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Control of polymer surface molecular architecture via amphipathic endgroups

Polymers whose surfaces are modified by endgroups that include amphipathic surface-modifying moieties. An amphipathic endgroup of a polymer molecule is an endgroup that contains at least two moieties of significantly differing composition, such that the amphipathic endgroup spontaneously rearranges its positioning in a polymer body to position the moiety on the surface of the body, depending upon the composition of the medium with which the body is in contact, when that re-positioning causes a reduction in interfacial energy. An example of an amphipathic surface-modifying endgroup is one that has both a hydrophobic moiety and a hydrophilic moiety in a single endgroup. For instance, a hydrophilic poly(ethylene oxide) terminated with a hydrophilic hydroxyl group is not surface active in air when the surface-modifying endgroup is bonded to a more hydrophobic base polymer. If the hydroxyl group on the oligomeric poly(ethylene oxide) is replaced by a hydrophobic methoxy ether terminus, the poly(ethylene oxide) becomes surface active in air, and allows the poly(ethylene oxide) groups to crystallize in the air-facing surface. In this example, immersion in water destroys the crystallinity as the poly(ethylene oxide) sorbs water and the hydrophobic methoxy group retreats below the surface of the polymer. Also disclosed are methods and articles of manufacture that make use of these polymers.
Owner:THE POLYMER TECH GROUP

Transmitting station, receiving station, communications method, communications program, computer-readable storage medium containing the program

The current Draft IEEE 802.11e standard specifies two types of schemes for obtaining an acknowledgement from a receiving station: BlockAck and NormalAck. The current specifications allow temporary use of NormalAck while transmitting data frames in a BlockAck scheme. The specifications however does not explicitly describe the data frames that are allowed to be transmitted using NormalAck. Should these data frames follow the same rules as in BlockAck schemes, and if the transmitting station has dynamically switched between these two types of schemes, the receiving station can know only with extended delays that unreceived data frames are no longer valid. Therefore, the passing of subsequent, successfully received data frames from the receiving station to an upper layer may be significantly delayed, which is a problem. Another problem occurs if a BlockAck scheme timeout is determined in accordance with the rules in the current draft: the resource being used for BlockAck, which should be released, may not be released forever. The present invention addresses these problems by making suitable changes to the transmission sequence of data that is allowed to be transmitted by NormalAck while transmitting data by BlockAck and the determination process for a BlockAck scheme timeout.
Owner:SHARP KK
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