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Negative plate and lithium ion battery comprising the same

A negative electrode sheet and negative electrode technology, applied in the direction of negative electrodes, battery electrodes, secondary batteries, etc., can solve problems such as battery failure, binder aging, high temperature rise, etc.

Pending Publication Date: 2021-03-26
ZHUHAI COSMX BATTERY CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] Under the fast charging system, without sacrificing energy density, the requirements for the negative electrode charging capacity of lithium-ion batteries are getting higher and higher. During the fast charging process, the negative electrode sheet is prone to the problem of electrolyte drying up caused by lithium precipitation and side reactions. Cause battery failure; at the same time, fast charging brings higher temperature rise and binder aging problems, resulting in hard and bulging growth of negative electrodes

Method used

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  • Negative plate and lithium ion battery comprising the same
  • Negative plate and lithium ion battery comprising the same
  • Negative plate and lithium ion battery comprising the same

Examples

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preparation example Construction

[0066] The preparation method of the present invention will be further described in detail in conjunction with specific examples below. It should be understood that the following examples are only for illustrating and explaining the present invention, and should not be construed as limiting the protection scope of the present invention. All technologies realized based on the above contents of the present invention are covered within the scope of protection intended by the present invention.

[0067] Unless otherwise specified, the experimental methods used in the following examples are conventional methods; the reagents and materials used in the following examples, unless otherwise specified, can be obtained from commercial sources.

[0068] In the description of the present invention, it should be noted that the terms "first", "second" and so on are only used for descriptive purposes, and do not indicate or imply relative importance.

[0069] The solubility parameter used in...

Embodiment 1-7 and comparative example 1-4

[0075] The preparation process of Examples 1-7 and Comparative Examples 1-4 is the same, the difference is that the structure of the negative plate is different, and the specific operations are as follows:

[0076] Add positive electrode active material (lithium cobalt oxide), conductive agent (super-p), and binder (PVDF) into N-methylpyrrolidone in a mass ratio of 97:2:1, mix well and coat on the positive electrode On the current collector (aluminum foil), after drying at a temperature of 90°C, it is rolled with a roller press, cut into pieces, slit, vacuum-dried, and welded with tabs to make a positive electrode sheet.

[0077] Ethylene carbonate (EC), propylene carbonate (PC), diethyl carbonate (DEC), propyl propionate (PP), ethyl propionate (EP) in a volume ratio of 15:15:10:60 Mix well, then add LiPF to it 6 Modulate into 1mol / L electrolyte, and add 2wt% vinylene carbonate (VC), 5wt% fluoroethylene carbonate as additive, make final electrolyte, calculate the solubility p...

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Abstract

The invention provides a negative plate and a lithium ion battery comprising the same. A first negative active material layer in the negative plate is arranged on a bottom layer and comprises a firstbinder resistant to electrolyte swelling, a chemical corrosion resistance effect is better, aging is not prone to happening, long-acting bonding between the bottom layer of active materials and a current collector is guaranteed, and battery cell expansion under quick charging is reduced. The negative plate disclosed by the invention can maintain good mechanical strength and ductility under the soaking of an electrolyte, and ensures that the negative active material layer is not separated from a negative current collector; and a second binder in a second negative active material layer far awayfrom the negative current collector selects a high-swelling material with a solubility parameter similar to that of the electrolyte, the affinity of the high-swelling binder and the electrolyte is better, the infiltration speed of the electrolyte is good, lithium ion conduction is facilitated, and meanwhile, the high-swelling binder is better bonded with a diaphragm in the hot pressing process sothat an interface bonding effect between the negative electrode active material layer and the diaphragm is improved.

Description

technical field [0001] The invention belongs to the technical field of lithium ion batteries, and in particular relates to a negative electrode sheet and a lithium ion battery including the negative electrode sheet. Background technique [0002] In recent years, with the increasing popularity of new energy vehicles and the rapid development of electronic devices such as notebook computers and smart phones, the development and progress of lithium-ion battery technology as the core of energy supply has been driven, and more and more advanced lithium-ion battery technology has been proposed. There are higher requirements, such as higher energy density, faster charging and discharging speed, better battery life and more relaxed use environment. [0003] Under the fast charging system, without sacrificing energy density, the requirements for the negative electrode charging capacity of lithium-ion batteries are getting higher and higher. During the fast charging process, the negat...

Claims

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Application Information

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IPC IPC(8): H01M4/133H01M4/62H01M10/0525
CPCH01M4/133H01M4/622H01M10/0525H01M2004/027Y02E60/10H01M4/134H01M4/366H01M10/4235H01M4/0404H01M4/139H01M4/663
Inventor 陈伟平李素丽郭盼龙储霖李俊义徐延铭
Owner ZHUHAI COSMX BATTERY CO LTD
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