1399results about "Non-explosive/non-thermic compositions" patented technology

A well dispersed oxygen scavenging particulate compounded in a polymer matrix. The oxygen scavenging formulation consists of iron powder with a mean particle sizes within 1-25 um and pre-coated with at least one or more activating and acidifying powdered compounds, usually in the form of solid organic and inorganic salts of alkaline and alkaline earth metals such as sodium chloride and sodium bisulfate. The pre-coated iron particulate is dispersed into a polymer resin by using a conventional melt processing method such as twin-screw extrusion. The oxygen scavenging compound is mixed with polymer pellets in the solid state prior to melting. The polymer resin pellets and the coated iron powder are preferably treated with a surfactant in the dry state to help dispersing the iron / salt powder with the resin pellets. The melt extruded compounds are pelletized and kept in the dry state to prevent premature activation.

Opaque flakes, such as pigment or bright flake used in paints and inks, have a selected shape and / or other indicia to provide a covert security feature to an object. In some embodiments the composition includes base pigment, and the opaque covert flakes match the visual characteristics of the base pigment. In another embodiment, opaque covert flakes are mixed in the carrier with base pigment at a concentration sufficient to avoid changing the appearance of the composition. In another embodiment, opaque covert flakes are mixed in a clear or tinted varnish base that can be applied over an existing security feature. Shaped opaque covert flakes are not readily detectable by causal observation, but in some embodiments are easily seen at 50× magnification. In manufacturing the flakes a sheet of embossed frames are provided having symbols or indicia within; upon removing a coating from the sheet the coating material tends to break along frame lines and the resulting flakes are substantially uniform in size.

The present invention relates generally to a pharmaceutical packaging for increasing the product shelf life, reducing discoloration, and reducing degradation of pharmaceuticals by reducing the oxygen level present in the pharmaceutical package. The pharmaceutical package comprises a substantially oxygen impermeable container, at least one oxygen scavenging element disposed in the container, and at least one packaged pharmaceutical product disposed in the oxygen impermeable container.

Thermally stable gas generant compositions incorporate a combination of one or more primary nonazide high-nitrogen fuels selected from a group including tetrazoles, bitetrazoles, and triazoles, and salts thereof; and one or more secondary nonazide high nitrogen fuels selected from azodicarbonamide and hydrazodicarbonamide. The primary and secondary fuels are combined with phase-stabilized ammonium nitrate that when combusted, results in a greater yield of gaseous products per mass unit of gas generant, a reduced yield of solid combustion products, lower combustion temperatures, and acceptable burn rates, thermal stability, and ballistic properties. These compositions are especially suitable for inflating air bags in passenger-restraint devices.

The invention relates to compounds of the structure of formula I and II:where X is selected from the group consisting of O, S and NH; Y, A and B are independently selected from the group consisting of N and CH; D, E and F are independently selected from the group consisting of CH, N, O and S; the symbol — represents a single or a double bond; and R1, R2 and R3 are independently selected from the group consisting of H, electron withdrawing groups and electron releasing groups. In other embodiments, the compounds are used as oxygen scavengers and in barrier compositions and articles.

The specification discloses a polymer blend especially well-suited for coating paperboard substrates used in food packaging, particularly acidic or acid-generating foods such as fruit and vegetable juices. The blend contains an acid-activatable oxygen scavenger dispersed in a film-forming synthetic polymer such as an EVOH copolymer. When placed as a film or layer on the side of the substrate inside the container in contact with the food the blend is effective to reduce the oxygen in the container over time to a very low concentration, replacing the same with carbon dioxide, for an excellent preservative effect.

The instant invention concerns a composition comprising a base polymer, at least one compound of the formula E-(L-E)x wherein: E is and L is a linking group; and at least one transition metal in a positive oxidation state. The invention also concerns packages containing walls comprising such compositions, methods of forming such packages, and methods of packaging an oxygen-sensitive item within such a package

Provided is a cellulosic composite comprised of cellulosic material and a binder. The binder comprises a reaction product of an amine and a reactant in the form of an amino-amide intermediate. To the amino-amide is added an aldehyde or ketone to form a curable binder composition. The composition when mixed with cellulosic material and cured forms a cellulosic composite.

A gas propelled munitions anti-fouling system has a case having an open forward mouth end, a rear end, and an interior, the rear end defining a pocket that receives a primer and a passage communicating between the pocket and the interior of the case, a quantity of propellant received within the interior of the case, a quantity of anti-fouling composition received within the interior of the case, and a bullet having a rear portion inserted into the open forward mouth end of the case. The anti-fouling composition may have at least one salt and at least one acid. The acid may be anhydrous. The salt may be sodium chloride or sodium nitrate. The acid may be anhydrous citric acid. The anti-fouling composition may have at least one abrasive. The abrasive may be stannic acid. The anti-fouling composition may be 50% salt by weight and 50% acid by weight.

A method includes providing an article including an oxygen scavenger; forming the article into a container; placing an oxygen sensitive product into the container; and exposing the container to actinic radiation at a dosage effective to sterilize the container, and trigger the oxygen scavenger in the article. Alternative methods are also disclosed. A package includes a container, the container including an activated oxygen scavenger; wherein the container is sterilized; and wherein an oxygen sensitive product is disposed in the container.

Provided is a cellulosic composite comprised of cellulosic material and a binder. The binder comprises a reaction product of an amine and a reactant in the form of an amino-amide intermediate. To the amino-amide is added an aldehyde or ketone to form a curable binder composition. The composition when mixed with cellulosic material and cured forms a cellulosic composite.

The present invention relates to methods for producing non-detonable and non-explosive parent-odor scent simulants of both detonable and entropy-burst chemical explosive materials. A detonable explosive material is a material that explosives with the aid of detonation while an entropy burst explosive material is a very sensitive energetic material that does not require detonation, but explodes through a spontaneous decomposition of its molecules into gaseous products. The invention also presents representative non-detonable, non-hazardous compositions of such simulants that can be safely and effectively utilized within a broad spectrum of biological and non-biological explosives detection programs, non-limiting examples being the training of biological search-and-detect creatures such as explosive detecting dogs and the calibration of electronic explosive detecting instruments that rely on the principles of vapor sampling for their operations.

A polyester composition containing: a) aluminum atoms; and b) alkaline earth atoms or alkali metal atoms or alkali compound residues such as lithium atoms; and c) particles comprising titanium, zirconium, vanadium, niobium, hafnium, tantalum, chromium, tungsten, molybdenum, iron, or nickel atoms or combinations thereof, where the particles improve the reheat rate of the polyester composition. The polyester polymer compositions may also contain phosphorus catalyst deactivators / stabilizers. The polyester compositions and the articles made from the compositions such as bottle preforms and stretch blow molded bottles have improved reheat rate while maintaining low haze, high L*, a b* below 3, and have low levels of acetaldehyde. In the process for making the polyester polymer, the polymer melt is polycondensed in the presence of a) and b), with the particles c) added in a melt phase process or added to the polymer in an injection molding machine or extruder. The polyester polymer composition can be made to high IV from the melt phase while avoiding solid state polymerization.

A composition for the generation of chlorine dioxide including at least one non-iodo interhalide, polyhalide or salt thereof having the formulaBrmClnFoXpwherein m=0–3, n=0–4, o=0–3, p=0–2, X is a cationic moiety and with the provisos that m+n+o cannot be zero; if m+n+p<2, or mixtures thereof, and at least one source of chlorite ions.

The present invention relates to the use of an exothermic composition having, as essential components, a water absorptive polymer and / or tackifier, carbon component and / or metal chloride and features that the product is as a whole ink-like or cream-like in a method of manufacturing an exothermic device.

The present invention relates to nanocomposite materials comprising nanoclays as support of metal oxide particles which give the materials multi-functional properties. Said properties are obtained through the formulation of a specific type of additives based on layers of natural and / or synthetic clays which are intercalated with metal oxides with antimicrobial and / or oxygen sequestrating and / or catalytic and / or self-cleaning and / or anti-abrasive capacity; and which may optionally contain other organic, metal, inorganic compounds or combination thereof which may exercise a role of compatibilization and / or dispersion and / or increase in the functionality of the metal oxides and / or providing new functionalities, both passive of physical strengthening and active such as biocide character, antioxidant and chemical-species absorbers.Furthermore, the present invention discloses the use of said materials for multi-sector applications.

Monolayer packages comprised of an oxygen scavenging composition suitable for direct contact with package contents and recycle with other polyester bottles are disclosed. The oxygen scavenging composition is comprised of a modified copolymer which is comprised of predominantly polyester segments and an oxygen scavenging amount of oxygen scavenging segments. The polyester segments comprise segments derived from typical bottling and packaging polyesters such as PET and PEN. Use of these oxygen scavenging copolymers in bottles provides a clear and rigid monolayer bottle similar in appearance to unmodified polyester bottles. In a series of preferred embodiments, bottles fabricated with the oxygen scavenging copolymers of this invention are over 99 wt % PET and contain less than 50 ppb of extractable components.

A composition that includes a polymer having mer units derived from at least one vinyl aralkyl compound, a transition metal catalyst, preferably a photoinitiator, and optionally a polymeric diluent is capable of scavenging oxygen and of being processed into articles with oxygen scavenging capabilities.

A device for controlling relative humidity in an environment with a solidified humectant composition. The solidified humectant composition is made from a humectant salt, water, and a carrier. The solidified humectant may be formed into a tablet with the aid of a binder, or it may be contained within a thermoformed felt material, a sachet, or a water permeable canister. In a preferred embodiment, the sachet is made of a micro-perforated polyester / paper / polyethylene material. Preferred humectant salts include CaCl2, K2CO3, LiCl2, NaCl, K2SO4, and combinations thereof. A preferred embodiment of the present invention includes the use of one or more of: an antimicrobial agent, activated carbon, a volatile organic, a moisture adsorber and an oxygen absorber, in combination with the solidified humectant salt.

Opaque flakes, such as pigment or bright flake used in paints and inks, have a selected shape and / or other indicia to provide a covert security feature to an object. In some embodiments the composition includes base pigment, and the opaque covert flakes match the visual characteristics of the base pigment. In another embodiment, opaque covert flakes are mixed in the carrier with base pigment at a concentration sufficient to avoid changing the appearance of the composition. In another embodiment, opaque covert flakes are mixed in a clear or tinted varnish base that can be applied over an existing security feature. Shaped opaque covert flakes are not readily detectable by causal observation, but in some embodiments are easily seen at 100× magnification.

A humidity control device for use in maintaining a desired humidity in packages of food, the device including a protective case, a water vapor permeable pouch and a thickened saturated solution, the solution having a suitable humidity control point for use within a food container. The device further employs a combination of an oxygen scavenger system to stop mold growth with anaerobic conditions and / or a mold inhibitor in the filling of the pouch or preferentially printed on the outside of the pouch.

Oxygen is removed or maintained in a sealed container by electrochemically reducing the oxygen to water using an enzymatic O2 scavenging system based on a laccase enzyme. Activation of the O2 scavenging system typically occurs by water (liquid or vapor) adsorption; in preferred embodiments, ascorbate and isoascorbate (and their corresponding acids) are especially advantageous for their dual role as reductant and hygroscopic agent. The capacity of the O2 scavenging system can be manipulated by altering the concentration of reductant that is included in the O2 scavenging composition. The O2 scavenging system can be prepared in a variety of formats (e.g., inks, labels, packets, liners, patches, caps, within the packaging material itself) and is readily produced by apparatuses conventionally used in the industry on a high speed continuous basis.

Monolayer packages comprised of an oxygen scavenging composition suitable for direct contact with package contents and recycle with other polyester bottles are disclosed. The oxygen scavenging composition is comprised of a modified copolymer which is comprised of predominantly polyester segments and an oxygen scavenging amount of oxygen scavenging segments. The polyester segments comprise segments derived from typical bottling and packaging polyesters such as PET and PEN. Use of these oxygen scavenging copolymers in bottles provides a clear and rigid monolayer bottle similar in appearance to unmodified polyester bottles. In a series of preferred embodiments, bottles fabricated with the oxygen scavenging copolymers of this invention are over 99 wt % PET and contain less than 50 ppb of extractable components.

A spontaneous firing explosive composition for use in a gas generator for an airbag containing a fuel, an oxidizer, a combustion modifier, and a binder.

A container (22) includes a shell (24) made from a polymer, for example PET, and incorporating a catalyst, for example a palladium catalyst. A closure (40) incorporates a plug which includes a source of hydrogen, for example a hydride. In use, with container (22) including a beverage and closure (40) in position, the headspace in the container will be saturated with water vapor. This vapor contacts the hydride associated with plug (42) and as a result the hydride produces molecular hydrogen which migrates into the polymer matrix of shell (24) and combines with oxygen which may have entered the container through its permeable walls. A reaction between the hydrogen and oxygen takes place, catalysed by the catalyst, and water is produced. Thus, oxygen which may ingress the container is scavenged and the contents of the container are protected from oxidation.

The present invention concerns compositions, apparatus and methods for hydrogen storage. In certain embodiments, the compositions comprise sodium alanate and {n5-C5H5}2TiH2. In preferred embodiments, the components of the composition are present in specified molar ratios, for example 0.7 NaH to 1.0 Al to 0.1 Ti. In various embodiments, the hydrocarbon rings coordinating the titanium are removed from the composition, for example by melting at 182° C. or higher or by cyclic discharge and recharge of hydrogen at temperatures of 100° C. or less. Methods for producing and using the claimed compositions are also provided. In various embodiments, the alanate composition may be stored, shipped and used in a modular container, such as a cassette. Exemplary hydrogen utilizing systems and methods for ordering, distribution and shipping of cassettes are also disclosed herein.

A humidity control device for use in maintaining a desired humidity in packages of food, the device including a protective case, a water vapor permeable pouch and a thickened saturated solution, the solution having a suitable humidity control point for use within a food container. The device further employs a combination of an oxygen scavenger system to stop mold growth with anaerobic conditions and / or a mold inhibitor in the filling of the pouch or preferentially printed on the outside of the pouch.

An article, such as a polymeric film, sachet, purge control pad, or label, includes a sulfur scavenger. In some embodiments, an oxygen scavenger is also included. A method includes providing an article, including a sulfur scavenger and an oxygen scavenger; and subjecting the article to a dosage of actinic radiation effective to trigger the oxygen scavenger. A method of reducing the sulfur content of a package containing a food product includes either (1) providing a film including a layer including a zinc ionomer, and a layer including an oxygen scavenger; packaging the food product in the film; and storing the package for at least 24 hours; or (2) providing the food product at a temperature of ≦40° F.; providing a film including a layer including a sulfur scavenger; packaging the food product in the film; and storing the package for at least 24 hours.