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N-ferrocenylmethyl-3-amino-1,2,4-triazole energy-containing transition metal complex and preparation method thereof

A ferrocene methyl, transition metal technology, applied in the directions of metallocene, ammonium perchlorate composition, chemical instruments and methods, etc., can solve the problems of easy volatility, easy migration, low energy, etc. Low volatility, stable chemical properties, good thermal stability

Active Publication Date: 2018-09-21
SHAANXI NORMAL UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0010] The technical problem to be solved by the present invention is to overcome the disadvantages of existing ferrocene-based burning rate catalysts such as easy migration, easy volatilization, and low energy, and provide a catalyst with good thermal stability under natural conditions, which itself has relatively high heat of formation and combustion N-ferrocenylmethyl-3-amino-1,2,4-triazole energetic transition metal complexes with tunable catalytic performance, and provide a simple and low-cost complex for this complex low preparation method

Method used

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  • N-ferrocenylmethyl-3-amino-1,2,4-triazole energy-containing transition metal complex and preparation method thereof
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  • N-ferrocenylmethyl-3-amino-1,2,4-triazole energy-containing transition metal complex and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0030] 0.09g (0.25mmol) Cu(ClO4 ) 2 ·6H 2 O was dissolved in a 100mL round bottom flask filled with 10mL of distilled water. When the temperature rose to 60°C, 0.14g (0.5mmol) N-ferrocenylmethyl-3-amino - 1,2,4-triazole in absolute ethanol and 10 mL of an aqueous solution in which 0.05 g (0.25 mmol) of 1,1'-dihydroxy-5,5'-bitetrazolium disodium salt tetrahydrate was dissolved, After the dropwise addition, stir and react at constant temperature for 2 hours, a precipitate is formed, filter it, wash the filter cake with absolute ethanol and distilled water, and dry it under vacuum at room temperature to obtain N-ferrocenylmethyl-3-amino-1,2 , 4-triazole energetic Cu complexes:

[0031]

[0032] Its yield rate is 59.9%, and the structural characterization data is: IR (KBr, cm -1 ):3391(s,br),3107(m),2362(w),1626(s),1590(s),1439(vs),1253(vs),1182(s),1102(m),1005 (m),836(w),748(s),491(m)cm -1 , Elemental analysis (theoretical calculation value in brackets): C% 38.47 (38.66),...

Embodiment 2

[0034] In the present embodiment, use equimolar Zn(ClO 4 ) 2 ·6H 2 O replaces Cu(ClO in Example 1 4 ) 2 ·6H 2 0, the reaction time is extended to 3 hours, and other steps are identical with embodiment 1, obtain the N-ferrocenyl methyl-3-amino-1,2,4-triazole energy-containing Zn complex of following structural formula:

[0035]

[0036] Its yield is 32.21%, and the structural characterization data is: IR (KBr, cm -1 ):3391(vs,br),1617(s),1563(m),1439(vs),1253(vs),1182(s),1013(m),836(w),748(s),491 (m)cm –1 , Elemental analysis (theoretical calculation value in brackets): C% 39.80 (39.37), H% 4.78 (4.44), N% 25.75 (25.33).

Embodiment 3

[0038] In this embodiment, with equimolar Mn(ClO 4 ) 2 ·6H 2 O replaces Cu(ClO in Example 1 4 ) 2 ·6H 2 0, the reaction time is extended to 5 hours, other steps are identical with embodiment 1, obtain the N-ferrocenyl methyl-3-amino-1,2,4-triazole energy-containing Mn complexes of following structural formula:

[0039]

[0040] Its yield rate is 50.86%, and the structural characterization data is: IR (KBr, cm -1 ):3374(vs,br),1617(s),1546(m),1439(vs),1253(vs),1182(s),1013(m),836(w),748(m),491 (m)cm –1 , Elemental analysis (theoretical calculation value in brackets): C% 41.80 (41.55), H% 4.57 (4.21), N% 26.46 (26.73).

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Abstract

The invention discloses an N-ferrocenylmethyl-3-amino-1,2,4-triazole energy-containing transition metal complex and a preparation method thereof. The structural formula of the complex is as shown in the description, wherein M represents Cu, Zn, Mn, Ni, Co, Cd or Fe, L is 1H, 1'H-(5,5'-bistetrazole)-1,1'-diol dianion, and x is an integer from 0 to 3. The complex disclosed by the invention is simplein preparation method, low in cost and high in yield and has better burning catalysis effect on main components (ammonium perchlorate and hexogen) of a composite solid propellant; the N-ferrocenylmethyl-3-amino-1,2,4-triazole ligand in the complex has high nitrogen content, has higher positive enthalpy of formation and has synergistic catalysis effect with transition metal ions; and by addition of energy-containing compound 1,1'-dihydroxy-5,5'-bistetrazole disodium salt tetrahydrate, the sensitivity of a burning rate catalyst can be reduced, the energy can be supplied for the solid propellant, and the decomposed and released nitrogen gas is friendly to the environment.

Description

technical field [0001] The invention belongs to the technical field of solid propellants, and in particular relates to a class of N-ferrocenylmethyl-3-amino-1,2,4-triazole energetic transition metal complexes and a preparation method of the complexes. Background technique [0002] With the development of modern defense technology, many countries have shown increasing interest in improving the performance of tactical missiles (including improving the range, maneuverability and flight speed of missiles), which puts forward more and more requirements for the energy of engines and propellants. Come higher demands. Regardless of the miniaturization, mobile launch, concealment, low cost and low-level maintenance requirements of strategic missiles, or the signal and penetration of tactical missiles, environment, mobility (thrust adjustment), increased range, vulnerability requirements, and aerospace The requirements of high energy and "cleanness" in the field make the research on ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C07F17/02C05D5/00C06B23/00C06B29/22C07D257/04
CPCC05D5/00C06B23/007C06B29/22C07D257/04C07F17/02
Inventor 张国防姜丽萍许镭李莎莎张伟强高子伟
Owner SHAANXI NORMAL UNIV
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