394 results about "Oxygen scavenger" patented technology

The invention relates to compounds of the structure of formula I and II:where X is selected from the group consisting of O, S and NH; Y, A and B are independently selected from the group consisting of N and CH; D, E and F are independently selected from the group consisting of CH, N, O and S; the symbol — represents a single or a double bond; and R1, R2 and R3 are independently selected from the group consisting of H, electron withdrawing groups and electron releasing groups. In other embodiments, the compounds are used as oxygen scavengers and in barrier compositions and articles.

The specification discloses a polymer blend especially well-suited for coating paperboard substrates used in food packaging, particularly acidic or acid-generating foods such as fruit and vegetable juices. The blend contains an acid-activatable oxygen scavenger dispersed in a film-forming synthetic polymer such as an EVOH copolymer. When placed as a film or layer on the side of the substrate inside the container in contact with the food the blend is effective to reduce the oxygen in the container over time to a very low concentration, replacing the same with carbon dioxide, for an excellent preservative effect.

In one embodiment, a method for depositing a cobalt-containing capping layer on a metal layer is provided which includes rinsing the metal layer with a deionized water wetting step, depositing a palladium layer on the metal layer by exposing the metal layer to an electroless activation solution comprising a palladium precursor and an acid, and depositing the cobalt-containing capping layer on the palladium layer by exposing the palladium layer to an electroless cobalt-containing solution comprising a cobalt source, a tungsten source, an oxygen scavenger and a surfactant. Ascorbic acid may be used as the oxygen scavenger. In another embodiment, a composition of an electroless plating solution is provided which includes a cobalt source at a concentration in a range from about 50 mM to about 250 mM, a tungsten source at a concentration in a range from about 10 mM to about 100 mM, a complexing agent at a concentration in a range from about 10 mM to about 200 mM, at least one reductant at a concentration in a range from about 1 mM to about 100 mM, a surfactant at a concentration in a range from about 1 mg / L to about 100 mg / L, and ascorbic acid at a concentration in a range from about 30 mg / L to about 300 mg / L.

The present invention relates to the non-invasive use of a luminescent compound to detect and measure concentrations of oxygen dissolved in a rigid container, especially a bottle, a tray, a carton, a lidstock associated with a tray, a stand up pouch, or a paperboard container. The measurement is made independent of the oxygen concentration of the surrounding atmosphere. The invention is especially useful as a quality assurance check to verify oxygen scavenger activation during the assembly of bottled products, and modified atmosphere and vacuum packages. The method according to the invention is faster and less wasteful than previous methods that rely on measuring oxygen concentration within the headspace of an assembled package.

Composites containing a hydrocarbon-soluble well treatment agent may be supplied to a well using a porous particulate. Such well treatment agents may for example inhibit the formation of paraffins, salts, gas hydrates, asphaltenes and / or other deleterious processes such as emulsification (both water-in-oil and oil-in-water). Further, other well treatment agents include foaming agents, oxygen scavengers, biocides and surfactants as well as other agents wherein slow release into the production well is desired.

Composites containing a hydrocarbon-soluble well treatment agent may be supplied to a well using a porous particulate. Such well treatment agents may for example inhibit the formation of paraffins, salts, gas hydrates, asphaltenes and / or other deleterious processes such as emulsification (both water-in-oil and oil-in-water). Further, other well treatment agents include foaming agents, oxygen scavengers, biocides and surfactants as well as other agents wherein slow release into the production well is desired.

A method includes providing an article including an oxygen scavenger; forming the article into a container; placing an oxygen sensitive product into the container; and exposing the container to actinic radiation at a dosage effective to sterilize the container, and trigger the oxygen scavenger in the article. Alternative methods are also disclosed. A package includes a container, the container including an activated oxygen scavenger; wherein the container is sterilized; and wherein an oxygen sensitive product is disposed in the container.

Disclosed is a combination of hydrofluoroolefins and / or hydrochlorofluoroolefins with stabilizers wherein the stabilizers minimize the degradation of the hydrofluoroolefins and hydrochlorofluoroolefins during storage, handling and use yet allow for atmospheric degradation. The combinations exhibit low or zero ozone depletion potential and lower global warming potential making them of interest as replacements for chlorofluorocarbons and hydrfluorocarbons. The combinations of the present invention comprise hydrofluoroolefins and / or hydrochlorofluoroolefins in combination with a stabilizer or stabilizers selected from free radical scavengers, acid scavengers, oxygen scavengers, polymerization inhibitors and combinations thereof.

An oxygen scavenger composition includes a block co-polymer having at least one block including a polyester condensation polymer segment having cycloalkenyl group(s) or functionality directly or indirectly bonded to the polymer chain of said block, and having at least one second block including a polymer segment of a thermoplastic, film forming material. The block copolymer has been found to act as an oxygen scavenger agent under both ambient and refrigerated conditions, to be compatible with conventional film forming packaging materials, and to provide compositions exhibiting low tack which can be readily formed and processed using conventional film forming equipment. A packaging material, such as a film or laminated product suitable for packaging applications, can include the oxygen scavenger composition.

The present invention provides improved drilling fluids that comprise improved shale inhibiting components, and methods for using these drilling fluids in connection with drilling in a subterranean formation. The drilling fluids comprise water and an improved shale inhibiting component. Optionally, other additives may be added to the drilling fluids of the present invention, including, inter alia, antifoams, biocides, bridging agents, corrosion control agents, dispersants, flocculants, fluid loss additives, foamers, H2S scavengers, lubricants, oxygen scavengers, salts, scale inhibitors, viscosifiers, and weighting agents.

A method for improving hydraulic fracturing creates coated proppants containing one or more chemical constituents bonded to a substrate and introduced into the fracturing fluid itself. The substrate that eventually acts as a proppant may be sand, ceramic, resin coated sand, and other materials. Typically, the materials that are coated as powders adhered to the substrate may include friction reducers, biosides, oxygen scavengers, clay stabilizers, scale inhibitors, gelling agents, or the like. By adhering solid materials to a substrate 12 by a binder 14, a single, solid, granular material may be maintained onsite, requiring reduced footprint, reduced mixing and may introduce almost instantaneously into a fracturing flow stream all the necessary chemical constituents, which will eventually become mixed. The result is reduced time, energy, manpower, equipment, and space at the sight, while reducing the environmental impact of transportation, spills, hydrocarbon use, and the like.

The present invention is directed to an oxygen scavenger composition comprising a mixture of (i) a polyester polymer composed of polymer segments containing cycloalkenyl group or functionality; and (ii) an ester type polymer selected from (a)a polyester having a high content of alkylene groups; (b) a polylactone; and (c) a polyvinylacetate having at least about 50 weight percent vinyl acetate mer units therein. The present polymer composition has been found to act as an oxygen scavenger agent under both ambient and refrigerated conditions, to be compatible with conventional film forming packaging materials, to provide compositions exhibiting low tack, and to be capable of being readily processed using conventional film forming equipment.

Exemplary compositions and methods for reducing hexavalent chromium in cementitious compositions involve the use of a liquid additive composition, comprising stannous chloride. Along with the stannous chloride may be used at least one co-additive comprising an antioxidant, oxygen scavenger, or mixture thereof, and / or at least one agent comprising a cement grinding aid, cement quality improver, or mixture thereof.

This invention concerns methods and apparatus for measuring oxidation reduction potentials of water in a hot water system at system temperature and pressure and methods of using the measured oxidation-reduction potential to monitor and control the addition of oxygen scavengers or oxygen to the system in order to maintain effective corrosion inhibiting concentrations of the oxygen scavengers or dissolved oxygen in the system.

Rigid containers are provided comprising oxygen scavenger compositions that produce only low levels of volatiles or by-products as a consequence of oxygen scavenging. In particular, a family of polymers containing selected cyclic olefinic pendent groups are used in the rigid containers to achieve oxygen scavenging that is associated with minimal or no organoleptic by-products after oxidation.

A humidity control device for use in maintaining a desired humidity in packages of food, the device including a protective case, a water vapor permeable pouch and a thickened saturated solution, the solution having a suitable humidity control point for use within a food container. The device further employs a combination of an oxygen scavenger system to stop mold growth with anaerobic conditions and / or a mold inhibitor in the filling of the pouch or preferentially printed on the outside of the pouch.

An article of manufacture includes an oxygen scavenger and poly(lactic acid). The article can be in the form of a film, coating, gasket, liner, insert, sealant, or fibrous matte. A film includes at least one layer including an oxygen scavenger, and at least one layer including poly(lactic acid). A package can be made from the film for enclosing an oxygen-sensitive artice such as food. The poly(lactic acid) blocks the migration of odor causing byproducts of the oxygen scavenging process. A method includes providing a film including at least one layer including an oxygen scavenger; and at least one layer including the poly(lactic acid); and exposing the film to actinic radiation. A method for reducing migration of organoleptically significant compounds is also disclosed.

A package for prolonging the storage life of produce is disclosed. The package comprises a gas permeable container and an atmosphere modifying device contained within the container. The atmosphere modifying device comprises a carbon dioxide emitter, an oxygen scavenger, and an optional ethylene scavenger. Produce is stored in the container with the device. The device and container are suitable to use in a consumer's home (e.g., kitchen cabinet or refrigerator).

A composition that comprises a) an admixing of at least one epoxy resin and aliphatic amine wherein the ratio of epoxy function group / amine is greater than 1; b) a conductive filler; c) one or more corrosion inhibitors, oxygen scavengers or both; d) imidazole as a curing agent / catalyst; and e) optionally other additives such as organic solvents, flow additives, adhesion promoters and rheology modifiers. The reaction of epoxy and aliphatic amine with excess epoxy functionality results in a flexible resin with remaining active epoxy groups. The compositions exhibit improved electrical stability and impact resistance over other conductive adhesive compositions that do not comprise the admixture.

Novel alloy / blends barrier resins consisting of a composition of Polyethylene Terephthalate (PET) and Polytrimethylene Naphthalate (PTN) or PET and Polybutylene Naphthalate (PBN) exclusively for packaging beverages like beer in a monolayer bottle outperforming the existing other barrier multi-layer bottles is described. The alloy / blends of PET / PTN and PET / PBN are produced by using in situ polymerization or melt blending the two polymers or compounding the two polymers to get the PTN and PBN in a PET polymer matrix. The composition of PET alloy / blends with PTN and PBN additionally contains other barrier improving additives. Incorporating a suitable oxygen scavenger in these new alloy / blends and converting to a stretch blow molded bottle, with or without heat setting, allows this monolayer bottle to be tunnel pasteurized for protecting beverages like beer filled at specific gas pressure to its maximum shelf life of >180 days keeping under control both oxygen ingress and carbon dioxide egress. The recyclability of used bottles into bottles, fibres and strappings has been established.

A humidity control device for use in maintaining a desired humidity in packages of food, the device including a protective case, a water vapor permeable pouch and a thickened saturated solution, the solution having a suitable humidity control point for use within a food container. The device further employs a combination of an oxygen scavenger system to stop mold growth with anaerobic conditions and / or a mold inhibitor in the filling of the pouch or preferentially printed on the outside of the pouch.

A chemical and associated systems and methods for creating a gas barrier and microbiologically resistant coating consisting of a quaternary ammonium salt, nano-clay and oxygen scavenger to protect metallic surfaces from microbiologically influenced corrosion, oxygen and acid gas (hydrogen sulfide and carbon dioxide) corrosive processes.

The invention provides an extended shelf life package comprising a material for mammal ingestion that degrades by oxidation, comprising an oxygen scavenger comprising a transition metal oxygen scavenger, a container substantially impervious to oxygen, wherein the container has a filter suspended in the container, the filter holds the material for mammal ingestion, the container also holds a support for the filter below the filter, and wherein the support holds the oxygen scavenger.In another embodiment, the invention provides an extended shelf life package comprising mammal ingestible material that degrades by giving off CO2 comprising a carbon dioxide scavenger, a container substantially impervious to carbon dioxide, wherein the container has a filter suspended in the container, the filter holds the mammal ingestible material, and the container also holds a support for the filter below the filter, and wherein the support holds the carbon dioxide scavenger.

Multilayered plastic bottles are disclosed having oxygen scavenging capacity sufficient to maintain substantially zero or near zero (depending on product requirements) presence of oxygen in the bottle cavity for the planned shelf life of the bottled product under specified storage conditions. The bottles feature a layer comprised of oxygen scavenger copolyester and may be used for bottling beer and other products requiring nearly total absence of oxygen for the duration of the target product shelf life.

A process for applying an oxidation resistant coating to an article includes the steps of mixing at least about 10% by volume to up to about 99% by volume of a slurry at least one silica based material having a viscosity of about 1×102 poise to about 1×107 poise at a temperature of about 1,292° F. (700° C.) to about 3,272° F. (1,800° C.) at least about 1% by volume to up to about 90% by volume of the slurry at least one oxygen scavenger, and a liquid medium to form the slurry; coating an article with the slurry to form a slurry coated article; and heat treating under an inert atmosphere the slurry coated article to form an article having at least one oxidation resistant coating layer containing the at least one oxygen scavenger.

An article, such as a polymeric film, sachet, purge control pad, or label, includes a sulfur scavenger. In some embodiments, an oxygen scavenger is also included. A method includes providing an article, including a sulfur scavenger and an oxygen scavenger; and subjecting the article to a dosage of actinic radiation effective to trigger the oxygen scavenger. A method of reducing the sulfur content of a package containing a food product includes either (1) providing a film including a layer including a zinc ionomer, and a layer including an oxygen scavenger; packaging the food product in the film; and storing the package for at least 24 hours; or (2) providing the food product at a temperature of ≦40° F.; providing a film including a layer including a sulfur scavenger; packaging the food product in the film; and storing the package for at least 24 hours.

Compositions and methods effective to minimize or eliminate the presence of oxidative degradation products in solid dosage forms comprising sufentanil are provided.

A multilayer film includes a first and second outer layer each including a polymer; and an internal layer including an oxygen scavenger; where the first outer layer includes a blend of a polymer and an antifog agent, where the antifog agent includes at least one of a mono fatty acid derivative of glycerol, and a polyglycerol mono fatty acid derivative; and wherein the first outer layer includes from 0.1% to 3%, by weight of the first outer layer, of the antifog agent.

An article of manufacture includes an oxygen scavenger and a zeolite. The article can be in the form of e.g. a film or sealing compound. A package can be made from the article for containing an oxygen-sensitive article such as food. The zeolite reduces migration of odor causing by-products of the oxygen scavenging process. A method of making an article of manufacture having reduced migration of by-products of an oxygen scavenging reaction includes providing an article including an oxygen scavenger and a zeolite; and exposing the article to actinic radiation.