The application discloses a
crown ether polymer and a preparation method and application thereof, and relates to the technical field of material preparation. The preparation method of the
crown ether polymer provided by the application comprises the following steps: mixing HHT (4,4',4'',4'''-(6,7,9,10,17,18,20,21-octahydrodibenzo[B,K][1,4,7,10,13,16]hexaoxacyclooctadecine-2,3,13,14-tetrayl) tetrakisbenzaldehyde) and DBD (2,5-diamino-1,4 benzodithiophene) to prepare a reticular
crown ether polymer with rich crown
ether and
thiazole structures. When the crown
ether polymer is used as a light
anode protective layer, the active specific surface area of an
electrode surface can be improved, and Cl ‑ penetration into the light
anode can be prevented, so that the active specific surface area of the light
anode cannot be reduced, and the cycle performance of the light anode cannot be reduced. Meanwhile, the crown
ether polymer has
semiconductor characteristics, and can improve the photo-generated carrier separation efficiency of the light anode.