388results about "Electrolyte layer coating" patented technology

Solid-state, ion-conducting batteries with an ion-conducting, solid-state electrolyte. The solid-state electrolyte has at least one porous region (e.g., porous layer) and a dense region (e.g., dense layer). The batteries are, for example, lithium-ion, sodium-ion, or magnesium-ion conducting solid-state batteries. The ion-conducting, solid-state electrolyte is, for example, a lithium-garnet material.

An object is to increase the conductivity of an electrode including active material particles and the like, which is used for a battery. Two-dimensional carbon including 1 to 10 graphenes is used as a conduction auxiliary agent, instead of a conventionally used conduction auxiliary agent extending only one-dimensionally at most, such as graphite particles, acetylene black, or carbon fibers. A conduction auxiliary agent extending two-dimensionally has higher probability of being in contact with active material particles or other conduction auxiliary agents, so that the conductivity can be improved.

Electrochemical cells or batteries featuring functional gradations, and having desirable, periodic configurations, and methods for making the same. One or more methods, in alone or in combination, are utilized to fabricate components of such electrochemical cells or batteries, which are designed to achieve certain thermal, mechanical, kinetic and spatial characteristics, and their effects, singly and in all possible combinations, on battery performance. The thermal characteristics relate to temperature distribution during charge and discharge processes. The kinetic characteristics relate to rate performance of the cells or batteries such as the ionic diffusion process and electron conduction. The mechanical characteristics relate to lifetime and efficiency of the cells or batteries such as the strength and moduli of the component materials. Finally, the spatial characteristics relate to the energy and power densities, stress and temperature mitigation mechanisms, and diffusion and conduction enhancements. The electrochemical cells or batteries constructed according to the methods presented in this invention are useful for all applications that require high rate performance, high energy/power density, good durability, high safety and long lifetime.

A method employing a bonding layer is used to form active metal electrodes having barrier layers. Active metals such as lithium are highly reactive in ambient conditions. The method involves fabricating a lithium electrode or other active metal electrode without depositing the barrier layer on a layer of metal. Rather a smooth barrier layer is formed on a smooth substrate such as a web carrier or polymeric electrolyte. A bonding or alloying layer is formed on top of the barrier layer. Lithium or other active material is then attached to the bonding layer to form the active metal electrode. A current collector may also be attached to the lithium or active metal during the process.

The application relates to the field of energy storage materials, and discloses a combined electrode with ultrahigh electron and ionic conductivity and a preparation method thereof. The combined electrode is formed in a manner that a battery active material is uniformly tied in a three-dimensional multi-hole network formed by carbon nano tubes which are connected in a crossing manner, and meshes and the surface of the active material are filled or coated with a solid electrolyte material. According to the combined electrode, the carbon nano tubes, which are communicated with one another, can form an ultrahigh electrical transmission network, on the one hand, a solid electrolyte can provide the ultrahigh lithium-ion transmission capacity while not influencing the connection of the carbon nano tubes and the conductive capacity of the electrode; on the other hand, the three-dimensional network formed by the carbon nano tubes is also fixed by virtue of the solid electrolyte, the formation of a solid electrolyte interface is controlled, and an active material is protected under the high charge-discharge voltage. The combined electrode has the high reversible capacity and the enhanced rate capability, and can meet the requirement of a power automobile or a mixed power automobile.

A method for preparing a multilayer material based on active lithium, by depositing a film of active lithium on a protective layer at a sufficient speed so that substantially no oxidation of the lithium occurs, and/or during a sufficient time for the adhesion of the lithium to develop after contact with the protective layer. The multilayer material, when incorporated in an electrochemical battery as an anode, has excellent impedance stability and no formation of dendrites during the cycling. Batteries where the anode is the multilayer material are particularly efficient in terms of their coulomb efficiency.

A method for manufacturing a lithium ion secondary battery includes a step of preparing a laminate comprising a solid electrolyte and a solid electrode or an electrode green sheet which is laminated on at least one surface of the solid electrolyte, and a step of providing a collector by laminating a collector material in the form of particles on the electrode or the electrode green sheet and sintering the collector material.

The present invention relates to nanostructured materials for use in rechargeable energy storage devices such as lithium batteries, particularly rechargeable secondary lithium batteries, or lithium-ion batteries (LIBs). The present invention includes materials, components, and devices, including nanostructured materials for use as battery active materials, and lithium ion battery (LIB) electrodes comprising such nanostructured materials, as well as manufacturing methods related thereto. Exemplary nanostructured materials include silicon-based nanostructures such as silicon nanowires and coated silicon nanowires, nanostructures disposed on substrates comprising active materials or current collectors such as silicon nanowires disposed on graphite particles or copper electrode plates, and LIB anode composites comprising high-capacity active material nanostructures formed on a porous copper and/or graphite powder substrate.

The present invention provides a lithium secondary battery and its fabrication method. More particularly, the present invention provides a lithium secondary battery comprising a super fine fibrous porous polymer separator film and its fabrication method, wherein the porous polymer separator film is fabricated by the following process: a) melting at least one polymer or dissolving at least one polymer with organic solvents to obtain at least one polymeric melt or at least one polymeric solution; b) adding the obtained polymeric melt or polymeric solution to barrels of an electrospinning machine; and c) discharging the polymeric melt or polymeric solution onto a substrate using a nozzle to form a porous separator film. The lithium secondary battery of the present invention has the advantages of better adhesion with electrodes, good mechanical strength, better performance at low and high temperatures, better compatibility with organic electrolyte solution of a lithium secondary battery.

The present invention relates to Lithium Metal batteries. In particular, it is related to lithium metal batteries containing a polyimide-based electrolyte. The present invention concerns a new concept of polyimide-based electrolytic component having an electrolyte consisting of at least one solvent and at least one alkali metal salt, with specific amounts of solvents, to optimize the properties of conductivity of the polyimide-based electrolyte and the mechanical properties of the polyimide-based electrolyte separator towards metallic lithium anode to prevent dendrites growths.

A gradient of ionomeric material is generated, disposed, or otherwise provided in an electrode suitable for use in a fuel cell. The ionomer concentration, e.g., with respect to the carbon content of the catalyst layer (e.g., expressed as a ratio), is greatest in the area closest to the membrane, e.g., of the fuel cell (e.g., the membrane side), and is decreased in the area furthest from the membrane (e.g., the gas side). By way of another non-limiting example, the ionomer gradient can be formed such that the concentration (or the ratio if expressed in relation to the carbon content of the catalyst layer) can gradually, as opposed to rapidly, decrease as the distance away from the membrane increases.

Provided is a battery stack for use in an electric current producing cell, wherein the coated stack comprises a porous separator, an electrode layer adjacent the porous separator, and a current collector layer coated on the electrode layer, wherein the current collector layer comprises sintered metal particles. Also provided are methods of manufacturing such coated stacks.

A technique for fabricating an MEA. The technique includes providing a polymer electrolyte proton conducting membrane, and then spraying a catalyst ink directly on the membrane to form a catalyst layer. In one embodiment, the catalyst ink includes the proper ionomer to carbon ratio, such as 0.8/1, for the desired fuel cell performance. In another embodiment, the catalyst ink includes too little ionomer for the proper ionomer to carbon ratio for the desired fuel cell performance. An ionomer layer is sprayed on the membrane before the catalyst layer to provide the proper final ionomer to carbon ratio.

The invention provides an additive for a lithium sulphur battery, a cathode material containing the same and a preparation method for the cathode material. The additive is a product formed by carbonizing and compounding a carbon material and monosaccharide or polysaccharide polymerized by monosaccharide, wherein the monosaccharide and the polysaccharide contain intensive arc pair electron groups. The intensive arc pair electron group is -C=O or -OH. The monosaccharide is selected from glucose, fructose, galactose, ribose, glycogen and ribodesose. The conductive carbon material in the cathode material has good adsorption capacity, large specific surface area, and high pore volume and adopts a porous structure, and the electrochemical active substance is sulphur. The additive is the substance containing the intensive arc pair electron group. Polysulfide lithium produced during the discharge process can perform interaction with the additive in a mode of coordination and the like, so that the dissolution of the polysulfide lithium in electrolyte is restrained, and the loss of the active substance and the lithium cathode corrosion, rapid capacity fading influence and the like can be effectively reduced.

Provided is an all solid state battery which has the same level of discharge capacity as in the case of using an electrolyte solution, and is able to improve the cycle stability. An all solid state battery includes a solid electrolyte layer, as well as a positive electrode layer and a negative electrode layer provided in positions opposed to each other with the solid electrolyte layer interposed therebetween. At least one of the positive electrode layer and the negative electrode layer is bonded to the solid electrolyte layer by firing. The negative electrode layer contains an electrode active material composed of a metal oxide containing no lithium, and a solid electrolyte containing no titanium.

An energy storage device includes a nano-structured cathode. The cathode includes a conductive substrate, an underframe and an active layer. The underframe includes structures such as nano-filaments and/or aerogel. The active layer optionally includes a catalyst disposed within the active layer, the catalyst being configured to catalyze the dissociation of cathode active material.

Method of making Li-intercalateable electrodes for a lithium-ion battery by applying a first film onto a first face of an electrically conductive grid, which film comprises a plurality of Li-intercalateable particles dispersed throughout a mixture of a polymeric binder and a plasticizer for the binder. Thereafter, a film-forming slurry having the same composition as the first film, plus a solvent therefor, is applied to a second face of the grid opposing the first face so as to provide a second film and such that the solvent in the slurry dissolves at least a portion of the first film and promotes solvent bonding of the films with the grid embedded therein. A polymeric backing film treated with plasma and defining a separator is used as a manufacturing process aid, thereby eliminating the step of using a carrier film onto which the electrodes are fabricated and stripping off the carrier and discarding the same. Treating the separator with plasma enhances surface energy thereby improving the lamination process of the film-forming slurries to the separator and reducing degradation of the separator.

A method of making ceramic electrode materials comprising intimate mixtures of two or more components, including at least one nanoscale ionically conducting ceramic electrolyte material (e.g., yttrium-stabilized zirconia, gadolinium-doped ceria, samarium-doped ceria, etc.) and at least one powder of an electrode material, which may be an electrically conducting ceramic electrode material (e.g., lanthanum strontium manganite, praseodymium strontium manganese iron oxide, lanthanum strontium ferrite, lanthanum strontium cobalt ferrite, etc.) or a precursor of a metallic electrode material (e.g., nickel oxide, copper oxide, etc.). The invention also includes anode and cathode coatings and substrates for solid oxide fuel cells prepared by this method.

A method for roughening a surface of an ion exchange system structure using laser interaction with a surface. The laser surface roughening process allows the use of a wide range of substrates such as metals, ceramics, silicates, polymers and the like, including varieties which can not be fabricated in a fine fibrous structure. The surface roughened ion exchange system structure may be used as an ion-exchange media in applications such as fuel cells, batteries, and other catalysis systems where a high surface exchange area is desirable.

The thin battery of the invention comprises an anode material, a cathode material, two or more separator paper layers there between, and electrolyte. One of the outer separator paper layers has an anode material applied thereon, another separator paper layer being an outer layer on the opposite side having a cathode material applied thereon. The method of the invention for manufacturing such a thin battery is mainly characterized by the steps of wetting a separator paper with an electrolyte solution, applying an anode material on a first separator paper and applying a cathode material on a second separator paper. The separator papers are then combined by pressing them together so that the anode and cathode materials are outmost, respectively in order to form a layered structure. The combined layers are then cut in desired sizes.

The present invention provides a lithium-air hybrid battery and a method for manufacturing the same, which has a structure in which a liquid electrolyte electrode and a solid electrolyte electrode are stacked on both sides of an ion conductive glass ceramic. That is, disclosed is a lithium-air hybrid battery and a method for manufacturing the same, which has a structure in which a lithium metal negative electrode includes a liquid electrolyte and a porous air positive electrode comprising a carbon, a catalyst, a binder and a solid electrolyte are separately stacked on both sides of an impermeable ion conductive glass ceramic, and the liquid electrolyte is present only in the lithium metal negative electrode.

Embodiments of the present invention provide a lithium ion battery silicon negative electrode sheet preparation method, which comprises: taking a silicon material, a plasticizer, a binder and a conductive agent to form a silicon negative electrode slurry preparation solid component, dispersing the slurry preparation solid component in an organic solvent, and stirring to prepare a silicon negative electrode slurry, wherein the amount of the plasticizer is 4-30% of the total weight of the silicon negative electrode slurry preparation solid component; and coating the silicon negative electrode slurry onto the surface of a current collector, carrying out drying and rolling, placing the rolled negative electrode sheet in methanol or ethanol to extract, and drying to prepare the lithium ion battery silicon negative electrode sheet. According to the preparation method, the silicon negative electrode sheet with characteristics of high porosity, large pore size and porous structure can be prepared with the small amount of the plasticizer, and characteristics of simpleness, easy performing, low cost, no pollution and easy industrial production are provided. Embodiments of the present invention further provide a lithium ion battery silicon negative electrode sheet and a lithium ion battery containing the lithium ion battery silicon negative electrode sheet.