High mechanical property and low cost SCR denitration catalyst and preparation method thereof

A denitration catalyst and mechanical properties technology, applied in catalyst activation/preparation, chemical instruments and methods, physical/chemical process catalysts, etc., can solve the problems of high price and unstable mechanical properties of catalysts, and achieve enhanced mechanical wedging effect , Reduce the preparation cost, good coating effect

Active Publication Date: 2010-05-26
JIANGSU KEHANG ENVIRONMENT ENG TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

V2O 5 / TiO 2 SCR-based catalysts were successfully developed in Japan in the 1970s and were first commercially applied, and then quickly spread to Europe. At present, they are widely used in Asia, Europe and the Americas. This type of catalyst has high denitrification efficiency and selectivity. Strong, moderate reaction temperature (300 ~ 400 ℃), strong anti-poisoning ability, stable and reliable operation, etc., but due to the use of nano-sized TiO 2 , which is more expensive under the condition of high performance, and at the same time adopts the processing technology of coating or extrusion, so that the mechanical properties of the catalyst are not stable enough

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  • High mechanical property and low cost SCR denitration catalyst and preparation method thereof

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Embodiment 1

[0035] The high-performance low-cost SCR denitrification catalyst described in this embodiment is based on steel mesh as a skeleton material, and industrial-grade and nano-scale TiO 2 As a composite carrier, V 2 o 5 -WO 3 / TiO 2 The calcined particles are used as batching seeds, with V 2 o 5 and WO 3 As the active component, silica sol, methyl cellulose, glass fiber and ethanolamine are used as auxiliary agents. 80 parts by weight of the composite carrier, wherein, technical grade TiO 2 The weight component is 5.6 parts, and the rest is nano-sized TiO 2 ; The weight component of the batching seed crystal is 13.4 parts; The weight component of the active component is 9.6 parts, wherein V 2 o 5 1.6 copies, the rest are WO 3; The weight component of the auxiliary agent is 10.4 parts; wherein, the weight component of silica sol, methyl cellulose, glass fiber silk and ethanolamine is 2.6 parts.

[0036] The low-cost SCR denitration catalyst with high mechanical propertie...

Embodiment 2

[0050] The high mechanical performance low-cost SCR denitrification catalyst described in this embodiment is based on reinforced glass fiber board as the skeleton material, with industrial grade and nano-scale TiO 2 As a composite carrier, V 2 o 5 -WO 3 / TiO 2 The calcined particles are used as batching seeds, with V 2 o 5 and WO 3 As the active component, silica sol, methyl cellulose, glass fiber and ethanolamine are used as auxiliary agents. 78 parts by weight of the composite carrier, wherein, technical grade TiO 2 The weight component is 7.8 parts, and the rest is nano-sized TiO 2 ; The weight component of the batching seed crystal is 26.4 parts; The weight component of the active component is 10 parts, wherein V 2 o 5 1.87 copies, the rest are WO 3 ; The weight component of the auxiliary agent is 12 parts; wherein, the weight component of silica sol, methyl cellulose, glass fiber silk and ethanolamine is 3 parts.

[0051] The low-cost SCR denitration catalyst w...

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Abstract

The invention provides a high mechanical property and low cost SCR denitration catalyst and a preparation method thereof. A steel screen or a reinforced glass fiber board is used as a framework material, and 78-80 weight parts of industrial grade and nano scale TiO2 is used as a composite carrier, wherein the weight parts of the industrial grade TiO2 are 5-8, and the balance is the nano scale TiO2; 13-27 weight parts of V2O5-WO3/TiO2 roasting particle is used as batching seed crystal, and 9-10 weight parts of V2O5 and WO3 are used as active components, wherein the weight parts of the V2O5 are 1.5-2, and the balance is WO3; and 10-12 weight parts of ludox, methylcellulose, fiberglass yarn and ethanolamine are used as auxiliary agents, wherein the weight parts of the ludox, the methylcellulose, the fiberglass yarn and the ethanolamine are all 2.5-3.5. The invention reduces the preparation cost and the operation expense of the SCR denitration catalyst, and improves the mechanical properties of abrasion resistance, pressure resistance, strength, and the like of the catalyst.

Description

technical field [0001] The invention relates to the technical field of environmental protection for flue gas purification, in particular to an SCR denitrification catalyst with high mechanical performance and low cost and a preparation method thereof. Background technique [0002] Selective catalytic reduction method (SCR method), because of its high denitrification efficiency and mature technology, is currently the most widely used in flue gas denitrification projects at home and abroad. The catalyst is the core of the SCR process, and its cost usually accounts for 30-50% of the total investment of the denitration device, which has a direct impact on the total investment and operation. There are three main types of SCR denitration catalysts, namely noble metal catalysts, metal oxide catalysts and molecular sieve catalysts. [0003] Noble metal catalysts were developed in the 1970s and were first used for NO X reduced catalyst. At present, it is mainly used in low-tempera...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B01J23/30B01J37/00B01D53/86B01D53/56
Inventor 俞进旺宋正华陈开明刑国梁
Owner JIANGSU KEHANG ENVIRONMENT ENG TECH
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