The invention discloses an energetic material compound 3,3'-diamido-2,2'-2(2,2,2-trinitroethyl)-5,5'-linked triazole-diamine and a preparation method and intermediate of the energetic material compound 3,3'-diamido-2,2'-2(2,2,2-trinitroethyl)-5,5'-linked triazole-diamine. Firstly, 3,3'-diamido-5,5'-2(1H-1,2,4-triazole) is adopted as raw materials, and synthesized into 3,3',4,4'-tetramino-5,5'-linked triazole through nitrogenation and ammoniation of nucleophilic animation reagent 2,4,6-trimethylbenzene sulfonyl hydroxylamine, then hydroxylation is carried out through formaldehyde solutions, and finally a condensation reaction is carried out on the 3,3'-diamido-5,5'-2(1H-1,2,4-triazole) and trinitromethane to generate a target product. Solvents adopted in the preparation method are low in price. The raw materials are prepared easily, reaction steps are few, and productivity is high. The detonation energy of the target product can be equivalent to that of HMX, sensitivity is lower than that of RDX, intramolecular oxygen balance is high, and the energetic material compound 3,3'-diamido-2,2'-2(2,2,2-trinitroethyl)-5,5'-linked triazole-diamine is a high-energy explosive with the good application prospect.