The invention discloses a
lithium ion battery cell with
ultrahigh energy density and a preparation method thereof. The negative
electrode of the
battery cell is prepared from the following raw materials:
graphite,
silicon carbon, conductive
carbon black,
polyacrylic acid,
butadiene styrene rubber and single-walled carbon nanotubes. According to the
battery cell negative
electrode disclosed by the invention, a
silicon-carbon material is used as a novel gas-phase
silicon-carbon material, so that a silicon-based material can be reduced to a nanometer level, and more gaps can be formed for buffering stress and deformation generated by silicon in a
lithium ion de-intercalation process; a
porous carbon skeleton structure is adopted, a silicon expansion space is fully reserved, in addition, a double-layer
carbon coating technology can inhibit silicon expansion, and the
conductivity of the material is improved; the single-walled carbon nanotubes can inhibit the expansion of the silicon material and improve the
conductivity by forming a reticular conductive network;
polyacrylic acid can be combined with
graphite and silicon carbon surface functional groups through carboxyl to promote the formation of an SEI film, so that the cycle performance is improved, and the negative
electrode expansion is reduced. The
gram capacity of the prepared battery negative electrode can reach 400 mAh / g or above, the first efficiency reaches 93%, and the battery negative electrode has
high energy density and good cycle performance.