4521 results about "Spray dried" patented technology

The present invention is directed to a storage-stable formulation of long-chain RNA. In particular, the invention concerns a dry powder composition comprising a long-chain RNA molecule. The present invention is furthermore directed to methods for preparing a dry powder composition comprising a long-chain RNA molecule by spray-drying. The invention further concerns the use of such a dry powder composition comprising a long-chain RNA molecule in the preparation of pharmaceutical compositions and vaccines, to a method of treating or preventing a disorder or a disease, to first and second medical uses of such a dry powder composition comprising a long-chain RNA molecule and to kits, particularly to kits of parts, comprising such a dry powder composition comprising a long-chain RNA molecule.

The invention discloses a preparation method of a high-compaction-density lithium iron phosphate material, through grading of large and small particle lithium iron phosphate, optimization of a sintering process and reasonable selection of a carbon source and a titanium dopant, the compaction density and the electrochemical performance of the material are remarkably improved, and the preparation method specifically comprises the following steps: mixing iron phosphate, lithium carbonate, the carbon source and auxiliary materials; the preparation method comprises the following steps: carrying out coarse grinding and fine grinding, respectively preparing large-particle lithium iron phosphate and small-particle lithium iron phosphate (a material A and a material B) by adopting spray drying and high-temperature calcination processes, mixing the material A and the material B according to a ratio, adding auxiliary materials, grinding, further carrying out spray drying, calcining and crushing to obtain a final lithium iron phosphate product, and the maximum compaction density of the prepared material can reach 2.712 g / cm < 3 >. According to the present invention, the maximum 1C discharge specific capacity can achieve 140.5 mAh / g, the maximum 1C 3.2 V discharge platform retention rate is 91.4%, and the prepared lithium ion battery negative electrode material has characteristics of excellent conductivity, high discharge capacity and good cycle stability, and is suitable for power batteries and energy storage batteries.

The present invention includes a spray drying disposable device for use in a spray drying system. The disposable has a spray drying head and a plasma drying chamber. The head has a spray dry nozzle assembly in fluid communication with the plasma source and the pressurized aerosol gas source. The pressurized gas flows in a vortex pattern that atomizes plasma droplets in the chamber. The head also includes a plenum has uniform air pressure of the drying gas. A baffle plate forms the floor of the plenum having drying gas jets that supply drying gas to the chamber. The atomized plasma droplets evaporate in the presence of the drying gas emitted from the jets to obtain dried plasma particles and humid air. A capture filter captures the dried plasma particles and allows the humid air to pass. The humid air passes through the gas outlet and the exhaust port.

The invention discloses a spray drying device for boron carbide production, the spray drying device comprises a spray drying tower, a hot blast stove, a cyclone separator and a system controller, an atomizer and an online detection module are arranged in the spray drying tower, and the online detection module is used for monitoring temperature parameters in the spray drying process; comprising a first temperature sensor, a second temperature sensor and a temperature signal processing unit, the temperature signal processing unit adopts a multi-stage filtering and error compensation technology, noise and interference are effectively suppressed, and the accuracy of detection data is ensured. The air inlet temperature and the air outlet temperature are monitored in real time through the online detection module, the fuzzy-PID control algorithm is combined, the temperature control precision and the response speed are remarkably improved, and temperature fluctuation is reduced. The device dynamically adjusts the heating power of the hot blast stove according to real-time working conditions, the energy utilization efficiency is optimized, and the energy consumption is reduced.

The invention belongs to the technical field of new energy, and discloses a preparation method and application of a LiaMXb-based composite solid electrolyte membrane, and the preparation method comprises the following steps: S1, carrying out spray drying on a mixed solution in which a Li source, an M source and an ammonium salt are dissolved, placing the mixed solution in a crucible of which the bottom is paved with the ammonium salt, and annealing for 2-10 hours at 350-800 DEG C in an inert atmosphere to obtain a LiaMXb solid electrolyte; s2, mixing the LiaMXb solid electrolyte with a fluorine-containing monomer A and a dispersing agent, and performing spray drying to obtain electrolyte powder wrapped by the fluorine-containing monomer A; s3, ball-milling and uniformly mixing the electrolyte powder wrapped by the fluorine-containing monomer A, a lithium salt, a thermal curing agent and a monomer B in an inert atmosphere to obtain composite electrolyte powder; and S4, carrying out cold isostatic pressing and hot pressing curing on the composite electrolyte powder to prepare the LiaMXb-based composite solid electrolyte membrane. The prepared LiaMXb-based composite solid electrolyte membrane not only has excellent air stability, flexibility and machinability, but also has a continuous three-dimensional ion conduction path, and the assembled all-solid-state lithium battery has good electrochemical performance.

The invention provides a biomass-derived spherical porous carbon material and a preparation method thereof, and a silicon-carbon negative electrode material and a preparation method thereof, and relates to the field of lithium ion batteries. The preparation method of the biomass-derived spherical porous carbon material comprises the following steps: carrying out pre-carbonization treatment on vinasse to obtain pre-carbonized vinasse, mixing the pre-carbonized vinasse with an acidic solution, and washing with water until the mixture is neutral to obtain pre-treated vinasse; mixing the pretreated vinasse with a pore-forming agent, a binder and water to prepare slurry, and performing spray drying on the slurry to obtain a spheroidized precursor; carrying out carbonization treatment on the spheroidized precursor; washing the carbonized spheroidized precursor with water until the spheroidized precursor is neutral, and drying the spheroidized precursor to obtain an intermediate; and activating the intermediate with water vapor to obtain the biomass-derived spherical porous carbon material. The material with a regular spherical and porous structure can be prepared, the material can be used for preparing a silicon-carbon negative electrode material with a stable structure, and the electrochemical performance of the silicon-carbon negative electrode material is improved.

The invention belongs to the technical field of lithium ion battery materials, and discloses a bismuth silicate coated lithium ferric manganese phosphate material, a preparation method thereof and a lithium ion battery. The bismuth silicate coated lithium ferric manganese phosphate material comprises lithium ferric manganese phosphate and a coating layer coating at least part of the surface of the lithium ferric manganese phosphate, and the coating layer is made of bismuth silicate. Carrying out ball-milling mixing on the ferric manganese phosphate material, a lithium source, a carbon source and water to obtain mixed slurry; performing low-temperature spray drying on the mixed slurry to obtain a spray material; and carrying out wet mixing on a silicon source, a bismuth source and the spray material, carrying out high-temperature pyrolysis on the wet-mixed material in a spray pyrolysis furnace, and sintering to obtain the bismuth silicate coated lithium ferric manganese phosphate material. When the bismuth silicate coated lithium ferric manganese phosphate material is used as a positive electrode active material of a lithium ion battery, the high-temperature cycle performance of the battery can be improved while the high discharge capacity of the battery is ensured.

The invention belongs to the technical field of building materials, and particularly relates to a preparation method of a high-strength sintered tile. The preparation method of the high-strength sintered tile comprises the following steps: (1) crushing green body raw materials, sieving, adding water, carrying out ball milling, and carrying out spray drying to obtain powder; (2) performing compression molding on the powder obtained in the step (1) to obtain a green body; drying the green body to obtain a tile blank; (3) coating the tile blank obtained in the step (2) with glaze, and drying to obtain a glazed tile blank; and sintering the glazed tile blank, and then cooling to room temperature to obtain the ceramic tile. The high-strength sintered tile obtained by the preparation method is high in bending strength, high in thermal stability, low in water absorption and good in freezing resistance, and has a wide application prospect.

The invention provides a composite lithium manganese iron phosphate positive electrode material and a preparation method and application thereof, the preparation method comprises the following steps: (1) mixing a lithium source, an iron source, a manganese source, a phosphorus source, a fluxing agent, a dispersing agent and a solvent to obtain mixed slurry, spray-drying the mixed slurry, and calcining to obtain a lithium manganese iron phosphate intermediate; and (2) mixing the lithium iron manganese phosphate intermediate, a lithium source, a dispersing agent and a solvent to obtain mixed slurry, performing spray drying on the mixed slurry, and performing calcination treatment to obtain the composite lithium iron manganese phosphate positive electrode material. According to the method, the lithium iron manganese phosphate positive electrode material is prepared in a sectional manner, and the lithium iron manganese phosphate positive electrode material which is compact in structure, good in structural stability, high in grain strength, uniform in particle size distribution and high in compaction density can be prepared by adjusting the adding types of the materials and the adding amount of each section.

The invention relates to a preparation method of a nickel ion doped modified ferric sodium pyrophosphate positive electrode material, and belongs to the technical field of sodium ion battery positive electrode materials. The nickel ion doped modified ferric sodium pyrophosphate positive electrode material is prepared by adopting an integrated process system of liquid phase uniform mixing, spray granulation and precise segmented calcination. According to the process system, atomic-scale uniform doping of nickel ions and a specific microstructure of a precursor are realized through spray drying, and a plurality of inherent key technical problems of low electronic conductivity, low ion diffusion rate, impurity phase generation and the like of an NFPP material are solved together through a synergistic effect with a subsequent calcining process; furthermore, the discharge capacity of the ferric sodium phosphate pyrophosphate composite material at high rate is improved, so that the battery has relatively high cycling stability.

The invention belongs to the technical field of sodium ion batteries, and particularly relates to a sodium ferric pyrophosphate positive electrode material as well as a preparation method and application thereof. The invention provides a preparation method of a sodium ferric pyrophosphate positive electrode material, which comprises the following steps: (1) mixing an iron source, a sodium source, a phosphorus source and citric acid for the first time, and performing spray drying for the first time to prepare a first precursor with D50 of 10-12 [mu] m; performing secondary mixing on an iron source, a sodium source, a phosphorus source and citric acid, and performing secondary spray drying to prepare a second precursor with D50 of 3-5 microns; the iron source comprises a first iron source with D50 of 1.1-1.8 [mu] m and a second iron source with D50 of 0.3-0.8 [mu] m; the mass ratio of the first iron source to the second iron source is (0.3-0.5): (0.5-0.7); and (2) mixing the first precursor, the second precursor and sodium metaborate, and sintering to obtain the sodium ferric pyrophosphate positive electrode material. After the prepared pyrophosphate ferric phosphate sodium positive electrode material is prepared into a pole piece, the compaction density is proper, and the prepared battery is high in specific capacity and cycle performance.

The invention relates to the technical field of lithium ion batteries, in particular to a lithium-doped silicon-carbon composite material, a preparation method thereof, a negative plate and a lithium ion battery. The preparation method of the lithium-doped silicon-carbon composite material comprises the following steps: carrying out reduction reaction and activated pore-forming on a mixed material containing a carbon source, an organic pore-forming agent, a lithium supplement agent and a reducing agent to obtain lithium-doped porous carbon; performing first deposition on the lithium-doped porous carbon and mixed gas containing an inorganic lithium compound and an organic lithium compound; carrying out second deposition on the material obtained after the first deposition and silane gas to obtain a lithium compound doped silicon carbon precursor material; and mixing the lithium compound doped silicon carbon precursor material, an organic metal compound, asphalt and an organic solvent, performing spray drying, and then performing carbonization. According to the preparation method, the initial efficiency and the power performance of the silicon-carbon composite material can be improved.

The invention relates to the technical field of metal amino acid chelate preparation, and discloses high-bioavailability magnesium glycinate and a preparation method thereof.The method comprises the steps that a glycine solution and a magnesium salt solution are mixed, the initial pH value is adjusted to be within the alkaline range, and a low-polarity organic phase is added to construct a two-phase solvent system; dynamically adjusting the pH value of the reaction system by stages, and sequentially inducing amino and carboxyl of glycine to chelate magnesium ions step by step to form a chelate; and blending the chelated product with a chitosan-sodium alginate composite carrier, and carrying out spray drying to obtain magnesium glycinate particles. The molar ratio of magnesium ions to glycine in the chelating structure of magnesium glycinate is 1: 3. Through the synergistic effect of dynamic pH regulation and a two-phase solvent system, directional synthesis of the magnesium glycinate 1: 3 high-coordination chelate is achieved, the bioavailability and the targeted slow release performance are remarkably improved by combining a composite carrier nano embedding technology, and meanwhile, the process is efficient and environmentally friendly.

The preparation method comprises the following steps: 1, dispersing an iron source, a phosphorus source, a lithium source, a carbon source, a dispersing agent, an element doping agent and a solvent in proportion, dividing the dispersed slurry into three parts of slurry A, B and C in proportion, respectively grinding the three parts of slurry, and respectively carrying out spray drying; 2, pre-sintering the three parts of spray materials at different temperatures, and crushing the pre-sintered materials; and step 3, mixing the crushed pre-sintered materials so as to realize multi-stage grain composition. Carrying out dry mixing on a carbon source and the pre-crushed material according to a certain mass ratio; and 4, carrying out secondary sintering, crushing and demagnetizing on the mixed material to obtain the multi-stage grading high-compaction lithium iron phosphate positive electrode material. According to the invention, primary sintering material grain grading and secondary carbon coating and sintering strengthening are realized through graded particle size design, and the compaction density and the specific capacity of the lithium iron phosphate positive electrode material are synergistically improved.

Methods for preparing high entropy carbides (HECs), and powders thereof, are provided. One method includes spray-drying a base carbide feedstock and consolidating. Another method includes cold crucible induction of a base carbide feedstock. The HECs produced are of a quality suitable for use in industry. The methods are scalable in size, and suitable for use on an industrial scale. Also included are HEC feedstocks produced by the methods, and articles, such as coatings, produced from the HECs.

The invention discloses a preparation method and application of silymarin spray curing nano-carrier powder, and relates to the technical field of medicines and the field of foods. The method comprises the following steps: firstly, constructing a silymarin-carrier compound through a molecular self-assembly technology, and then, carrying out curing treatment on a nano-carrier by adopting a spray drying technology, so as to obtain nano-powder with good flowability. According to the preparation method disclosed by the invention, the silymarin spray curing nano-carrier powder with a core-shell structure is successfully prepared by optimizing a carrier material ratio and spray drying conditions. Experimental results show that the spray-cured nano-carrier powder prepared by the method significantly improves the solubility and stability of silymarin, and enhances the bioavailability and efficacy, so that silymarin can be more efficiently absorbed and released in a targeted manner in vivo, thereby significantly improving the therapeutic effect.

The invention discloses a plant-source nutritional supplement based on glycoside compounds and a preparation method thereof, and relates to the technical field of preparation of plant-source nutritional supplements.The preparation method comprises the steps that raw materials are prepared; the preparation method comprises the following steps: respectively carrying out ultrasonic-assisted extraction on flavonoid glycoside, saponin and geniposide raw materials to obtain an extracting solution; carrying out centrifugal separation on the extracting solution, taking supernate, and then purifying by adopting a macroporous resin adsorption method to obtain a purified glycoside compound solution; mixing the purified glycoside compound solution with lycium barbarum polysaccharide, Chinese yam starch, vitamin E and other auxiliaries in proportion, and uniformly stirring to form a mixed solution; carrying out spray drying on the mixed solution to obtain a powdery nutritional supplement; and screening the powdery nutritional supplement. The high-purity plant source glycoside compound and the functional auxiliary agent are scientifically compounded, and ultrasonic extraction, resin purification and precise process control are combined, so that the integrated improvement of activity synergy, quality stability and personalized scene adaptation of the nutritional supplement is realized.

The invention relates to the technical field of batteries, and discloses a high-compaction ferric sodium pyrophosphate positive electrode material and a preparation method thereof.The chemical formula of the positive electrode material is Na4Fe2.9VxTiyZrz (PO4) 2P2O7, 0.001 < = x < = 0.01, 0.002 < = y < = 0.01, and 0.001 < = z < = 0.01. The preparation method comprises the following steps that a sodium source, an iron source, a phosphorus source, a carbon source, a vanadium source, a titanium source and a zirconium source are weighed and mixed to be uniform, and a mixture is obtained; carrying out primary sanding treatment to obtain first sanding slurry, carrying out spray drying, and carrying out primary sintering treatment to obtain a pre-sintered material; adding a proper amount of carbon source into the pre-sintered material, and carrying out secondary sanding treatment to obtain a second ground material; and carrying out spray drying on the second grinding material, and carrying out secondary sintering treatment to obtain the positive electrode material. The high-compaction ferric sodium pyrophosphate positive electrode material provided by the invention has high compaction density and excellent rate capability and cycle performance, and can be used for preparing a sodium ion battery with high compaction density, high capacity and good rate capability and cycle performance.

The present invention includes a spray drying disposable device for use in a spray drying system. The disposable has a spray drying head and a plasma drying chamber. The head has a spray dry nozzle assembly in fluid communication with the plasma source and the pressurized aerosol gas source. The pressurized gas flows in a vortex pattern that atomizes plasma droplets in the chamber. The head also includes a plenum has uniform air pressure of the drying gas. A baffle plate forms the floor of the plenum having drying gas jets that supply drying gas to the chamber. The atomized plasma droplets evaporate in the presence of the drying gas emitted from the jets to obtain dried plasma particles and humid air. A capture filter captures the dried plasma particles and allows the humid air to pass. The humid air passes through the gas outlet and the exhaust port.

The invention relates to the technical field of building materials, and particularly discloses a slag and ardealite synergetic activated gypsum batten and a preparation method thereof.The slag and ardealite synergetic activated gypsum batten comprises pretreated ardealite, superfine slag powder, a composite exciting agent, reinforced fibers, self-repairing microcapsules, a foaming agent and water, and the composite exciting agent is formed by compounding nano SiO2, CaO and metakaolin; the preparation method comprises the following steps: mixing nano silica sol and a lignin solution, performing spray drying, and performing heat treatment to obtain the self-repairing microcapsule; the preparation method comprises the following steps: carrying out dry mixing on pretreated phosphogypsum, superfine slag powder and a composite exciting agent, adding water, adding reinforced fibers, self-repairing microcapsules and a foaming agent, stirring to form slurry, carrying out injection molding on the slurry, and carrying out stepped maintenance of pre-maintenance, main maintenance and carbonization treatment to prepare the modified red mud-pretreated phosphogypsum-based self-repairing self-repairing composite phosphogypsum-based self-repairing self-repairing composite phosphogypsum-based self-repairing composite phosphogypsum-based self-repairing composite phosphogypsum-based self-repairing composite phosphogypsum. The composite excitant synergistically activates the activity of the slag, and is matched with the reinforced fibers, the self-repairing microcapsules and stepped curing, so that solid waste resource utilization is realized, the compression resistance, bending resistance and impact resistance of the batten are improved, and the environment-friendly and high-performance effects are achieved.

The present invention includes a spray drying disposable device for use in a spray drying system. The disposable has a spray drying head and a plasma drying chamber. The head has a spray dry nozzle assembly in fluid communication with the plasma source and the pressurized aerosol gas source. The pressurized gas flows in a vortex pattern that atomizes plasma droplets in the chamber. The head also includes a plenum has uniform air pressure of the drying gas. A baffle plate forms the floor of the plenum having drying gas jets that supply drying gas to the chamber. The atomized plasma droplets evaporate in the presence of the drying gas emitted from the jets to obtain dried plasma particles and humid air. A capture filter captures the dried plasma particles and allows the humid air to pass. The humid air passes through the gas outlet and the exhaust port.

The invention relates to the technical field of sodium ion battery positive electrode materials, and discloses a preparation method and application of a carbon-coated sodium ferric sulfate positive electrode material, and the preparation method comprises the following steps: (1) adding an iron source into an aqueous solution containing an organic acid, and stirring, the organic acid being ascorbic acid and / or citric acid; adding a sodium source or the sodium source and a sulfuric acid source, and stirring; (2) finally adding a carbon source, dropwise adding absolute ethyl alcohol while stirring, vacuumizing after dropwise adding, and continuously stirring for 2-4 hours to obtain a mixed solution; and (3) carrying out closed spray drying on the mixed solution, and calcining in an inert atmosphere to obtain the carbon-coated sodium ferric sulfate positive electrode material. According to the preparation method, coating of the carbon material is achieved in a closed spray drying mode, the conductivity of sodium ferric sulfate is greatly improved, in the whole preparation process, contact with oxygen is avoided, organic acid with an anti-oxidation effect is avoided, ferrous iron is prevented from being oxidized, and then the electrochemical performance can be further improved.

A kind of preparation method of high compaction lithium iron phosphate of multistage gradation, including step one: iron source, phosphorus source, lithium source, carbon source, dispersing agent, element dopant and solvent are dispersed according to proportion, slurry after dispersion is divided into A, B, C three slurry according to proportion, three slurry are grinded respectively, and then are respectively carried out spray drying;Step two: three spray materials are respectively pre-sintered at different temperatures, and pre-sintered material is respectively crushed;Step three: the material after pre-sintering is mixed to realize multistage particle gradation.Certain mass ratio of carbon source and pre-crushed material are dry mixed;Step four: after secondary sintering, crushing and magnetic removal process, the multistage gradation high compaction lithium iron phosphate positive material is obtained.The present application realizes particle gradation of once sintered material, secondary carbon coating and sintering strengthening by grading particle size design, and realizes the collaborative improvement of compaction density and specific capacity of lithium iron phosphate positive material.

The present invention includes a spray drying disposable device for use in a spray drying system. The disposable has a spray drying head and a plasma drying chamber. The head has a spray dry nozzle assembly in fluid communication with the plasma source and the pressurized aerosol gas source. The pressurized gas flows in a vortex pattern that atomizes plasma droplets in the chamber. The head also includes a plenum has uniform air pressure of the drying gas. A baffle plate forms the floor of the plenum having drying gas jets that supply drying gas to the chamber. The atomized plasma droplets evaporate in the presence of the drying gas emitted from the jets to obtain dried plasma particles and humid air. A capture filter captures the dried plasma particles and allows the humid air to pass. The humid air passes through the gas outlet and the exhaust port.

The invention discloses a biodegradable polylactic acid composite material and a preparation method thereof, and relates to the technical field of polylactic acid materials. The method comprises the steps that firstly, chitosan activated through hydrochloric acid is subjected to graft modification through a KH550 silane coupling agent, meanwhile, nano-zinc oxide is subjected to surface modification through stearic acid, the chitosan and the nano-zinc oxide are mixed, spray drying is conducted, and antibacterial composite powder is prepared; the preparation method comprises the following steps: performing hydrochloric acid activation and KH570 silane coupling agent modification on nano silicon dioxide, performing hydroxypropylation modification on alkali lignin, and performing reflux crosslinking reaction on the modified alkali lignin, KH570 modified nano silicon dioxide, polycaprolactone, methyl methacrylate and azodiisobutyronitrile to prepare a heat-resistant reinforcer; uniformly mixing polylactic acid, poly (butylene succinate), the antibacterial composite powder, the heat-resistant reinforcer, tributyl citrate, polyethylene glycol and talcum powder, and extruding and granulating by using a twin-screw extruder to obtain the heat-resistant antibacterial material. The composite material prepared by the invention has excellent antibacterial property, heat resistance and biodegradability.

Stable and bioavailable formulations and dosage forms comprising a dispersion (e.g., spray-dried dispersion) of solid amorphous 6-(cyclopropancamido)-4-((2-methoxy-3-(1-methyl-1H-1,2,4-triazol-3-yl)phenyl)amino)-N-(methyl-d3)pyridazine-3-carboxamide (Formula (I): BMS-986165) in a solid polymer matrix are provided for the treatment of auto-immune and auto-inflammatory diseases such as an inflammatory bowel disease (IBD) and psoriasis.

The invention discloses a production process of a modified p-phenylenediamine rubber anti-aging agent, which comprises the following steps: S1, catalyzing a ring-closure reaction through lipase, and accurately controlling pH by combining a phosphate buffer solution, so that the bonding efficiency of 6PPD and tea polyphenol is remarkably improved, and the release amount of aniline is effectively reduced; s2, carrying out spray drying to obtain EP-TP powder to control the particle morphology; s3, increasing the load rate of the anti-aging agent and effectively inhibiting the migration rate of the anti-aging agent through the pore diameter physical confinement of mesoporous silica and an amination gas phase modification technology, and ensuring uniform dispersion of anti-aging agent particles through the synergistic effect of staged load reaction and a polyethylene glycol dispersant; and S4, the particle morphology is cooperatively controlled through vacuum microwave drying, the dispersion requirement of the rubber mixing technology is met, and the interface bonding strength is improved by combining the staged loading reaction with a polyethylene glycol dispersing agent.

The invention discloses a lithium iron phosphate positive electrode material and a preparation method thereof, and belongs to the technical field of lithium battery materials. Mixing and stirring the chelating dispersant, titanium dioxide and part of water for 2-3 hours, then adding the phosphorus source, the lithium source, the coated carbon source and the residual water, and continuously stirring for 0.5-1 hour to obtain mixed slurry; grinding the mixed slurry at 20-50 DEG C, and performing spray drying after grinding to obtain a lithium iron phosphate precursor; and heating the lithium iron phosphate precursor to 650-750 DEG C in 4-6 hours under the protection of nitrogen, roasting for 8-12 hours in the temperature range, and cooling and crushing to obtain the lithium iron phosphate positive electrode material. The lithium iron phosphate positive electrode material is prepared by the method; according to the method, the doped titanium forms linear order through chelating of the long-chain polymer, the doped titanium can be exposed on the surface of an iron-lithium atomic layer in the preparation process, and the electron conductivity is improved; and the long-chain structure of the polymer can promote the ordered arrangement of the iron-lithium atomic layer, so that the cycling stability and rate capability of the positive electrode material are further improved.

The invention belongs to the technical field of scattered metal recovery, and particularly relates to a recycling method of tungsten-rhenium alloy waste. The tungsten-rhenium alloy is a solid solution strengthened alloy which takes tungsten element as a matrix and consists of the tungsten element and rhenium element, and has the characteristics of high melting point, high strength and high hardness. As the price is high, it is very necessary to comprehensively utilize the tungsten-rhenium alloy waste. The invention discloses a recycling method of tungsten-rhenium alloy waste. Firstly, tungsten-rhenium alloy waste is cleaned, dried and smashed, and waste powder is formed; then dispersing the waste material powder into water dissolved with ammonium metatungstate and a surfactant; then, carrying out spray drying to form mixed powder; and finally, the mixed powder is subjected to roasting and hydrogen reduction, and tungsten-rhenium alloy powder with the metal rhenium content lower than the metal rhenium content in the tungsten-rhenium alloy waste is formed. Compared with an existing tungsten-rhenium alloy waste recycling method, the recycling method has the advantages of being simple in process, low in energy consumption, small in loss and good in uniformity.

The invention relates to a high-activity feather hydrolyzed amino acid water-soluble fertilizer and a preparation method thereof. The preparation method comprises the steps of pretreatment, complex enzyme stepped hydrolysis, nanofiltration separation, chelation and stabilization, spray drying and the like. Feather keratin is hydrolyzed step by step through a compound enzyme, small molecule peptide and amino acid are separated in combination with a nanofiltration membrane, trace elements are added for chelation, and a drying process is optimized, so that the activity and stability of the fertilizer are remarkably improved. The feather keratin can be efficiently degraded, the problem of amino acid racemization caused by a traditional strong acid / alkali method is solved, meanwhile, energy consumption is reduced, and the requirements of modern agriculture for environment-friendly and efficient fertilizer are met.