The invention discloses an unsymmetrical lithia battery. The battery takes lithium peroxide as a positive pole active material, lithium peroxide and a catalyst which are uniformly mixed are loaded on a porous carbon material so as to form a positive pole, the material capable of realizing deintercalation of lithium ions is taken a negative pole, and the weight content of lithium peroxide is 1-50% in a composite material. According to the invention, the discharging product lithium peroxide of the traditional lithia battery is directly used as the positive pole active material, the pole material of the traditional lithium ion battery, which is capable of realizing deintercalation of lithium ions, is taken as the negative pole, the damage of negative pole lithium dendrites of a lithia battery to the battery is solved, and meanwhile, the controllable distribution of the discharging product is realized, an unblocked oxygen diffusion channel is guaranteed, and the charge-discharge capacity and cycle performance of the lithia battery are effectively improved.