently breaking cell walls, so that the extraction efficiency of tea active components represented by tea polyphenol is effectively improved; the selected NaDES solvent is natural, green and easy to obtain; the tea extract disclosed by the invention has an anti-saccharification effect, blocks glycosylation reaction, reduces and inhibits generation of AGEs, improves the problems of dark skin, skin laxity and aging caused by saccharification, reduces collagen loss, keeps skin elasticity and delays skin aging.

The invention discloses equipment and a process for efficiently and continuously extracting astaxanthin by a low-frequency microwave-assisted eutectic solvent method, and belongs to the technical field of bioactive substance extraction. The method for extracting astaxanthin by the low-frequency microwave-assisted eutectic solvent method comprises the following steps: performing low-frequency microwave pretreatment on a eutectic solvent to obtain a high-temperature pretreated eutectic solvent; cooling the pretreated eutectic solvent, then mixing the pretreated eutectic solvent with crustacean byproducts, performing eutectic solvent extraction treatment, performing ultrasonic-assisted extraction in the process, and then performing solid-liquid separation to obtain filtrate; mixing the filtrate with an extraction solvent, and extracting to obtain an extraction solvent phase containing astaxanthin and a eutectic solvent phase; and removing the extraction solvent in the extraction solvent phase containing the astaxanthin to obtain an astaxanthin product.

The invention discloses a method for recovering Mo and Fe from direct coal liquefaction oil residues, and belongs to the technical field of hydrometallurgy. The method comprises the steps of solvent extraction, roasting enrichment, wet leaching, extracting agent extraction, ammonia water reverse extraction and evaporative crystallization, and ammonium molybdate and Fe (OH) 3 are obtained. Wherein in the wet leaching process, a leaching aid and sulfuric acid are jointly used for leaching, so that Ca and Si in the oil residues are left in leaching residues, and Mo, Fe, Al and the like enter a solution. The method comprises the following steps: simultaneously extracting Mo and Fe from a solution by using an extracting agent, precipitating Fe in a Fe (OH) 3 state by using an ammonia water reverse extraction method, leaving Mo in a reverse extraction solution in the form of ammonium molybdate, and further evaporating and crystallizing the reverse extraction solution to obtain the ammonium molybdate. According to the method, two valuable metals Mo and Fe in the direct coal liquefaction oil residue can be effectively recovered, and resource recycling is facilitated.

The invention relates to an extraction method for strengthening low-concentration rare earth elements and equipment for implementing the extraction method. The extraction method is a continuous extraction process based on the combination of a microfluid technology and a solvent extraction technology, and efficient enrichment and recovery of low-concentration rare earth elements are realized through combined use of a gas-liquid-liquid three-phase system and an extraction agent. The extraction method provided by the invention has the advantages of high mass transfer efficiency, simple operation, recyclable extraction agent, high extraction efficiency, good stability and the like, and is suitable for enrichment and recovery of low-concentration rare earth elements on an industrial scale under the condition of a large phase ratio (greater than 50).

The invention discloses an imidazole derivative-organic phosphoric acid combined extracting agent and an application method thereof, and belongs to the technical field of hydrometallurgy. The molar ratio of the imidazole derivative to the organic phosphoric acid is (10: 1)-(1: 10). The combined extraction agent can be used for extracting nickel, cobalt and manganese from a solution containing one or more nickel, cobalt and manganese. The selectivity of the solvent extraction system to nickel, cobalt and manganese is far higher than that of impurity metal ions such as calcium, magnesium, lithium, sodium and potassium, the extraction system is good in stability, free of emulsification phenomenon and third phase generation, easy to operate, low in cost and environmentally friendly. In lithium battery recovery and other systems containing coexistence of nickel, cobalt, manganese and calcium, magnesium and lithium, the solvent extraction system is particularly good in selectivity, and efficient co-extraction of nickel, cobalt and manganese can be achieved. When a mixed solution and a weak acid solution are treated, purification and concentration of target metal can be synchronously achieved, the recovery period is greatly shortened, the recovery rate is increased, and the method has great significance in efficient utilization of nickel-cobalt-manganese resources.

A production method of high-structure carbon black based on petroleum-based composite raw oil comprises the following steps: S1, performing fraction cutting on the petroleum-based composite raw oil to obtain crude carbon black raw oil; s2, carrying out solvent extraction on the crude carbon black raw oil to obtain aromatic-rich carbon black raw oil; and S3, vaporizing and cracking the aromatic-rich carbon black raw oil to generate the high-structure carbon black. The method for producing the high-structure carbon black based on the petroleum-based composite raw material oil is different from the domestic existing production process of coal tar and anthracene oil, and the structure degree of the carbon black product can be improved by pretreating the petroleum residual oil and the tail oil, so that the production of the high-structure carbon black product is realized, the domestic raw material source of the high-structure carbon black is broadened, and the production cost of the high-structure carbon black is reduced. And the competitiveness of the product is improved.

The invention discloses a ganoderma lucidum liver-protecting pill and a preparation method thereof, and the ganoderma lucidum liver-protecting pill comprises the following components: 8-20% of ganoderma lucidum polysaccharide extract, 5-15% of coptis chinensis extract, 4-10% of pulvis fellis saponin extract, 3-8% of oriental wormwood, 2-8% of taurine, 1-3% of vitamin E and 2-6% of scleroprotein (ganoderma lucidum sclerotium extract). The auxiliary materials comprise microcrystalline cellulose, corn starch, licorice extract, polyvinyl alcohol and the like, and the balance is 100%. Therefore, the problem of ingredient inactivation caused by traditional high-temperature / solvent extraction is solved through process innovation (such as supercritical CO2 pressure 300bar / enzymolysis pH 5.0 parameter optimization), the dissolution rate is increased to be more than or equal to 90% in 30 minutes (traditional pills need 45 minutes and only 75%), the limitation of single ingredient liver protection is broken through through the synergistic effect of the composite ingredients, and the liver protection effect is improved. Animal experiments prove that a liver injury marker ALT / AST can be reduced by more than 50%, the hepatic fibrosis area can be reduced by 40%, the degradation rate of the active ingredients within 6 months in a stability test is less than or equal to 5%, and the comprehensive bioavailability is improved by 30% compared with that of a traditional product.

The present disclosure provides a method of recovering a spent battery cathode material comprising lithium and at least one of nickel, cobalt and / or manganese, the method comprising: heating the spent battery cathode material in a reducing atmosphere to form a heat-treated spent battery cathode material comprising LiF and one or more of LijO, LiOH and LijCOs; washing the heat treated waste battery cathode material in an aqueous solvent to extract lithium-containing species and fluorine-containing species wherein the aqueous solvent is free of alkaline earth metal hydroxides or other species intended to reduce or prevent soluble fluorine species from remaining dissolved in the aqueous solvent; separating an aqueous solvent comprising lithium and fluorine species from the heat treated waste battery material; after separating an aqueous solvent comprising lithium and fluorine species from the heat-treated waste battery material, treating the aqueous solvent to separate lithium species from fluorine species; recycling a lithium substance in the form of lithium hydroxide or lithium carbonate; forming an acidic aqueous recovery feed comprising one or more of nickel, cobalt and / or manganese by leaching the heat treated waste battery cathode material with a mineral acid after the step of separating the aqueous solvent from the heat treated waste battery material; and recovering one or more of nickel, cobalt and / or manganese from the acidic aqueous recovery feed by a further process step selected from one or more of solvent extraction, solid phase extraction, electrochemical extraction and precipitation processes.

The invention relates to a low-softening-point spinnable mesophase pitch and a continuous production process thereof, and belongs to the technical field of pitch-based carbon materials. The technical problems of low purity, high softening point, non-uniform structural composition, high production cost and the like of the mesophase pitch prepared by a process for producing the mesophase pitch from aromatic hydrocarbon-rich heavy oil in the prior art are solved. According to the continuous production process disclosed by the invention, coal-based or petroleum-based aromatic hydrocarbon-rich heavy oil is taken as a raw material, raw oil refining is realized through a continuous solvent extraction process, and shallow polycondensed asphalt is prepared by adopting a multi-section heating tubular reactor through a thermal polycondensation process; then the pitch is subjected to a supercritical or subcritical extraction process at a certain temperature and pressure to obtain the mesophase pitch with enriched polycyclic aromatic hydrocarbon molecules with low softening point, narrow molecular weight distribution and uniform structural composition, and the mesophase pitch has excellent spinning performance, so that the prepared carbon fiber has excellent mechanical properties and is suitable for industrial production. The high-value utilization of the aromatic hydrocarbon-rich heavy oil is realized.

The invention discloses a flos magnoliae chloroform part extract, a preparation method thereof and application of the flos magnoliae chloroform part extract in resisting tumors and reversing tumor drug resistance. According to the method disclosed by the invention, the magnolia flower methanol extract, especially the chloroform extract thereof, is efficiently extracted by adopting operation means of extracting and separating natural products such as solvent extraction and extraction, and experiments prove that the magnolia flower chloroform extract has the activity of inhibiting the growth of tumor cells in vitro, so that the magnolia flower chloroform extract has the anti-tumor activity. Meanwhile, the chloroform part of flos magnoliae also can inhibit the expression of EGFR TKI drug-resistant pathway related proteins, so that the tumor drug resistance can be reversed. According to the invention, the raw material channel of the anti-tumor medicine is expanded, the application of the magnolia flower is expanded, the magnolia flower is developed into a new raw material of the anti-tumor medicine, and the medicinal value of the magnolia flower can be obviously improved.

The invention discloses a method for separating vanadium and iron in a high-iron-vanadium electrolyte. The method comprises the steps of pH regulation and control, iron removal, vanadium extraction and vanadium reverse extraction. In the step of iron removal, an iron ion targeted complexing agent and a solid phase adsorbent are added into the high-iron vanadium electrolyte with the pH adjusted, reaction is conducted for 10-15 min under stirring, then direct filtering is conducted, and low-iron vanadium electrolyte and a solid phase are obtained; in the vanadium extraction step, vanadium in the low-iron vanadium electrolyte is extracted by adopting a mixed solvent of pretreated P204, TBP and sulfonated kerosene, and a vanadium-containing organic solution is obtained; and the vanadium reverse extraction comprises the step of carrying out reverse extraction on the vanadium-containing organic solution through a sulfuric acid solution with the concentration of 2.0-5.0 mol / L to obtain a vanadium electrolyte. The method can be used for treating iron ions in all valence states, particularly ferric ions which are easier to extract than vanadium ions, qualified vanadium electrolyte with the iron ion concentration meeting the industrial standard can be directly obtained after reverse extraction, and a complexing agent and an adsorbent can be recycled.

The invention relates to a method for ultrasonic-enhanced extraction of a multicoloured leaf extract by using an ethanol and ethyl acetate cosolvent, and belongs to the technical field of chemical engineering and plant extraction. (2) synergistically degrading cellulose by using multi-component glycosidase; (3) cosolvent extraction; 4, chloroplast pigment is efficiently separated and purified, chlorophyll and other impurities in an extracting solution are effectively separated and removed through silica gel column chromatography, and therefore the high purity of the multicoloured leaf extract is achieved; according to the invention, ethanol and ethyl acetate are used as cosolvents to extract the multicoloured leaf extract, so that the extraction efficiency and the purity of the extract can be improved.

Devices, systems, and techniques can be provided for processing an oil-containing material with an alcohol-based solvent to extract oil from the material. In some examples, a system includes a pretreatment dehydration vessel that removes water from the oil-containing material prior to processing the oil-containing material in an extractor to extract oil from the material. An alcohol-based solvent may also be supplied to the dehydration vessel to remove water from the oil-containing material, thereby generating a dehydrated material that can be extracted in a downstream extractor.

The invention relates to hollow silicon dioxide microspheres and a preparation method thereof.The preparation method comprises the steps that an aqueous solution of a polymer, azide salt, an initiator and an organic solvent are mixed to obtain an azide-modified polymer, and the azide-modified polymer is added into a polar solvent to obtain a solution of the azide-modified polymer; mixing alkynyl-containing silane, the azido-modified polymer solution and a click chemistry catalyst, and then adding an acid catalyst or a base catalyst to carry out hydrolytic condensation reaction, so as to obtain a core-shell structure precursor of the silicon dioxide coated polymer; and carrying out roasting treatment or solvent extraction treatment on the core-shell structure precursor to obtain the hollow silicon dioxide microspheres. The preparation method provided by the invention is simple in process, relatively low in cost and relatively high in efficiency, can effectively control the particle size, the wall thickness and the density of the prepared hollow silicon dioxide microspheres, and has a wide application prospect.

The invention discloses an oxygen control process for injection-molded titanium alloy based on oxygen-free solvent degreasing, which belongs to the technical field of powder metallurgy materials and comprises the following steps of: banburying and cooling pre-alloyed titanium powder and a binder matrix, granulating and injection-molding, and degreasing, drying and sintering by using an oxygen-free solvent. According to the method, a full-process oxygen control process chain of vacuum pre-drying of pre-alloyed titanium powder, preparation of an oxygen-free binder, extraction and degreasing of an oxygen-free solvent, vacuum thermal degreasing and graphite furnace temperature control sintering is constructed, invasion of impurity elements such as carbon, oxygen and nitrogen is blocked from the source to a finished product, and the core bottleneck that the oxygen content of the powder metallurgy titanium alloy is difficult to control is solved; and the consistency of the strength and plasticity of the product is guaranteed through stable impurity control, and performance fluctuation caused by out-of-control of the oxygen content is avoided.

The invention provides a shale oil mass and mobility evaluation method and device, and belongs to the technical field of oil exploitation and geological and mining exploration and development. The method comprises the following steps: acquiring the oil content and the porosity of a rock sample, and calculating the oil saturation of the rock sample according to the oil content and the porosity; calculating a first shale oil mobility evaluation parameter according to the oil content of the rock sample; calculating a second shale oil mobility evaluation parameter according to the oil saturation of the rock sample; evaluating the mobility of the shale oil based on the first shale oil mobility evaluation parameter and the second shale oil mobility evaluation parameter; wherein the oil content comprises a first oil content, a second oil content and a third oil content, the first oil content is obtained by the first rock sample based on a low-field nuclear magnetic resonance test, the second oil content is obtained by the second rock sample based on the low-field nuclear magnetic resonance test, and the third oil content is obtained by the second rock sample based on solvent extraction. According to the embodiment of the invention, the mobility evaluation result of the shale oil can more accord with objective conditions.

The invention provides a method for extracting, rectifying and separating an ethano-2-pentanone azeotropic system by using a tetramethylammonium chloride eutectic solvent, and relates to the technical field of extracting, rectifying and separating the ethano-2-pentanone azeotropic system, which comprises the following steps: taking an ethano-2-pentanone mixture as a raw material to be separated; the method comprises the following steps: mixing and stirring a hydrogen bond acceptor and a hydrogen bond donor according to a certain proportion and temperature to obtain the eutectic solvent, firstly heating a material S01 to be separated by a heat exchanger E101 and then entering the middle part of a T101 tower, adjusting a eutectic solvent material flow S02 to a proper temperature and then entering the upper part of the T101 tower, carrying out heat exchange on a tower top ethanol material flow S03, enabling a part of material flow S05 to flow back to the tower top, and carrying out heat exchange on a tower top ethanol material flow S03; according to the method, a specific eutectic solvent is adopted as an extracting agent, an extractive distillation process is matched, an ethano-2-pentanone azeotropic system can be effectively broken, the yields of ethanol and 2-pentanone can reach 99% or above finally, the purities of ethanol and 2-pentanone can reach 99.5% (mass percent) or above finally, and efficient separation is achieved.