740 results about "Oxygen evolution" patented technology

The invention belongs to the field of microbial electrochemistry and solid organic waste recycling, and discloses a microbial electrosynthesis enhanced solid wastewater hydrolysis and anaerobic digestion biogas high-value utilization system coupling microbial electrosynthesis, organic solid waste electrochemical-biological synergistic hydrolysis oxidation and anaerobic digestion. The system comprises a cathode chamber and an anode chamber which are separated by an ion exchange membrane, an electrochemical driving device and an anaerobic digestion unit communicated with the anode chamber. And the cathode chamber is provided with a cathode electrode and an anaerobic acetic acid production microbial system and is communicated with biogas generated by anaerobic digestion, so that carbon dioxide in the biogas is reduced at the cathode to generate acetic acid and methane-enriched gas is output. The anode chamber is provided with an anode electrode, organic solid waste and a hydrolytic microorganism system are added, electrochemical-biological synergistic hydrolytic oxidation of the organic solid waste and hydrolysates of the organic solid waste is used as an anode reaction, oxygen evolution is inhibited, and oxygen transmembrane migration is reduced; and the hydrolysate in the anode chamber flows into the anaerobic digestion unit to produce biogas, so that the integrated operation of solid wastewater hydrolysis and biogas upgrading is realized.

The invention is suitable for the technical field of photocatalyst preparation, and provides a modified tubular g-C3N4 loaded Ni-CoP photocatalyst and a preparation method thereof. The preparation method comprises the following steps: calcining a carbon nitride precursor in stages to obtain tubular carbon nitride, stirring the tubular carbon nitride with a cobalt and nickel-containing compound and an alkaline compound, washing and drying to obtain a precipitate, calcining, mixing and grinding with a phosphorus-containing compound, calcining again, and modifying the product with polydopamine and polypyrrole to obtain the composite material. The photocatalyst modified by the polydopamine and the polypyrrole and loaded with the Ni-CoP by taking the tubular g-C3N4 as the carrier is obtained. According to the invention, three-in-one synergistic integration of'carrier-modifier-cocatalyst 'is realized, the prepared photocatalyst still keeps tubular morphology and has a larger specific surface area, the requirements of anode oxygen evolution reaction (OER) on rapid charge separation and transmission can be met, meanwhile, the light absorption range is widened, the solar energy utilization rate is increased, and a foundation is laid for efficient OER reaction.

The invention relates to the technical field of electro-catalysis oxygen evolution, and particularly discloses a nickel-molybdenum foam composite oxygen evolution electro-catalysis material with high-valence nickel induced by molybdate radicals and a preparation method of the nickel-molybdenum foam composite oxygen evolution electro-catalysis material aiming at the problem that an existing oxygen evolution electro-catalysis material is insufficient in comprehensive performance or poor in performance stability. Soaking in a NaCl aqueous solution, and taking out; s2, mixing the nickel-molybdenum alloy foam with a K3 [Fe (CN) 6] aqueous solution, heating, and carrying out a hydrothermal reaction; and S3, finally, the nickel-molybdenum alloy foam is placed in the air or oxygen atmosphere and heated to 350-450 DEG C, heat preservation treatment is conducted for 2 h, and the nickel-molybdenum foam composite oxygen evolution electro-catalysis material is obtained. Molybdate anions are adopted as a sustainable induction source to be coupled with a NixOy / Fe3O4 heterogeneous interface, integrated construction is achieved on a nickel-molybdenum foam framework, and the nickel-molybdenum foam composite material has the advantages of being low in overpotential, high in stability, high in activity, high in binding force and long-term in durability and meanwhile being simple in process, easy to amplify on a large scale and the like.

One embodiment of the invention discloses a La-doped two-phase heterojunction catalyst, the catalyst comprises a precursor and an amorphous coating layer, the amorphous coating layer wraps at least part of the precursor, the precursor is crystal-phase La-doped Ni3S2, and the amorphous coating layer is FeOOH. The oxygen evolution catalyst has good oxygen evolution performance. The invention further discloses a preparation method and application of the La-doped two-phase heterojunction catalyst.

The invention relates to the field of efficient integrated assemblies of PEM water electrolysis hydrogen production systems, and discloses an efficient integrated assembly for a PEM exchange membrane water electrolysis hydrogen production system, an anode electrode unit in the integrated assembly comprises a ruthenium-based high-entropy metal oxide electrocatalyst, and the ruthenium-based high-entropy metal oxide electrocatalyst comprises ruthenium, tin, manganese, chromium and tantalum elements; the preparation method of the ruthenium-based high-entropy metal oxide electrocatalyst comprises the following steps: grinding solid inorganic ruthenium salt, tin salt, manganese salt, chromium salt, tantalum salt and sodium chloride to obtain a metal salt mixture; carrying out ball milling to obtain a high-entropy metal oxide precursor; and carrying out heat treatment and water washing treatment on the precursor to obtain the ruthenium-based high-entropy metal oxide electrocatalyst. The invention also discloses application of the electrocatalyst in water electrolysis oxygen evolution reaction in an acid solution and water electrolysis hydrogen production reaction of a PEM proton exchange membrane, and the electrocatalyst shows excellent electrocatalytic activity.

The invention relates to an oxygen evolution catalyst for hydrogen production through electrolysis of proton exchange membrane water, a membrane electrode and a preparation method of the membrane electrode, and the oxygen evolution catalyst is iridium oxide in a nanoparticle form and contains 2-2.5% of crystal water; the preparation method of the catalyst comprises the following steps: carrying out ultrasonic treatment on an iridium salt solution, mixing the iridium salt solution with magnesium sulfate and water, carrying out ultrasonic treatment, volatilizing a solvent, drying, carrying out ball milling to obtain powder, carrying out high-temperature calcination, dissolving with dilute acid, carrying out suction filtration with water and ethanol until the conductivity is less than 10 [mu] s / cm, carrying out vacuum drying to remove moisture, and grinding to obtain the catalyst. The membrane electrode comprises the catalyst powder prepared by the method and an anode catalyst layer formed by perfluorinated sulfonic acid resin; and the cathode catalyst layer is formed by Pt / C and perfluorosulfonic acid resin. The oxygen evolution catalyst provided by the invention has high activity and high stability, magnesium sulfate is adopted in the preparation method, and the oxygen evolution catalyst has the advantages of simple operation, low cost and the like.

The invention relates to an IrO2-Ta2O5 titanium anode coating based on graphene doping and temperature programming sintering synergistic enhancement and a preparation method of the IrO2-Ta2O5 titanium anode coating, and belongs to the technical field of electrode material preparation. According to the method, graphene is doped in an IrO2-Ta2O5 coating, the content of the graphene is controlled to be 0.2-0.8 mg / mL, preferably 0.6 mg / mL, the content of iridium is 26 g / m, and a 200-500 DEG C temperature programming sintering process is adopted. By optimizing the graphene dispersing and sintering process, the conductivity, the electrocatalytic activity and the structural stability of the coating are remarkably improved. Experimental results show that the coating has lower charge transfer resistance and higher electric double layer capacitance and oxygen evolution reaction activity, and the strengthening life of the coating exceeds 1100 hours and is far longer than that of a traditional titanium anode coating. The method is suitable for high-requirement electrochemical scenes such as electrolytic copper foil and chlor-alkali industry, and has a good industrial popularization prospect.

The invention discloses a Joule thermal preparation method of a carbon-supported high-entropy sulfide catalyst and application of the carbon-supported high-entropy sulfide catalyst in a zinc-air battery. A metal chlorine salt solution is used as a metal precursor, and sulfur is used as a sulfur source. Sulfur, carbon powder and a metal chlorine salt solution are uniformly mixed and loaded on a conductive carrier, and Joule heat treatment is carried out. Instantaneous high temperature acts on a carbon-supported metal precursor, the metal precursor is decomposed, S8 is decomposed into high-activity S2 gas, diffusion of sulfur atoms is accelerated at high temperature, combination of S2 and reduced metal atoms is promoted, sulfide bonds are formed, meanwhile, segregation is inhibited through rapid cooling, and finally the uniform single-phase carbon-supported high-entropy sulfide catalyst is formed. The uniformly distributed carbon-loaded high-entropy sulfide catalyst is prepared by Joule thermal pyrolysis, the preparation method is simple, energy-saving and environment-friendly, and the catalyst can simultaneously catalyze an oxygen reduction reaction and an oxygen evolution reaction, is used as a bifunctional catalyst for a zinc-air battery, has excellent catalytic activity and stability, and is easy to popularize and use.

The invention belongs to the technical field of preparation of electrocatalytic oxygen evolution catalysts, and particularly discloses a doping regulation type ruthenium-iridium-based electrocatalytic oxygen evolution catalyst and a preparation method thereof.The preparation method comprises the following steps that S1, ruthenium salt, iridium salt and doped metal salt are dispersed in a solvent, the doped metal salt is selected from one or more of yttrium salt, strontium salt, potassium salt, calcium salt, magnesium salt, scandium salt, gallium salt and aluminum salt; s2, preparing a precursor mixture; s3, performing heat treatment to obtain a solid product; and S4, washing and drying to obtain the metal element doped ruthenium-iridium-based electro-catalytic oxygen evolution catalyst. According to the doping regulation type ruthenium-iridium-based electro-catalysis oxygen evolution catalyst and the preparation method thereof, the process is simple, the universality is high, doping of multiple elements can be achieved only by replacing the doped metal salt, and the obtained catalyst has excellent acidic water electrolysis oxygen evolution activity and long circulation stability; and excessive phase splitting of the Y element and excessive lattice distortion of other elements can be avoided.

The invention belongs to the technical field of electro-catalysis, and particularly relates to a short-range ordered neodymium element doped iridium oxide catalyst, an iridium oxide-based catalyst and a preparation method and oxygen evolution application thereof. The preparation method comprises the following steps: reacting iridium source metal salt with strong alkali, then carrying out alkali-assisted co-precipitation reaction with neodymium source metal salt to form iridium-neodymium co-coordinated hydrated hydroxide, and then sequentially carrying out drying, heat treatment and acid treatment to obtain the short-range ordered neodymium element doped iridium oxide catalyst. According to the method, the amorphous iridium oxide matrix dominated by side sharing [IrO6] connectivity is directly generated, meanwhile, low-valence Nd < 3 + > cations with large ion radius and obvious oxyphilicity are in a short-range frame of the amorphous iridium oxide matrix so as to synergistically activate an OPM oxide path mechanism, and the OPM oxide path mechanism overcomes the technical defects existing in an existing LOM lattice oxygen mechanism.

The invention relates to a porous nickel-iron alloy integrated electrode and a preparation method and application thereof, and belongs to the technical field of electrochemistry. The preparation method comprises the following steps: carrying out cleaning pretreatment on a stainless steel mesh substrate; then electro-deposition is carried out in a solution containing ferric salt and nickel salt, and a nickel-iron alloy layer is formed; carrying out secondary electro-deposition in a solution containing zinc salt, and carrying out high-temperature calcination treatment to obtain a nickel-iron-zinc alloy; and finally, the zinc component is removed through selective corrosion of an alkaline solution, and the nickel-iron alloy integrated electrode with the porous structure is formed on the stainless steel mesh. The method is controllable in process, and a porous structure which is high in specific surface area and beneficial to mass transfer is effectively constructed through step-by-step electro-deposition, calcination and corrosion treatment. The obtained integrated electrode can be directly used as an alkaline water electrolysis oxygen evolution reaction (OER) anode, shows high electrocatalytic activity and stability, and is suitable for the fields of water electrolysis hydrogen production and the like.

The application discloses a bifunctional In-doped Ni2Mo3N@Mo2C binary heterojunction catalyst and a preparation method and application thereof. A dimethyl imidazole solution is slowly added into a Mo salt solution to obtain a suspension liquid containing a Mo metal organic framework Mo-MOF; the suspension liquid is left to stand, and a precipitate is centrifuged and washed, and vacuum dried to obtain the Mo-MOF containing the Mo metal organic framework; a Ni salt, an In salt and the Mo-MOF are added into an anhydrous ethanol solution to perform ion exchange, and the precursor is vacuum dried to obtain the bifunctional In-doped Ni2Mo3N@Mo2C binary heterojunction catalyst. The catalyst material has excellent basic oxygen evolution and urea oxidation activity, and has a good application prospect in electrocatalytic decomposition of water, urea-assisted electrolysis of water and treatment of sewage containing urea.

The invention discloses an oxygen evolution-free sodium carbonate composite material as well as a preparation method and application thereof. The preparation method of the composite material comprises the following steps: carrying out powder refinement treatment on a sodium carbonate precursor to obtain particles with the average particle size from micron to nanoscale; s2, uniformly mixing the sodium carbonate precursor treated in S1 with a conductive carbon material to form a composite precursor; placing the composite precursor in an inert atmosphere or a reducing atmosphere, calcining the composite precursor at 400-900 DEG C, and then cooling the composite precursor to room temperature to obtain the oxygen evolution-free sodium carbonate composite material, wherein the conductive carbon material is a high-specific-surface-area carbon material of which the surface is rich in at least one of carbonyl, carboxyl and hydroxyl. The composite material obtained by the method disclosed by the invention is applied as a pre-sodium-modified additive, so that the decomposition voltage of the pre-sodium-modified additive can be greatly reduced, and oxygen evolution is effectively inhibited, thereby improving the first-week coulombic efficiency, cycling stability and overall safety performance of the sodium-ion battery.

The invention relates to a RuSe2-MoSe2 / NF heterojunction bifunctional catalyst for fully hydrolyzed seawater as well as a preparation method and application of the RuSe2-MoSe2 / NF heterojunction bifunctional catalyst, and belongs to the technical field of seawater electrolysis electrocatalysis. The preparation method of the bifunctional catalyst comprises the following steps: (1) mixing deionized water and absolute ethyl alcohol, and magnetically stirring to obtain a mixed solvent; then adding sodium borohydride and selenium powder into the mixed solvent, and stirring until the mixture is completely dispersed to obtain a mixed solution; adding sodium molybdate dehydrate and ruthenium trichloride into the mixed solution, introducing high-purity nitrogen, replacing air, and continuing magnetic stirring to obtain a dark brown precursor mixed solution; and (2) completely immersing the pretreated nickel foam NF in the precursor mixed solution, carrying out hydrothermal reaction, cooling to room temperature after the reaction, taking out the nickel foam NF, washing with deionized water for 3-5 times, then washing with absolute ethyl alcohol for 3-5 times, and drying to obtain the nickel foam NF. The bifunctional catalyst provided by the invention can efficiently catalyze a hydrogen evolution reaction and an oxygen evolution reaction in seawater at the same time.

The invention discloses a modified cobaltosic oxide catalyst and a preparation method and application thereof.The catalyst comprises a carrier foamed nickel, tungsten and chlorine co-doped cobaltosic oxide nanosheets W and Cl-Co3O4, the tungsten and chlorine co-doped cobaltosic oxide nanosheets W and the Cl-Co3O4 are loaded on the carrier, cobalt chloride and tungsten salt serve as precursors of the catalyst, and the tungsten and chlorine co-doped cobaltosic oxide nanosheets W and the Cl-Co3O4 are loaded on the carrier. The preparation method comprises the following steps: firstly, carrying out a hydrothermal reaction to obtain a nickel foam loaded tungsten-doped basic cobalt chloride nanosheet W-Co2 (OH) 3Cl2, and then carrying out in-situ conversion on the Co2 (OH) 3Cl2 into a nickel foam loaded tungsten and chlorine co-doped cobaltosic oxide nanosheet W, Cl-Co3O4 through calcination. According to the invention, chlorine and tungsten are introduced into cobaltosic oxide, so that the activity and stability of electrocatalytic oxygen evolution are improved, and the cobaltosic oxide is used as an anode catalyst for electrocatalytic seawater decomposition and has excellent activity and stability of electrocatalytic oxygen evolution.

The invention belongs to the technical field of hydrogen production by water electrolysis, and discloses a device and a method for hydrogen production by alkaline water electrolysis enhanced by active ions regulated and controlled by a magnetic field. An anode magnetic flow channel and an anode non-magnetic substrate in the electrolytic cell are integrally designed and are combined to form an anode magnetic field functional bipolar plate, and the anode magnetic flow channel is formed. In the electrolysis operation process, the migration behavior and spatial distribution of iron ions dissolved in the electrolyte are actively regulated and controlled by applying an external magnetic field to the anode region, so that the iron ion concentration of the electrolyte phase is not increased, and the main body structure and material system of the existing industrial electrolytic cell are not changed; and the dissolved iron ions are directionally enriched on an anode interface. Through the regulation and control, relatively high dynamic iron active site coverage can be maintained on the surface of the anode, the polarization loss of oxygen evolution reaction is reduced, and the efficiency and stability of the process of hydrogen production by alkaline water electrolysis under the conditions of high current density and wide load operation are improved.

The invention relates to a RuO2-Co3O4 electro-catalytic material as well as a preparation method and application thereof. The electro-catalytic material comprises a carbon cloth substrate and a nanosheet array growing on the surface of a carbon cloth fiber, the nanosheet comprises a heterostructure which is composed of crystalline state Co3O4 particles and amorphous state RuO2. The preparation method comprises the following steps: taking activated carbon cloth as a working electrode, performing constant-potential electrodeposition in electrolyte containing cobalt salt, and then cleaning and drying to obtain Co (OH) 2 loaded carbon cloth; carrying out heat treatment on the carbon cloth for the first time to obtain carbon cloth loaded with Co3O4 nanosheets; then immersing the carbon cloth into a solution containing ruthenium salt to enable the ruthenium salt to be adsorbed on the Co3O4 nanosheet, and then cleaning and drying to obtain a precursor; and carrying out second heat treatment on the precursor to obtain the RuO2-Co3O4 heterojunction electro-catalytic material. The RuO2-Co3O4 electrocatalyst has the advantages that the RuO2-Co3O4 electrocatalyst has excellent electrocatalytic oxygen evolution activity and long-time operation stability. The preparation process is simple, the thickness of the catalyst layer can be controlled, and the process operation complexity and the requirement on equipment are reduced.

The invention discloses a preparation method and application of a high-entropy layered double hydroxide oxygen evolution catalyst, and relates to the field of oxygen evolution reaction catalysis, and the preparation method comprises the following steps: S1, washing foamed nickel in absolute ethyl alcohol and deionized water, and then carrying out ultrasonic treatment in a hydrochloric acid solution to obtain pretreated foamed nickel; s2, adding ferric salt, cobalt salt, nickel salt, manganese salt, zinc salt and a proper amount of urea into deionized water, then adding ammonium fluoride, and uniformly stirring to obtain a mixed solution; and S3, transferring the mixed solution and the pretreated foamed nickel into a reaction kettle, carrying out a hydrothermal reaction, and washing and drying the obtained product to obtain the high-entropy layered double hydroxide oxygen evolution catalyst. According to the method, the key regulation and control effect of NH4F on the structure, chemical and electro-catalytic properties of HELDHs in the synthesis process of the HELDHs is analyzed, and the performance enhancement is attributed to NH4F-induced morphology and crystal engineering and catalytic active cation vacancies generated in situ through selective leaching of Zn < 2 + > and adsorption of sulfate under the alkaline condition.

The invention relates to the field of novel energy conversion, and provides a construction method of an electrochemical device simulating artificial photosynthesis. Comprising the following steps: treating foamed nickel through a FeCl3 solution under the conditions of different concentrations and soaking durations, preparing an iron / nickel-based anode catalyst to separate out oxygen, and selecting foamed copper as a cathode catalyst to reduce carbon dioxide; the solar cell panel is used for converting light energy into electric energy to drive electro-catalytic reaction. According to the construction method of the electrochemical device simulating artificial photosynthesis, the solar panel is used for supplying power, and CO2 reduction reaction is catalyzed while water is electrolyzed. The equipment simulates artificial photosynthesis to realize conversion of water and CO2 into clean energy and low-carbon chemicals. By adopting a mode of combining solar power supply with electro-catalysis, the problems of low efficiency and poor stability of traditional photocatalysis are solved, and the cost of an existing electrochemical catalysis oxygen evolution reaction catalyst is reduced.

The application discloses a preparation method and application of a zirconium dioxide loaded iridium oxide nanocluster oxygen evolution electrocatalyst. A mixed solution of zirconium salt, amide solvent and organic acid is prepared, and the mixed solution is kept at 120 DEG C for 24 hours; after cooling, the white product is separated, washed and dried. Then, the product and iridium salt are dispersed in a mixed solution of tetrahydrofuran and water, and sodium nitrate and potassium nitrate aqueous solution are added under stirring; after stirring, rotary evaporation is carried out at 60 DEG C, and the greenish powder obtained after drying is vacuum dried at 60 DEG C for 12 hours; the greenish powder is kept in a muffle furnace at 450 DEG C for 30 minutes, and then cooled in air; the greenish powder is washed with deionized water and anhydrous ethanol for multiple times, and finally vacuum dried at 60 DEG C for 12 hours. The zirconium dioxide loaded iridium oxide material based on oxygen overflow stable tetragonal zirconia can be specially applied to an electrocatalyst for an oxygen evolution reaction in an acidic electrolyte, has excellent oxygen evolution reaction activity, follows a lattice oxygen mechanism in the reaction process, and can realize an oxygen overflow effect from tetragonal zirconia to iridium oxide nanoclusters to stabilize the catalyst.

The invention discloses a CO2 trapping system and method based on seawater grading pretreatment and electrochemical coupling. The system comprises a seawater grading pretreatment unit, an electrochemical coupling trapping unit and a CO2 separation and collection unit. The seawater grading pretreatment unit is used for removing suspended matters step by step and retaining carbonate through a triple filtering device, and preparing desalted seawater by utilizing a reverse osmosis device to meet electrolysis requirements; the electrochemical coupling trapping unit adopts a three-compartment structure including an anode chamber, a middle compartment and a cathode chamber, a cation exchange membrane and a proton exchange membrane are combined, protons generated by an anode are migrated to the middle compartment to react with seawater carbonate to generate CO2, and cathode hydrogen evolution and anode oxygen evolution are synchronously realized; and the CO2 separating and collecting unit is used for collecting high-purity CO2 through a membrane separation and vacuum negative pressure technology. According to the method, the problem of local consumption of deep and far sea wind power is solved, collaborative coupling of seawater purification, CO2 capture and green hydrogen preparation is realized, the green fuel synthesis cost is reduced, and the method has remarkable environmental and economic benefits.

The invention belongs to the technical field of electrocatalytic materials, and discloses a CeO2 / NiCo2O4 heterojunction oxygen evolution reaction electrocatalyst and a preparation method thereof. According to the electrocatalyst, a composite protection layer composed of nitrogen-doped carbon quantum dots and CeO2 is constructed on the surface of a NiCo2O4 nanosheet array, cobalt ions are captured and dissolved out through pyridine nitrogen, reintegration is promoted through CeO2 oxygen vacancy, and interface dynamic self-repairing is achieved. And the nitrogen-doped carbon quantum dots are embedded into the CeO2 layer and are in direct contact with NiCo2O4 to synergistically inhibit cobalt loss and maintain structural integrity. By constructing the CeO2 / nitrogen-doped carbon quantum dot composite interface layer with dynamic ion capture and self-repairing capabilities, the problems of structure instability and performance degradation caused by cobalt ion dissolution of the NiCo2O4-based oxygen evolution reaction electrocatalyst under the working condition of strong oxidizing property are successfully solved; the method has important application value and industrialization prospect in the technical field of green hydrogen energy electrolyzed water.

This invention relates to the field of functional materials technology, and discloses a ruthenium-based catalyst for the acidic oxygen evolution reaction (OER), its preparation method, and its application. The preparation method includes dissolving 100-200 parts by mass of RuCl3·H2O and 1-40 parts by mass of VCl3 in 20-60 parts by volume of anhydrous methanol, stirring to obtain a mixed solution; slowly adding hydrazine hydrate dropwise to the mixed solution, continuing stirring, centrifuging and filtering; washing alternately with anhydrous methanol and ultrapure water, freeze-drying, and heat-treating at 300-500℃ for 1-4 hours to obtain a V-doped RuO2 catalyst. The prepared V-RuO2 catalyst exhibits excellent initial activity and long-term durability under acidic conditions, providing a new solution for developing high-performance anode catalysts suitable for proton exchange membrane water electrolyzers.

The application provides a preparation method of a large-size tungsten-doped NiFe nanowire electrocatalyst, wherein the foam nickel is immersed in a corrosion solution containing Fe and W for 3-15 minutes to obtain a W-doped NiFe catalyst. The nanometer structure of the catalyst is an ordered nanowire with a diameter of 40-60 nm, and there is no agglomeration phenomenon, which is beneficial to the exposure of active sites and the release of oxygen, and the dense structure can improve the stability of the catalyst. When the W-NiFe catalyst is applied to an oxygen evolution reaction, the overpotential is only 143.7 mV when the current density is 10 mA cm ‑2 , and the catalyst can be stably operated for 150 hours under a current density of 500 mA cm ‑2 . The catalytic performance and stability of the catalyst are superior to those of a noble metal IrO2.

The invention provides a ferronickel-based oxygen evolution electrode and a preparation method thereof based on interface confinement. The preparation method of the ferronickel-based oxygen evolution electrode comprises the following steps: preparing a precursor solution containing ferrous ions and ferric ions; the foamed nickel substrate is cleaned; the cleaned foamed nickel is tightly attached to the surface of the bottom of the reaction container, the foamed nickel is immersed in the precursor solution, under the room-temperature standing condition, divalent and trivalent iron ions are induced to be subjected to a synergistic hydrolysis and coprecipitation reaction through a physical interface confinement space formed by an attached interface, and the nickel-based composite material is obtained. Therefore, a high-activity and high-uniformity nickel-iron-based (oxygen) hydroxide catalyst layer (DIC-NiFeOOH / NF) is grown on the surface of the foamed nickel in situ. The method is simple in process, green and energy-saving, and the prepared nickel-iron-based oxygen evolution electrode shows excellent performance in oxygen evolution reaction and anion exchange membrane water electrolysis.

The application provides a porous carbon nanofiber electrocatalyst loaded with cobalt / lanthanum hydroxide heterojunction and a preparation method. The preparation method comprises the following steps: adding 4,4-diamino diphenyl ether and pyromellitic dianhydride into a solvent, uniformly mixing, and preparing a polyamide acid precursor spinning solution; electrospinning the prepared polyamide acid precursor spinning solution to prepare polyamide acid nanofibers; immersing the prepared polyamide acid nanofibers in a mixed metal salt solution containing cobalt salt, lanthanum salt and zinc salt to prepare polyamide acid nanofiber precursors loaded with metal ions; and performing programmed temperature heat treatment on the prepared polyamide acid nanofiber precursors loaded with metal ions in a protective atmosphere to prepare the porous carbon nanofiber electrocatalyst loaded with cobalt / lanthanum hydroxide heterojunction. The prepared porous carbon nanofiber electrocatalyst loaded with cobalt / lanthanum hydroxide heterojunction has excellent electrochemical oxygen reduction reaction and oxygen evolution reaction bifunctional catalytic activity.

The invention discloses a high-activity oxygen evolution electrode. According to the structure of the oxygen evolution electrode, sheet-shaped nickel-iron alloy vertically grows on the surface of foamed nickel or a nickel net substrate, the surface of the nickel-iron alloy is modified with nickel-iron hydroxide, and the nickel-iron hydroxide and the nickel-iron alloy jointly form an electrode catalyst layer. The prepared oxygen evolution electrode has high conductivity and specific surface area, the nickel-iron alloy and the nickel-iron hydroxide have a strong synergistic effect, and the prepared oxygen evolution electrode has excellent oxygen evolution activity in seawater.

The invention discloses a self-weight configuration oxygen evolution electrode and a preparation method and application thereof.The preparation method comprises the steps that a nickel substrate serving as a working electrode, a platinum sheet serving as a counter electrode and a saturated calomel electrode serving as a reference electrode are placed in a NiCo2O4 precursor solution, constant-potential electro-deposition is conducted on the nickel substrate, and a precursor electrode with a Ni-Co LDH precursor on the surface is obtained; putting the precursor electrode into a heating device for heating and heat preservation, and then taking out the precursor electrode for cooling to obtain a NiCo2O4 electrode with a spinel structure; and sequentially putting the NiCo2O4 electrode into a ferric nitrate nonahydrate aqueous solution and a sodium hydroxide solution, and loading alpha-Fe2O3 nanoparticles on the surface of the NiCo2O4 electrode by using a continuous ion layer adsorption reaction method to obtain the self-weight configuration oxygen evolution electrode. According to the preparation method of the self-weight configuration oxygen evolution electrode, a composite catalyst layer composed of NiCo2O4 and alpha-Fe2O3 of a spinel structure is constructed on a nickel substrate, and the self-weight configuration oxygen evolution electrode can adapt to power fluctuation.

The application discloses a preparation method and application of an oxygen-evolving electrocatalyst of iridium oxide anchored by surface titanium oxygen species. The catalyst is obtained by electro-oxidizing a titanium nitride supported metal iridium cluster pre-catalyst. The surface titanium oxygen species is obtained by electrochemical reconstruction of titanium nitride, and the iridium oxide is obtained by electro-oxidizing a metal iridium cluster. When the catalyst is used for an anode oxygen evolution reaction, the catalyst has excellent catalytic activity and significantly improved stability. Compared with existing catalysts, the catalyst provided by the application is obtained by electro-oxidizing a pre-catalyst. In a PEM electrolytic cell, the titanium nitride carrier in the pre-catalyst plays a role of a pore-forming agent in the electro-oxidation dissolution process, and the catalytic layer is spontaneously thickened, thereby solving the problems of poor uniformity and mechanical stability of a super-thin catalytic layer electrode of a PEM water electrolysis cell, and more easily realizing large-scale industrial application under an ultra-low iridium load.

The present application relates to a kind of wastewater treatment system and processing method of electrolytic water anode oxygen coupling biological technology, belong to sewage treatment technical field, solve the technical problems such as the micro-aerobic sewage biological treatment technology needs accurate dissolved oxygen, organic matter remains, total nitrogen removal efficiency needs to be improved, including electrolytic water device, including polymer membrane electrolytic cell, proton exchange membrane is arranged in polymer membrane electrolytic cell, proton exchange membrane is used to divide polymer membrane electrolytic cell into cathode chamber and anode chamber, pure water is used to be introduced in cathode chamber, and the wastewater to be treated is used to be introduced in anode chamber;The wastewater inlet of anode chamber is connected with bioreactor, and the wastewater outlet of anode chamber is connected with bioreactor.In electrolysis process, oxygen evolution reaction occurs in anode, and the dissolved oxygen generated is immediately mixed with wastewater, enters bioreactor, improves the degradation efficiency of organic matter, ammonia nitrogen and other pollutants, while avoiding the disadvantages such as high energy consumption and low oxygen utilization rate caused by traditional air blowing aeration of bioreactor.