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Residual oil hydrogenation catalyst as well as preparation method and application thereof

A residue hydrogenation and catalyst technology, applied in the field of coal chemical industry, can solve the problems of easy blockage of microporous structure and easy coking of catalysts, so as to improve the metal removal rate, improve the conversion rate of residue oil and liquid yield, and improve stability. sexual effect

Active Publication Date: 2014-06-18
BEIJING HUASHI UNITED ENERGY TECH & DEV +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] The purpose of the present invention is to solve the problem that the micropore structure is easy to block and the catalyst is easy to coke in the residual oil hydrogenation catalyst based on activated carbon in the prior art, and to provide a new residual oil hydrogenation catalyst

Method used

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  • Residual oil hydrogenation catalyst as well as preparation method and application thereof
  • Residual oil hydrogenation catalyst as well as preparation method and application thereof
  • Residual oil hydrogenation catalyst as well as preparation method and application thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0031] (1) Crush the blue carbon raw material, pass through a 280-mesh sieve, dry at 120°C to remove water, place it in a high-temperature furnace, and treat it at 1500°C for 8.0 hours under the protection of an inert gas, and take it out when the temperature drops to room temperature;

[0032] (2) After dry mixing the graphitized carbon material and KOH pore expander at a mass ratio of 1:2, place it in a tube furnace with a mixed atmosphere of oxygen and nitrogen (volume ratio 1:9) , carry out hole expansion treatment at 500°C for 0.5h;

[0033] (3) After acid washing and water washing, the reamed sample was centrifuged and dried at 100°C for 3 hours to obtain the graphitized pore reamed blue carbon carrier;

[0034] (4) Weigh 150g FeSO 4 ·7H 2 O is used as the precursor of the active component, and it is impregnated onto 100 g of the above-mentioned graphitized pore-expanding blue carbon by the equal volume impregnation method. After the impregnation, it is dried at 120°C ...

Embodiment 2

[0037] (1) Crush the blue carbon raw material, pass through a 280-mesh sieve, dry at 120°C to remove water, place it in a high-temperature furnace, and treat it at 1500°C for 3.0 hours under the protection of an inert gas, and take it out when the temperature drops to room temperature;

[0038] (2) Combine the graphitized carbon material with Na 2 CO 3 After the pore-enlarging agent is dry-mixed evenly with a mass ratio of 1:4, it is placed in a tube furnace with a mixed atmosphere of oxygen and helium (volume ratio 1:9), and the pore-enlarging treatment is performed at 700°C for 6 hours;

[0039] (3) After acid washing and water washing, the reamed sample was centrifuged and dried at 100°C for 3 hours to obtain the graphitized pore reamed blue carbon carrier;

[0040] (4) Weigh 118g FeSO 4 ·7H 2 O and 0.9g (NH 4 ) 6 Mo 7 o24 4H 2 O is used as the precursor of the active component, and it is impregnated onto 100 g of the above-mentioned graphitized pore-expanding blue c...

Embodiment 3

[0043] (1) Crush the blue carbon raw material, pass through a 280-mesh sieve, dry at 120°C to remove water, place it in a high-temperature furnace, and treat it at 1700°C for 6.0 hours under the protection of an inert gas, and take it out when the temperature drops to room temperature;

[0044] (2) Combine graphitized carbon material with K 2 CO 3 After the pore-enlarging agent is dry-mixed uniformly with a mass ratio of 1:6, it is placed in a tube furnace with a mixed atmosphere of oxygen and nitrogen (volume ratio 1:9), and the pore-enlarging treatment is performed at 800°C for 12 hours;

[0045] (3) After acid washing and water washing, the reamed sample was centrifuged and dried at 100°C for 3 hours to obtain the graphitized pore reamed blue carbon carrier;

[0046] (4) Weigh 123g ammonium ferrous sulfate ((NH 4 ) 2 SO 4 ·FeSO 4 ·6H 2 O) and 3.2g (NH 4 ) 6 MO 7 o 24 4H 2 O is used as the precursor of the active component, and it is impregnated onto 100 g of the ...

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Abstract

The invention discloses a residual oil hydrogenation catalyst, comprising a carrier and an active metal component loaded on the carrier, wherein the carrier is a graphited reaming coal material; the specific surface area of the graphited reaming coal material is 200-960m<2> / g, the mean pore size is 10-100nm, the pore volume is 0.3-1.0cm<3> / g, the active metal component comprises one or more of VIII metallic oxides and VIB metal oxides, and the graphited reaming coal material is graphited reaming activated coal or graphited reaming semicoke. The invention also discloses a preparation method of the residual oil hydrogenation catalyst. Firstly, a carbon raw material is graphited and chambered to obtain the required carrier, and then the active component is soaked into the vector to obtain the residual oil hydrogenation catalyst.

Description

technical field [0001] The invention relates to a residual oil hydrogenation catalyst and its preparation method and application, belonging to the technical field of coal chemical industry. Background technique [0002] The world's oil resources are increasingly scarce, and the development of heavy and inferior crude oil makes the deep processing and upgrading technology of inferior residue / heavy oil more and more people's attention. Among them, the catalytic cracking process of residual oil is one of the most effective processes for lightening heavy oil, and the use of various hydrogenation catalysts is indispensable in the process of lightening residual oil. Common residual oil hydrogenation catalysts use alumina as the carrier and Mo / W and Ni / Co as the main active components. Patent CN102240555A discloses a residual oil hydrogenation catalyst with alumina as a carrier, the content of Ni / Co in the catalyst is 0.1-4wt%, the content of Mo / W is 1-5wt%, and the alumina carrie...

Claims

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Application Information

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IPC IPC(8): B01J23/745B01J23/881B01J23/882B01J23/888B01J23/75B01J35/10B01J32/00C10G45/04C10G45/08
Inventor 林科江莉龙李林曹彦宁马永德
Owner BEIJING HUASHI UNITED ENERGY TECH & DEV
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