Negative plate and lithium ion battery comprising the same
A negative electrode sheet and negative electrode technology, applied in the direction of negative electrodes, battery electrodes, secondary batteries, etc., can solve problems such as battery failure, binder aging, high temperature rise, etc.
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[0066] The preparation method of the present invention will be further described in detail in conjunction with specific examples below. It should be understood that the following examples are only for illustrating and explaining the present invention, and should not be construed as limiting the protection scope of the present invention. All technologies realized based on the above contents of the present invention are covered within the scope of protection intended by the present invention.
[0067] Unless otherwise specified, the experimental methods used in the following examples are conventional methods; the reagents and materials used in the following examples, unless otherwise specified, can be obtained from commercial sources.
[0068] In the description of the present invention, it should be noted that the terms "first", "second" and so on are only used for descriptive purposes, and do not indicate or imply relative importance.
[0069] The solubility parameter used in...
Embodiment 1-7 and comparative example 1-4
[0075] The preparation process of Examples 1-7 and Comparative Examples 1-4 is the same, the difference is that the structure of the negative plate is different, and the specific operations are as follows:
[0076] Add positive electrode active material (lithium cobalt oxide), conductive agent (super-p), and binder (PVDF) into N-methylpyrrolidone in a mass ratio of 97:2:1, mix well and coat on the positive electrode On the current collector (aluminum foil), after drying at a temperature of 90°C, it is rolled with a roller press, cut into pieces, slit, vacuum-dried, and welded with tabs to make a positive electrode sheet.
[0077] Ethylene carbonate (EC), propylene carbonate (PC), diethyl carbonate (DEC), propyl propionate (PP), ethyl propionate (EP) in a volume ratio of 15:15:10:60 Mix well, then add LiPF to it 6 Modulate into 1mol / L electrolyte, and add 2wt% vinylene carbonate (VC), 5wt% fluoroethylene carbonate as additive, make final electrolyte, calculate the solubility p...
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