2142 results about "Nitrogen removal" patented technology

A wastewater treatment system is provided including an aerobic membrane bioreactor and an anaerobic digester system connected to receive wasted solids continuously from the aerobic membrane bioreactor and also connected to return effluent from the anaerobic digester system continuously to the aerobic membrane bioreactor. Further, a process is provided for treating wastewater including the step of wasting a volume fraction of organic cell mass from an aerobic membrane bioreactor to an anaerobic digester system and maintaining a solids retention time (SRT) in the bioreactor that is (1) greater than a time needed to achieve growth of organisms suitable for converting carbonaceous biochemical oxygen demand (CBOD) into cell mass and (2) less than a time at which substantial decay of the organisms occurs. The system and process may further include optional pretreatment and/or phosphorus and/or nitrogen removal downstream of the membrane bioreactor system.

The invention relates to aerobic denitrifying paracoccus denitrificans and application thereof. A bacterial strain provided in the invention is paracoccus denitrificans DN-3CGMCC No. 3658; the Paracoccus denitrificans can carry out aerobic denitrification by using nitrate nitrogen under both aerobic and oxygen-limited conditions and can also carry out heterotrophic nitrification-aerobic denitrification by using ammonia-N, and a total nitrogen removal rate on above mentioned occasions is greater than 90%. The paracoccus denitrificans provided in the invention has stable hereditary features, isapplicable to treatment of a variety of nitrogen-containing waste water and produces a good nitrogen removal effect.

A process for removing metals, sulfur and nitrogen in the upgrading of hydrocarbons comprising: mixing hydrocarbons containing metals, sulfur and nitrogen with a fluid comprising water that has been heated to a temperature higher than its critical temperature in a mixing zone to form a mixture; passing the mixture to a reaction zone; reacting the mixture in the reaction zone under supercritical water conditions in the absence of externally added hydrogen for a residence time sufficient to allow upgrading reactions to occur while maintaining an effective amount of metals, derived from the hydrocarbon undergoing upgrading, in the reaction zone to catalyze the upgrading reactions; and recovering upgraded hydrocarbons having a lower concentration of metals, sulfur and nitrogen than the hydrocarbons before reaction is disclosed.

The invention relates to an apparatus and a method for nitrogen removal by combining garbage leachate SBR and anaerobic ammoxidation, which belongs to the low carbon nitrogen (CN) ratio high density ammonia nitrogen garbage leachate biological denitrogenation technical field. The apparatus comprises an integrated water tank, a SBR short distance nitrated reactor and an anaerobic ammoxidation reactor; a preposition water tank and a postposition water tank in the integrated water tank are communicated with a peristaltic pump and the SBR short distance nitrated reactor, the postposition water tank is connected with the bottom of the anaerobic ammoxidation reactor through the outlet pipe and the peristaltic pump, an self-circulation pipeline is provided on the anaerobic ammoxidation reactor, and is connected with the SBR preposition water tank through the outlet pipe and the peristaltic pump. The method comprise the following steps starting the SBR short distance nitrated reactor, starting the anaerobic ammoxidation reactor, and an operation is in series of the SBR short distance nitrated reactor and the anaerobic ammoxidation reactor is carried out. The apparatus of the present invention is suitable for organic matter removal and short distance nitrogen removal of the garbage leachate at late period in the garbage landfill, the process is advanced, and the advantages of energy saving and consumption reduction is obvious.

The invention discloses a device and method for nitrogen and phosphorus removal treatment by denitrification on high-ammonia nitrogen anaerobic ammonia oxidation effluent and domestic sewage, belonging to the field of biological sewage treatment. The device comprises a high-ammonia nitrogen inflow water tank, an integrated partial nitrification and anaerobic ammonia oxidation reactor, a sedimentation tank, a domestic sewage inflow water tank, a denitrification nitrogen and phosphorus removal reactor and an effluent water tank sequentially connected in series. The method comprises the following steps: in the integrated reactor, effectively removing nitrogen of the high-ammonia nitrogen wastewater through the effect of partial nitrification and anaerobic ammonia oxidation; in the denitrification nitrogen and phosphorus removal reactor, performing anaerobic phosphorus release by phosphorus-accumulating bacteria by use of an organic carbon source in the domestic sewage, and performing hypoxia denitrification phosphorus removal by use of nitrate nitrogen in the anaerobic ammonia oxidation effluent; and finally, further absorbing phosphorus at the aerobic zone in accompany with the nitrification effect generated by the nitrification bacteria. According to the method, the nitrogen removal by anaerobic ammonia oxidation and phosphorus removal by denitrification are coupled into a biological nitrogen and phosphorus removal system for sewage, the nitrate nitrogen generated in the anaerobic ammonia oxidation process is effectively utilized, and the oxygen consumption and energy consumption are greatly reduced.

The invention relates to a bacterial strain used for short-cut denitrification for nitrogen removal and its application. The bacterial strain used for short-cut denitrification for nitrogen removal is flavobacterium mizutaii FDN-2, which is preserved in China general microbiological culture collection center on March 11, 2012 and has a preservation number of CGMCC NO.3659. The bacterial strain can directly utilize nitrite nitrogen as a substrate to complete a short-cut denitrification process. When treating ammonia-containing wastewater with the flavobacterium mizutaii FDN-2 of the invention,the process is simple, and the flavobacterium mizutaii FDN-2 can tolerate a high concentration organic carbon source. When the flavobacterium mizutaii FDN-2 in the invention is put into use, a systemcan be rapidly initiated, so that the flavobacterium mizutaii FDN-2 boasts very broad application prospects in various nitrogen removal processes of wastewater.

The invention relates to a biofilm full-rang autotrophic nitrogen removal device of digested sludge dehydrolysis liquid and a method thereof; wherein, the device is provided with a digested sludge dehydrolysis liquid pool, a pre-hypoxia denitrification pool, a short-range biofilm nitrification pool, a sedimentation pool, an intermediate pool and a biofilm anaerobic ammonia oxidation pool; the method consists of the following steps: 1. the pre-hypoxia denitrification pool and the short-range biofilm nitrification pool are started to operate; 2. the biofilm anaerobic ammonia oxidation pool is started; 3. the biofilm full-rang autotrophic nitrogen removal system of the digested sludge dehydrolysis liquid is operated in series. The device is suitable for biological nitrogen removal of wastewater containing high ammonia nitrogen, such as the digested sludge dehydrolysis liquid, late landfill percolate, coking wastewater, monosodium glutamate wastewater, etc. The device realizes efficient biological nitrogen removal of wastewater with high NH4<+>-N and low ratio of C/N, greatly decreases the construction and operation cost of nitrogen removal of wastewater, reduces alkalinity demand of the nitrification, runs stably, operates easily and has stronger shock resistance loading capability; meanwhile, the device is strongly adaptable to temperature fluctuation and toxic substances, which is easy to recover after being restrained.

The invention discloses a method for preparing an aerobiotic nitrifier immobilizing vector, and belongs to the field of water treatment. The method comprises the steps of: firstly, carrying out acid washing on thermally modified attapulgite; adsorbing the nitrifier using the nanometer grade attapulgite; carrying out rapid inclusion by using the mixture gel of polyvinyl alcohol (PVA) and sodium alginate (SA); dropping the mixture into a crosslinking agent to soak for 24 hours using a granulator to obtain an immobilized nitrifier pellet; and finally, repeatedly washing the immobilized nitrifier pellet for three times using normal saline to obtain a vector particle. By taking advantage of pretty large specific surface area and pretty strong adsorption performance of the modified attapulgite, an adsorption vector which is conductive to the growth and reproduction of the aerobiotic nitrifier is prepared; the modified attapulgite is capable of ammonia and nitrogen adsorption, and can increase the ammonia and nitrogen removal rate in water; the carrier particle composited from the modified attapulgite and a macromolecular material can improve the activity and ammonia and nitrogen removal capacity of denitrification microorganisms; and the repeated use rate of the carrier is high.

The invention provides a technology and a method for treating urban sewage by three-section short-cut nitrification/ anaerobic ammonia oxidation, and belongs to the technical field of biological treatment of sewage. A raw water tank, an organic substance removal sequencing batch reactor (SBR), a first regulating water tank, a short-cut nitrification SBR (provided with an on-line monitoring and feedback control system), a second regulating water tank and an autotrophic nitrogen removal up-flow anaerobic sludge bed/ blanket (UASB) reactor are sequentially connected in series in the technology; and the sludge is separated according to the sludge age, so that the contradiction between denitrification and phosphorus removal sludge age is solved. By applying the real-time control technology of the short-cut nitrification SBR to the autotrophic nitrogen removal technology, the problems that the half short-cut of low ammonia nitrogen short-cut nitrification in continuous flow is difficult to maintain, the concentration ratio of ammonia nitrogen to nitrous in the effluent is difficult to control and the like are solved. By successfully applying the anaerobic ammonia oxidation technology todeep denitrification treatment of the domestic sewage, urban sewage treatment with high efficiency and low energy consumption is realized.

The invention discloses a treatment method for biological nitrogen removal of reinforced sewage, which comprises the following steps of: 1, feeding all or partial treated sewage and sludge refluxed from a secondary sedimentation tank into a reflux sludge denitrification unit together by adopting division point inflow; 2, feeding the outflow of the reflux sludge denitrification unit and the residual sewage to an anaerobic unit or an anoxic unit; 3, feeding the outflow of the anaerobic unit to the anoxic unit, and refluxing the mixed solution of an aerobic unit to the anoxic unit; 4, feeding the outflow of the anoxic unit to a transition unit; 5, feeding the outflow of the transition unit to the aerobic unit, and refluxing the mixed solution of the aerobic unit to the anoxic unit from the outflow end of the aerobic unit; and 6, feeding the outflow of the aerobic unit to the secondary sedimentation tank to perform sludge-water separation. The method can be operated in multiple modes of A-A2O, nitrogen removal AO, inverse AAO and the like and has high controllability, and a system has strong nitrogen removal capability. The method is suitable for upgrade and reform of newly built sewage treatment plants of towns lacking the land and the conventional sewage treatment plants.

The invention relates to an integrated electrolysis nitrogen and phosphorus removal wastewater treatment method, which realizes to remove the nitrogenous and phosphorus nutrition salt and organic pollutants in wastewater in same electrolytic tank. The invention adopts graphite and iron plate as electrodes, alternates electrolysis phosphorus removal and electrolysis nitrogen removal process by alternating the electrode polarities to remove the nitrogenous and phosphorus nutrition salt and organic pollutants in wastewater. The invention performs optimization and integration according to the change characteristics of the parameters including electrolysis time, current density, pH value, pollutants removal rate in the electrolysis phosphorus removal and electrolysis nitrogen removal process, can remove the nitrogenous and phosphorus nutrition salt and organic pollutants in wastewater in high efficiency in short time without adding any medicament in the process, achieves the advantages of small occupation area, short treatment time and high pollutants removal efficiency.

The invention relates to a method for quickly starting shortcut nitrification of ammonia-containing wastewater, which comprises the following steps: firstly, putting an inoculums into a bioreactor, adopting an intermittent operation mode, and ensuring that the inflow ammonia nitrogen initial concentration is between 200 and 300mg/L and the pH value is controlled between 7.8 and 8.5; gradually improving the inflow ammonia nitrogen concentration, and changing the intermittent operation mode to a continuous operation mode when the ammonia nitrogen concentration reaches between 400 and 700mg/L; and setting hydraulic retention time of the continuous operation mode to between 14 and 20h, controlling the pH value in a range between 8.2 and 8.5, and gradually improving the wastewater ammonia nitrogen concentration or gradually reducing the dilution multiple of the ammonia-containing wastewater with high concentration under the condition of keeping the nitrogen removal efficiency above 70 percent until the inflow ammonia nitrogen concentration reaches between 800 and 1,200mg/L. Compared with the prior art, the method has the advantages of having not rigorous starting requirement but high starting speed, treating the ammonia-containing wastewater with high concentration and the like.

The invention relates to multistage anaerobic, aerobic and anoxic dephosphorization and denitrogenation technology, which is mostly suitable for treating urban domestic sewage. The sewage is divided into two parts, namely approximately 30 percent of the sewage is mixed with return sludge and enters into an anaerobic tank, and most of the sewage exceeds the anaerobic tank and directly enters into an anoxic tank for denitrogenation in a multipoint mode; after denitrogenation is completed, the mixed solution is mixed with a small part of the sewage and enters into a secondary settling tank for sludge-water separation; and denitrogenation reaction is continuously completed during sludge-water separation; and the return sludge and nitrite nitrogen and nitrate nitrogen of discharged water are reduced, and residual sludge is discharged regularly. The multistage anaerobic, aerobic and anoxic dephosphorization and denitrogenation technology has high phosphor and nitrogen removal rate, reduces the capacity of a structure, saves investment, fully utilizes carbon sources and simultaneously reduces direct oxygen consumption because the sewage does not directly enter into an aerobic tank and then the carbon sources in the sewage do not directly contact oxygen, and improves the catch rate of air bubbles and obviously saves the aeration cost due to ultrahigh sludge concentration in the aerobic tank under the condition of blast aeration.

The invention discloses a low-carbon urban sewage biological phosphorus removal and autotrophic biological nitrogen removal device and a low-carbon urban sewage biological phosphorus removal and autotrophic biological nitrogen removal method. The device comprises a raw water tank, a biological phosphorus removal and half shortcut nitrification reactor, a secondary sedimentation tank, an intermediate water tank and an anammox reactor, wherein the biological phosphorus removal and half shortcut nitrification reactor is a university of cape town (UCT) reactor without internal returning of digestive fluid; the secondary secondary sedimentation tank is a radial-flow sedimentation tank; and the anammox reactor is an upflow anaerobic sludge blanket (UASB) reactor. The method comprises: introducing urban sewage first to the anaerobic zone of the biological phosphorus removal and half shortcut nitrification reactor for phosphorus release, then to an anoxic zone of the biological phosphorus removal and half shortcut nitrification reactor for denitrification and phosphorus absorption and finally to an aerobic zone for aerobic phosphorus absorption and half shortcut nitrification; subjecting mixed liquid containing ammonia nitrogen and nitrite nitrogen to sludge and water separation in the secondary sedimentation tank; and introducing the water to the anammox UASB reactor for autotrophic biological nitrogen removal under anammox action. When the method is used, process aeration can be reduced, energy consumption can be reduced, and carbon source is saved. The method is suitable for treating low-carbon sewage.

Methods are provided for hydrotreating high nitrogen feeds with improved results for nitrogen removal, aromatic saturation, and/or sulfur removal. The method includes hydrotreating the feed with a supported hydrotreating catalyst followed by a bulk metal catalyst, the hydrotreated effluent of which can be suitable for use as a feed to an FCC reactor.

The invention discloses a multi-stage A/O biological nitrogen removal device and a multi-stage A/O biological nitrogen removal method based on shortcut nitrification-anaerobic ammonia oxidation of municipal sewage, and belongs to the field of sewage biological treatment. The device mainly consists of an SBR (styrene butadiene rubber) carbon removal reactor, a middle water tank, a multi-stage A/P nitrogen removal reactor and a sedimentation tank, wherein domestic sewage firstly enters the SBR reactor to aerate to remove part of organic substances in raw water, and then enters the A/O reactor to realize shortcut nitrification-anaerobic ammonia oxidation by virtue of alternating aerobic/anoxic reaction. Sludge in a secondary sedimentation tank flows back to a first-section anoxic zone, so that nitric nitrogen in the flowed-back sludge can be reduced by utilizing COD (chemical oxygen demand) in raw material while the concentration of sludge in the A/O reactor is guaranteed. According to the multi-stage A/O biological nitrogen removal device, shortcut nitrification and anaerobic ammonia oxidation reaction of the domestic sewage are realized by utilizing low-oxygen aeration and bio-contact oxidation, so that the aeration rate is low, and the sludge yield is low; and moreover, an external carbon source is not required to add, so that the multi-stage A/O biological nitrogen removal device has the characteristics of energy saving and consumption reducing, improves the stability of the reactor, and is convenient to operate.

The invention discloses a granular sludge integrated autotrophic nitrogen removal device, which is provided with a water feed tank and an integrated anammox reactor, wherein the reactor is provided with a shell, a reaction area and a settling area are arranged in the shell, and the reaction area is provided with a microporous aerator, a fixed packing layer and a top area; the settling area is provided with an inclined plate settling area, an overflow weir and a water outlet pipeline; a guide plate and a reflow hole are formed between the reaction area and the settling area; the top of the reaction area has an air return port and an air outlet; and a sludge discharge pipeline is arranged at the bottom of the reaction area. The operating method comprises the following steps of (1) seeding sludge; (2) starting stage; and (3) continuous operation. The device and the method disclosed by the invention are suitable to be used for carrying out side treatment on high-ammonia-nitrogen and low-carbon-nitrogen-ratio digested sludge dewatering liquid in urban sewage treatment plants, and also suitable to be applied to the denitrification treatment of other high-ammonia-nitrogen industrial wastewater. The device and the method disclosed by the invention are perfect in process, simple in operation, agile in control, low in operation cost, good in sewage treatment effect and high in efficiency.

The invention relates to a synchronous nitrogen and phosphorus-removal domestic sewage treatment process of an integral bio-enhancement activated carbon dynamic membrane. The solid-liquid separation effluent process is completed by a dynamic membrane module. The domestic sewage treatment process comprises the following steps: pumping sewage into a bio-enhancement activated carbon dynamic membrane device, and carrying out biodegradation and removal on pollutants by utilizing a bio-enhancement activated carbon mixed liquor in the device; forming a dynamic membrane on the surface of the dynamic membrane module by the bio-enhancement activated carbon to carry out the solid-liquid separation of the mixed liquor; stirring raw water by a stirrer and sufficiently mixing the raw water with microorganisms in the reaction device of the bio-enhancement activated carbon dynamic membrane assembly, staying for a period of time and then filtering and discharging water through the dynamic membrane, wherein dissolved oxygen in the mixed liquor is provided by the aeration of an air blower. The invention has simple process and can realize a synchronous nitrification-denitrification nitrogen removal process and a nitrification phosphorus removal process; the structure of the adopted dynamic membrane assembly is stainless steel silk screen and the like, and therefore, the domestic sewage treatment process has low cost and simple control; and the domestic sewage treatment process can rapidly and effectively remove substances in the water, such as organic matter, SS (suspended substances), nitrogen, phosphorus and the like under the condition of low temperature; the hydraulic retention time is short, and thereby, the volume of reaction structures is effectively reduced.

The invention relates to a sewage treatment system comprising: a pre-anoxic tank which is connected to a sewage inlet pipeline and is used for an anoxic denitrification reaction of returned sludge and the sewage; an anaerobic tank which is connected to the sewage inlet pipeline and communicated with the pre-anoxic tank and is used for anaerobic phosphorus releasing during biochemical dephosphorization; an anoxic tank which is connected to the sewage inlet pipeline and communicated with the anaerobic tank and is used for nitrogen removal by denitrification; an aerobic tank which is communicated with the anoxic tank and is used for degrading organic substances, nitrating organic nitrogen and ammonic nitrogen and absorbing phosphorus; a post-anoxia tank which is communicated with the aerobic tank and is used for performing nitration and denitrification at the same time; and a sequencing batch sloping plate sedimentation tank which is communicated with the post-anoxia tank and is used for separating muddy water and concentrating the returned sludge, herein the returned sludge is flown back to the pre-anoxic tank. The sewage treatment system is excellent in comprehensiveness and flexibility and can flexibly fit various water quality and treatment requirements generally.

A recycling treatment method for feces and wastewater in a large-scale livestock and poultry breeding farm includes the following steps: (1) pre-treating the feces and wastewater in the large-scale livestock and poultry breeding farm in a pretreatment unit to form slurry; (2) feeding the slurry into an energy recovery unit, and performing solid anaerobic digestion in a solid anaerobic reactor to obtain an energy gas, methane; (3) performing solid-liquid separation to the digested slurry to generate wastewater, which is then fed into a UASB reactor to perform further anaerobic fermentation to remove organic pollutants from the wastewater; (4) feeding the treated wastewater into a nitrogen and phosphorus removal unit to perform nitrogen and phosphorus removal treatment; (5) separating and purifying a precipitate, which is generated in the nitrogen and phosphorus removal unit and mainly includes magnesium ammonium phosphate, to obtain an organic fertilizer additive, wherein the nitrogen removal process is autotrophic nitrogen removal and can reduce aeration quantity by 62.5% without addition of any carbon sources, thus saving large quantity of operation cost; and (6) feeding the treated wastewater into a deep-treatment unit to remove bio-refractory substances and disinfect the wastewater so as to finally reach emission and recovery standards of wastewater.

The invention discloses a polymorphic microorganism aggregate autotrophic nitrogen removal integrated device which is provided with a reaction tank, wherein the reaction tank is internally filled with microorganism aggregates and is provided with a water decanting device with a vertical push rod, fixed packing, an aerator, an online pH value detector, an online dissolved oxygen detector, an online ammonia nitrogen detector and an online nitrate nitrogen detector; the reaction tank is connected with a water inlet pipeline, a water outlet pipeline, a sludge outlet pipeline, an air pipeline, an overflow pipeline, a water inlet pump, a blast blower and an electrically operated valve; the reaction tank is also provided with an online gas flowmeter and a PLC (Programmable Logic Controller); the online gas flowmeter, the online pH value detector, the online dissolved oxygen detector, the online ammonia nitrogen detector and the online nitrate nitrogen detector are all connected with the PLC through signals. An operation method comprises the steps: (1) inoculating sludge; (2) carrying out habituated culture; (3) starting partial nitrification reaction; (4) inoculating anaerobic ammonium oxidization granular sludge; (5) proliferating the anaerobic ammonium oxidization granular sludge; (6) culturing an anaerobic ammonium oxidization bacterium biological film; (7) stably operating the autotrophic nitrogen removal integrated device. The polymorphic microorganism aggregate autotrophic nitrogen removal integrated device is suitable for denitrification treatment of medium and high concentration ammonia nitrogen sewage, simple in structure, high in degree of automation, good in denitrification effect and low in operation cost.

The invention discloses a multi-point water inlet aeration anoxic-aerobic high-efficient nitrogen and phosphorus removal method. The method sequentially comprises the following steps of: (1) introducing sewage to be treated into a grille regulating tank through a water inlet pipe; (2) dividing the water after pretreatment by the grille regulating tank into two lines, wherein one line leads to an aeration tank and the other line leads to an anoxic tank; (3) sending the water in the anoxic tank into an aerobic tank; (4) dividing nitrified water after nitrification treatment in the aerobic tank into two lines, wherein one line returns to the anoxic tank, and the other line flows into a precipitation tank to perform mud-water separation; and (5) lifting sludge through a sludge lifting device, transporting the residual sludge to the outside through a sludge discharge pipe after passing through a sludge treatment system, and returning the sludge after lifting into the aeration tank. The method disclosed by the invention is suitable for new and transformation upgrading projects of high-ammonia nitrogen village and small town/industrial sewage treatment works, has the advantages of simplicity and convenience in management and maintenance, low cost, good treatment effects, strong nitrogen removal effect and the like, and is less affected by climatic conditions.

The invention discloses a power-free integrated constructed wetland waste water treatment technology. The technology is characterized in that a vertical-flow waste water ecological purifying tank is divided into an upper region and a lower region; a waste water pre-treatment system is one or more pre-treatment processes of a grid, a three-grid type settling tank and an anaerobic tank, living waste water after the pre-treatment enters a water distribution system by being lifted by a water pump or relying on the natural liquid level height difference; the waste water after the pre-treatment is evenly distributed on a nitrification region of the vertical subsurface flow ecological purifying tank through a cross water distribution pipe network and is sequentially vertically penetrated in the nitrification region and an artificial matrix layer of a denitrification region; the water distribution system implements intermittent water distribution for the ecological purifying tank and is provided with a power-free gas distribution system at the bottom and in the upper nitrification region for realizing the continuous oxygen restoration of the nitrification region; outlet water of the upper nitrification region directly enters the lower denitrification region; a water collecting and water outlet system is arranged in the lower denitrification region, a water collecting port is arranged below the denitrification region, and a water outlet is arranged above the denitrification region, thereby leading the outlet water to maintain a certain water level in the denitrification region. The technology can realize the power-free natural oxygen restoration of the wetland, occupy small area and realize the nitrification-denitrification integrated high-efficient nitrogen removal.