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86results about How to "Improve electrical activity" patented technology

Carbon nanosphere/sulfur composite and preparation method and application thereof

The invention discloses a carbon nanosphere / sulfur composite and a preparation method and application thereof. The carbon nanosphere / sulfur composite comprises a carbon nanosphere and elemental sulfur; the carbon nanosphere is composed of petal-shaped carbon plates which are combined into a sphere shape, gaps exist between the carbon plates, and the carbon plates are arranged in a wrinkled form and provided with through holes; the elemental sulfur and the carbon nanosphere are combined through a fusion permeation method to form the carbon nanosphere / sulfur composite, wherein sulfur accounts for 75-84 wt% of the composite. The gaps and through holes in the carbon nanosphere facilitate fusion loading of sulfur and dispersion and transportation of electrolyte ions, and the carbon nanosphere with a large specific surface area can load more sulfur active substances and effectively inhibit dissolution of polysulfide; the nitrogen element is doped on the carbon nanosphere to improve the electroactivity of a carbon material and enhance physisorption on sulfur; the carbon nanosphere / sulfur composite can serve as a positive electrode of a lithium-sulfur battery to improve the capacity, rate capability, cycling stability and coulombic efficiency of the lithium-sulfur battery.
Owner:WENZHOU UNIVERSITY

Process for preparing power type lithium-ion battery anode material by using supercritical/subcritcal water thermal process

The invention relates to a process for preparing a power type lithium-ion battery anode material by using a supercritical / subcritcal water thermal process. The process comprises the following steps of: (1) continuously injecting two fluids of a raw material lithium source and a mixed liquid consisting of an iron source / manganese source and a phosphoric acid source into a mixer for mixing; (2) preheating a third fluid formed by deionized water, and adding the third fluid into the mixer to be mixed with the two fluids in the step (1); (3) leading the mixed liquid of the three fluids discharging from the mixer in the step (2) to enter a high temperature and high pressure reaction kettle for carrying out hydrothermal crystallization reaction; (4) cooling a product liquid obtained from the hydrothermal crystallization reaction through a heat exchanger, filtering by a filter to remove large-grain particles and impurities, and leading the filtrate into a solid-liquid separator; (5) continuously collecting particles precipitated in the solid-liquid separator, and drying to obtain dry powder of the battery anode material. The process can be carried out continuously and is beneficial to improving the operation efficiency and reducing the energy consumption.
Owner:GUANGZHOU HKUST FOK YING TUNG RES INST

Integrated system for solar-driven microbial electrolysis cell strengthening treatment on rural domestic sewage

The invention discloses an integrated system for solar-driven microbial electrolysis cell strengthening treatment on rural domestic sewage. In the system, the integrated device comprises an anaerobic tank, a facultative tank, an aerobic tank and a secondary sedimentation tank. Each two zones are separated by a stainless steel plate and the stainless steel plates are communicated at intervals from top to bottom. The bottom of the anaerobic tank is provided with a water inlet. The top of the sedimentation tank is provided with a water outlet. An aeration head is arranged in the aerobic tank and is connected to an air pump. A guide plate and a mud guard are arranged in the secondary sedimentation tank. A sludge outlet of the secondary sedimentation tank is connected to a sludge flowing direction inlet of the aerobic tank by a sludge reflux pump. An anode carbon felt is arranged in the anaerobic tank. A cathode carbon felt is arranged in the aerobic tank. An anode and a cathode are connected to a storage battery by stainless steel wires. A solar cell panel provides powder for the storage battery. The integrated system greatly improves the original biological treatment technology, reduces an operation cost by natural solar energy and provides a novel rural domestic sewage treatment technology.
Owner:ZHEJIANG UNIV

Amide polymer derived one-dimensional nitrogen-doped nano-carbon electrode material and preparation method

The invention provides an amide polymer derived one-dimensional nitrogen-doped nano-carbon electrode material and a preparation method. The one-dimensional nitrogen-doped nano-carbon electrode material, which can be used as an electrode material of a lithium/sodium ion battery and a super capacitor, is prepared, so that the original amide engineering plastic with a low added value can be used in the field of green energy, the cost is effectively reduced, and the electrochemical performance is improved. The one-dimensional nitrogen-doped nano-carbon electrode material is characterized in that the one-dimensional nitrogen-doped nano-carbon electrode material is prepared by the raw material of an amide polymer or an amide polymer composite material through high-temperature carbonization underthe protection of an inert gas, wherein the amide polymer is an amide polymer with a one-dimensional nano structure, which is obtained by carrying out low-temperature salification on anhydride and amine monomers and then carrying out solvothermal reaction; the amide polymer composite material is an amide polymer composite material with a one-dimensional nano structure obtained by carrying out low-temperature salification on anhydride and amine monomers, mixing salt with a one-dimensional carbon nano material and carrying out solvothermal reaction.
Owner:SOUTH CENTRAL UNIVERSITY FOR NATIONALITIES

Shell core type Poly(3,4-ethylenedioxythiophene)/polyethelene alcohol fiber composite film and preparing method thereof

The present invention relates to a shell core type Poly(3,4-ethylenedioxythiophene)/polyethelene alcohol fiber composite film, and a preparing method thereof. The preparing method comprises the following steps: preparing a polyvinyl alcohol water solution, adding sodium lauryl sulfate into the solution, finally adding ethylenedioxythiophene monomer, ultrasonic dispersing and then mixing for forming the homogeneous emulsion. The emulsion is executed with electrostatic spinning for obtaining the fiber with the uncontinuous shell core type spindle-shaped structure, wherein the ethylenedioxythiophene monomer is positioned at the core layer. The spinning film is placed into the chlorine for sealed-placing for 24h for polymerizing the ethylenedioxythiophene monomer of the core layer and obtaining the pale-blue film. The invention has the advantages of: simple and feasible method, realized polymerization in the nanometer reactor composed of spinning fiber shell layer, high concentration of PEDOT in the final film up to 45% (w/w PVA), and better electroactivity. Furthermore the shell core type Poly(3,4-ethylenedioxythiophene)/polyethelene alcohol fiber composite film of the invention is synthesized with the bioavailability of the PVA and is likely used for the field of biological sensor.
Owner:TIANJIN UNIV

Synthetic method of electrode material polyaniline

The invention provides a synthetic method of electrode material polyaniline. The synthetic method comprises the following steps of: (a) dissolving aniline into a perchloric acid solution, and reacting at below 10 DEG C in the presence of ferric sulfate or manganese dioxide, thereby obtaining reaction liquid; and (b) dropping a perchloric acid solution with dissolved ammonium persulfate in batches in the reaction liquid obtained from the step (a), and reacting continuously at below 10 DEG C, thereby obtaining the electrode material polyaniline. According to the invention, ferric sulfate or manganese dioxide as well as ammonium persulfate are taken as oxidizing agents for complex use; perchloric acid is taken as a reaction medium, and the reaction temperature is controlled to be below 10 DEG C; the synthetic technology enables the productivity and capacity of polyaniline during the whole synthetic process to be much high, solves the problems of low productivity and poor capacity of a traditional method, and is suitable for industrial production; and further, according to the invention, activated carbon with excellent conductivity and adsorption is added during the synthetic process, so that a traditional chemical oxidation method is changed into an electrochemical oxidation method, and meanwhile, the utilization ratio of the electrode material is improved.
Owner:WEICHAI POWER CO LTD

ZIF-L-based epoxy resin composite coating, preparation method and coating product

The invention relates to an epoxy resin composite coating based on ZIF-L, a preparation method and a coating product, and relates to the technical field of coatings and surface coatings. According to the main technical scheme, the ZIF-L-based epoxy resin composite coating is prepared from two-dimensional metal organic framework material ZIF-L nanoparticles, 8-hydroxyquinoline terminated aniline tripolymer and an epoxy resin coating body. In the ZIF-L-based epoxy resin composite coating, the mass fraction of the two-dimensional metal organic framework material ZIF-L nanoparticles is 0.1-10 wt%, and the mass fraction of the two-dimensional metal organic framework material ZIF-L nanoparticles is 0.1-10 wt%. The mass of the 8-hydroxyquinoline terminated aniline tripolymer is 5 to 50 percent of the mass of the two-dimensional metal organic framework material ZIF-L nano-particles. The invention is mainly used for providing and preparing the ZIF-L-based epoxy resin composite coating with excellent antibacterial, antifouling and anticorrosive properties and a coating product, can prevent gram-negative bacteria and gram-positive bacteria, and has good poisoning and anti-adhesion effects on chlorella, phaeodactylum tricornutum and navicula.
Owner:INST OF METAL RESEARCH - CHINESE ACAD OF SCI

Nitrogen-doped barbed carbon nanosphere/sulfur composite material and preparation method and application thereof

The invention discloses a nitrogen-doped barbed carbon nanosphere / sulfur composite material and a preparation method and application thereof. The composite material comprises sulfur and nitrogen-dopedbarbed carbon nanospheres serving as a sulfur host material, wherein the carbon nanosphere is formed by combining a plurality of nitrogen-doped needle-like carbon fibers according to a spherical shape, the lengths of the carbon fibers are different, all the carbon fibers are shot from the spherical edge to the spherical center to form barbed distribution, gaps exist between the carbon fibers, andthe carbon fibers are gathered to the center to form a cavity. Furthermore, 60-75wt% of sulfur supported by the nitrogen-doped barbed carbon nanospheres is applied to a lithium-sulfur battery as a positive electrode. Sufficient space is provided for sulfur volume expansion in the charging and discharging process by utilizing the internal cavity and the carbon fiber gaps; the carbon fibers with different lengths in the spheres can well disperse sulfur and adsorb polysulfide, so that the sulfur utilization rate is increased, and the polysulfide loss is inhibited; and the loss of polysulfide ions can be more effectively inhibited by doping carbon in the outer layer of nitrogen atoms, thereby effectively prolonging the cycle life of the lithium-sulfur battery and improving the capacity of thelithium-sulfur battery.
Owner:WENZHOU UNIVERSITY

Trace palladium nanoparticle for electrochemical catalysis ethanol oxidation, preparation method and application of trace palladium nanoparticle

The invention discloses a preparation method of a trace palladium-located catalyst. Meanwhile, the trace palladium-located catalyst has excellent catalytic activity for oxidation of ethanol. The preparation method comprises the following steps: firstly, loading nickel nanoparticles (nano-Ni/GP) with a certain size on the surface of graphene by using a two-dimensional film structure of the graphene; then making the nano-Ni/GP formed in this way react with a palladium chloride solution with a certain concentration, reducing Pd<2+> ions into palladium nanoparticles, oxidizing nickel into Ni<2+> and leaving from the surfaces of the nanoparticles to enter a solution; and performing in-situ uniform deposition on the formed palladium nanoparticles on the surfaces of unreacted nickel nanoparticles so as to form nickel nanoparticle-loaded palladium nanoparticles. Because the palladium nanoparticles are uniformly dispersed on the surfaces of the nickel nanoparticles, the dispersing degree of the palladium is extremely high; however, the palladium loading amount is very small; meanwhile, because the palladium nanoparticles are in mutual contact with the nickel nanoparticles, so-called 'dual-function effect' is formed, so that the electroactivity of the catalyst for the oxidation of ethanol is greatly enhanced.
Owner:HUNAN UNIV OF SCI & TECH
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