The invention relates to the technical field of negative-
electrode-free batteries, in particular to a negative-
electrode-free composite all-
solid-state battery and a preparation method thereof.The preparation method comprises the steps that a negative
electrode current collector is modified, and target
metal is adopted for modification so as to improve the
lithium-loving characteristic or the
sodium-loving characteristic; the first
solid electrolyte layer is formed on the modified negative electrode
current collector; the second
solid electrolyte layer is coated on the first solid
electrolyte layer; and the positive
electrode material layer is formed on the second solid electrolyte layer through magnetron
sputtering. In order to solve the problem of poor
interface bonding between a negative
current collector and a solid electrolyte of a negative-electrode-free solid-state battery in the prior art, in the embodiment, the negative current collector is modified so as to improve the
lithium-loving /
sodium-loving characteristic of the surface of the current collector, and then a compact first solid electrolyte layer is formed through magnetron
sputtering, so that the
lithium-loving /
sodium-loving characteristic of the surface of the current collector is improved. Therefore, the heterogeneous materials can be tightly combined, and then the complete solid electrolyte is formed in a
coating mode to avoid the interface problem, so that the yield of the battery is improved.