30results about "Nitrated explosive compositions" patented technology

Disclosed is a photocurable and combustible composition, including an energetic prepolymer, a diluent and a photoinitiator; where the energetic prepolymer is one of or a mixture of two of acrylate-terminated poly(3-nitratomethyl-3-methyloxetane) and acrylate-terminated poly(glycidyl nitrate). The photocurable and combustible composition has an energetic group, i.e., a nitrate group, which can be subjected to self-sustaining combustion in an oxygen-free environment, and the composition can be used to prepare combustible components such as combustible ordnance components.

The invention discloses a double-base propellant gelling material substitute and a preparation method and application thereof, and the double-base propellant gelling material substitute comprises the following components by mass: 10%-20% of an absorption tablet, 40%-60% of nitrocellulose, 20%-35% of a plasticizer, 10%-20% of an inert filler and 1%-5% of a stabilizer, totaling 100%. Preparing a mixed solvent of acetone and absolute ethyl alcohol; weighing a stabilizer, pouring the stabilizer into the mixed solvent, and stirring until the stabilizer is completely dissolved in the mixed solvent; the absorption tablets, nitrocellulose, the plasticizer and the inert filler are mixed and poured into a kneading machine, the mixed solvent dispersed with the stabilizer is poured into the kneading machine, and the mixture is kneaded to form gelling powder strips, so that the double-base propellant gelling material substitute is obtained. The substitute material of the gelling material of the double-base propellant prepared after gelling and the real double-base propellant have high consistency in density, viscosity, specific heat capacity and other key performance parameters, and can effectively replace the real double-base propellant to be used for experimental research and performance test.

The invention discloses a composite energetic material and a preparation method and application thereof, the composite energetic material provided by the invention is a composite energetic material of ammonium salt and FOX-7, and the ammonium salt comprises one or more of ammonium chloride, ammonium bromide, ammonium dihydrogen sulfate and ammonium sulfate. By constructing a composite system, the high-temperature decomposition peak temperature of the FOX-7 can be increased, the apparent thermal activation energy can be increased, low-temperature decomposition can be inhibited, and the thermal stability of the FOX-7 can be remarkably improved. Compared with complex processes (such as electrostatic spraying, ultrasonic-assisted precipitation-spray drying and the like) in the prior art, the composite energetic material provided by the invention can be realized only by mixing and grinding, and the thermal stability of FOX-7 is remarkably improved by constructing a composite system.

The present invention provides an explosive composition containing at least one explosive and at least one heteroatom compound, the heteroatom compound including at least one type of heteroatom selected from the group consisting of B, P, Si, S, Cr, Sn, Al, Ge, Li, Na, K, Cs, Mg, Ca, Sr, Ba, Ti, Zr, V, Nb, Ta, Mo, W, Mn, Ni, Cu, Ag, Cd, Hg, Ga, In, Tl, As, Sb, Bi, Se, Te, Co, Xe, F, Y, and lanthanoids.

The invention discloses a nitrogen-rich multi-hydrogen solid-liquid mixed propellant fuel and a preparation method thereof. The fuel is prepared by taking paraffin as a matrix, mixing the paraffin with nitrogen-rich multi-hydrogen green high-energy particles (composed of a nitrogen-rich multi-hydrogen azole material, a catalyst and a binder) and adopting a temperature control'kneading-die casting 'process, and the fuel comprises the following components in percentage by mass: 30-95% of the paraffin matrix and 5-70% of the nitrogen-rich multi-hydrogen green high-energy particles (95-99.4% of the nitrogen-rich multi-hydrogen azole material, 0.5-3.5% of the catalyst and 0.1-1.5% of the binder). The preparation method comprises the following steps: performing interface compounding treatment on a nitrogen-rich multi-hydrogen azole material, a catalyst and a binder to form nitrogen-rich multi-hydrogen green high-energy particles, and uniformly dispersing the particles into a paraffin matrix through a temperature-controlled'kneading-die-casting 'process. By introducing the azole material, the combustion retrogradation rate and the energy density of the fuel are remarkably improved, and meanwhile, the problem of solid product generation is avoided; and meanwhile, the preparation process solves the problems of particle sedimentation and internal fracture of the traditional high-solid-content fuel, and realizes the uniformity and high safety of the fuel. The propellant fuel disclosed by the invention is suitable for a propulsion system of a solid-liquid hybrid rocket, and has the advantages of greenness, safety, high energy and the like.

The application discloses an energetic metal complex and a synthesis method thereof, and the method is characterized by the molar ratio of 3-aminomethyl-4,5-diamino-1,2,4-triazole, rubidium nitrate and nitric acid being 1:1:1-6, after the feeding is completed, the reaction system is heated to 25-100 DEG C to react, and the reaction time is 0.5-4 hours. After the reaction is completed, the reaction system is cooled to room temperature, filtered, washed and dried to obtain the energetic metal complex [TATT][Rb](NO3)3. The triazol ring with high nitrogen content is selected as a basic skeleton, and the metal complex is obtained by further reacting with the rubidium nitrate and the nitric acid, the single crystal density of the metal complex at normal temperature reaches 2.078 g / cm 3 , the thermal stability reaches 230 DEG C, the electronic density is as high as 4.6419*10 21 / m 3 , the electronic temperature reaches 0.58683 eV, and the metal complex has a great application prospect in the direction of plasma explosives.

The invention belongs to the field of production and manufacturing of energetic materials for fireworks and crackers, and particularly relates to a preparation method of a nitrocotton-based pyrotechnic composition for fireworks and crackers. The preparation method comprises the following steps: sequentially adding water, nitrocotton, a stabilizing agent and ethyl acetate into a reaction kettle provided with a heating and stirring device, then adding protective glue, continuously stirring, adding a sodium sulfate solution into the reaction kettle, dehydrating, adding microcrystalline wax / paraffin into the reaction kettle after the particle morphology is stable, and continuously stirring; melting microcrystalline wax / paraffin under the stirring action, and uniformly coating the surfaces of the nitrocotton particles with the microcrystalline wax / paraffin to form a layer of hydrophobic protective film, so as to obtain a semi-finished product; washing with warm water to remove residual sodium sulfate, protective glue and a small amount of ethyl acetate; and drying the washed product at the temperature of lower than 50 DEG C to obtain a final gunpowder particle product. According to the method, the spherical and dense nitrocotton-based pyrotechnic composition particles with good surface coating can be prepared, and the free-running property, the combustion consistency and the moisture absorption resistance of the product are effectively improved.

The invention discloses a smokeless firework material and a preparation method thereof. The smokeless firework material comprises the following components: 60%-75% of nitrocotton, 5%-10% of nitroglycerin, 5%-25% of a plasticizer and 1%-2% of a stabilizing agent. The plasticizer is triacetin, dibutyl phthalate or diethyl phthalate, and the plasticizer is dibutyl phthalate or diethyl phthalate; the stabilizing agent is a methyl centralite agent or an ethyl centralite agent. The method comprises the following steps: weighing the raw materials according to the formula proportion, and preparing a mixed medicine material by utilizing a jet absorption process; then, after the treatment of a water expelling process, preparing into a drug group; and crushing the mixture into particles with the granularity of 80-150 meshes by using a hammer crusher, adding the particles into the smokeless firework powder according to the proportion of 20-40%, and mixing the particles with the oxidizing agent and the metal powder for use. After the smokeless firework powder is added into the smokeless firework material, the smokeless firework material has the characteristics of less smoke during combustion, less residue and the like.

A method of using cerium metal complexes / compounds to modify the burning rate of solid rocket motor propellants by preparing a double-based propellant composition including cerium metal ion.

The application provides a TNBA cast explosive and a preparation method thereof, and belongs to the technical field of cast explosive preparation. The TNBA cast explosive is prepared according to the mass percentage of 50.6-55.2% of a liquid carrier, 4.4-4.8% of a fluxing agent and 40-45% of a solid filler. The TNBA cast explosive prepared by the application has the following advantages: the liquid carrier and the fluxing agent have high density, low volatility, low toxicity, low sensitivity and good formability, and no shrinkage hole and crack after pouring; the solid filler has the characteristics of high energy, low sensitivity, high density and high explosion heat; the raw material cost is low, the preparation process is simple, and the explosive can be produced on a large scale; compared with the existing explosives, the cast explosive has high oxygen balance, can generate more heat, has high density, detonation velocity, explosion heat and explosion pressure, and low impact sensitivity, and has higher performance than ordinary explosives.

The invention discloses a method for preparing a microporous single-base flat-bulb explosive by adopting a microchannel reactor. The method comprises the following steps: dissolving nitrocotton in a solvent, emulsifying and foaming a solution as a dispersion phase, and adding a dispersing agent into water as a continuous phase; a cross-shaped micro-channel reactor is adopted, a dispersed phase is injected into a micro-channel through a main channel, and a continuous phase is injected into the micro-channel through double channels; the dispersion phase forms liquid drops under the action of shearing force of the continuous phase, a spherical structure is formed under the action of surface tension, the liquid drops are subjected to flooding and curing forming in a channel, and further curing and drying are carried out under the stirring condition in a collecting device to prepare the microporous single-base flat-bulb explosive. The microporous flat-bulb powder prepared by the method disclosed by the invention is uniform in particle size and controllable in component form, and has the advantages of controllable flat-bulb powder density, simple device, high efficiency, good stability, good repeatability and the like.

The present application relates to a kind of preparation method of preparation method of amino acid configuration's amphoteric energetic compound, belong to energetic material technical field.The present application is based on amino acid configuration, synthesis simultaneously possesses acidic and basic amino acid configuration's energetic compound.The present application also discloses the preparation method of amino acid configuration's energetic compound and the preparation method of corresponding cation salt and anion salt obtained by the reaction of different acid and base.From known available raw material, by one-step method, high yield is obtained simultaneously with acidic and basic amino acid configuration's energetic compound.The compound exists basic N atom and acidic N-H group, with amphoteric characteristics, can be reacted with different acid or base, generate corresponding ionic salt and water.The compound and its ionic salt are ideal insensitive high-energy molecule with good application prospect, with the potential as high-energy insensitive energetic material, provide new ideas for synthesis of new high-energy energetic compound in energetic material.

The invention discloses a novel multi-nitromethyl green energetic compound, and belongs to the technical field of energetic material synthesis and preparation. The compound is 5-(3, 4-dinitro-1H-pyrazol-5-yl)-3-(dinitromethyl)-1H-1, 2, 4-triazole dipotassium salt, and the structural formula of the compound is shown in the specification. The compound can be 9, 10-dinitro-2-(trinitromethyl)-pyrazol [1, 5-d] [1, 2, 4] triazole [5, 1-f] [1, 2, 3, 4] tetrazine. According to the invention, the multi-nitromethyl group is introduced into a pyrazole-triazole skeleton and a tetrazine fused ring skeleton as an energy group, so that the oxygen balance of molecules is improved, and the detonation performance of the energetic material is improved.

The invention discloses a high-density zero-oxygen-equilibrium hydrogen-free high-energy propellant component and a preparation method thereof, the molecular formula of the high-density zero-oxygen-equilibrium hydrogen-free high-energy propellant component is C6N20O12, the density is 1.913 gcm <-3 >, and the oxygen equilibrium of carbon dioxide is zero. The synthesis method comprises the following synthesis steps: dissolving 1, 2-bis (5-azido-1H-1, 2, 4-triazole-3-yl) diazene serving as a raw material in a potassium hydroxide solution to react with chloroacetone, and then carrying out nitration in nitric-sulfuric acid to obtain the 1, 2-bis (5-azido-1-(trinitromethyl)-1H-1, 2, 4-triazole-3-yl) diazene, namely the 1, 2-bis (5-azido-1-(trinitromethyl)-1H-1, 2, 4-triazole-3-yl) diazene. The 1, 2-bis (5-azido-1-(trinitromethyl)-1H-1, 2, 4-triazole-3-yl) diazene disclosed by the invention has the advantages of high density, zero carbon dioxide oxygen balance, excellent energy performance, high specific impulse, low characteristic signal (not generating water) and the like, and can be used as an environment-friendly propellant component.

The invention relates to a fuel consisting of nitromethane for spacecraft and / or missiles, wherein the fuel contains at least one additive in the form of an inhibitor that reduces the impact sensitivity, wherein the inhibitor is dimethyl sulphoxide, or wherein the inhibitor is at least one of n-butanol compounds or nitroethane or an ionic liquid, wherein the inhibitor is a phlegmatiser and reduces the impact sensitivity.

The invention discloses a synthesis method of tetrazine high-nitrogen compounds and salts thereof, and belongs to the technical field of organic synthesis.The synthesis method of the tetrazine high-nitrogen compounds comprises the following steps that 3, 6-bis-3, 5-dimethylpyrazole-1, 2, 4, 5-tetrazine and a nucleophilic reagent are mixed and subjected to a heating and stirring reaction, after the reaction is finished, suction filtration, washing and drying are conducted, and the tetrazine high-nitrogen compounds are obtained. The tetrazine high nitrogen compound is obtained. The method comprises the following steps: mixing a tetrazine high-nitrogen compound with a nitrogen-containing reaction ligand in a solvent for reaction, and after the reaction is finished, carrying out solid-liquid separation and drying to obtain the ionic salt of the tetrazine high-nitrogen compound. The obtained compound is good in thermal stability and low in mechanical sensitivity, the specific impulse value of a solid propellant can be increased to a certain degree, the characteristic signal of the propellant can be reduced, and the research and application field of the asymmetric tetrazine energetic compound is further expanded.

The present invention discloses a photocurable flammable polymer and its application. The polymer comprises an energetic prepolymer, a diluent and a photoinitiator; the energetic prepolymer is a mixture of one or two of terminal acrylate-based poly-3-nitrate methyl-3-methyloxetane and terminal acrylate-based polyglycidyl ether nitrate; the polymer component of the present invention has an energetic group nitrate group, the flammable polymer can self-sustain combustion in an oxygen-free environment, and the polymer can be used to prepare flammable components such as flammable ordnance components.

A severing apparatus is used for severing a conduit. The apparatus includes a main body section having an upper portion, a lower portion, and an intermediate portion. A combustible charge is located in the intermediate portion, and an ignition mechanism is coupled to the upper portion for igniting the combustible charge. A nozzle head is located in the lower portion and includes an internal cavity and a nozzle portion having apertures at spaced apart positions for providing passages from the internal cavity to outside of the nozzle head. The ignition mechanism is configured to ignite the combustible charge to create a flame and combustion products and pressure in the internal cavity for moving the nozzle head relative to the lower portion so that the nozzle portion protrudes out of the lower portion for passage of the flame and hot combustion products out of the apertures to sever the conduit.

The invention belongs to the technical field of nitrocotton processing, and particularly relates to nitrocotton for fireworks and a preparation method of the nitrocotton. In order to overcome the defects that an existing stabilizing agent is toxic and low in safety and environment-friendly index, nontoxic oleamide or acrylamide serves as the stabilizing agent, a desensitizer is not used, nitrocotton, a solvent and the stabilizing agent are added into a kneading machine according to the mass ratio of 100: (70-120): (0.7-1.5) to be plasticized, water is added for granulation after plasticization, and then wet smashing and dehydration are conducted to prepare the nitrocotton for fireworks. The nitrocotton is composed of two kinds of nitrocotton with different nitrogen contents, the nitrogen content of one kind of nitrocotton is 11.5-12.2%, the mass ratio of the other kind of nitrocotton is 40-60%, and the nitrogen content of the other kind of nitrocotton is 13.2-13.4%. The nitrocotton for fireworks prepared by the invention has the same performance as the existing product, and is high in stability and more environment-friendly.

The invention relates to the technical field of explosives, in particular to an energetic binder coated DNTF explosive and a preparation method thereof.The preparation method comprises the following steps that S1, an energetic binder is dissolved in an organic solvent, and an energetic binder solution with the mass percent being 1%-20% is obtained; s2, putting 3, 4-dinitrofurazan furazan (DNTF) powder into water, heating, stirring and dispersing, so as to obtain DNTF turbid liquid; s3, dropwise adding the energetic binder solution prepared in the step S1 into the DNTF suspension prepared in the step S2, stirring, then carrying out vacuumizing treatment, and after the organic solvent is volatilized, sequentially carrying out suction filtration, washing and sieving to obtain DNTF explosive particles; the problem that the energy output of the DNTF explosive is reduced in the existing DNTF explosive packaging technology, so that the further application of the DNTF explosive in the application scene requiring high performance and high safety is limited is solved.

The invention provides a dinitramide ammonium-based liquid propellant combustion simulation data labeling method and system based on digital twinning, and the method comprises the steps: constructing a labeling correlation map through combing and refining combustion physical rules and multi-batch historical labeling data of a dinitramide ammonium-based liquid propellant in different combustion environments; the method comprises the following steps: comparing new combustion simulation data generated by a digital twin system through iterative simulation with an annotation association map, extracting a covering combustion state description item and multiplexing a corresponding annotation label, synchronously separating a new combustion state description item which is not matched with the annotation association map, performing targeted annotation to obtain a newly added annotation label, and performing annotation on the newly added annotation label to obtain a new combustion state description item; and updating a combustion state description item-labeling label association corresponding record of the labeling association map, performing adaptive calibration on all combustion simulation historical labeling data generated in an early stage, updating original labeling label contents, and synchronously updating a combustion simulation data labeling reference library of the digital twin system. According to the method, the integrating degree of simulation and labeling can be improved.

A tool (1), for example, a tool for use downhole in a tubular oil or gas well, and a method of deploying and operating the tool (1), are disclosed herein. The tool (1) includes a generally cylindrical body (4), which includes a chamber (6). A fuel source (8) is also included. The fuel source (8) is a pressurised fuel and oxidant mixture (9) which is released into the chamber by an injector device through injector nozzles (16). The fuel and oxidant mixture (9) is ignited to form a combustion jet (20). The combustion jet (20) exits the nozzle outlet (28) as directed combustion jets, which perforate the walls of the tubular oil or gas well 30, wherein the walls of the tubular oil or gas well represent a material to be manipulated.

The invention provides a dinitramide ammonium-based high-energy ion eutectic and a preparation method thereof, the eutectic is named as ADN / OHD eutectic and is composed of dinitramide ammonium and oxalyl dihydrazine, dinitramide ammonium molecules and oxalyl dihydrazine molecules are combined through intermolecular hydrogen bonds, and the dinitramide ammonium-based high-energy ion eutectic belongs to a monoclinic system and a P21 / c space group. Two strategies can be adopted for preparation: the first strategy is as follows: ammonium dinitramide and oxalyl dihydrazine are mixed in water, and the mixture is left to stand or stirred until eutectic crystals are separated out; and the second method comprises the following steps: mixing ammonium dinitramide and oxalyl dihydrazine, dropwise adding the solvent, and mechanically grinding until the solid becomes uniform white powder and the solvent is completely volatilized to obtain the ADN / OHD eutectic crystal. The critical relative humidity of the dinitramide ammonium-based high-energy ion eutectic prepared by the preparation method disclosed by the invention is as high as 70%; meanwhile, the eutectic crystal also has the characteristics of high specific impulse and high energy, the oxygen balance of the eutectic crystal based on CO is high (4.37%), and the theoretical specific impulse of the eutectic crystal is up to 251.28 N * S / kg through NASA software calculation. And the preparation method is simple, green and environment-friendly.

The invention discloses a treatment device for separating liquid nitrate in wastewater. The treatment device comprises a wastewater temporary storage tank, a separation membrane, a liquid discharge pump, a recovery ejector and a washing separator, a wastewater outlet is formed in the upper part of a right side plate of the wastewater temporary storage tank; the separation membrane is used for isolating nitrate from passing through the wastewater; a liquid inlet pipeline is led out of the nitrate-containing wastewater storage equipment and is inserted into the leftmost end of the inner cavity of the wastewater temporary storage tank, and a valve is arranged on the liquid inlet pipeline; a wastewater outlet of the wastewater temporary storage tank is connected with a wastewater pipeline, a liquid discharge pump and a valve are arranged on the wastewater pipeline, and a separation membrane is arranged at an inlet end of the wastewater pipeline; a liquid inlet lead-out pipeline of the recovery ejector is inserted into the bottom of the rightmost end of the inner cavity of the waste water temporary storage tank, and a liquid outlet of the recovery ejector is connected with a liquid inlet of the washing separator through a pipeline. The treatment device disclosed by the invention realizes normal-temperature treatment of the nitrate-containing wastewater.

The invention discloses a non-hygroscopic dinitramide compound and a preparation method thereof, a series of non-hygroscopic dinitramide compounds are synthesized by introducing cations capable of forming strong hydrogen-bond interaction with N (NO2) <-> to replace NH4 < + >, and the structural characteristics of the compounds are as follows: dinitramide radicals are used as anions, and N (NO2) <-> and N (NO2) <-> are used as negative ions; and the protonated pyridine or pyrimidine compound is a cation. The compound prepared by the invention has the advantages of no moisture absorption, low sensitivity, simple synthesis, environmental protection and the like, the synthesis method is simple and efficient, the cation adjustability is strong, and the compound has very high application potential in the field of energetic materials.

The present invention discloses a core-shell ammonium dinitramide-based composite material and a preparation method thereof, including the following component mass ratios: 0.02 to 0.24 parts of the intermediate layer, 4 parts of the solvent, and 0.04 parts of ADN. By adopting the above-mentioned core-shell ammonium dinitramide-based composite material and the preparation method thereof, the saturated moisture absorption rate is extremely low, the surface coating layer is complete, the preparation method is simple, and mass production can be achieved.

The invention relates to the technical field of explosives, in particular to a DNTF (dinitrofurazan furazan) melt-cast explosive with an energetic binder for inhibiting the increase rate of hot ignition and a preparation method, the preparation method comprises the following steps: S1, heating and melting 3, 4-dinitrofurazan furazan (DNTF) powder to obtain molten DNTF; s2, adding an energetic binder into the molten DNTF, and uniformly stirring to obtain a molten mixed solution; s3, pouring the molten-state mixed solution into a mold, and putting the mold into a constant-temperature box for cooling, so as to obtain the DNTF melt-cast explosive with the energetic binder for inhibiting the hot ignition growth rate; the problem that the energy of a whole casting explosive system is reduced due to the fact that a traditional inert material is introduced into an existing DNTF casting explosive to serve as an inhibitor to reduce the thermal sensitivity is solved.

The invention provides a kettle type overflow synthesis method of a glycerol trinitrate / diethylene glycol dinitrate mixture. The kettle type overflow synthesis method comprises the following steps: step 1, mixing concentrated nitric acid and concentrated sulfuric acid to prepare nitric acid and sulfuric acid mixed acid; mixing glycerol with diethylene glycol to obtain mixed polyol; step 2, continuously pumping the mixed acid of nitric acid and sulfuric acid and the mixed polyol according to the formula ratio into an overflow reaction kettle by virtue of a metering pump, carrying out nitration reaction, and enabling a reaction product to flow out of an overflow port of the reaction kettle and enter a separator; step 3, separating in a separator to obtain an organic phase; 4, the organic phase enters a collecting tank after being subjected to water washing and alkali washing, and a glycerol trinitrate / diethylene glycol dinitrate mixture is obtained. According to the method disclosed by the invention, a kettle type overflow synthesis method is adopted, so that the process operation is simplified, the online amount of reaction is reduced, the safety of a nitration reaction process is improved, and the reaction yield of a glycerol trinitrate / diethylene glycol dinitrate mixture is improved.

The present invention relates to a pyrotechnic protection device for an electrical energy storage device comprising a housing, wherein at least one igniter and at least one pyrotechnic charge connected to the igniter are present in the housing, wherein the pyrotechnic charge consists of organic substances or organic substances and metal-free nitrogen-containing inorganic salts so that after an ignition of the pyrotechnic charge initiated by the igniter, reaction products of the pyrotechnic charge are electrical non-conductors and the use of a pyrotechnic protection device.