The invention provides a synthetic method of a biological structural carbon/cerium oxide artificial photosynthesis material. The synthetic method comprises the following steps: leaf pretreatment is carried out, plant leaves are soaked in mixed liquor of dilute hydrochloric acid, absolute ethyl alcohol and distilled water, then is taken out, is cleaned with the distilled water, and is soaked in the mixed liquor of dilute hydrochloric acid, absolute ethyl alcohol and the distilled water; a cerium solution is prepared, a pretreated leaf template is soaked in the cerium solution, is taken out, is washed with the distilled water, and is dried; the treated leaf template is calcined under nitrogen atmosphere protection, then is calcined in an air atmosphere, and is subjected to natural cooling, and the biological structural carbon/cerium oxide artificial photosynthesis material is obtained. The synthetic method of the biological structural carbon/cerium oxide artificial photosynthesis material adopts a relatively simple chemical technology, the reaction requires no complicated equipment, the varieties of required chemical raw materials are few, the cost is low, the experiment repeatability is good, the biological structural carbon/cerium oxide artificial photosynthesis material has very high photocatalysis value, a utilization ratio of visible light by the biological structural carbon/cerium oxide artificial photosynthesis material can be raised substantially, the effect of photocatalytically splitting of water into hydrogen of the biological structural carbon/cerium oxide artificial photosynthesis material under sunlight can be improved, and the biological structural carbon/cerium oxide artificial photosynthesis material has wide potential application value.