The present invention concerns compositions, apparatus and methods for
hydrogen storage. In certain embodiments, the compositions comprise
sodium alanate and {n5-C5H5}2TiH2. In preferred embodiments, the components of the composition are present in specified
molar ratios, for example 0.7 NaH to 1.0 Al to 0.1 Ti. In various embodiments, the
hydrocarbon rings coordinating the
titanium are removed from the composition, for example by melting at 182° C. or higher or by cyclic
discharge and recharge of
hydrogen at temperatures of 100° C. or less. Methods for producing and using the claimed compositions are also provided. In various embodiments, the alanate composition may be stored, shipped and used in a modular container, such as a cassette. Exemplary
hydrogen utilizing systems and methods for ordering, distribution and shipping of cassettes are also disclosed herein.