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234 results about "Activated Coal" patented technology

Activated charcoal is a fine black powder made from bone char, coconut shells, peat, petroleum coke, coal, olive pits or sawdust. The charcoal is "activated" by processing it at very high temperatures.

Method for preparing P type molecular sieve by using coal ash as raw material

The invention relates to a method for preparing a P type molecular sieve by using coal ash as a raw material. The method for preparing the P type molecular sieve by using coal ash as the raw material comprises the following steps: I, pre-treating and activating coal ash; II, preparing sodium silicate and sodium metaaluminate by using activated coal ash; and III, synthesizing the P type molecular sieve: firstly, uniformly mixing a sodium silicate solution with a sodium salt, then, dropwise adding the sodium metaaluminate solution into the mixed liquid, and finally, adding an organic steric hindering agent and a proper amount of deionized water to form a reaction mixture, wherein the molar ratios of the reaction mixture are as follows: SiO2/Al2O3=0.4-1.8, M/Al2O3=1-5, Na2O/Al2O3=2-4 and H2O/SiO2=20-150 and the organic spatial steric hindering agent is at least one of ethanol amine, diethanol amine and triethanol amine; packing the mixed materials in a polytetrafluoroethylene container, stirring, then putting in a stainless steel reaction kettle, and carrying out hydro-thermal synthesis for 2-8 hours; and taking out products in the reaction kettle, carrying out centrifugal separation and washing by deionized water, and drying to obtain the P type molecular sieve. The method provided by the invention is short in synthetic cost, short in crystallization time and high in yield of the P type molecular sieve.
Owner:NORTHEAST GASOLINEEUM UNIV

Method for preparing aluminum oxide through treatment of coal ashes with hydrochloric acid

The invention discloses a method for producing aluminum oxide through treatment and utilization of industrial solid wastes and particularly relates to a method for preparing aluminum oxide through treatment of coal ashes with hydrochloric acid. The method comprises the following steps: activating coal ashes; mixing the activated coal ashes with 15%-36% hydrochloric acid, wherein a molar ratio of HCl in the hydrochloric acid to aluminum oxide and iron oxide in the coal ashes is 4-9; feeding mixed serous fluid into a reactor, heating to 90 DEG C-230 DEG C, wherein reaction time is 1 hour-8 hours; carrying out solid-liquid separation after reacting and cooling to obtain aluminum chloride liquid and high-silicon residue, and evaporating, concentrating or drying to obtain crystallized aluminum chloride; decomposing the crystallize aluminum chloride to obtain crude gamma-Al2O3 and a hydrogen chloride gas; and preparing metallurgical-level aluminum oxide by gamma-Al2O3 through a Bayer process, wherein the residue is high-iron residue and can be used as a steelmaking material. According to the method, any auxiliary agent is not added, so that aluminum oxide in the coal ashes can be effectively leached out, and the leaching rate of the aluminum oxide can reach over 85%.
Owner:SHENYANG ALUMINIUM MAGNESIUM INSTITUTE

Method for co-producing aluminum oxide and sodium carbonate from coal gangue

The invention relates to a method for co-producing aluminum oxide and sodium carbonate from coal gangue. The method comprises the following steps of: calcining and activating the coal gangue and dissolving the calcined and activated coal gangue in acid to prepare an aluminum chloride acid extract; concentrating and crystallizing the acid extract to prepare crystalline aluminum chloride; calcining and decomposing the crystalline aluminum chloride to prepare crude aluminum oxide; dissolving the crude aluminum oxide in alkali to prepare sodium metaaluminate; performing solid-liquid separation on iron and titanium insoluble substances and other impurities and washing the product to obtain solution of sodium metaaluminate; adding an aluminum hydroxide seed crystal into the solution of sodium metaaluminate to prepare aluminum hydroxide deposit and solution of sodium carbonate; performing solid-liquid separation to obtain an aluminum hydroxide crystal and solution of sodium carbonate; concentrating and crystallizing the aluminum hydroxide crystal and the solution of sodium carbonate to obtain sodium carbonate; and calcining the aluminum hydroxide to prepare metallurgical-grade aluminum oxide. In a production process, sodium hydroxide from a chlorine industry, hydrochloric acid which is a byproduct of a PVC industry and carbon dioxide discharged from a calcium carbide plant in a production place of the coal gangue are fully utilized, so that industry pollution is reduced, a useful product is obtained and comprehensive resource utilization is realized. The method has the advantages of simple production technology, easily-controlled production process, high aluminum oxide extraction ratio, low production cost and stable product quality.
Owner:CHANGCHUN CHAOWEI NEW MATERIALS TECH

Method for producing low iron aluminum sulfate by utilization of coal gangue

InactiveCN102311136AGood slag activityUnderburn noneWaste processingSolid waste disposalSlagAluminum sulphate
The invention relates to a method for producing low iron aluminum sulfate by the utilization of coal gangue and belongs to the technical field of coal solid waste resource utilization. The method provided by the invention comprises the following steps of: carrying out calcination activation on coal gangue at the temperature of 785-850 DEG C, adjusting the pH of an aluminum sulfate solution by directly using the activated coal gangue, oxidizing divalent iron ions into trivalent ions, removing iron precipitate and a few gel in the aluminum sulfate solution by the utilization of the adsorption property of the coal gangue, producing low iron aluminum sulfate, recycling the removed iron slag, and terminating the recycling operation when the removed iron slag amount is greater than 120% of the acid-leach residue amount or the mass ratio of aluminium to iron in an iron-removing liquid is less than 160. The temperature of the calcinated coal gangue satisfies the operation condition for the boiling of a circulating fluidized bed. No addition of an auxiliary agent helps heat recovery. The activity of the coal gangue cinder is good, the grinding requirement is not high and the energy consumption is low. Hydrogen peroxide or ozone, air and variable valence element-containing hypervalent compounds KMnO4, MnO2 oxidizing agents are adopted to remove iron with less loss of aluminium. The ratio of Al2O3 to Fe in the product is greater than 160 and the quality of the product is high. The acid leaching reaction is carried out at normal pressure. And the production is easy to operate at low cost.
Owner:KUNMING UNIV OF SCI & TECH

Process method for extracting aluminum oxide in coal ash of pulverized coal furnace by using acid method

InactiveCN106966415ARealize direct recyclingEasy roasting operationAluminium oxides/hydroxidesExtractive distillationBiological activation
The invention relates to a process method for extracting aluminum oxide in coal ash of a pulverized coal furnace by using an acid method. The process method comprises the following steps; adding ammonium sulfate into the coal ash of the pulverized coal furnace for activating, and performing the high-temperature calcination to obtain activated coal ash clinker, adding hydrochloric acid, heating and dissolving out, to obtain aluminum chloride digesting liquor; pumping hydrogen chloride gas into the digesting liquor for crystallizing, performing the solid-liquid separation and washing to obtain high-purity aluminum chloride hexahydrate crystal and waste acid solution, calcining the crystal to generate metallurgy-level aluminum oxide; adding inorganic salt chloride, such as calcium chloride or magnesium chloride, into the waste acid, heating, extractive-distilling and recycling the hydrochloric acid and the hydrogen chloride gas for the dissolving out and crystallization working procedures, performing the absorption-crystallization to tail gas generated in the roasting-calcining activation to generate ammonium sulfate, and realizing the cyclic utilization of materials, wherein the obtained solid residue with abundant silicon dioxide can be used for generating white carbon black or the materials for building. The process method is capable of realizing the reduced recycling of the coal ash of the pulverized coal furnace, and realizing the full cyclic utilization of the materials. The purity of the obtained aluminum oxide product is the first level, the quality of the metallurgy-level aluminum oxide is standard, and the extraction efficiency is up to 84.6%-90.4%.
Owner:XIAN AEROSPACE PROPULSION TESTING TECHN INST

Gas, solid and liquid integrated combustion system

The invention relates to a gas, solid and liquid integrated combustion system, and belongs to the technical field of the environment. The system is composed of a waste gas collection system, a granulation system, a feeding system, a rotating furnace, a combustion furnace, a waste heat boiler, a heat exchanger, a rapid quenching tower, a smoke dry type washing system, a cloth bag dust removal device, a spray tower, a reheater and a chimney. Coal, solid waste and liquid waste are evenly mixed according to the mass ratio (1-12):(2-30):(1-16) in the granulation system for granulation; after collected waste gas is preheated, part of the waste gas enters the rotating furnace, and the other part of the waste gas enters the combustion furnace to be processed through high temperature combustion; high temperature tail gas of the combustion furnace enters the rapid quenching tower, the dry type washing system, the cloth bag dust removal device and the spray tower after heat energy recovery, and is sent to the chimney by a draught fan after the tail gas is cooled and fly ash, dioxin and acid gas are removed, so that emission reaching the standard is completed. Liquid waste produced in the running process of the system is recycled in the granulation system, solid waste such as activated carbon is fed into the rotating furnace to be combusted, and therefore harmless treatment is achieved while running cost of the system is reduced.
Owner:JIANGSU ANQIER WASTE GAS PURIFICATION

Supercritical (or subcritical) activation method for coal gangue and application of supercritical (or subcritical) activation method

The invention relates to a subcritical or supercritical activation method for coal gangue. According to the method, alkali as an auxiliary is added to the coal gangue and the coal gangue is subjectedto an activating reaction under the subcritical or supercritical condition, and an activated coal gangue sample can be obtained. The invention further relates to a comprehensive utilization method ofthe coal gangue. According to the comprehensive utilization method, the activated coal gangue sample obtained by subcritical or supercritical activation is subjected to a contact reaction with acid, by means of acid leaching, not only can an aluminum oxide product and a white carbon black product be obtained, but also lithium and gallium which are enriched in the coal gangue can be extracted, final filter residues are used for preparing raw materials of cement, and one zero-pollution and zero-emission way of coal gangue waste recovery is really obtained. The methods have the advantages as follows: coal gangue can be activated at the low temperature of about 400 DEG C, few operation steps are required, reaction temperature is low, reaction time is short, no secondary pollution is produced in the whole process, and the novel environment-friendly coal gangue activation method and the way of coal gangue waste recovery are obtained.
Owner:TAIYUAN UNIV OF TECH

Method for preparing aluminum oxide by using hydrochloric acid treatment coal ash

ActiveCN103663510AGuaranteed concentration of hydrochloric acidAvoid Corrosion HazardsSolid waste disposalAluminium oxides/hydroxidesAluminium chlorideSlag
The invention discloses a method for preparing aluminum oxide by using hydrochloric acid treatment coal ash. The method comprises the steps: activating coal ash; mixing the activated coal ash with hydrochloric acid with the concentration of 5-10 percent; feeding mixed slurries into a heat exchanger to be heated to be between 90 and 200 DEG C; feeding the heated slurries into a reactor; adding hydrogen chloride gas into the reactor and reacting for 1-8 hours; separating solid from the liquid after reaction is finished and the temperature is reduced to obtain aluminum chloride and ferric chloride solution and high silicon slag; evaporating and condensing or drying to obtain crystallized aluminum chloride and ferric chloride; heating and decomposing the crystallized aluminum chloride to obtain coarse gamma-Al2O3 containing a large number of impurities and hydrogen chloride gas; and treating coarse gamma-Al2O3 by using the Bayer process to prepare metallurgical-level aluminum oxide, wherein residual slag is high iron slag and can be used an iron-making raw material. According to the method, the problem of severe corrosion of the equipment can be avoided, aluminum oxide in the coal ash is effectively leached, and the produced aluminum oxide can meet the industrial requirement of electrolytic aluminum.
Owner:SHENYANG ALUMINIUM MAGNESIUM INSTITUTE

Method and apparatus for preparing fumed silica from coal gangue

The invention discloses a method and an apparatus for preparing fumed silica from coal gangue. The method comprises: performing pressurized reaction, in microwave fields, on activated coal gangue powder and hydrofluoric acid, converging the generated silicon tetrafluoride gas with water vapor to obtain a mixture and introducing the mixture into a micorwave-absorbing agent packed column under microwave irradiation, and performing high-temperature pyrohydrolysis reaction on the mixture to generate gas silicon dioxide and hydrogen fluoride; performing shock chilling, gathering, separating, acid-removing and purging on the generated gas silicon dioxide and hydrogen fluoride as well as unreacted water vapor to prepare a fumed silica product; separating the hydrogen fluoride gas and the water vapor from a cyclone separator and the top of an acid removing furnace, and adding the water to prepare hydrofluoric acid for recycling, wherein the fumed silica product can be used as a thickening agent, a rubber reinforcing agent and a washing assistant agent, and the like; by-products are aluminum fluoride, iron fluoride and magnesium fluoride and the like; the microwave-absorbing agent in the present invention can significantly improve the direct hydrolysis efficiency of silicon tetrafluoride; the pressurized microwave reaction can significantly increase the reaction rate and conversion rate of silicon dioxide and hydrofluoric acid; and the microwave-absorbing agent is recycled and easy to regenerate, and has a high utilization rate, a simple process and low preparation cost.
Owner:LIUPANSHUI NORMAL UNIV

Concrete reinforced water-retaining internal curing material and preparation method thereof

The invention discloses a concrete reinforced water-retaining internal curing material and a preparation method thereof. The method comprises the following steps: respectively weighing the following components in parts by weight: 10 parts of acrylic acid, 4 parts of acrylamide, 3 parts of ground zeolite powder, 2 parts of activated coal gangue powder, 0.005 part of N,N-methylene bisacrylamide and 0.1 part of potassium persulfate, adding the components into a container, uniformly stirring, dropwise adding a NaOH solution, uniformly stirring until the neutralization degree is 60 percent, reacting for 10 hours, and drying, thereby obtaining a solid cross-linking agent; weighing the solid cross-linking agent, coal ash beads, silica colloidal particles, phosphorus gypsum, natural alunite, magnesium oxide and calcium oxide according to the weight ratio of 82:5:4:3:3:2:1, adding the mixture into a ball mill, and grinding, thereby obtaining the concrete reinforced water-retaining internal curing material. The concrete reinforced water-retaining internal curing material disclosed by the invention is excellent in water retention capacity, pores reserved by water release inside concrete filled with the traditional internal curing material can be canceled, the compaction rate and strength of the concrete are guaranteed, the later maintenance cost is greatly reduced, the self-shrinkage within 28 days is reduced by 50-80 percent compared with that of common concrete, and the compressive strength is improved by 5-10 percent.
Owner:CHANGAN UNIV

Production system of suspended-state calcined coal gangues

The invention discloses a production system of suspended-state calcined coal gangues. The production system comprises a material preparing and feeding sub system, a preheating and decomposition furnace-calcining sub system, a product cooling and heat-recycling sub system, a hot air preparing and supplying sub system and a system power and waste gas-purifying sub system, wherein the material preparing and feeding sub system is used for quantitatively and stably supplying coal gangue powder to a pre-heater; the preheating and decomposition furnace-calcining sub system is used for preheating materials to a set temperature under a suspended state, and decomposing and sintering the materials in a decomposition furnace; the product cooling and heat recycling sub system is used for sucking in cold air to cool the sintered materials under the suspended state to obtain low-temperature activated coal gangues; the hot air preparing and supplying sub system is used for ventilating hot air to the hot air furnace for burning pulverized coal or fluidized block coal, and providing hot air to the decomposition furnace of the preheating and decomposition furnace-calcining sub system, wherein the hot air is from the product cooling and heat-recycling sub system; and the system power and waste gas purifying sub system is used for providing gas flow power to the preheating and decomposition furnace-calcining sub system, purifying all waste gas of the preheating and decomposition furnace-calcining sub system and excessive gas emitted by the hot air preparing and supplying sub system. The production system disclosed by the invention can massively, efficiently, continuously and stably produce and process high-activity cinerite coal gangues.
Owner:XI'AN UNIVERSITY OF ARCHITECTURE AND TECHNOLOGY
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