766 results about "Synergistic catalysis" patented technology

The invention discloses a high-entropy oxide for synergic nitrogen removal and catalysis as well as a preparation method and application thereof, and belongs to the technical field of material preparation, the high-entropy oxide is a single solid solution phase formed by five or more metal elements of Fe, Co, Ni, Cu, Mn, Ti and Ce and an oxygen element, the configuration entropy of the high-entropy oxide is greater than or equal to 1.5 R, R is a gas constant, and R is an oxygen constant. The mole fraction of each metal element is 0.1-0.3, and the sum of the mole fractions of the metal elements is 1. According to the high-entropy oxide with the synergistic nitrogen removal and catalysis effects and the preparation method and application thereof, a synergistic catalysis system is constructed through the high-entropy oxide and silicon carbide, and the high-entropy oxide has the multiple advantages of being high in nitrogen removal efficiency, high in stability, simple in process, environmentally friendly and wide in application range; the removal rate of total nitrogen and key nitrogen pollutants can reach 90% or above in the seawater high-salt environment, and the environment-friendly emission requirement is met.

The invention provides a cerium oxide photo-thermal synergistic catalytic material loaded with a metal promoter as well as a preparation method and application of the cerium oxide photo-thermal synergistic catalytic material. The cerium oxide photo-thermal synergistic catalytic material loaded with the metal promoter comprises a cerium oxide nanocrystal and the metal promoter loaded on the surface of the cerium oxide nanocrystal, the exposed crystal face of the cerium oxide nanocrystal comprises a {111} crystal face, and the area of the {111} crystal face accounts for more than 50% of the total area of the outer surface of the crystal face; the mass fraction of the metal cocatalyst is 0.1-2wt% of the mass of the cerium oxide. The catalytic material provided by the invention takes cerium oxide with a {111} crystal face as an exposed special crystal face as a carrier, photons can be captured and charges can be separated more efficiently, and phonons further promote deep trap state charge release. Meanwhile, the metal additive is added and cooperates with cerium oxide with exposed special crystal faces for catalysis, so that the catalytic effect is remarkably improved, and efficient catalytic combustion of methane is achieved under the mild condition.

The invention discloses a method for degrading polystyrene (PS) plastic and upgrading and recycling the PS plastic into benzoic acid based on nano MnO2 photocatalytic ozonation, and belongs to the technical field of solid waste recycling. The method comprises the following steps: firstly, mixing PS plastic fragments with nano MnO2 and an organic solvent, then simultaneously introducing ozone into a reaction system at normal temperature and normal pressure, and irradiating with light. Through synergistic catalysis of light and ozone, molecular chains of the PS plastic can be efficiently and selectively broken and oxidized, and finally the PS plastic is directionally converted into benzoic acid with high additional value. After the reaction is finished, a benzoic acid product can be obtained through simple separation, concentration and purification steps. The method provided by the invention realizes high-valued recycling of the waste PS plastic under mild conditions, solves the problems of high energy consumption, complex products, easy generation of secondary pollution and the like in a traditional treatment method, and has the outstanding advantages of green process, efficient reaction, high product value and the like.

The invention provides a method for promoting acquisition of clean fuel by light / sound concerted catalytic degradation of waste plastics and upgrading and conversion thereof, which comprises the following steps: uniformly mixing g-C3N4, cadmium acetate and thioacetamide according to a predetermined proportion, pouring into a reaction kettle, placing in a high-temperature oven for a predetermined time, centrifuging, cleaning and drying to obtain a catalyst, the method comprises the following steps: loading a catalyst on the surface of aerogel, hydrogel or non-woven fabric to obtain an MTSJA-loaded catalyst, treating waste plastic with NaOH, adding the MTSJA-loaded catalyst, stirring under irradiation of a xenon lamp, starting ultrasound for reaction, and carrying out light / sound synergistic catalytic degradation on the waste plastic. According to the method, energy consumption is not needed, toxic and harmful gas is not generated, the purposes of energy conservation and environmental protection can be achieved, meanwhile, carbon dioxide in water can be catalytically reduced to generate clean energy such as methane in the process of degrading the waste plastic, and further obtaining of the energy is promoted.

The invention discloses an immunosensor for detecting cytokine interferon gamma through electrochemiluminescence as well as a preparation method and application of the immunosensor. The immunosensor comprises a three-electrode system consisting of an immunoelectrode, a reference electrode and a counter electrode, the immunoelectrode is a VMSF modified electrode confined to cerium dioxide nano enzyme and platinum nano particles, and is obtained by covalently immobilizing an IFN-gamma antibody and closing a non-specific site; when the immunosensor is used for detection, a solution containing luminol is used as an electrolyte. The CeO2 and the PtNPs which are confined in the nano channel show a remarkable synergistic catalysis effect. Compared with direct modification on a plate electrode, CeO2-PtNPs has higher catalytic activity and stability. The sensor provided by the invention is used for INF-gamma detection, has the advantages of high sensitivity, low detection limit and wide detection range, does not need complex pretreatment and separation processes during detection, reduces the detection cost, is simple to operate, and is suitable for large-scale application.

The invention discloses a metal supported activated carbon catalyst for efficiently preparing aquacide dichloride and application of the metal supported activated carbon catalyst. The catalyst is prepared by taking activated carbon as a carrier, loading Lewis acid active components such as aluminum ions, zinc ions, iron ions, copper ions and the like through an impregnation method, and carrying out vacuum pyrolysis activation treatment at 300-600 DEG C. The catalyst synergistically catalyzes a nucleophilic substitution reaction of a pyridine derivative and alkyl halide in an aprotic polar solvent such as acetonitrile or nitrobenzene, and synthesis of diquat dichloride can be realized under the conditions that the temperature is 100-180 DEG C and the pressure is 1-3 MPa. In a reaction system, the mass ratio of the pyridine derivative to the catalyst to the solvent is 1: (0.01-0.05): (5-8), and real-time monitoring and regulation are performed through an online infrared spectrum, a liquid chromatograph and a gas chromatograph-mass spectrometer. The purity of the product is more than 99% after the product is subjected to filtration, recrystallization with an ethanol-water mixed solvent and vacuum drying. The catalyst provided by the invention has the characteristics of high activity, strong stability and recoverability, obviously improves the atom economy of the reaction, simplifies the production process, reduces the energy consumption and pollution, and is suitable for large-scale industrial production.

The invention discloses a two-dimensional metal oxide composite reduced graphene oxide burning rate catalyst, which is prepared by the following steps: uniformly grinding glucose, ammonium nitrate and transition metal nitrate, calcining at high temperature to generate a two-dimensional metal oxide nanosheet, mixing the two-dimensional metal oxide nanosheet with surfactant modified reduced graphene oxide powder, and sintering at high temperature to obtain the two-dimensional metal oxide composite reduced graphene oxide burning rate catalyst. And transferring into a high-pressure hydrothermal kettle for solvothermal reaction, so that the reduced graphene oxide and the two-dimensional metal oxide nanosheet are compounded to form the composite burning rate catalyst with a 2D-2D structure. Two two-dimensional materials are compounded through a solvothermal method, the defects of accumulation of reduced graphene oxide and aggregation of the two-dimensional metal oxide due to high surface energy are effectively avoided, meanwhile, the high conductivity of the reduced graphene oxide is utilized, the synergistic catalysis effect of the metal oxide and the carbon material is enhanced, and the performance of the composite material is improved. The composite material has a good catalytic effect on the thermal decomposition process of ammonium perchlorate.

The invention discloses a gas-sensitive material based on double noble metal doped holmium iron oxide and application of the gas-sensitive material to detection of hydrogen sulfide in a sulfur-containing ore body exploration environment, and relates to the technical field of gas-sensitive materials. HoFeO3 is used as a substrate material, and two elements of Au and Pt are used for doping modification of the HoFeO3 to prepare the gas sensitive material based on double noble metal doped holmium iron oxide. Au and Pt are combined to perform doping modification on HoFeO3, a synergistic effect is achieved on improving the temperature stability of the gas-sensitive material, the sensitivity of the gas-sensitive material in a high-humidity environment can be improved, in addition, due to the synergistic catalysis effect of Au and Pt, an energy barrier of H2S adsorption reaction can be remarkably reduced, surface electron transfer and reaction activity are promoted, and the sensitivity of the gas-sensitive material in a high-humidity environment is improved. Therefore, the working temperature is reduced, the response value is improved, and the method is suitable for detecting hydrogen sulfide gas in a sulfur ore body exploration environment.

The invention discloses a synthesis process of vitamin C ethyl ether, and belongs to the technical field of vitamin C derivative synthesis. The process comprises the following steps: taking L-ascorbic acid as a raw material, adding acetone, anhydrous cupric sulfate and acetyl chloride, and reacting for 1-2 hours at 38-40 DEG C under the protection of nitrogen to obtain a vitamin C protector; adding alkali, water, an alkylating reagent and absolute ethyl alcohol into the reaction product, reacting for 3 hours at 75-78 DEG C under the protection of nitrogen, and performing reduced pressure distillation to obtain a vitamin C protector etherate; and finally, hydrolyzing by using cationic resin, removing a protecting group, and recrystallizing by using ethyl acetate to obtain the vitamin C ethyl ether. Through the synergistic catalysis of anhydrous cupric sulfate and acetyl chloride, the reaction time is remarkably shortened, and the product purity and yield are improved. Through detection, the product purity is more than 99.5%, the total yield can reach more than 80%, and an efficient and economical method is provided for industrial production of vitamin C ethyl ether.

The invention discloses a phase transfer catalyst of metal ion complexing crown ether for efficiently preparing aquacide dichloride and application of the phase transfer catalyst. The catalyst is prepared by taking crown ethers as 18-crown-6 and dicyclohexyl-18-crown-6 ether and complex ions as lewis acid active components such as potassium ions, lithium ions, cobalt ions, copper ions and the like through a direct chemical method. The catalyst synergistically catalyzes a nucleophilic substitution reaction of a pyridine derivative and alkyl halide in an aprotic polar solvent such as acetonitrile or nitrobenzene, and synthesis of diquat dichloride can be realized under the conditions of 60-140 DEG C, normal pressure and no oxygen. The mass ratio of the pyridine derivative to the catalyst to the solvent in a reaction system is 1: (0.001-0.05): (5-8), and real-time monitoring and regulation are performed through an online infrared spectrum, a liquid chromatograph and a gas chromatograph-mass spectrometer. The purity of the product is more than 99% after the product is subjected to filtration, recrystallization with an ethanol-water mixed solvent and vacuum drying. The catalyst provided by the invention has the characteristics of high activity, strong stability and recoverability, obviously improves the atom economy of the reaction, simplifies the production process, reduces the energy consumption and pollution, and is suitable for large-scale industrial production.

The invention provides a ceramic fiber tube and a preparation method thereof, the ceramic fiber tube is provided with a tube body, the tube body is provided with multiple fiber filter paper layers formed by overlapping fiber cotton layers, and the tube body comprises a denitration area and a CO removal area which are arranged along the wall thickness direction; the denitration area comprises a fiber filter paper layers, the CO removal area comprises b fiber filter paper layers, and a + b is greater than or equal to 100; the pipe body is overlapped between the adjacent fiber filter paper layers to form nanoscale pores, and the pore diameter of the nanoscale pores is 10-50nm; and the CO removal area at least further comprises a CO catalyst which is loaded in the pores and on the surface of the fiber cotton in a nano-scale manner. Different active components are loaded on the carrier structure according to functional areas, and the number of layers of the fiber filter paper layers and nanoscale pores are configured, so that the three-in-one design of partition loading, gradient pores and collaborative catalysis is realized, the technical bottleneck of collaborative purification of multiple pollutants in complex flue gas is overcome, and the application prospect is wide. And high efficiency, economical efficiency and long service life are achieved.

The invention discloses a method for detecting glucose on the basis of cascade catalysis of cerium dioxide / gold nano cluster-Prussian blue nano enzyme (AuNCs-CeO-HMPB). The material is prepared by compounding cerium dioxide (CeO) with similar glucose oxidase activity and hollow Prussian blue nanoparticles (AuNCs-HMPB) modified by gold nanoclusters with similar peroxidase activity through a hydrothermal assembly method. In the presence of glucose, CeO catalyzes oxidation of glucose to generate gluconic acid and H2O2, then AuNCs-HMPB synergistically catalyzes decomposition of newly generated H2O2 to generate high active oxygen species, further a colorless 3, 3 ', 5, 5'-tetramethyl benzidine (TMB) color developing agent is oxidized to generate obvious color change, and based on the cascade catalytic reaction, the enzyme-free glucose colorimetric sensor is successfully constructed. The sensor shows excellent detection performance on glucose under optimized conditions (pH = 4.0, 50 DEG C), the linear detection range is 10.00-90.00 [mu] mol / L, and the detection limit is 2.1 [mu] mol / L (S / N = 3).

The invention discloses a microwave catalysis and plasma combined waste gas treatment system and method. The system is formed by connecting a pretreatment module, a pretreatment cavity module, a main catalysis cavity module, a tail end purification module and an intelligent control module in series. The pretreatment module adopts two-stage condensation and multi-stage dust removal and is provided with a humidity particle return valve; the pretreatment cavity completes low-temperature oxidation under the cooperation of multi-frequency microwaves and a catalyst; the main catalytic cavity integrates a pulse corona-enhanced plasma discharge structure and a 2.45 / 5.80 GHz double-frequency microwave source, and cooperates with a catalyst to deeply crack VOCs. The tail end module achieves waste heat recovery and fine purification through double heat exchangers and double activated carbon adsorption, and a terminal monitors emission online through Fourier infrared. And the intelligent control module predicts and adjusts the microwave power, the discharge frequency and the valve position in real time based on a long short-term memory (LSTM) network algorithm, namely LSTM, so that the system keeps high-efficiency, low-energy-consumption and stable operation under the conditions of high humidity and multi-component VOCs (Volatile Organic Compounds).

The present invention discloses a titanium dioxide / manganese dioxide / carbon composite catalyst supported on a macroscopic carrier, a preparation method thereof and an application. The preparation process is as follows: titanium dioxide is added to deionized water, stirred, potassium permanganate is added, and stirring is continued; a carbon source is added, after stirring evenly, a macroscopic carrier is added, ultrasonic mixing is carried out, and reaction is carried out under water bath conditions. After the reaction is completed, it is cooled and dried to obtain the product. Compared with the existing formaldehyde removal materials, through the mutual synergistic effect among the components of the composite catalyst in the present invention, that is, the photo-thermal synergistic catalytic oxidation under light conditions and the adsorption / catalytic oxidation under dark conditions act together to mineralize formaldehyde into environmentally harmless water and carbon dioxide. In addition, the preparation method of the present invention has a simple operation process and low raw material prices. Combining the support on a macroscopic carrier and the synergistic effect among the composite catalysts, it has the characteristics of a wide range of applicable scenarios, convenient subsequent recovery, and all-weather formaldehyde removal, and has broad application prospects.

The present invention provides a microplastic degradation device based on acoustic-photothermal synergistic catalysis, which first promotes a Fenton-like activation oxidation reaction between a water sample to be tested and an activated oxidant by acoustic wave catalysis through an acoustic mold component, and simultaneously promotes the above-mentioned Fenton-like activation oxidation reaction by photothermal catalysis after being irradiated with light through a photothermal catalytic layer. Compared with the existing microplastic degradation technology, the microplastic degradation device based on acoustic-photothermal synergistic catalysis can simultaneously utilize more catalytic reaction modes and have a synergistic effect, and can achieve degradation treatment with lower energy consumption and shorter degradation time in the field of microplastic degradation, thereby effectively improving the degradation efficiency of microplastics in the water sample to be tested.

The invention discloses a method for degrading and recycling waste plastics based on a deep eutectic solvent, and belongs to the technical field of waste plastic resource recycling. The method comprises the following steps: treating waste PET plastic by using a decolorizing agent, carrying out catalytic alcoholysis on the waste PET plastic and ethylene glycol at 180-200 DEG C under normal pressure by using a choline chloride / ethylene glycol / zinc acetate ternary eutectic solvent as a catalyst and a solvent to generate a bis (2-hydroxyethyl) terephthalate monomer, and synthesizing the waterborne polyurethane with isophorone diisocyanate. The preparation method comprises the following steps: mixing waterborne polyurethane with an acrylamide-acrylic acid copolymer and a ternary eutectic solvent, and carrying out UV photopolymerization to prepare the dual-network eutectic gel. The method has the characteristics that the ternary eutectic solvent and Zn < 2 + > synergistically catalyze the degradation of the waste PET to obtain the bis (2-hydroxyethyl) terephthalate monomer with the purity of more than or equal to 96.1% and the yield of more than or equal to 95.3%, and then the eutectic gel with the tensile strength of more than or equal to 1.5 MPa is prepared through photopolymerization, and the temperature is reduced by 60-80 DEG C compared with that of the traditional process. The method effectively solves the problems of high energy consumption, more waste acid and low yield of the traditional waste PET plastic recovery technology.

The invention provides a catalyst for synthesizing N-methylaniline and a preparation method thereof, the catalyst comprises an active component, a carrier and an auxiliary agent, the active component comprises oxygen-containing compounds of copper, zinc and chromium, the carrier is gamma-alumina subjected to surface hydroxylation treatment, and the auxiliary agent is a cerium-molybdenum bimetallic alloy. The preparation method comprises the following steps: loading the active component on the hydroxylation carrier through ultrasonic impregnation, drying, further loading the cerium-molybdenum auxiliary agent, and carrying out reduction alloying and roasting activation to form the composite catalyst. The catalyst is a regular cylinder, has the diameter of 4-6mm and the length of 4-6mm, has an optimized pore structure and surface properties, and is suitable for methylation reaction of aniline and methanol. According to the method, the dispersity of active components is improved through modified chromic oxide, the mass transfer efficiency is enhanced through a hydroxylation carrier, the synergistic catalysis effect of cerium-molybdenum alloy is combined, the reaction activity and selectivity are remarkably improved, meanwhile, side reactions are inhibited, the stability is enhanced, and the method can be widely applied to industrial production of N-methylaniline.

The invention provides a low-temperature concerted catalytic denitration device which comprises a lower shell and an upper shell, a cavity is formed in the lower shell, an infiltration assembly and a stirring assembly are arranged in the cavity, and a circulation assembly is arranged on the upper surface of the upper shell. By designing the infiltration assembly, nitrogen oxide gas can be introduced into absorption liquid to be in full contact with the absorption liquid, so that the contact area of the nitrogen oxide gas and the solution is increased, and the chemical reaction efficiency is greatly improved; according to the invention, nitrogen oxide gas can be broken into finer bubbles from the longitudinal direction and the transverse direction when the nitrogen oxide gas is introduced into the absorption liquid, and the bubbles slowly float up through the guide plate in the process of rotating along with vortex and floating up, so that the floating-up time of the bubbles in the solution can be fully prolonged, the reaction time is prolonged, the denitration rate is further improved, and the denitration efficiency is improved. Meanwhile, the backflow assembly is used for detecting gas at the exhaust port, and unqualified gas obtained after reaction is subjected to secondary circulation.

The invention belongs to the technical field of petroleum processing, and particularly relates to a preparation method and application of a catalyst. The catalyst comprises a metal active component and a molecular sieve, a metal complex is added in situ in the synthesis process of the molecular sieve, anchoring of metal in a molecular sieve cage is realized by using a confinement effect in the molecular sieve cage, sub-nanometer approaching of a metal site and an acid site is realized, and the synergistic effect of the metal site and the acid site is improved; the catalytic cracking catalyst is used for synergistic catalytic cracking of biomass pyrolytic oil and petroleum distillate oil. The high-activity confinement type catalyst is synthesized, the synthesis time of the catalyst is greatly shortened by adding the metal complex while the HY molecular sieve is synthesized, the original crystal structure is kept, metal dispersion is promoted, and the catalytic reaction activity is improved. The catalyst provided by the invention is simple and controllable in active component loading capacity and size, and can be applied to the co-catalytic cracking process of biomass pyrolytic oil and / or a model compound thereof and petroleum distillate oil and / or VGO.

The invention discloses a preparation method and application of a catalyst based on pyridine ionic liquid, and belongs to the technical field of catalyst preparation. According to the invention, a hydrolysis reaction of a silane coupling agent is utilized to prepare a silicon oxide nanotube containing a pyridine unit, and then a quaternization reaction is carried out to obtain the catalyst based on the pyridine ionic liquid. The catalyst has a high specific surface area and a rich pore channel structure, exposure of active sites and contact of the active sites and reactants are facilitated, and the catalytic rate is increased. Meanwhile, the silicon oxide nanotube contains hydroxyl, and can cooperate with a pyridine ionic liquid site to catalyze a carbon dioxide cycloaddition reaction. The obtained catalyst can catalyze the reaction of carbon dioxide and an epoxy compound to prepare cyclic carbonate under solvent-free and metal-free conditions, and the catalyst is easy to recover and simple in product purification, and has a good application prospect.

The invention provides a method for preparing rare ginsenoside through conversion of kombucha, the rare ginsenoside and application, and belongs to the technical field of biological medicine. A symbiotic system is formed by multiple bacteria such as acetic acid bacteria, gluconacetobacter, foal bacillus and the like and fungi, after the symbiotic system is domesticated, the American ginseng stem and leaf extract is fermented through multi-bacteria synergistic catalysis, the rare ginsenoside can be efficiently prepared, the highest conversion rate of Rb3 and Rd can reach about 90%, and the yield of Rb3 and Rd can reach about 90%. Meanwhile, the contents of rare ginsenosides Rg3 (20S), Rg5, Rh2 (20R) and Rh2 (20S) are remarkably increased and are increased by about 15 times at most, and efficient conversion of various ginsenosides is achieved.

The invention belongs to the technical field of chemical synthesis, and discloses a method for synthesizing cyclic carbonate through urea alcoholysis under photo-thermal synergistic catalysis. Uniformly mixing the mixed solution of methanol and ionic liquid, zinc salt and other metal salts, and reacting; and after the reaction is finished, centrifugally separating a product, washing, drying, and calcining to obtain the zinc-based homojunction photo-thermal catalyst. The method comprises the following steps: mixing urea, dihydric alcohol and a zinc-based homojunction photo-thermal catalyst, and reacting for 1-6 hours under the conditions that the light intensity is 1-150 mW / cm, the temperature is 130-160 DEG C and the pressure is 5-30 kPa to obtain the cyclic carbonate. The catalyst used in the method effectively overcomes the limitations of low target product synthesis efficiency and high reaction energy barrier in single thermocatalysis, and the yield of the synthesized cyclic carbonate can reach up to 84.1%. Through light energy excitation coupling thermocatalysis, the harshness of reaction conditions is significantly reduced, and efficient synthesis of cyclic carbonate under mild conditions is realized.

The invention belongs to the technical field of composite catalysts, and particularly discloses a metal composite catalyst constructed based on a metal phenolic complex-crystalline porous material as well as a preparation method and application of the metal composite catalyst. The preparation method comprises the following steps: mixing a polyphenol solution and an organic salt solution, and carrying out coordination complexation reaction to obtain a metal phenolic complex; sequentially carrying out first reaction and second reaction on the metal phenolic complex solution and the crystalline porous material precursor solution to obtain a metal phenolic complex-crystalline porous material core-shell structure compound; and then blending with an inorganic metal salt solution, and sequentially carrying out reduction reaction and centrifugal separation to obtain the metal composite catalyst. The hierarchical porous structure and the metal-organic concerted catalysis interface are constructed through interface coordination engineering, and the method has wide application in the fields of electro-catalysis, electro-biological coupling catalysis systems, photo-thermal sterilization and the like. The catalyst is mild in preparation process condition, controllable in structure and suitable for large-scale production.

The invention provides a nitrogen-doped carbon-coated nickel-manganese-based bimetallic nanosphere composite material as well as a preparation method and application thereof. The preparation method of the composite material comprises the following steps: fully dissolving a nickel source and a manganese source in isopropanol, adding glycerol, uniformly mixing, and carrying out solvothermal reaction, centrifugation, drying and calcination to obtain nickel-manganese-based nanospheres; and fully dispersing the nickel-manganese-based nanospheres in an alkaline aqueous solution, adding a dopamine source, reacting, centrifuging, washing, drying and calcining to obtain the nickel-manganese-based nanospheres. The preparation method is simple, the product structure and performance are controllable, and the obtained composite material is a nickel-manganese-based bimetallic nanosphere with the surface coated with a nitrogen-doped carbon layer and has the advantages of high specific surface area, small and uniform particle size and good dispersity; the composite material disclosed by the invention is applied to the field of magnesium-based solid hydrogen storage, nickel-manganese bimetals play a synergistic catalytic effect, and the composite material shows excellent magnesium-based solid hydrogen storage catalytic modification performance in combination with surface defects and high cycle stability brought by a nitrogen-doped carbon layer.

The present application provides a transition metal single atom carbon-based catalyst, characterized by comprising a transition metal single atom, a nitrogen-doped carbon substrate and an oxygen-doped carbon substrate, and the carbon-based catalyst comprises a 4-coordination structure unit M-N4 structure and a 5-coordination structure unit M-N2O3 structure of the transition metal single atom in the structure of the carbon-based catalyst. The carbon-based catalyst also has high conductivity, and the existence of the two coordination structures can synergistically catalyze the oxidative dehydrogenation of organic matter and the efficient reduction of hydrogen peroxide and oxygen to generate hydroxyl radicals and superoxide radical active species. The synergistic oxidation of the two free radicals on the organic matter in water can significantly improve the mineralization degree of the organic pollutants, thereby efficiently catalyzing the degradation of the organic pollutants in water. The present application also provides a method for preparing the carbon-based catalyst.

The invention relates to the technical field of biochemistry, in particular to an enzyme mutant and application thereof in preparation of conopeptide. According to the preparation method, a strategy of combining green chemistry and an enzyme method is adopted, seven tripeptide fragments are taken as raw materials, a conopeptide main chain is prepared through a liquid-phase synthesis method, and then enzymatic precise modification and synthesis are realized by utilizing a multiple directed evolution enzyme concerted catalysis system. Based on the efficient connection characteristic of a liquid-phase synthesis system and the high substrate specificity of an enzymatic system, the complex protection group operation in traditional solid-phase synthesis is effectively avoided, generation of by-products is remarkably reduced, meanwhile, fixed-point modification and precise assembly of a conopeptide main chain are achieved, and the application prospect is wide. And an efficient and green new path is provided for the continuous production of the cosmetic-grade high-purity conopeptide.

The invention discloses a bio-oil enhanced hydrodenitrogenation method, which comprises the following steps: adding bio-oil, a catalyst, formic acid and deionized water into a reaction kettle, uniformly stirring to obtain a mixed solution, continuously stirring for reaction, and after the reaction is finished, carrying out suction filtration and distillation to obtain reformed bio-oil. The preparation method of the catalyst comprises the following steps: mixing corn straw and ammonium molybdate, adding deionized water after mixing, stirring and dipping, and then carrying out vacuum drying and calcining to obtain the catalyst. In the catalytic reforming process, formic acid is innovatively introduced to serve as a hydrogen source, the gas-liquid interface transmission resistance of a traditional gaseous hydrogen source is eliminated through the homogeneous hydrogen supply characteristic of liquid formic acid, the flammable and explosive risk of high-pressure hydrogen is avoided, the process safety is improved, meanwhile, formic acid is subjected to in-situ decomposition on the surface of the catalyst to generate active hydrogen species, and the catalytic reforming efficiency is improved. And a synergistic catalysis mechanism is formed with a platinum-like active site of the catalyst, so that the kinetic advantage of the hydrodenitrification reaction is enhanced, and an efficient, safe and environment-friendly bio-oil hydrodenitrification process system is constructed.

The method comprises the following steps: firstly, putting a catalyst into a reaction system, and introducing a nitrogen source and a hydrogen source; wherein the catalyst comprises a carrier and a heterojunction material loaded on the surface of the carrier; and then illuminating, heating and applying an electric field to the reaction system at the same time, so that the N = N bond or N = O bond in the reaction system is adsorbed and cracked, and the ammonia is catalytically synthesized. The heterojunction material has a metal property, a thermoelectric property and heterojunction interface double active sites, and photoproduction local oscillation photoproduction of the metal heterojunction is precisely enriched at the interface double active sites under the thermoelectric synergistic effect, so that the charge density of the interface double active sites is remarkably improved; a traditional activation mode of single nitrogen atom in a single site adsorption N = N bond or N = O bond is changed, heterojunction interface charge-rich double-site synergistic adsorption and splitting of the N = N bond or N = O bond are realized, and a nitrogen source activation energy barrier is reduced, so that the yield of synthesis ammonia is remarkably improved.

The present invention belongs to the field of nano drug preparations, and discloses a multifunctional nanozyme platform and its preparation method and application, which is mainly composed of nanozymes, carrier materials and targeting substances. The synthesis of nanozymes, the loading of nanozymes on carrier materials and the modification of their surface targeting substances are carried out by methods such as stirring synthesis, coprecipitation, strong acid oxidation, chemical reduction, covalent bonding, solvent thermal method, physical adsorption, etc. The targeting substance on the surface of the nanozyme platform can be accurately and efficiently positioned to the inflammation site, and the acidic microenvironment of the inflammation site causes the targeting substance and the carrier material to undergo structural depolymerization, thereby releasing a variety of nanozymes, which not only realize the self-cascade and synergistic catalytic enhancement of enzymes at the inflammation site, but also form a substrate self-circulation catalytic system, thereby achieving the effect of efficiently alleviating and treating various inflammation-related diseases.

The invention discloses a preparation method and application of a boron nitride confined platinum single atom-platinum cluster double-site catalyst. The preparation method comprises the following steps: mixing urea, boric acid and carbon nanotubes, and grinding; the ground mixture is placed in an ammonia-argon mixed atmosphere environment for first pyrolysis, and powder is obtained; adding the powder into a boric acid solution, heating and stirring to obtain a defect-rich boron nitride carrier; and washing and drying the carrier, immersing the carrier in a platinum salt aqueous solution, carrying out ultrasonic dispersion, carrying out a vacuum freeze drying method, and finally carrying out second pyrolysis on the dried sample in an ammonia-argon mixed atmosphere to obtain the platinum single atom-platinum cluster composite structure (PtSA-C (at) eBN-CNT) material. The material can efficiently and synergistically catalyze an electrochemical hydrogen evolution reaction (HER) under an alkaline condition (1M KOH), can be applied to a membrane electrode electrochemical cell as a cathode catalyst, shows excellent catalytic activity and stability under working conditions, and has good industrial application potential.