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79results about How to "Facilitates ion transport" patented technology

Stable lithium metal negative electrode

The invention belongs to the technical field of a battery and particularly relates to a stable lithium metal negative electrode. The stable lithium metal negative electrode comprises a negative electrode current collector and a negative active material layer loaded on the surface of the current collector; the negative active material layer is a lithium metal layer; the negative electrode current collector comprises a current collector body and a lithium-philic nanometer array growing on the current collector body in situ; the thickness of the lithium-philic nanometer array is 0.8 <mu>m to 20 <mu>m. Compared with the prior art, the stable lithium metal negative electrode has the following advantages: the lithium-philic nanosheet array is arranged on the current collector body, so that ion transmission is facilitated, uniform distribution of lithium ions can be realized, the affinity of the stable lithium metal negative electrode and the lithium metal can be improved, a lithium-philic nucleation site is provided, and uniform nucleation and stable deposition of the lithium metal in the deposition process are realized. The array structure growing in situ can guarantee to be in tight contact with a copper current collector and reduce the effective current density of the electrode, so that uniform deposition of the lithium metal is realized; the lithium-philic current collector can inhibit the growth of lithium dendrites.
Owner:SHENZHEN GRADUATE SCHOOL TSINGHUA UNIV

Sodion-embedded manganese dioxide nanometer sheet electrode as well as preparation method and application of electrode

The invention relates to a sodion-embedded manganese dioxide nanometer sheet electrode as well as a preparation method and an application of the electrode. The electrode can be used as the active material of a supercapacitor and comprises sodion-embedded manganese dioxide nanometer sheets evenly distributed on the surface of a foamed nickel substrate. The preparation method comprises the following steps of: (1) mixing sodium sulfate and manganese acetate to prepare an electrochemical deposition precursor solution; (2) setting up an electrochemical deposition platform through a three-electrode method and taking the foamed nickel substrate after pretreatment as a working electrode, a platinum electrode as a counter electrode and a saturated calomel electrode as a reference electrode; (3) soaking the electrodes in the electrochemical deposition precursor solution at same depth; (4) opening an electrochemical workstation, setting the working electrode to the anode, setting the working mode to a timing potential mode, and starting up the electrochemical workstation; (5) taking out and washing the working electrode after the electrochemical workstation stops working; and (6) drying to obtain the sodion-embedded manganese dioxide nanometer sheet electrode. The sodion-embedded manganese dioxide nanometer film electrode as well as the preparation method and the application of the electrode disclosed by the invention have the characteristics of simple technique, mild reaction condition and excellent electrochemical performance of materials.
Owner:WUHAN UNIV OF TECH

Carbon nanosphere/sulfur composite and preparation method and application thereof

The invention discloses a carbon nanosphere / sulfur composite and a preparation method and application thereof. The carbon nanosphere / sulfur composite comprises a carbon nanosphere and elemental sulfur; the carbon nanosphere is composed of petal-shaped carbon plates which are combined into a sphere shape, gaps exist between the carbon plates, and the carbon plates are arranged in a wrinkled form and provided with through holes; the elemental sulfur and the carbon nanosphere are combined through a fusion permeation method to form the carbon nanosphere / sulfur composite, wherein sulfur accounts for 75-84 wt% of the composite. The gaps and through holes in the carbon nanosphere facilitate fusion loading of sulfur and dispersion and transportation of electrolyte ions, and the carbon nanosphere with a large specific surface area can load more sulfur active substances and effectively inhibit dissolution of polysulfide; the nitrogen element is doped on the carbon nanosphere to improve the electroactivity of a carbon material and enhance physisorption on sulfur; the carbon nanosphere / sulfur composite can serve as a positive electrode of a lithium-sulfur battery to improve the capacity, rate capability, cycling stability and coulombic efficiency of the lithium-sulfur battery.
Owner:WENZHOU UNIVERSITY

Three-dimensional porous MXene/graphene composite membrane and preparation method and application thereof

The invention belongs to the technical field of electrode materials, and particularly relates to a three-dimensional porous MXene/graphene composite membrane and a preparation method and application thereof. The invention provides a preparation method of a three-dimensional porous MXene/graphene composite membrane. The preparation method comprises the following steps: providing a dispersion liquidof single-lamella MXene and a dispersion liquid of single-lamella graphene oxide; mixing the dispersion liquid of the single-lamella MXene and the dispersion liquid of the single-lamella graphene oxide to obtain a mixed dispersion liquid, and forming a membrane to obtain an MXene/graphene oxide composite membrane; and carrying out a self-propagating reduction reaction on the MXene/graphene oxidecomposite membrane to obtain the three-dimensional porous MXene/graphene composite membrane. According to the preparation method disclosed by the invention, the three-dimensional porous MXene/graphenecomposite membrane can be rapidly prepared, and the three-dimensional porous MXene/graphene composite membrane has relatively high specific capacitance and excellent rate capability when being applied to a supercapacitor.
Owner:BEIJING UNIV OF CHEM TECH

Stretchable supercapacitor with stainless steel spring adopted as base

The invention discloses a stretchable supercapacitor with a stainless steel spring adopted as a base. The stretchable supercapacitor includes a stainless steel spring, an inner-layer electrode, an outer-layer electrode, and a gel electrolyte, wherein the stainless steel spring is adopted as the base of the stretchable supercapacitor, the inner-layer electrode and the outer-layer electrode are formed on the surface of the spring through in-situ growth or coat the surface of the spring, and the gel electrolyte is located between the two electrodes; the whole device is encapsulated with a flexible polymer material, so that the leak of the electrolyte can be prevented; the stainless steel spring, on the one hand, is adopted as a current collector of the inner-layer electrode, and on the otherhand, provides excellent stretchability for the device; the inner-layer electrode is made of a material such as a carbon material, a metal oxide and conductive polymer; the electrolyte is made of a polymer/electrolyte gel system such as PVA/H2SO4 and PVA/H3PO4; and carbon nanotubes or MXenes are wound so as to form the outer-layer electrode. The supercapacitor of the present invention can work normally under large tensile strain; the expected tensile strain of the supercapacitor can be as high as 100% under premise that the performance of the supercapacitor is not affected; and the outer spaceof the spring structural component can be efficiently utilized. The supercapacitor can be applied to systems such as high-speed train wireless monitoring systems.
Owner:SOUTHWEST JIAOTONG UNIV

Negative plate and lithium ion battery comprising the same

The invention provides a negative plate and a lithium ion battery comprising the same. A first negative active material layer in the negative plate is arranged on a bottom layer and comprises a firstbinder resistant to electrolyte swelling, a chemical corrosion resistance effect is better, aging is not prone to happening, long-acting bonding between the bottom layer of active materials and a current collector is guaranteed, and battery cell expansion under quick charging is reduced. The negative plate disclosed by the invention can maintain good mechanical strength and ductility under the soaking of an electrolyte, and ensures that the negative active material layer is not separated from a negative current collector; and a second binder in a second negative active material layer far awayfrom the negative current collector selects a high-swelling material with a solubility parameter similar to that of the electrolyte, the affinity of the high-swelling binder and the electrolyte is better, the infiltration speed of the electrolyte is good, lithium ion conduction is facilitated, and meanwhile, the high-swelling binder is better bonded with a diaphragm in the hot pressing process sothat an interface bonding effect between the negative electrode active material layer and the diaphragm is improved.
Owner:ZHUHAI COSMX BATTERY CO LTD

Gel-state electrode and preparation method thereof

The invention discloses a gel-state electrode and a preparation method thereof. The electrode comprises an electrode active material, a conductive agent, SN, a lithium salt, a polymer and an additive. The preparation method comprises the following steps of dissolving the lithium salt and the additive in SN at 60-80 DEG C, adding the polymer, and fully stirring and dissolving to form a gel-state substance, and then, mixing the prepared gel-state substance, an electrode active material and a conductive agent, stirring or uniformly grinding, and coating one side of a solid electrolyte with the mixture to serve as the gel-state electrode of the solid-state battery. According to the type of the added polymer, whether cross-linking treatment is carried out or not is determined. The lithium salt can be completely dissolved in SN to form a plastic crystal electrolyte, and the selected polymer can also be dissolved in the plastic crystal electrolyte. According to the gel-state electrode provided by the invention, the contact performance between the electrode and the solid electrolyte can be improved, the ion transmission in the electrode can be improved, and the negative effect on the battery performance caused by the volume change generated in the charging and discharging process of the electrode active material can also be inhibited.
Owner:SHANGHAI INST OF SPACE POWER SOURCES

Treatment method for low-pollution recycling of lithium iron phosphate material

The invention discloses a treatment method for low-pollution recycling of a lithium iron phosphate material. The method comprises the following steps: discharging, disassembling and separating a wastelithium iron phosphate battery to obtain positive and negative pole pieces, and soaking the positive and negative pole pieces in a hot acid solution, ultrasonically loosening and stripping by a high-pressure water gun to obtain a lithium iron phosphate mixed material; calcining the lithium iron phosphate mixed material, detecting the contents of elements Fe, Li and P in the lithium iron phosphatemixed material, supplementing an Fe source, a Li source, a P source and a sugar source according to a detection result, adding a Mg source, a Ti source and a Mn source for doping, loosening a crystalgrain structure of the calcined material by using an acid solution with the weight percentage concentration of 1-5%, and adding a proportioned supplementing material to obtain slurry; and finally, grinding the slurry, performing spray pelletizing, drying, and calcining again to obtain the lithium iron phosphate material. The method is simple to operate, low in pollution, high in conversion rate and better and more stable in performance, and the waste lithium iron phosphate batteries are recycled to form the qualified lithium iron phosphate finished product.
Owner:HEFEI GUOXUAN HIGH TECH POWER ENERGY CO LTD CO LTD
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