[Problem] An object of the invention is to provide a lithium secondary battery that shows good cycle performance and at the same time prevents a battery thickness increase due to charge-discharge cycles, and a method of manufacturing such a battery.
[Means for Solving the Problem] A lithium secondary battery includes a negative electrode (2) having a negative electrode current collector (11) and a negative electrode active material layer (12) disposed on the negative electrode current collector (11), a positive electrode (1) having a positive electrode active material, a separator (3), and a non-aqueous electrolyte. The negative electrode active material layer includes negative electrode active material particles and a negative electrode binder, and the negative electrode active material particles include silicon particles and/or silicon alloy particles. The silicon particles and the silicon alloy particles have a crystallite size of 100 nm or less.