354 results about "Nitrogen removal" patented technology

The invention discloses a sewage denitrification dosing method and system based on machine learning and a storage medium, and belongs to the technical field of sewage treatment.The method includes the steps that data are collected and preprocessed, and variable data influencing biochemical pool carbon source dosing behaviors are obtained; and lagging influence of carbon source input on the denitrification amount index is analyzed, and the duration time range of the drug effect is determined. And adopting the trained prediction model, and based on the denitrification amount index and the prediction variable of the future t + X period, obtaining the dosage of the (t + 1) th period. Through a correlation analysis method, the correlation rule of nitrogen conversion in the future X period after the carbon source is added is analyzed, the duration time of the drug effect is determined, the lag effect is accurately quantified, and the problem of mismatching of regulation and control opportunities is avoided. The hysteresis effect is captured and subjected to multi-factor coupling analysis based on the prediction model, the carbon source adding amount and time are optimized, system load fluctuation caused by excessive carbon sources or incomplete nitrogen removal caused by insufficient carbon sources are avoided, and the stability of an original sewage ecological system is gradually improved.

An improved method and apparatus for removing acid gases and other impurities from raw biogas streams, such as biogas from landfills or biogas from controlled anaerobic digestion, is disclosed. The method provides efficient generation of high-purity renewable natural gas from raw biogas. The biogas is treated in a multi-stage membrane system integrated with compression equipment. The membrane separation units are arranged into interconnected high-pressure and low-pressure gas recycling loops powered by high-pressure and low-pressure compressors. The multi-stage membrane system can be integrated with deoxygenation and auxiliary nitrogen removal systems. The combined system provides for the generation of efficient contaminant removal from raw biogas to generate high-purity methane products with reduced compression energy consumption.

The invention relates to the technical field of sewage treatment, in particular to a coupling control system and method for deep denitrification of sewage, and the system comprises a real-time water quality monitoring module, a microorganism twinborn modeling module, a real-time prediction module, an intelligent decision module, an execution mechanism module and a prediction regulation and control module. Compared with the prior art that a passive feedback control strategy based on an effluent quality index is generally adopted, the hysteresis quality is high, and violent fluctuation of an inflow load cannot be coped with; according to the method, a digital twinborn body capable of reflecting the functional state of a microbial community in real time is constructed, and a control target is improved from a traditional process parameter set point to direct optimization of microbial ecological functions; according to the invention, the method achieves the fundamental crossing from the control of technological parameters to the regulation and control of microbial ecology, can carry out intervention from the root of the reaction process, enables the system to have the active health management capability, and remarkably improves the stability of the treatment efficiency and the intelligent level of coping with complex working conditions.

The invention discloses a gradient optimization control method for an aeration system of a sewage plant. The gradient optimization control method comprises the following steps: S1, acquiring key monitoring multi-source data of the aeration system of the sewage plant in real time through an online sensor; s2, setting a security threshold value of each monitoring data to form a security constraint condition; s3, taking unit nitrogen removal energy consumption minimization as an optimization target, and constructing a comprehensive loss function fusing an energy consumption item and a water quality deviation item; s4, iteratively updating the air volume of the aeration system by adopting a self-adaptive gradient algorithm; s5, the optimized and updated air volume is issued to the aeration equipment to be executed, and water quality data and energy consumption data after execution are collected in real time, a control effect is calculated, an award signal is generated, and the award signal serves as feedback to be input into an optimization module; and S6, dynamically adjusting key parameters including the learning rate and the gradient threshold according to a feedback result. According to the invention, the energy consumption can be effectively reduced and the control precision can be improved while ensuring that the effluent stably reaches the standard, and the stable operation of the aeration system of the sewage plant under a complex working condition is ensured.

The invention discloses a high-entropy oxide for synergic nitrogen removal and catalysis as well as a preparation method and application thereof, and belongs to the technical field of material preparation, the high-entropy oxide is a single solid solution phase formed by five or more metal elements of Fe, Co, Ni, Cu, Mn, Ti and Ce and an oxygen element, the configuration entropy of the high-entropy oxide is greater than or equal to 1.5 R, R is a gas constant, and R is an oxygen constant. The mole fraction of each metal element is 0.1-0.3, and the sum of the mole fractions of the metal elements is 1. According to the high-entropy oxide with the synergistic nitrogen removal and catalysis effects and the preparation method and application thereof, a synergistic catalysis system is constructed through the high-entropy oxide and silicon carbide, and the high-entropy oxide has the multiple advantages of being high in nitrogen removal efficiency, high in stability, simple in process, environmentally friendly and wide in application range; the removal rate of total nitrogen and key nitrogen pollutants can reach 90% or above in the seawater high-salt environment, and the environment-friendly emission requirement is met.

The invention belongs to the technical field of sewage treatment, and particularly relates to an anaerobic ammonia oxidation-photoelectric denitrification deep nitrogen removal method. The method comprises the following steps: firstly, adopting a double-chamber reactor; introducing part of sewage into the cathode chamber, carrying out Anammox reaction under a dark state condition to remove ammonia nitrogen and part of nitrite nitrogen, and synchronously generating nitrate nitrogen; turning on a light source to irradiate the anode chamber, exciting photo-induced electrons by a photosensitizer, transmitting the photo-induced electrons to the cathode chamber through an external circuit, and driving the sulfur autotrophic denitrification sludge to reduce residual nitrite nitrogen and nitrate nitrogen generated by Anammox; the total nitrogen removal rate is close to 100%. According to the invention, photo-induced electrons are used as the only denitrification electron donor, so that the addition of a carbon source / sulfide is thoroughly avoided, and the risk of secondary pollution is eliminated. The method is suitable for green low-carbon deep treatment of sludge digestion liquid and pharmaceutical wastewater high-ammonia-nitrogen low-carbon-nitrogen-ratio sewage.

The invention relates to a vertical flow enhanced biological denitrification device and a sewage treatment method, a denitrification agent adding assembly is additionally arranged at a proper position of an existing vertical flow reaction device, namely the outer side of an outer inclined flow guide part, a corresponding enhanced denitrification agent can be added at a selected point position, a denitrification reaction is further enhanced, and the denitrification effect is improved. The selective reaction of the functional microorganism reaction is improved, nitrate generated by the anaerobic ammonia oxidation reaction is consumed, and a sufficient matrix is provided for anaerobic ammonia oxidation, so that the anaerobic ammonia oxidation reaction is greatly promoted, and the total nitrogen removal rate is further improved; by accurately controlling the dosing position and accurately dosing according to the reaction, the nitrogen removal efficiency of the autotroph is enhanced, the coordination of the minimization of the dosing amount of the medicament and the maximization of the nitrogen removal efficiency is realized, and finally, the green, low-carbon, economical and efficient nitrogen removal target of the sewage is achieved.

The invention discloses a Fe / C loaded membrane module, a PN / A-MABR autotrophic nitrogen removal device, a preparation method and a sewage treatment method, and belongs to the technical field of sewage treatment. According to the invention, the problem that the treatment effect is influenced by NO3 <->-N accumulation in the existing membrane aeration coupling partial nitrification-anaerobic ammonia oxidation process is solved. Comprising a frame and a membrane body attached to the outer portion of the frame, the membrane body comprises a hydrophobic organic membrane layer, an iron-carbon material layer and a biological membrane layer which are sequentially arranged, and the hydrophobic organic membrane layer is attached to the outer portion of the frame. The iron-carbon material is added between the hydrophobic organic membrane layer and the biological membrane layer, the iron-carbon micro-electrolysis process is coupled with the dissimilatory process of nitrate generated by microbial metabolism, the removal of NO3 <->-N generated by anaerobic ammonia oxidation is enhanced, and the total nitrogen removal efficiency is improved.

The invention relates to the technical field of sewage / wastewater denitrification, in particular to a method for predicting and explaining denitrification performance and microbial abundance of a single-stage PNA system, which comprises the following steps: constructing an ML model of nitrogen removal rate and functional microbial abundance, and incorporating key water quality and operating parameters into the model to improve the interpretability and prediction accuracy of the model; and the influence of each input feature on the model and the optimal range of the environmental parameters are determined, so that targeted operation adjustment is realized. Quantitative analysis is carried out through the model, potential synergistic effects among the characteristics can be explored, and therefore the optimal characteristic range can be found, the wastewater treatment efficiency can be improved, and the optimal water environment can be obtained.

An improved method and apparatus for removing acid gases and other impurities from raw biogas streams, such as biogas from landfills or biogas from controlled anaerobic digestion, is disclosed. The method provides efficient generation of high-purity renewable natural gas from raw biogas. The biogas is treated in a multi-stage membrane system integrated with compression equipment. The membrane separation units are arranged into interconnected high-pressure and low-pressure gas recycling loops powered by high-pressure and low-pressure compressors. The multi-stage membrane system can be integrated with deoxygenation and auxiliary nitrogen removal systems. The combined system provides for the generation of efficient contaminant removal from raw biogas to generate high-purity methane products with reduced compression energy consumption.

The invention relates to the technical field of equipment compensation control, and discloses a medical suction device with an altitude compensation function and a control method thereof. The method comprises the following steps: reading ambient air pressure data of a first pressure sensor, reading molecular sieve tank differential pressure data of a second pressure sensor, collecting pressure data of an output end of a third pressure sensor, and determining a real-time altitude according to the ambient air pressure data; a breathing pressure fluctuation value is calculated based on the molecular sieve tank differential pressure data, when the breathing pressure fluctuation value is lower than a preset negative pressure threshold value, the current breathing frequency is recorded, and nitrogen removal time, pressure equalizing time and flushing time are determined to control an electromagnetic valve to work; and when the oxygen concentration is lower than a first concentration threshold value and the real-time altitude height is lower than a preset height, increasing the nitrogen removal time by a first preset proportion and increasing the target rotating speed by a second preset proportion, and when the oxygen concentration is lower than a second concentration threshold value, stopping the operation of the compressor and closing all the electromagnetic valves. According to the invention, the false alarm rate is effectively reduced, and the equipment safety is improved.

The utility model discloses an advanced treatment system for high-concentration nitrogen-containing organic wastewater, which sequentially comprises an anaerobic tank, an anoxic tank, an aerobic tank, a secondary sedimentation tank, a sulfur autotrophic denitrification filter tank and a limestone filter tank, a water passing hole is formed in the upper part of a wall body between the anaerobic tank and the anoxic tank, a hollow aeration fiber membrane assembly is arranged in the anoxic tank, an aeration pipe is arranged at the bottom of the aerobic tank, a mixed liquid reflux pump is arranged at the bottom of the aerobic tank in a penetrating manner and is connected with the anoxic tank through a pipeline, and the aeration pipe is connected with the anoxic tank through a pipeline. A sludge reflux pump penetrates through the bottom of the secondary sedimentation tank and is connected with the anaerobic tank through a pipeline. Iron-carbon micro-electrolysis is intervened in the anaerobic reactor to achieve the purposes of improving the biodegradability of high-concentration degradation-resistant wastewater and enhancing biochemical treatment, and the nitrogen removal mode of anaerobic section MABR bubble-free aeration synchronous nitrification and denitrification is organically combined, so that the treatment load of the system and the utilization rate of activated sludge are improved.

The utility model relates to the technical field of nitrogenous wastewater treatment, in particular to a nitrogenous wastewater treatment device. The device comprises a reactor, an aeration assembly, a water inlet assembly and a monitoring assembly, a guide cylinder is coaxially arranged in the reactor; the reactor is filled with microorganism balls; the monitoring assembly comprises a main controller and a plurality of detection probes; the main controller is arranged outside the reactor, and each detection probe is arranged inside the reactor; the main controller is respectively connected with each detection probe through a line; one end of the water inlet assembly is communicated with nitrogenous wastewater, and the other end is communicated with the bottom of the reactor; the water inlet assembly comprises a water inlet pump connected with the main controller; one end of the aeration assembly is communicated with air or oxygen, and the other end is communicated with the bottom of the reactor; and the aeration assembly comprises an air blower connected with the main controller. The device disclosed by the utility model has the effects of simple and compact structure, small occupied area, low operation cost and good nitrogen removal performance.

The invention relates to the technical field of sewage biochemical treatment, and discloses a preparation method of an efficient composite biological carbon source, which comprises the following steps: solid-liquid two-phase fermentation treatment, microbial community echelon relay treatment, fermentation liquor reflux and biological detoxification system and biomass enhancement treatment. According to the invention, the preparation of the composite biological carbon source with high concentration (COD > = 50,000 mg / L), high stability (stable operation time > = 120 days) and high activity is realized by combining solid state fermentation and liquid state fermentation, constructing a microbial echelon metabolic network, applying a porous carrier layer to eliminate an inhibitor, implementing active factor regeneration and other technical means; according to the present invention, the organic matter conversion efficiency is improved by more than 30%, the stable operation time of the system is improved, the technical problems of insufficient concentration, unbalanced components, poor stability and the like in the traditional carbon source preparation are solved, the method is suitable for the nitrogen and phosphorus removal process of the large-scale sewage treatment plant, the total nitrogen removal rate of the sewage treatment system can be improved by 15-25%, and the nitrogen removal rate can be improved by 30-40%.

The invention discloses a sewage treatment system and treatment method suitable for a plateau low-pressure environment, and the sewage treatment system suitable for the plateau low-pressure environment comprises a first SBR reactor which is provided with a water inlet pipe, a stirrer and a first water decanter; the second SBR reactor is provided with an MABR aeration assembly and a second water decanter; a hollow fiber membrane cavity of the MABR aeration assembly is connected with an air supply unit; the control unit is used for coordinating and controlling the periodic operation of the first SBR reactor and the second SBR reactor, and is used for regulating and controlling the output power of the air supply unit or the valve opening degree according to the real-time monitoring value of the DO sensor in the aeration stage of the second SBR reactor; therefore, the air supply pressure in the membrane cavity of the MABR aeration assembly is dynamically controlled. According to the invention, the limitation of low atmospheric pressure is eliminated, the synergistic interaction of nitrogen removal and phosphorus removal is realized, and the aeration requirement is further reduced.

The utility model discloses a micro-power nitrogen removal tank. The micro-power nitrogen removal tank comprises a first chamber, a second chamber, a fluid discharge channel and a gas supply unit, wherein the first chamber is used for reducing oxygen content; the second chamber is used for removing nitrogen; the first chamber is provided with a water inlet, the upper part of the first chamber is communicated with the upper part of the second chamber, and the lower part of the second chamber is communicated with the lower part of the fluid discharge channel; the gas supply unit is communicated with the lower part of the fluid discharge channel and is used for introducing gas into the fluid discharge channel; during application, aerobic bacteria can be added into the first chamber, and anaerobic bacteria can be added into the second chamber; sinking the micro-power nitrogen removal tank added with the strain into a sewage water body; the micro-power nitrogen removal tank disclosed by the utility model can realize flowing of an internal water body only under the action of airflow, is extremely low in energy consumption, and can assist in realizing removal of total nitrogen under the condition that the ecology of a natural water body is not changed.

The invention discloses a multi-stage biological deodorization system with double bacterium areas. The system comprises N circulating units formed by sequentially arranging desulfurization biological reaction zones and denitrification biological reaction zones according to the airflow direction, wherein N is greater than or equal to 1; the desulfurization biological reaction zone comprises a biological filler layer I, a desulfurization strain and a nutrient solution I, and the denitrification biological reaction zone comprises a biological filler layer II, a denitrification strain and a nutrient solution II; wherein the biological filler layer I and the biological filler layer II are respectively arranged at the middle parts of the desulfurization biological reaction area and the denitrification biological reaction area, the volume ratio is 1: 2, and waste gas enters from the bottom end of the system and flows back in the system. The biological deodorization system can obviously improve the deodorization efficiency and the system stability.

The invention provides a method and a system for regulating and controlling nitrogen circulation of a constructed wetland by using root exudates, and relates to the technical field of constructed wetland sewage treatment. The method comprises the following steps: 1) constructing a plant root exudate database; 2) training a machine learning prediction model and optimizing parameters by adopting a machine learning algorithm and using the data of the plant root exudate database; 3) screening the compounds in the natural product database by using the machine learning prediction model in the step 2), predicting the denitrification potential of the compounds, and selecting candidate substances; and 4) constructing a microcosm culture system, in the microcosm culture system, detecting nitrogen removal and microbial response by adding the candidate substances obtained in the step 3) with different concentration gradients, and verifying the denitrification effect of the candidate substances. The system disclosed by the invention is high in datamation degree, simple and convenient to operate, accurate in prediction and low in cost, provides a new technical means for enhanced denitrification of the constructed wetland, and has a good industrial application prospect.

This invention discloses a continuous-flow anaerobic bypass IFAS-AOA device and method for treating inert high-ammonia nitrogen wastewater, belonging to the field of biological treatment technology for high-ammonia nitrogen wastewater. The device consists of three parts: a raw water storage tank, a continuous-flow anaerobic bypass AOA reactor, and a sludge-water separation system. The effluent from the end of the anaerobic process enters the aerobic zone of the AOA reactor, while the anaerobic end-mixed liquor bypasses to the anoxic zone, mixes with the aerobic end-effluent, flows through the anoxic zone, and enters the sludge-water separation system. In the anaerobic zone, endogenous denitrifying bacteria store organic matter from the raw water as an intracellular carbon source and bypass to the anoxic zone. In the aerobic zone, short-cut nitrification coupled with anaerobic ammonia oxidation serves as the main nitrogen removal pathway. In the anoxic zone, anaerobic ammonia oxidation coupled with endogenous denitrification achieves deep nitrogen removal. The existence of anaerobic bypass allows some of the mixed liquor to bypass the aerobic zone and directly bypass to the anoxic zone, thus fully utilizing the carbon source in the raw water. This invention can achieve stable short-cut nitrification and effective retention of anaerobic ammonia oxidizing bacteria, showing broad application prospects.

The application discloses a method for simultaneously strengthening phosphorus removal and nitrogen removal by using an anaerobic-aerobic granular sludge reactor, and specifically comprises the following steps: adopting an anaerobic-aerobic operation mode to form aerobic granular sludge with biological phosphorus removal capacity in a sequencing batch reactor; sequentially performing an anaerobic water feeding stage, an aerobic stage, a sedimentation stage and a water discharge stage in each operation cycle; wherein the multi-point layered water feeding mode is adopted in the anaerobic water feeding stage; the wastewater to be treated is fed from the bottom and the middle of the granular sludge layer, wherein the water feeding amount at the bottom of the granular sludge layer accounts for 70-90% of the total water feeding amount; the intermittent aeration mode is adopted in the aerobic stage, each intermittent aeration cycle comprises an aeration period and a non-aeration period, and the time ratio of the single aeration period to the single non-aeration period is 2-3:1. By operation regulation, a microenvironment conducive to denitrification and phosphorus precipitation is constructed inside the aerobic granular sludge, carbon source competition can be effectively alleviated, phosphorus removal pathways are expanded, and the synergistic strengthening of the nitrogen removal and phosphorus removal processes is promoted.

The invention relates to the technical field of wastewater treatment, and discloses a modular electro-catalytic hydrolytic acidification reaction device and a wastewater treatment method. The modularized electro-catalysis hydrolytic acidification reaction device comprises a hydrolytic acidification area, an electro-catalysis area, a backflow system and a solar power supply system, the backflow system comprises a backflow pipe and a backflow channel, outlet water of the hydrolytic acidification area flows into the electro-catalysis area through the backflow pipe, and outlet water at the tail end of the electro-catalysis area flows into the hydrolytic acidification area through the backflow channel, the electro-catalysis area comprises a plurality of electro-catalysis modules which are electrically connected, each electro-catalysis module comprises an electrode assembly and an aeration device, each electro-catalysis module is divided into a micro-aerobic area and an anoxic area, and the micro-aerobic areas and the anoxic areas are alternately and continuously arranged. When the reaction device is used for treating wastewater, the function of synchronous nitrification and denitrification efficient nitrogen removal can be realized, the organic matter removal efficiency in the hydrolytic acidification stage is improved, and the biodegradability of sewage is enhanced.

The application discloses a kind of dispersing water supplementing devices for coastal plain river network direct ammonia oxidation denitrification of reclaimed water, including the pretreatment tank, direct ammonia oxidation device and water supplementing device connected in sequence, the upper electrode and lower electrode with longitudinal alignment hole are horizontally arranged in funnel-shaped desalination settlement area of the bottom of pretreatment tank, aeration disc is arranged at the top of desalination settlement area, flocculating agent storage tank is arranged in the upper part of pretreatment tank, its injection pipe is immersed below water surface, desalination settlement area is connected with direct ammonia oxidation device by communicating pipe, and the filler filled with direct ammonia oxidation microorganism is filled in the inside of direct ammonia oxidation device, the bottom of direct ammonia oxidation device is connected with water supplementing device, and water supplementing device is connected with a plurality of primary water distribution branch pipes through water distribution main pipe.The device can realize the maximization of direct ammonia oxidation unit denitrification efficiency through water supplementing front end pretreatment and water supplementing tail end treatment, and the maximization of coastal plain river network water supplementing benefit is realized through the designed dispersing water supplementing device.

The application discloses a high-salt-resistant denitrifying bacterial strain and a microsphere preparation thereof, a preparation method and application thereof, relates to the technical field of environmental microorganisms and wastewater biological treatment. Pseudomonas sp. The classification name of the strain is Pseudomonas sp., the preservation number is CGMCC No. 36626, the strain is preserved in the China General Microbiological Culture Collection Center, and the preservation date is November 14, 2025. The preparation method of the microsphere preparation containing the strain comprises the following steps: carrying out strain amplification culture to obtain a bacterial liquid, mixing the bacterial liquid with porous starch and a protective agent, then performing vacuum freeze drying to obtain bacterial powder, and then mixing the bacterial powder with a sodium alginate solution, and dropping the mixture into a calcium chloride solution to obtain the microsphere preparation. The microsphere preparation can maintain a nitrate nitrogen removal rate of more than 80% after being stored at-18 to-22 DEG C or 20 to 25 DEG C for 28 days, and can be used for denitrification and nitrogen removal of low-carbon-nitrogen-ratio and high-salt wastewater (such as urine wastewater in a closed circulation system).

A biological treatment of sewage device and method for realizing advanced nitrogen removal of domestic sewage by half partical nitrification-anammox coupled with sulfur autotrophic denitrification. The device includes a raw water tank, a half partical nitrification reactor, a regulating water tank and an anammox coupled denitrification reactor. The domestic sewage enters the half partical nitrification reactor, a mass concentration ratio of NO2−—N to NH4+—N in effluent water is 1-1.32 through real-time control, and then the effluent water enters the intermediate water tank. After it enters the upflow anammox coupled with autotrophic denitrification granular sludge reactor, the synergistic reaction of anammox and sulfur autotrophic denitrification in the reactor achieves the nitrogen removal. The device and the method improve denitrification efficiency by making full use of the synergistic effect between microorganisms, thereby realizing high-efficiency and energy-saving advanced nitrogen removal of municipal sewage.

This invention relates to the field of deep nitrogen removal technology, specifically to a method for simultaneous nitrification and denitrification deep nitrogen removal in a multi-stage AO process for wastewater. The method is characterized by using multiple functional tanks connected in series to form a multi-stage AO process wastewater biological treatment system, and constructing an activated sludge model. Specifically, the activated sludge model is constructed by: acquiring process parameters and effluent water quality indicators; constructing a complete measured dataset; defining prediction targets and input features; determining whether there is a significant correlation between the input features and the prediction targets, constructing a set of associated inputs, introducing other input features layer by layer as interference features, calculating the first-order correlation coefficient between the predicted targets and input features after introducing interference features; determining whether there is an interference effect in the correlation between the prediction targets and input features based on the first-order correlation coefficient, and updating the set of associated inputs; and iteratively training the activated sludge model based on fused features, virtual data, and the measured dataset.

The invention discloses a low-consumption green nitrogen removal method, and relates to a green nitrogen removal method of a sewage treatment plant. The method comprises the following steps: (1) mixing high nitrate nitrogen wastewater and high sulfur wastewater to obtain mixed wastewater; and (2) adding anaerobic sludge into the mixed wastewater, and stirring until the mixed treatment is stably operated to obtain nitrogen-removed wastewater. According to the invention, an operation mode is adopted under the conditions that carbon sources are saved and effluent is qualified, and finally, qualified emission, energy conservation and consumption reduction are realized.

The present application belongs to the technical field of water pollution control, and particularly relates to a kind of simultaneous denitrification and phosphorus removal slow-release filler and a preparation method thereof.The slow-release filler is used in water purification process, and can be used as a carrier for microbial attachment and growth, and can provide various electron donors for microbial denitrification and nitrogen removal; at the same time, the water treatment process also has a significant control of release of metal phosphorus removal agent and other phosphorus removal active components, to achieve the function of enhanced phosphorus removal; and when the water quality is purified by using the slow-release filler, no harmful ingredients are introduced into the water, and the possibility of secondary pollution is significantly reduced.

This invention discloses a denitrification biological carrier, its preparation method, and its application. The raw materials for preparing the denitrification biological carrier include an iron agent, modified activated carbon, polycaprolactone, sodium dodecyl sulfate, and a hydrogel binder. The modified activated carbon is 3-chloro-2-hydroxypropyltrimethylammonium chloride-modified activated carbon. The iron agent not only removes dissolved oxygen from water but also reduces total nitrogen in wastewater. The modified activated carbon improves its adsorption affinity for nitrogen-containing compounds. Polycaprolactone serves as a slow-release carbon source for denitrification, exhibiting high carbon source utilization. Sodium dodecyl sulfate, through its foaming properties, together with the modified activated carbon, iron agent, and polycaprolactone, forms a high-mechanical-strength, rough, and porous biological carrier structure, providing excellent attachment conditions for heterotrophic denitrifying bacteria. Therefore, applying the denitrification biological carrier of this invention to wastewater treatment systems can achieve good nitrogen removal efficiency and economic benefits.

The utility model relates to the technical field of high-concentration nitrate wastewater, in particular to a novel sulfur autotrophic denitrification nitrogen removal device which comprises a shell, a water inlet and a water outlet, wherein a water outlet area, a separation area, a sulfur autotrophic denitrification reaction area and a filtering area are sequentially arranged in the shell from top to bottom; the water outlet and the water inlet are located in the upper end and the lower end of the shell respectively, and the position of the water outlet area is matched with the position of the water outlet. And the filtering area specifically comprises a gauze layer and a quartz sand cushion layer. According to the utility model, products generated by denitrification precipitate and fall on the quartz sand layer, so that the problem that the water inlet is blocked by the products is avoided; and finally, the device is provided with an internal reflux pipeline, so that the low dissolved oxygen state can be effectively maintained, and the sulfur autotrophic denitrification reaction is facilitated. Meanwhile, the pyrite slag is used as the filler, so that the price is low.

The invention discloses photovoltaic driving type integrated biological filter equipment and a denitrification method thereof, and relates to the technical field of biological filters, the biological filter equipment comprises a biological filter and a photovoltaic driving unit, the photovoltaic driving unit comprises a photovoltaic power generation module, an execution module and a denitrification reaction module, the denitrification reaction module monitors the illumination intensity and the ammonia nitrogen concentration of the sewage in the biological filter in real time, and distributes photovoltaic electric energy to the denitrification reaction module or other units needing power supply on the basis of comparison of the monitored illumination intensity and the ammonia nitrogen concentration of the sewage in the biological filter with a preset threshold, so that the energy use efficiency is optimized; the denitrification reaction module is arranged in the biological filter, controllable current is applied to accelerate denitrification of the biological filter, ammonia nitrogen is directly oxidized at an anode or indirectly oxidized through active chlorine, hydrogen is generated at a cathode to serve as a denitrification electron donor, nitrate is accelerated to be reduced into nitrogen, and the problem that a traditional denitrification carbon source is insufficient is solved.