5489 results about "Solid-state battery" patented technology

A battery pack includes a battery housing; a battery module disposed in the battery housing, where the battery module includes multiple battery cells, and at least one of the battery cells is a solid-state battery; and a control circuit disposed in the battery housing and configured to use the battery module to supply the electric power to the power tool. The energy W of the battery pack and the volume V1 of the battery pack satisfy the following: when the energy W is greater than or equal to 200 Wh, the volume V1 is less than or equal to 400 cm3; or when the energy W is greater than or equal to 300 Wh, the volume V1 is less than or equal to 800 cm3; or when the energy W is greater than or equal to 700 Wh, the volume V1 is less than or equal to 2500 cm3.

The invention discloses a solid-state battery performance testing method and system based on data analysis, and relates to the field of battery performance testing, and the method comprises the steps: building a multi-physics field coupled digital twinborn model, collecting a strain signal and temperature field distribution of a failure region according to a three-dimensional physics field state map of the failure region, and when abnormally abruptly changed, carrying out the testing of the performance of a solid-state battery. Triggering multi-stage early warning, matching physical failure evidences with a historical database, extracting an optimal test parameter combination through a meta-learning framework, dynamically adjusting a charging and discharging strategy and monitoring frequency, generating a real-time data stream, and updating parameters of a multi-physics field coupled digital twin model through a back propagation algorithm. According to the method, the test parameters are dynamically optimized through the meta-learning framework, the performance of the solid-state battery is monitored and predicted, the safety and the reliability of the solid-state battery are improved, and a charging and discharging strategy is optimized to prolong the service life of the battery.

The present invention provides a composite binder for a sulfide solid-state battery, a preparation method thereof and an application thereof, wherein the composite binder comprises a binder A, a binder B and a solvent, wherein the mass ratio of the binder A to the binder B is (1-10):(5-1), and the mass ratio of the total mass of the binder A and the binder B to the solvent is 1:(10-100). The present invention adopts a binder having a polar functional group and a low-polarity / non-polar binder for combination, thereby making the prepared composite binder have good compatibility with the sulfide solid electrolyte, that is, it does not affect the ionic conductivity of the sulfide solid electrolysis, and at the same time makes the sulfide solid electrolyte membrane have good mechanical properties and flexibility.

The invention discloses a solid-state battery cell manufacturing method and device based on single-sided rubber frame forming, and relates to the technical field of solid-state battery manufacturing. The method comprises the following steps: manufacturing a rubber frame on one surface of a first pole piece positioned at a forming station; the second pole pieces and the first pole pieces with the rubber frames are sequentially and alternately conveyed to a lamination station, and the first pole pieces and the second pole pieces are sequentially and alternately laminated, so that the second pole pieces are embedded into the rubber frames of the first pole pieces; wherein the electrodes of the first pole piece and the second pole piece are opposite, and the thickness of the rubber frame is greater than or equal to that of the second pole piece. According to the invention, two times of rubber frame forming on one pole piece are not needed, so that the connectivity between the pole pieces is improved, and the conditions that the solid electrolyte layer and the pole pieces deviate relatively and the two adjacent pole pieces are short-circuited are avoided.

The invention relates to a high-voltage-resistant deep eutectic-based in-situ polymerization solid electrolyte as well as preparation and application thereof. The in-situ polymerization solid electrolyte is obtained through an in-situ polymerization reaction of a precursor solution comprising 30-80 wt% of a deep eutectic solution, 10-50 wt% of a polymerizable monomer, 1-30 wt% of an additive and 0.05-10 wt% of an initiator; the deep eutectic solution comprises a lithium salt and a hydrogen bond donor organic solvent; the hydrogen bond donor organic solvent comprises a nitrile solvent and a non-nitrile solvent; the polymerizable monomer comprises a monomer for free radical-initiated polymerization or ring-opening polymerization; the additive comprises lithium nitrate and fluoroethylene carbonate. The high-voltage-resistant in-situ polymerization solid electrolyte formed by in-situ compounding of an organic framework formed by in-situ polymerization of a deep eutectic solution, an additive and a monomer has the excellent characteristics of wide electrochemical window, high ionic conductivity, high mechanical strength, good flame retardance, wide-temperature applicability and the like, and can be suitable for a high-voltage system of 4.6 V or above; the solid-solid contact problem of a solid-state battery interface is effectively solved, and the side reaction between the electrolyte and the lithium metal negative electrode is reduced.

The invention provides an all-solid-state battery, a preparation method thereof and electric equipment. The all-solid-state battery comprises a positive plate, a negative plate and an electrolyte layer positioned between the positive plate and the negative plate, the positive plate comprises a positive current collector layer and a positive active material layer, one side of the positive active material layer is coated with an insulating layer at an interval, and the circumferential edge of the negative plate is in lap joint with the insulating layer. The all-solid-state battery can improve the insulation performance in the using process, and the effect of reducing the risk of short circuit is achieved.

The invention discloses a difunctional filler synergistically enhanced polymer solid electrolyte and a solid-state battery, and belongs to the field of solid-state batteries. The electrolyte adopts a polymer matrix, a lithium salt and two functional fillers: the first filler has a high dielectric constant, and can accelerate dissociation of the lithium salt, fix negative ions of the lithium salt and improve the transference number of lithium ions under the action of self polarization; and the second filler has high electrochemical window and ionic conductivity, can inhibit high-voltage decomposition, and is adaptive to a high-voltage positive electrode material. Through cooperation and balance design of the two kinds of filler, ion transmission, interface stability and high-pressure compatibility can be considered at the same time. In addition, the invention further designs a composite negative pole piece, the surface of the negative pole piece is coated with the solid electrolyte, and the ion transmission kinetics in the pole piece can be remarkably improved. On the basis, the invention develops a high-performance solid-state battery which is excellent in electrochemical performance and can play an important role in the fields of consumer electronics, electric automobiles, energy storage systems, low-altitude flight and the like.

The present invention relates to an all-solid-state battery (ASSB) comprising: an anode comprising a first solid electrolyte; a cathode composite comprising a second solid electrolyte, a solid electrolyte selected from the first and second solid electrolytes, and at least one buffer layer in contact with a surface of the solid electrolyte, where when the solid electrolyte is the first solid electrolyte, one buffer layer is at an interface of the electrolyte with the cathode, and when the solid electrolyte is the second solid electrolyte, one buffer layer is at least one of the first solid electrolyte and the second solid electrolyte. And when the solid electrolyte is a second solid electrolyte, a buffer layer is at the interface of the electrolyte and the anode, where the first electrolyte is selected from a sulfide solid electrolyte and a lithium oxide solid electrolyte, where the second electrolyte is a halide solid electrolyte, and where the buffer layer has a thickness of from 0.5 nm to less than 10 nm. The invention also relates to an anode assembly, a cathode assembly and an electrolyte assembly comprising at least one buffer layer. The invention also relates to a method for producing an ASSB or component according to the invention, in which the buffer layer is deposited by a vapor deposition-based method.

The invention discloses an all-solid-state battery cell as well as a preparation method and application thereof, and relates to the technical field of solid-state batteries. The cured insulation paste is attached to the edge of the positive electrode active layer, the size difference between the positive electrode active layer and the negative electrode active layer is supplemented through the cured insulation paste, the ends of the positive electrode active layer and the negative electrode active layer are flush, the insulation paste plays a supporting role under extrusion, and the problems of collapse, short circuit and the like caused by the size difference between the positive electrode active layer and the negative electrode active layer are avoided; the insulation paste at the edge can be bonded with the negative electrode under a high pressure condition, so that when the positive electrode is charged and discharged, the problem of poor cycle performance caused by volume change of the positive electrode plate in the charging and discharging process can be effectively relieved, and the cycle performance of the battery is improved; and the problems of material falling at the edge of the positive pole piece and the like can be effectively avoided. The electrolyte membrane is arranged between the positive active layer and the negative active layer, and the ionic liquid treatment layer on the electrolyte membrane is utilized, so that the impedance between the electrolyte membrane and the pole piece is reduced, and the battery performance is improved.

The invention relates to the technical field of solid-state batteries, in particular to a solid-state electrolyte composite membrane, a preparation method thereof and a solid-state battery. The preparation method comprises the following steps: performing ultrasonic-initiated cross-linking polymerization on a polymer solid electrolyte monomer, a cross-linking agent and a surface hydroxylated oxide solid electrolyte to obtain a polymer-oxide solid electrolyte matrix, washing the polymer-oxide solid electrolyte matrix, and soaking the polymer-oxide solid electrolyte matrix in an electrolyte to obtain the solid electrolyte composite membrane. According to the invention, crosslinking of the polymer electrolyte monomer is initiated by ultrasound, and chemical bonds are formed between part of the polymer electrolyte monomer and the surface-hydroxylated oxide solid electrolyte, so that the interfacial compatibility of the polymer electrolyte monomer and the surface-hydroxylated oxide solid electrolyte is effectively improved, and the ionic conductivity, chemical stability and mechanical strength of the polymer electrolyte are improved; due to the properties of easy processing, good flexibility and the like of the polymer electrolyte, the interface compatibility between the oxide solid electrolyte and the positive and negative pole pieces can be fully improved, the flexibility and the processability are improved, and a win-win effect is achieved.

The invention provides a self-repairing solid electrolyte membrane, a preparation method thereof, a solid-state battery and a mechanical device. The self-repairing solid electrolyte membrane comprises an organic framework and a polymer electrolyte, pores of the organic framework are filled with the polymer electrolyte, the polymer electrolyte is formed by polymerizing a polymeric monomer and a first lithium salt in the pores of the organic framework, the polymeric monomer contains a self-repairing S-S bond, and the first lithium salt contains a second lithium salt. The polymeric monomer also contains a C-O bond and a C = C bond. Therefore, the self-repairing solid-state electrolyte membrane has excellent mechanical properties and high ionic conductivity, and the solid-state battery prepared by adopting the self-repairing solid-state electrolyte membrane has high energy density, long cycle life and reliable safety.

The embodiment of the invention provides a synthesis method and application of lithium sulfide. The synthesis method of the lithium sulfide comprises the following steps: providing a sulfur source and a lithium source; performing first treatment on the sulfur source to obtain sulfur vapor; performing second treatment on the lithium source to obtain molten metal lithium; and in an inert atmosphere, introducing the sulfur vapor into the molten metal lithium, and reacting to generate lithium sulfide. According to the synthesis method and application of the lithium sulfide provided by the embodiment of the invention, the sulfur source is converted into the sulfur vapor, the lithium source is converted into the molten metal lithium, and the gas-liquid out-phase reaction is carried out in the inert atmosphere, so that the reaction efficiency and the purity are improved, the process is simplified, the cost is reduced, and the high-purity requirement can be met; the purity can be improved through raw material pretreatment of sulfur steam and molten metal lithium, and the strict requirement of a solid-state battery for high-purity lithium sulfide is met.

The invention relates to the technical field of batteries, in particular to a negative electrode, a preparation method thereof and a solid-state battery. The negative electrode comprises a composite current collector and a negative electrode protection layer, the composite current collector comprises a current collector substrate and a negative electrode material, the current collector substrate has a three-dimensional network structure, the negative electrode material is distributed in the three-dimensional network structure, and the negative electrode material comprises a lithium-loving carbon-based material and a lithium-loving metal material; the negative electrode protection layer is arranged on at least one side surface of the composite current collector, and the negative electrode protection layer comprises a solid electrolyte and a lithium-phobic carbon-based material. The solid-state battery comprises the negative electrode. The problem of dendritic crystal growth short circuit caused by non-uniform deposition of metal lithium can be relieved, the problem of volume expansion of a full-charge battery can be reduced, and the cycle stability of a solid-state battery can be improved.

The invention belongs to the technical field of solid-state battery materials, and discloses an inorganic solid-state electrolyte lanthanum lithium zirconate surface interface non-metallic element doped modified material using a plasma technology and a preparation method and application thereof, which can reduce the interface impedance of an electrolyte and improve the electrochemical performance of the electrolyte. By using the plasma technology, impurities such as lithium carbonate and the like on the surface of the inorganic solid electrolyte lanthanum lithium zirconate can be etched, a lithium-loving protective layer can be generated in situ on a surface interface, and the air stability of the electrolyte block is improved. According to the invention, multi-aspect modification can be realized by combining a plasma technology with a plurality of non-metallic element excitation sources, corresponding gain protection layers can be formed according to different requirements, and performance exertion of the battery in different fields is facilitated. When the inorganic solid electrolyte lanthanum lithium zirconate modified material obtained by the method disclosed by the invention is in contact with lithium metal to form a battery, the inorganic solid electrolyte lanthanum lithium zirconate modified material shows relatively low interface contact resistance and excellent cycling stability, and has a good application value.

The invention discloses an alkali metal ion oxychloride-based solid electrolyte material and a solid-state battery, and belongs to the technical field of solid electrolyte. The chemical general formula of the solid electrolyte material provided by the invention is A < 2-2x > Zr < 1-x > M < 2x > Cl < 6-6x > O < 3x >, wherein A is an alkali metal element Li or Na; m is metal or lanthanide elements of In, Bi, Sb, Ce and La; x is more than 0 and less than or equal to 0.3. The oxychloride-based solid electrolyte is prepared by the following preparation method: respectively weighing precursor ACl, ZrCl4 and M2O3 (A = Li and Na, and M = In, Bi, Sb, Ce and La) powder materials according to the stoichiometric ratio of a general formula, and carrying out one-step high-speed ball milling, so as to prepare target solid electrolyte powder; the method is applied to solid-state batteries. The alkali metal ion oxychloride-based solid electrolyte shows the advantages of high ionic conductivity, wide electrochemical window, air stability, good deformability and the like in a solid-state battery, and has the advantages of low cost, simple synthesis process, easiness in condition control and the like.

The invention relates to the technical field of solid-state batteries, in particular to oxyhalide solid-state electrolyte as well as a preparation method and application thereof. The method comprises the following steps: taking molten salt LiaMbXc as a raw material, reacting with an oxide AdOf in a molten state, removing steam impurities by utilizing a high-temperature vacuumizing mode, and cooling to prepare the oxyhalide solid electrolyte; according to the invention, the molten salt raw material is molten at high temperature to form the ion melt, and the oxygen element is introduced to replace part of halogen, so that the hardness of the target electrolyte is reduced after cooling, the deformability at room temperature is improved, and the obtained electrolyte is high in conductivity and wide in antioxidant electrochemical window. The prepared oxyhalide solid electrolyte is used for preparing a positive electrode, the adhesion force between the electrolyte and positive electrode material particles, the actual microscopic contact area and the ion migration rate are improved through melt permeation, the problem of a positive electrode interface is effectively relieved, and the electrochemical performance of an all-solid-state battery is improved.

The invention relates to a composite solid electrolyte membrane with high ceramic content and a preparation method and application thereof. The preparation method comprises the following steps: mixing ceramic solid electrolyte particles activated by a silane coupling agent with an in-situ polymerization solution containing a cross-linking agent, an organic monomer, a plasticizer, a lithium salt, an ultraviolet light initiator and a thermal initiator to form solid electrolyte slurry, wherein the ceramic solid electrolyte particles account for 60-90% of the total mass of the composite solid electrolyte membrane; the preparation method comprises the following steps: coating a positive pole piece with solid electrolyte slurry, initiating shallow organic matter monomers and a cross-linking agent to generate in-situ polymerization through an ultraviolet light initiator, covering a negative pole piece for hot pressing treatment, initiating residual organic matter monomers and the cross-linking agent to generate in-situ polymerization through a thermal initiator, and forming a composite electrolyte membrane with high ceramic content. The invention also discloses an all-solid-state battery containing the composite solid electrolyte membrane. The solid-state battery containing the in-situ formed composite solid-state electrolyte membrane has relatively high cycling stability.

The invention provides a wide-temperature-range chargeable and dischargeable semi-solid-state battery, a preparation method thereof and electric equipment, and relates to the technical field of new energy. According to the wide-temperature-range chargeable and dischargeable semi-solid-state battery provided by the invention, the solid-state electrolyte is added into the positive electrode material, and the diaphragm is coated with the solid-state electrolyte layer, so that atomic-scale contact between the solid-state electrolyte and the surfaces of electrode material particles is fully realized, and the thermal stability of the battery is greatly improved; meanwhile, the problem of slow reaction kinetics at low temperature is solved by using the nano solid electrolyte blended positive electrode material, and the low-temperature cycle performance of the battery is improved; the nanometer solid electrolyte coating diaphragm can solve the problem of poor electrolyte capacity diving, the electrolyte injection coefficient is effectively reduced, meanwhile, low internal resistance is achieved, and the long cycle stability of the battery is further improved; and a coating layer can be formed on the surface of the material by using the coating type binder, so that the side reaction between the electrode material and an electrolyte is effectively reduced, and the dissolution of transition metal Fe ions is remarkably inhibited.

The invention relates to the technical field of solid electrolyte, and discloses a double-layer solid electrolyte membrane, a preparation method thereof and an all-solid-state battery. The double-layer solid-state electrolyte membrane comprises a first solid-state electrolyte layer and a second solid-state electrolyte layer which are overlapped with each other, the first solid-state electrolyte layer comprises hydride solid-state electrolyte, and the second solid-state electrolyte layer comprises halide solid-state electrolyte; the hydride solid electrolyte comprises Li < 7-a > P (BH4) S < 6-a > and / or Li < 7-a-b > P (BH4) S < 6-a-b > X , a < = 2, 0lt; blt; 2. The interface between the double-layer solid-state electrolyte membrane and the positive electrode and the interface between the double-layer solid-state electrolyte membrane and the negative electrode have good interface stability, and the interface side reaction between the two solid-state electrolyte layers is less, so that the solid-state battery has high coulombic efficiency and cycling stability.

The invention discloses a preparation method and application of a sulfide solid electrolyte membrane based on a gradient polymer / ionic liquid composite binder, and an all-solid-state battery, and belongs to the technical field of all-solid-state batteries. The method comprises the following steps: firstly coating a polymer / ionic liquid / sulfide electrolyte composite layer through a gradient coating process, filling particle gaps under low pressure by utilizing the plasticizing effect of ionic liquid, and reducing the porosity of an interface; and then coating a polymer / sulfide electrolyte surface layer to provide mechanical support and inhibit side reaction of the electrode. According to the design, the electrolyte membrane still keeps high ionic conductivity under the working pressure of a commercial power battery module, and the interface impedance is reduced compared with that of a traditional homogeneous membrane. Through the innovative gradient structure and material combination, the ion transmission bottleneck of the sulfide electrolyte under the low-pressure condition is solved, excellent interface stability and process compatibility are achieved, and a key technical scheme is provided for all-solid-state battery industrialization.

The invention belongs to the technical field of solid-state electrolytes, and particularly discloses a modified PEO-based composite solid-state electrolyte, a preparation method thereof and a solid-state battery. The modified PEO-based composite solid electrolyte comprises the following components: lithium-doped indium gallium phosphate, PEO and a lithium-based electrolyte, wherein the chemical formula of the lithium-doped indium gallium phosphate is InxGa (1-x) PO4: Li, and x is more than or equal to 0.3 and less than or equal to 0.8. The indium gallium phosphate has an amorphous structure and shows excellent lithium ion transmission performance and conductivity; after lithium ions are further embedded into the indium gallium phosphate with the amorphous structure, the lithium ion conductivity of the indium gallium phosphate can be further improved, and more active sites are provided for transmission of the lithium ions; the lithium-doped indium gallium phosphate is added into the PEO-based solid electrolyte as an inorganic filler, so that the mechanical strength, the ion transmission capability and the conductivity of the PEO-based solid electrolyte can be effectively improved.

The invention provides a solid electrolyte slurry, an electrode slurry, a solid electrolyte sheet, an electrode sheet, a solid battery monomer, a battery device and a power utilization device.The solid electrolyte slurry comprises a sulfide solid electrolyte material, a solvent and a binder dissolved in the solvent, and the solvent is a non-polar solvent, a weak-polar solvent or a mixed solvent of the non-polar solvent and the weak-polar solvent; the binding agent comprises a polyacrylate binding agent and a non-polar polyolefin binding agent. The slurry disclosed by the invention has high dispersity, high suspension property and good cohesiveness, and can enable the solid-state battery monomer to have high initial coulombic efficiency when being used in the solid-state battery monomer.

The invention provides a sulfide electrolyte and a preparation method thereof, a solid-state battery and electronic equipment, the median particle size D50 and the specific surface area of the sulfide electrolyte are 10-5000 nm and 1-15 m < 2 > / g respectively, and the particle size distribution of the sulfide electrolyte meets the condition that (D90-D10) / D50 is greater than or equal to 0.9 and less than or equal to 2. The sulfide electrolyte provided by the invention is relatively small in particle size, relatively narrow in particle size distribution and relatively small in specific surface area, and the electrochemical performance of a solid-state battery can be effectively improved.

The invention provides a positive pole piece, a preparation method thereof and a sulfide all-solid-state battery. The positive pole piece comprises a positive current collector and a positive material layer arranged on the surface of the positive current collector, the positive electrode material layer comprises a modified positive electrode active material, an antioxidant, a sulfide electrolyte material, a conductive agent and a positive electrode binder, the modified positive electrode active material comprises an inner core and an oxide coating layer arranged on the surface of the inner core, and the inner core is a lithium-containing positive electrode active material. When the positive electrode plate containing the antioxidant and the modified positive electrode active material provided by the invention is applied to the sulfide all-solid-state battery, the synergistic effect of the antioxidant and the modified positive electrode active material can be exerted, so that the rate capability and the cycling stability of the sulfide all-solid-state battery are improved.

The disclosed subject matter relates to lithium ion conductors and batteries (such as pseudo solid state and all solid state batteries), and methods of making and use thereof. Disclosed herein are lithium ion conductors comprising Li1+xNb1−xZrxOX4, wherein X is a halide; and 0≤x≤1. Also disclosed herein are methods of making and use of any of the lithium ion conductors (e.g., Formula I) disclosed herein. Also disclosed herein are devices comprising any of the lithium ion conductors disclosed herein (e.g., Formula I), such as a solid state battery.

The invention relates to a tab-free battery cell, a preparation method thereof and a solid-state battery, the tab-free battery cell comprises a tab-free battery cell unit, and the tab-free battery cell unit comprises a tab-free battery cell assembly and a conductive buffer plate which are stacked; the tab-free battery cell assembly comprises a first current collector, a positive plate, an electrolyte plate, a negative plate and a second current collector which are stacked in sequence; the first current collector and the second current collector are lug-free current collectors; the conductive buffer sheet comprises a conductor and a buffer area; the buffer region comprises an insulating substance; the electric conductor comprises a built-in conductor and an external conductor; the external conductor at least partially extends out of the edge of the conductive buffer sheet; the conductor is of a sheet-shaped structure, and the buffer area surrounds the periphery of the built-in conductor; and / or the conductor is of a net structure, and the insulating substance is filled in at least part of pores of the net structure. The influence of edge shearing force on the tabs does not need to be considered in the battery cell pressing process, and the battery design is more flexible when the battery cell units without the tabs are stacked into the solid-state battery in the later period.

The invention relates to a full-temperature-range polymer-based solid electrolyte, a solid-state battery and a preparation method. Mixing alkali metal salt, a polymer monomer and a plasticizer to obtain an electrolyte precursor; the polymer monomer comprises a fluorinated acrylate compound; the plasticizer comprises a fluorinated carboxylic ester compound, a fluorinated carbonic ester compound or a fluorinated amide compound; and adding an initiator into the electrolyte precursor, heating and polymerizing to obtain the polymer-based solid electrolyte with the polar functional group forming the dipole group, namely the full-temperature-range polymer-based solid electrolyte. A polymer monomer with a soft long side chain is used, and plasticizer molecules are anchored between polymer chains, so that leakage of the plasticizer molecules and parasitic reaction between the plasticizer molecules and an electrode are reduced, and the interface stability of the electrolyte in a high-temperature environment is improved; a polar functional group in the solid electrolyte has relatively high electronegativity, and the formed dipole interacts with alkali metal ions, so that the ions are quickly decoupled from a polymer matrix, and the low-temperature conductivity is favorably improved.

The invention relates to a polymer-based composite solid electrolyte, a preparation method and a sodium solid-state battery, and belongs to the technical field of solid-state batteries. The polymer-based composite solid electrolyte is prepared from the following components in parts by mass: 8 to 12 parts of alkene polymer, 4 to 8 parts of sodium salt and 1 to 8 parts of filler, and the filler is nitrided nano TiO2. The polymer-based composite solid electrolyte can be prepared in a simple and efficient mode, the ionic conductivity is high, the electrochemical stability window is wide, the ionic conductivity reaches 0.3-1.2 mS / cm, and the electrochemical stability window reaches 4.3-5.5 V; and meanwhile, the formation of good SEI can be promoted in the sodium solid-state battery, and the interface stability between the electrolyte and the electrode is improved.

The invention relates to the technical field of solid-state electrolytes, and discloses a high-ionic-conductivity solid-state electrolyte, a preparation method thereof and a solid-state battery. The preparation method comprises the following steps: mixing lithium sulfide, lithium chloride, lithium oxide, phosphorus pentasulfide and boron nitride in an inert atmosphere to obtain a mixture; carrying out ball milling on the mixture to obtain precursor powder; and sintering the precursor powder, and dispersing the sintered precursor powder to obtain the high-ionic-conductivity solid electrolyte. The boron element, the nitrogen element and the oxygen element are introduced into a lithium phosphorus sulfur chlorine system as doping elements, lattice parameters of LPSC are changed through the boron element, the rotation rate of a PS4 / BS4 tetrahedron is enhanced, and a lithium ion diffusion channel is optimized, so that the lithium ion transition activation energy of the electrolyte is reduced, the migration rate of lithium ions is increased, and the performance of the electrolyte is improved. Therefore, the solid electrolyte has high ionic conductivity. The introduced nitrogen element and oxygen element can interact with atoms such as sulfur and phosphorus, the electron cloud distribution of anion groups is adjusted, the interaction energy of lithium ions and the anion groups is reduced, the lithium ion transmission performance is further improved, and the electrochemical stability of the anion framework is enhanced. This makes it possible to increase the energy density of an all-solid-state battery when used in a solid-state battery.

The invention belongs to the technical field of batteries, and discloses a pole piece and a preparation method thereof, a diaphragm-free battery and a solid-state battery. The pole piece comprises a current collector and an active substance layer, the active substance layer is arranged on at least one side of the current collector, the active substance layer comprises a mixed ion electron conductor material and an active substance, the mixed ion electron conductor material comprises an aggregate formed by reaction of a monomer, an initiator, a solid electrolyte and a conductive agent, a polymer formed by the monomer has cohesiveness and ion conductivity. According to the pole piece provided by the invention, the cycle performance, the safety performance and the rate capability of the battery can be improved.